Ammonium tetrathiovanadate

Last updated
Ammonium tetrathiovanadate
Names
Other names
Ammonium tetrathiovanadate(V)
Identifiers
Properties
H12N3S4V
Molar mass 233.30 g·mol−1
Appearanceviolet crystals
Density g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium tetrathiovanadate is a chemical compound with the chemical formula (NH4)3VS4. [1] [2]

Contents

Physical properties

Ammonium tetrathiovanadate forms violet crystals of orthorhombic symmetry. [3]

Chemical properties

Like other ammonium salts, ammonium tetrathiovanadate decomposes when heated: [4]

(NH4)3VS4 → 6NH3↑ + 3H2S↑ + V2S5
V2S5 → V2S3 + 2S

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References

  1. "CAS 14693-56-2 Ammonium tetrathiovanadate(v),99 - Alfa Chemistry". alfa-chemistry.com. Retrieved 24 December 2024.
  2. Scott, C. E.; Embaid, B. P.; Gonzalez-Jimenez, F.; Hubaut, R.; Grimblot, J. (1 March 1997). "Behavior of Iron–Vanadium Sulfide Catalysts for Hydrotreating Reactions". Journal of Catalysis . 166 (2): 333–339. doi:10.1006/jcat.1997.1526. ISSN   0021-9517 . Retrieved 24 December 2024.
  3. Donnay, Joseph Désiré Hubert (1973). Crystal Data: Inorganic compounds. National Bureau of Standards. p. 200. Retrieved 24 December 2024.
  4. Prasad, T. P.; Müller, A. (December 1976). "Thermal decompositions of (NH4)2WSe4 and (NH4)3VS4 under normal and reduced nitrogen pressures". Journal of Thermal Analysis and Calorimetry . 10 (3): 369–373. doi:10.1007/BF01909888 . Retrieved 24 December 2024.