Ammonium hexafluorovanadate

Last updated
Ammonium hexafluorovanadate
Names
IUPAC name
Vanadate(3-), hexafluoro-, ammonium (1:3), (OC-6-11)-
Other names
Ammonium hexafluorovanadate(III), triammonium vanadium hexafluoride, triammonium hexafluorovanadate(3-)
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/6FH.3 H3N.V/h6*1H;3*1 H3;/p-3
    Key: PURSFTZXXIKJST-UHFFFAOYSA-K
  • [F-].[F-].[F-].[F-].[F-] .[F-].[V].[NH4+].[NH 4+].[NH4+]
Properties
F6H12N3V
Molar mass 219.049 g·mol−1
AppearancePowder
Density g/cm3
Melting point 300
Hazards
GHS labelling:
GHS-pictogram-skull.svg
Danger
H301, H311, H319, H331
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium hexafluorovanadate is an inorganic chemical compound with the chemical formula (NH4)3VF6. [1] [2] [3]

Contents

Synthesis

The compound can be prepared by a fusion of ammonium hydrogen fluoride and vanadium trioxide. [4]

Physical properties

Ammonium hexafluorovanadate forms powder. It is toxic. [5]

Chemical properties

The compound decomposes to vanadium pentoxide if heated in open air: [6]

4(NH4)3VF6 + 11O2 → 2V2O5 + 6N2 + 12H2O + 24HF

Uses

Ammonium hexafluorovanadate is typically used as a catalyst at temperatures below 400 °C.

Related Research Articles

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Dysprosium(III) chloride</span> Chemical compound

Dysprosium(III) chloride (DyCl3), also known as dysprosium trichloride, is a compound of dysprosium and chlorine. It is a white to yellow solid which rapidly absorbs water on exposure to moist air to form a hexahydrate, DyCl3·6H2O. Simple rapid heating of the hydrate causes partial hydrolysis to an oxychloride, DyOCl.

<span class="mw-page-title-main">Ammonium hydrosulfide</span> Chemical compound

Ammonium hydrosulfide is the chemical compound with the formula [NH4]SH.

<span class="mw-page-title-main">Terbium(III,IV) oxide</span> Chemical compound

Terbium(III,IV) oxide, occasionally called tetraterbium heptaoxide, has the formula Tb4O7, though some texts refer to it as TbO1.75. There is some debate as to whether it is a discrete compound, or simply one phase in an interstitial oxide system. Tb4O7 is one of the main commercial terbium compounds, and the only such product containing at least some Tb(IV) (terbium in the +4 oxidation state), along with the more stable Tb(III). It is produced by heating the metal oxalate, and it is used in the preparation of other terbium compounds. Terbium forms three other major oxides: Tb2O3, TbO2, and Tb6O11.

<span class="mw-page-title-main">Erbium(III) chloride</span> Chemical compound

Erbium(III) chloride is a violet solid with the formula ErCl3. It is used in the preparation of erbium metal.

<span class="mw-page-title-main">Gadolinium(III) chloride</span> Chemical compound

Gadolinium(III) chloride, also known as gadolinium trichloride, is GdCl3. It is a colorless, hygroscopic, water-soluble solid. The hexahydrate GdCl3∙6H2O is commonly encountered and is sometimes also called gadolinium trichloride. Gd3+ species are of special interest because the ion has the maximum number of unpaired spins possible, at least for known elements. With seven valence electrons and seven available f-orbitals, all seven electrons are unpaired and symmetrically arranged around the metal. The high magnetism and high symmetry combine to make Gd3+ a useful component in NMR spectroscopy and MRI.

<span class="mw-page-title-main">Ammonium bifluoride</span> Chemical compound

Ammonium bifluoride is the inorganic compound with the formula [NH4][HF2] or [NH4]F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid.

<span class="mw-page-title-main">Yttrium(III) chloride</span> Chemical compound

Yttrium(III) chloride is an inorganic compound of yttrium and chloride. It exists in two forms, the hydrate (YCl3(H2O)6) and an anhydrous form (YCl3). Both are colourless salts that are highly soluble in water and deliquescent.

<span class="mw-page-title-main">Ytterbium(III) chloride</span> Chemical compound

Ytterbium(III) chloride (YbCl3) is an inorganic chemical compound. It reacts with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. It is poisonous if injected, and mildly toxic by ingestion. It is an experimental teratogen, known to irritate the skin and eyes.

<span class="mw-page-title-main">Vanadium(III) fluoride</span> Chemical compound

Vanadium(III) fluoride is the chemical compound with the formula VF3. This yellow-green, refractory solid is obtained in a two-step procedure from V2O3. Similar to other transition-metal fluorides (such as MnF2), it exhibits magnetic ordering at low temperatures (e.g. V2F6.4H2O orders below 12 K).

<span class="mw-page-title-main">Lanthanum(III) chloride</span> Chemical compound

Lanthanum chloride is the inorganic compound with the formula LaCl3. It is a common salt of lanthanum which is mainly used in research. It is a white solid that is highly soluble in water and alcohols.

<span class="mw-page-title-main">Ammonium tetrathiomolybdate</span> Chemical compound

Ammonium tetrathiomolybdate is the chemical compound with the formula (NH4)2MoS4. This bright red ammonium salt is an important reagent in the chemistry of molybdenum and has been used as a building block in bioinorganic chemistry. The thiometallate (see metallate) anion has the distinctive property of undergoing oxidation at the sulfur centers concomitant with reduction of the metal from Mo(VI) to Mo(IV).

<span class="mw-page-title-main">Ammonium iron(III) sulfate</span> Chemical compound

Ammonium iron(III) sulfate, NH4Fe(SO4)2·12 H2O, or NH4[Fe(H2O)6](SO4)2·6 H2O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO4)2 · 12 H2O. It has the appearance of weakly violet, octahedrical crystals. There has been some discussion regarding the origin of the crystals' color, with some ascribing it to impurities in the compound, and others claiming it to be a property of the crystal itself.

Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite.

<span class="mw-page-title-main">Sodium decavanadate</span> Chemical compound

Sodium decavanadate describes any member of the family of inorganic compounds with the formula Na6[V10O28](H2O)n. These are sodium salts of the orange-colored decavanadate anion [V10O28]6−. Numerous other decavanadate salts have been isolated and studied since 1956 when it was first characterized.

<span class="mw-page-title-main">Vanadium(II) sulfate</span> Chemical compound

Vanadium(II) sulfate describes a family of inorganic compounds with the formula VSO4(H2O)x where 0 ≤ x ≤ 7. The hexahydrate is most commonly encountered. It is a violet solid that dissolves in water to give air-sensitive solutions of the aquo complex. The salt is isomorphous with [Mg(H2O)6]SO4. Compared to the V–O bond length of 191 pm in [V(H2O)6]3+, the V–O distance is 212 pm in the [V(H2O)6]SO4. This nearly 10% elongation reflects the effect of the lower charge, hence weakened electrostatic attraction.

Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

Ammonium hexafluoroferrate is an inorganic chemical compound with the chemical formula (NH4)3FeF6.

Ammonium hexafluorochromate is an inorganic chemical compound with the chemical formula (NH4)3CrF6.

Ammonium hexachlorostannate, also known as pink salt) is an inorganic chemical compound with the chemical formula (NH4)2SnCl6.

References

  1. "Ammonium Hexafluorovanadate(III)". American Elements . Retrieved 23 August 2024.
  2. "AMMONIUM HEXAFLUOROVANADATE(III) 99.99%". chemicalbook.com. Retrieved 23 August 2024.
  3. Lewis (Sr.), Richard J.; Sweet, Doris V. (1986). Regulations, Recommendations, and Assessments Extracted from RTECS: A Subfile of the Registry of Toxic Effcts of Chemical Substances. U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health. p. 205. Retrieved 23 August 2024.
  4. Booth, Harold Simmons (1963). Inorganic Syntheses. London. p. 88. Retrieved 23 August 2024.{{cite book}}: CS1 maint: location missing publisher (link)
  5. "Ammonium hexafluorovanadate(III) (CAS 13815-31-1)". scbt.com . Retrieved 23 August 2024.
  6. Kleinberg, Jacob (22 September 2009). Inorganic Syntheses, Volume 7. John Wiley & Sons. p. 90. ISBN   978-0-470-13270-8 . Retrieved 23 August 2024.