Ammonium malate

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Ammonium malate
Names
IUPAC name
Diammonium malate
Other names
Ammonium hydroxybutanedioate; E349
Identifiers
ChemSpider
ECHA InfoCard 100.025.909 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 228-499-2
E number E349 (antioxidants, ...)
PubChem CID
UNII
Properties
C4H9NO5
Molar mass 151.118 g·mol−1
Appearancewhite solid
Density 1.498 g/cm3 (monohydrate)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Ammonium malate refers to organic compounds containing malate and ammonium. Two stoichiometries are discussed: NH4H(C2H3OH(CO2)2) with one ammonium ion per formula unit, and (NH4)2(C2H3OH(CO2)2). Malate, the conjugate base of malic acid, is chiral. Consequently a variety of salts are possible, R vs S vs racemic. The monoammonium salt has been crystallized as the monohydrate. [1]

As a food additive, diammonium malate has been used as flavoring agent and as an acidity regulator. [2] It has the E number E349. [2]

Related Research Articles

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An acid is a molecule or ion capable of either donating a proton (i.e. hydrogen ion, H+), known as a Brønsted–Lowry acid, or forming a covalent bond with an electron pair, known as a Lewis acid.

In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions.

Urea, also called carbamide, is an organic compound with chemical formula CO(NH2)2. This amide has two amino groups joined by a carbonyl functional group. It is thus the simplest amide of carbamic acid.

<span class="mw-page-title-main">Ammonium</span> Polyatomic ion (NH₄, charge +1)

The ammonium cation is a positively charged polyatomic ion with the chemical formula NH+4 or [NH4]+. It is formed by the protonation of ammonia. Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations, where one or more hydrogen atoms are replaced by organic or other groups.

<span class="mw-page-title-main">Tartaric acid</span> Organic acid found in many fruits

Tartaric acid is a white, crystalline organic acid that occurs naturally in many fruits, most notably in grapes, but also in bananas, tamarinds, and citrus. Its salt, potassium bitartrate, commonly known as cream of tartar, develops naturally in the process of fermentation. It is commonly mixed with sodium bicarbonate and is sold as baking powder used as a leavening agent in food preparation. The acid itself is added to foods as an antioxidant E334 and to impart its distinctive sour taste. Naturally occurring tartaric acid is a useful raw material in organic chemical synthesis. Tartaric acid, an alpha-hydroxy-carboxylic acid, is diprotic and aldaric in acid characteristics, and is a dihydroxyl derivative of succinic acid.

<span class="mw-page-title-main">Sodium nitrate</span> Chemical compound

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3
. This alkali metal nitrate salt is also known as Chile saltpeter to distinguish it from ordinary saltpeter, potassium nitrate. The mineral form is also known as nitratine, nitratite or soda niter.

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Ammonium bicarbonate is an inorganic compound with formula (NH4)HCO3. The compound has many names, reflecting its long history. Chemically speaking, it is the bicarbonate salt of the ammonium ion. It is a colourless solid that degrades readily to carbon dioxide, water and ammonia.

Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with composition [NH+
4
][OH
]
, it is actually impossible to isolate samples of NH4OH. The ions NH+
4
and OH do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions.

<span class="mw-page-title-main">Carbamate</span> Chemical group (>N–C(=O)–O–)

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Nitrogen assimilation is the formation of organic nitrogen compounds like amino acids from inorganic nitrogen compounds present in the environment. Organisms like plants, fungi and certain bacteria that can fix nitrogen gas (N2) depend on the ability to assimilate nitrate or ammonia for their needs. Other organisms, like animals, depend entirely on organic nitrogen from their food.

<span class="mw-page-title-main">Ceric ammonium nitrate</span> Chemical compound

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<span class="mw-page-title-main">Ammonium sulfate</span> Chemical compound

Ammonium sulfate (American English and international scientific usage; ammonium sulphate in British English); (NH4)2SO4, is an inorganic salt with a number of commercial uses. The most common use is as a soil fertilizer. It contains 21% nitrogen and 24% sulfur.

<span class="mw-page-title-main">Cyanuric acid</span> Chemical compound belonging to the class of triazine

Cyanuric acid or 1,3,5-triazine-2,4,6-triol is a chemical compound with the formula (CNOH)3. Like many industrially useful chemicals, this triazine has many synonyms. This white, odorless solid finds use as a precursor or a component of bleaches, disinfectants, and herbicides. In 1997, worldwide production was 160 000 tonnes.

<span class="mw-page-title-main">Ammonium acetate</span> Chemical compound

Ammonium acetate, also known as spirit of Mindererus in aqueous solution, is a chemical compound with the formula NH4CH3CO2. It is a white, hygroscopic solid and can be derived from the reaction of ammonia and acetic acid. It is available commercially.

The Kjeldahl method or Kjeldahl digestion (Danish pronunciation: [ˈkʰelˌtɛˀl]) in analytical chemistry is a method for the quantitative determination of nitrogen contained in organic substances plus the nitrogen contained in the inorganic compounds ammonia and ammonium (NH3/NH4+). Without modification, other forms of inorganic nitrogen, for instance nitrate, are not included in this measurement. Using an empirical relation between Kjeldahl nitrogen content and protein content it is an important method for analyzing proteins. This method was developed by Johan Kjeldahl in 1883.

<span class="mw-page-title-main">Ammonium ferric citrate</span> Chemical compound

Ammonium ferric citrate (also known as ferric ammonium citrate or ammoniacal ferrous citrate) has the formula (NH4)5[Fe(C6H4O7)2]. A distinguishing feature of this compound is that it is very soluble in water, in contrast to ferric citrate which is not very soluble.

<span class="mw-page-title-main">1-Phenylethylamine</span> Chemical compound

1-Phenylethylamine is the organic compound with the formula C6H5CH(NH2)CH3. This primary amine is a colorless liquid is often used in chiral resolutions. Like benzylamine, it is relatively basic and forms stable ammonium salts and imines.

<span class="mw-page-title-main">Ammonium iron(III) sulfate</span> Chemical compound

Ammonium iron(III) sulfate, NH4Fe(SO4)2·12 H2O, or NH4[Fe(H2O)6](SO4)2·6 H2O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO4)2 · 12 H2O. It has the appearance of weakly violet, octahedrical crystals. There has been some discussion regarding the origin of the crystals' colour, with some ascribing it to impurities in the compound, and others claiming it to be a property of the crystal itself.

<span class="mw-page-title-main">Ammonium carbamate</span> Chemical compound

Ammonium carbamate is a chemical compound with the formula [NH4][H2NCO2] consisting of ammonium cation NH+4 and carbamate anion NH2COO. It is a white solid that is extremely soluble in water, less so in alcohol. Ammonium carbamate can be formed by the reaction of ammonia NH3 with carbon dioxide CO2, and will slowly decompose to those gases at ordinary temperatures and pressures. It is an intermediate in the industrial synthesis of urea (NH2)2CO, an important fertilizer.

References

  1. Anandha Babu, G.; Bhagavannarayana, G.; Ramasamy, P. (2008). "Synthesis, crystal growth, structural, optical, thermal and mechanical properties of novel organic NLO material: Ammonium malate". Journal of Crystal Growth. 310 (6): 1228–1238. Bibcode:2008JCrGr.310.1228A. doi:10.1016/j.jcrysgro.2007.12.024.
  2. 1 2 "Class Names and the International Numbering System for Food Additive" (PDF). Food and Agriculture Organization of the United Nations.