Ammonium chromate

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Ammonium chromate
Chroman amonny.JPG
Names
Other names
Ammonium chromate(IV)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.217 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-138-4
PubChem CID
UNII
UN number 3085,3077
  • InChI=1S/Cr.2H3N.4O/h;2*1H3;;;;/q;;;;;2*-1/p+2
    Key: MFFLHUNPSHBKRG-UHFFFAOYSA-P
  • [NH4+].[NH4+].[O-][Cr](=O)(=O)[O-]
Properties
(NH4)2CrO4
Molar mass 152.07 g/mol
Appearanceyellow crystals
Density 1.90 g/ml
Melting point 185 °C (365 °F; 458 K)decomposes [1]
24.8 g/100ml (0 °C)
37.36 g/100ml (25 °C) [1]
45.3 g/100ml (40 °C)
70.06 g/100ml (75 °C) [1] [2]
Thermochemistry
657 J/K·mol
-1163 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Toxic
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-acid.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg [3]
Danger
H272, H314, H317, H334, H350, H400 [3]
P201, P220, P261, P273, P280, P305+P351+P338 [3]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Ammonium chromate is a salt with the formula (NH4)2CrO4. It forms yellow, monoclinic crystals; made from ammonium hydroxide and ammonium dichromate; used in photography as a sensitizer for gelatin coatings. It is often used in photography, textile printing, and fixing chromate dyes on wool. It is also used as an analytical reagent, catalyst, and corrosion inhibitor. It is soluble in water, and, when applied, can cause irritation in the mucous membrane, eyes, respiratory tract, skin, etc. It may cause skin sensitization after prolonged contact. It is also known to be carcinogenic (cancer-causing), and it can cause tissue ulceration and injury to the liver and kidneys. [4]

See also

Related Research Articles

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Chromate and dichromate Chromium(VI) anions

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4
. Dichromate salts contain the dichromate anion, Cr
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O2−
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. They are oxyanions of chromium in the 6+ oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible.

Potassium dichromate Chemical compound

Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in the laboratory because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.

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2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

Potassium chromate Chemical compound

Potassium chromate is the inorganic compound with the formula (K2CrO4). This yellow solid is the potassium salt of the chromate anion. It is a common laboratory chemical, whereas sodium chromate is important industrially.

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Caesium chromate Chemical compound

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Zinc chromate Chemical compound

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Ammonium dichromate Chemical compound

Ammonium dichromate is an inorganic compound with the formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting of ammonium ions and dichromate ions.

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Potassium chlorochromate Chemical compound

Potassium chlorochromate is an inorganic compound with the formula KCrO3Cl. It is the potassium salt of chlorochromate, [CrO3Cl]. It is a water-soluble orange compound is used occasionally for oxidation of organic compounds. It is sometimes called Péligot's salt, in recognition of its discoverer Eugène-Melchior Péligot.

Sodium chromate Chemical compound

Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.

References

  1. 1 2 3 Perry, Dale L. (2011). Handbook of Inorganic Compounds, Second Edition. Boca Raton, Florida: CRC Press. ISBN   978-1-43981462-8 . Retrieved 2014-04-28.
  2. "Ammonium chromate".
  3. 1 2 3 Sigma-Aldrich Co., Ammonium chromate. Retrieved on 28-04-2014.
  4. Information preview for Ammonium chromate, GIDEON