Ammonium hexafluoroantimonate

Last updated
Ammonium hexafluoroantimonate
Ammonium hexafluoro-antimonate3D.png
Names
IUPAC name
azanium;hexafluoroantimony(1-)
Other names
Ammonium antimony fluoride
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/6FH.H3N.Sb/h6*1H;1H3;/q;;;;;;;+5/p-5
    Key: ZPHCPPBIGJXZTF-UHFFFAOYSA-I
  • [NH4+].F[Sb-](F)(F)(F)(F)F
Properties
F6H4NSb
Molar mass 253.789 g·mol−1
AppearanceWhite crystalline powder
Density g/cm3
soluble
Hazards
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-skull.svg
Danger
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium hexafluoroantimonate is an inorganic chemical compound with the chemical formula NH4SbF6. [1] [2]

Contents

Synthesis

Also, a reaction of antimony pentafluoride and ammonium hexafluoromanganate:

4SbF5 + 2(NH4)2MnF6 → NF4SbF6 + 2MnF3 + F2

Physical properties

It is soluble in water. It can form needle-shaped or columnar crystals.

Uses

The compound is used in fine chemistry and organic synthesis, for example as a catalyst, and can replace organic fluorides. [3]

Related Research Articles

<span class="mw-page-title-main">Nitronium ion</span> Polyatomic ion

The nitronium ion, [NO2]+, is a cation. It is an onium ion because its nitrogen atom has +1 charge, similar to ammonium ion [NH4]+. It is created by the removal of an electron from the paramagnetic nitrogen dioxide molecule NO2, or the protonation of nitric acid HNO3.

In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon.

<span class="mw-page-title-main">Quaternary ammonium cation</span> Polyatomic ions of the form N(–R)₄ (charge +1)

In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR4]+, where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion and the primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium salts or quaternary ammonium compounds are salts of quaternary ammonium cations. Polyquats are a variety of engineered polymer forms which provide multiple quat molecules within a larger molecule.

<span class="mw-page-title-main">Diazonium compound</span> Group of organonitrogen compounds

Diazonium compounds or diazonium salts are a group of organic compounds sharing a common functional group [R−N+≡N]X where R can be any organic group, such as an alkyl or an aryl, and X is an inorganic or organic anion, such as a halide. The parent compound where R is hydrogen, is diazenylium.

An inorganic nonaqueous solvent is a solvent other than water, that is not an organic compound. These solvents are used in chemical research and industry for reactions that cannot occur in aqueous solutions or require a special environment. Inorganic nonaqueous solvents can be classified into two groups, protic solvents and aprotic solvents. Early studies on inorganic nonaqueous solvents evaluated ammonia, hydrogen fluoride, sulfuric acid, as well as more specialized solvents, hydrazine, and selenium oxychloride.

The Balz–Schiemann reaction is a chemical reaction in which a primary aromatic amine is transformed to an aryl fluoride via a diazonium tetrafluoroborate intermediate. This reaction is a traditional route to fluorobenzene and some related derivatives, including 4-fluorobenzoic acid.

<span class="mw-page-title-main">Hexafluorophosphate</span> Anion with the chemical formula PF6–

Hexafluorophosphate is an anion with chemical formula of [PF6]. It is an octahedral species that imparts no color to its salts. [PF6] is isoelectronic with sulfur hexafluoride, SF6, and the hexafluorosilicate dianion, [SiF6]2−, and hexafluoroantimonate [SbF6]. In this anion, phosphorus has a valence of 5. Being poorly nucleophilic, hexafluorophosphate is classified as a non-coordinating anion.

<span class="mw-page-title-main">Silver hexafluorophosphate</span> Chemical compound

Silver hexafluorophosphate, sometimes referred to "silver PF-6," is an inorganic compound with the chemical formula AgPF6.

Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH4)2SiF6. It is a toxic chemical, like all salts of fluorosilicic acid. It is made of white crystals, which have at least three polymorphs and appears in nature as rare minerals cryptohalite or bararite.

Nitrogen pentafluoride is a theoretical compound of nitrogen and fluorine with the chemical formula NF5. It is hypothesized to exist based on the existence of the pentafluorides of the atoms below nitrogen in the periodic table, such as phosphorus pentafluoride. Theoretical models of the nitrogen pentafluoride molecule are either a trigonal bipyramidal covalently bound molecule with symmetry group D3h, or [NF4]+F, which would be an ionic solid.

Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II). Many salts of nickel(II) are isomorphous with salts of magnesium due to the ionic radii of the cations being almost the same. Nickel forms many coordination complexes. Nickel tetracarbonyl was the first pure metal carbonyl produced, and is unusual in its volatility. Metalloproteins containing nickel are found in biological systems.

<span class="mw-page-title-main">Hexafluoroarsenate</span> Chemical compound

The hexafluoroarsenate anion is a chemical species with formula AsF−6. Hexafluoroarsenate is relatively inert, being the conjugate base of the notional superacid hexafluoroarsenic acid.

<span class="mw-page-title-main">Pentazenium tetraazidoborate</span> Chemical compound

Pentazenium tetraazidoborate is an extremely unstable chemical compound with the formula N5[B(N3)4]. It is a white solid that violently explodes at room temperature. This compound has a 95.7% nitrogen content which is the second highest known of a chemical compound, exceeding even that of ammonium azide (93.3%) and 1-diazidocarbamoyl-5-azidotetrazole (89.1%), being surpassed only by hydrazoic acid (97.7%).

Sodium hexafluoroantimonate is an inorganic chemical compound with the chemical formula NaSbF6.

<span class="mw-page-title-main">Potassium hexafluoroantimonate</span> Chemical compound

Potassium hexafluoroantimonate is an inorganic chemical compound with the chemical formula KSbF6.

<span class="mw-page-title-main">Lithium hexafluoroantimonate</span> Chemical compound

Lithium hexafluoroantimonate is an inorganic chemical compound with the chemical formula LiSbF6.

Ammonium hexafluoroferrate is an inorganic chemical compound with the chemical formula (NH4)3FeF6.

Ammonium hexafluoroindate is an inorganic chemical compound with the chemical formula (NH4)3InF6.

Ammonium hexafluoroniobate is an inorganic chemical compound with the chemical formula NH4NbF6.

<span class="mw-page-title-main">Ammonium hexafluorogallate</span> Chemical compound

Ammonium hexafluorogallate is an inorganic chemical compound with the chemical formula (NH4)3GaF6.

References

  1. "CAS 52503-06-7 Ammonium hexafluoroantimonate - Alfa Chemistry". alfa-chemistry.com. Retrieved 31 August 2024.
  2. Ma, Hailing; Zhang, Xin; Ju, Feifei; Tsai, Sang-Bing (14 February 2018). "A Study on Curing Kinetics of Nano-Phase Modified Epoxy Resin". Scientific Reports . 8 (1): 3045. Bibcode:2018NatSR...8.3045M. doi:10.1038/s41598-018-21208-0. ISSN   2045-2322. PMC   5813017 . PMID   29445228 . Retrieved 1 September 2024.
  3. Organometallic Compounds. R. H. Chandler. 1976. p. 180. Retrieved 31 August 2024.