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Names | |
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Other names Ammonium chromate(IV) | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.029.217 ![]() |
EC Number |
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PubChem CID | |
UNII | |
UN number | 3085,3077 |
CompTox Dashboard (EPA) | |
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Properties | |
(NH4)2CrO4 | |
Molar mass | 152.07 g/mol |
Appearance | yellow crystals |
Density | 1.90 g/ml |
Melting point | 185 °C (365 °F; 458 K)decomposes [1] |
24.8 g/100ml (0 °C) 37.36 g/100ml (25 °C) [1] 45.3 g/100ml (40 °C) 70.06 g/100ml (75 °C) [1] [2] | |
Thermochemistry | |
Std molar entropy (S | 657 J/K·mol |
Std enthalpy of formation (ΔfH⦵298) | -1163 kJ/mol |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | Toxic |
GHS labelling: | |
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Danger | |
H272, H314, H317, H334, H350, H400 [3] | |
P201, P220, P261, P273, P280, P305+P351+P338 [3] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Ammonium chromate is a salt with the formula (NH4)2CrO4. It forms yellow, monoclinic crystals; made from ammonium hydroxide and ammonium dichromate; used in photography as a sensitizer for gelatin coatings. It is often used in photography, textile printing, and fixing chromate dyes on wool. It is also used as an analytical reagent, catalyst, and corrosion inhibitor. It is soluble in water, and, when applied, can cause irritation in the mucous membrane, eyes, respiratory tract, skin, etc. It may cause skin sensitization after prolonged contact. It is also known to be carcinogenic (cancer-causing), and it can cause tissue ulceration and injury to the liver and kidneys. [4]
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.
In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions.
An oxidizing agent, also known as an oxidant or oxidizer, is a substance that has the ability to oxidize other substances — in other words to accept their electrons. Common oxidizing agents are oxygen, hydrogen peroxide and the halogens.
Cyanotype is a photographic printing process that produces a cyan-blue print. Engineers used the process well into the 20th century as a simple and low-cost process to produce copies of drawings, referred to as blueprints. The process uses two chemicals: ferric ammonium citrate and potassium ferricyanide.
Chromate salts contain the chromate anion, CrO2−
4. Dichromate salts contain the dichromate anion, Cr
2O2−
7. They are oxyanions of chromium in the 6+ oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible.
Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in the laboratory because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.
Sun printing may refer to various printing techniques which use sunlight as a developing or fixative agent.
Chromium(III) oxide is an inorganic compound with the formula Cr
2O
3. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.
Potassium chromate is the inorganic compound with the formula (K2CrO4). This yellow solid is the potassium salt of the chromate anion. It is a common laboratory chemical, whereas sodium chromate is important industrially.
Gum printing is a way of making photographic reproductions without the use of silver halides. The process uses salts of dichromate in common with a number of other related processes such as sun printing.
A solubility chart is a chart with a list of ions and how, when mixed with other ions, they can become precipitates or remain aqueous.
Chromate conversion coating or alodine coating is a type of conversion coating used to passivate steel, aluminium, zinc, cadmium, copper, silver, titanium, magnesium, and tin alloys. The coating serves as a corrosion inhibitor, as a primer to improve the adherence of paints and adhesives, as a decorative finish, or to preserve electrical conductivity. It also provides some resistance to abrasion and light chemical attack on soft metals.
Chromyl chloride is the inorganic compound with the formula CrO2Cl2. It is a reddish brown compound that is a volatile liquid at room temperature, which is unusual for transition metal complexes.
Caesium chromate or cesium chromate is an inorganic compound with the formula Cs2CrO4. It is a yellow crystalline solid that is the caesium salt of chromic acid, and it crystallises in the orthorhombic system.
Zinc chromate, ZnCrO4, is a chemical compound containing the chromate anion, appearing as odorless yellow powder or yellow-green crystals, but, when used for coatings, pigments are often added. It is used industrially in chromate conversion coatings, having been developed by the Ford Motor Company in the 1920s.
Ammonium dichromate is an inorganic compound with the formula (NH4)2Cr2O7. In this compound, as in all chromates and dichromates, chromium is in a +6 oxidation state, commonly known as hexavalent chromium. It is a salt consisting of ammonium ions and dichromate ions.
A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.
Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric.
Potassium chlorochromate is an inorganic compound with the formula KCrO3Cl. It is the potassium salt of chlorochromate, [CrO3Cl]−. It is a water-soluble orange compound is used occasionally for oxidation of organic compounds. It is sometimes called Péligot's salt, in recognition of its discoverer Eugène-Melchior Péligot.
Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.