Ammonium hexafluoroplatinate

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Ammonium hexafluoroplatinate
Ammonium hexafluoroplatinate.png
Names
Other names
Ammonium hexafluoroplatinate(IV)
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/6FH.2H3N.Pt/h6*1H;2*1H3;/q;;;;;;;;+4/p-4
    Key: XJAQQYJSKDIYFW-UHFFFAOYSA-J
  • [NH4+].[NH4+].F[Pt-2](F)(F)(F)(F)F
Properties
F6H8N2Pt
Molar mass 345.152 g·mol−1
Appearancepale yellow crystals
Density g/cm3
reacts with water
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Ammonium hexafluoroplatinate is an inorganic chemical compound with the chemical formula (NH4)2PtF6. [1]

Contents

Synthesis

A reaction of lanthanum(III) hexafluoroplatinate and ammonium hydroxide: [2]

La2[PtF6]3 + 6NH4OH → 3(NH4)2PtF6 + 2La(OH)3

Physical properties

Ammonium hexafluoroplatinate forms pale yellow crystals of cubic system, space group Fm3m. [3] [4]

Chemical properties

Ammonium hexafluoroplatinate hydrolyses, foming the insoluble platinum(IV) hydroxide:

(NH4)2PtF6 + 4H2O → Pt(OH)4 + 4HF + 2NH4F

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6
is strong enough to oxidise O
2
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References

  1. Fawcett, J.; Holloway, J.H.; Puddick, D.C.; Russell, D.R. (1921). "Ammonium Hexafluoroplatinate(IV)". Acta Crystallogr. (B36). Retrieved 2 September 2024.
  2. Simons, J. H. (2 December 2012). Fluorine Chemistry V5. Elsevier. p. 98. ISBN   978-0-323-14724-8 . Retrieved 2 September 2024.
  3. Physics Briefs: Physikalische Berichte. Physik Verlag. 1980. p. 6626. Retrieved 2 September 2024.
  4. Fawcett, J.; Holloway, J. H.; Puddick, D. C.; Russell, D. R. (15 August 1980). "Ammonium hexafluoroplatinate(IV)". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry . 36 (8): 1921–1922. Bibcode:1980AcCrB..36.1921F. doi:10.1107/S0567740880007479. ISSN   0567-7408 . Retrieved 2 September 2024.