Iron(III) chromate

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Iron(III) chromate [1]
Names
IUPAC name
iron(III) chromate
Identifiers
3D model (JSmol)
ECHA InfoCard 100.030.588 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/3Cr.2Fe.12O/q;;;2*+3;;;;;;;6*-1
    Key: OXLBLZDGMWMXSM-UHFFFAOYSA-N
  • [O-][Cr](=O)(=O)[O-].[O-][Cr](=O)(=O)[O-].[O-][Cr](=O)(=O)[O-].[Fe+3].[Fe+3]
Properties
Fe2(CrO4)3
Molar mass 459.6808 g/mol
Appearanceyellow powder
reacts, see also solubility chart
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
highly toxic (contain Cr(VI))
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Iron(III) chromate is the iron(III) salt of chromic acid with the chemical formula Fe2(CrO4)3.

Contents

Discovery

Iron(III) chromate was discovered by Samuel Hibbert-Ware in 1817 while visiting Shetland. [2]

Production

It may be formed by the reaction of potassium chromate and iron(III) nitrate. This reaction forms iron(III) chromate and potassium nitrate. It also can be formed by the oxidation by air of iron and chromium oxides in a basic environment:

4 Fe2O3 + 6 Cr2O3 + 9 O2 → 4 Fe2(CrO4)3

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Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal.

Oxidizing agent Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens.

Chromate and dichromate Chromium(VI) anions

Chromate salts contain the chromate anion, CrO2−
4
. Dichromate salts contain the dichromate anion, Cr
2
O2−
7
. They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible.

Potassium ferrate Chemical compound

Potassium ferrate is the chemical compound with the formula K2FeO4. This purple salt is paramagnetic, and is a rare example of an iron(VI) compound. In most of its compounds, iron has the oxidation state +2 or +3 (Fe2+ or Fe3+). Reflecting its high oxidation state, FeO2−4 is a powerful oxidizing agent.

Chromium(III) oxide Chemical compound

Chromium(III) oxide is an inorganic compound with the formula Cr
2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

Copper chromite Chemical compound

Copper chromite is an inorganic compound with the formula Cu2Cr2O5. It is a black solid that is used to catalyze reactions in organic synthesis.

Ferrate(VI) Ion

Ferrate(VI) is the inorganic anion with the chemical formula [FeO4]2−. It is photosensitive, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a weak base, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high pH.

In chemical nomenclature, the IUPAC nomenclature of inorganic chemistry is a systematic method of naming inorganic chemical compounds, as recommended by the International Union of Pure and Applied Chemistry (IUPAC). It is published in Nomenclature of Inorganic Chemistry. Ideally, every inorganic compound should have a name from which an unambiguous formula can be determined. There is also an IUPAC nomenclature of organic chemistry.

Chromate conversion coating Chemical treatment of metals

Chromate conversion coating or alodine coating is a type of conversion coating used to passivate steel, aluminium, zinc, cadmium, copper, silver, titanium, magnesium, and tin alloys. The coating serves as a corrosion inhibitor, as a primer to improve the adherence of paints and adhesives, as a decorative finish, or to preserve electrical conductivity. It also provides some resistance to abrasion and light chemical attack on soft metals.

Silver chromate Chemical compound

Silver chromate is an inorganic compound with formula Ag2CrO4 which appears as distinctively coloured brown-red crystals. The compound is insoluble and its precipitation is indicative of the reaction between soluble chromate and silver precursor salts (commonly potassium/sodium chromate with silver nitrate). This reaction is important for two uses in the laboratory: in analytical chemistry it constitutes the basis for the Mohr method of argentometry, whereas in neuroscience it is used in the Golgi method of staining neurons for microscopy.

A pyrotechnic composition is a substance or mixture of substances designed to produce an effect by heat, light, sound, gas/smoke or a combination of these, as a result of non-detonative self-sustaining exothermic chemical reactions. Pyrotechnic substances do not rely on oxygen from external sources to sustain the reaction.

Sodium chromate Chemical compound

Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.

Chromite (compound)

In chemistry the term chromite has been used in two contexts. Under IUPAC naming conventions, chromate(III) is preferred to chromite.

  1. For compounds containing an oxyanion of chromium in oxidation state 3
  2. For other compounds of chromium(III) as a means of distinguishing a chemical species such as hexacyanochromite(III). [Cr(CN)6]3− from an analogous compound in which chromium is a different oxidation state.
Jones oxidation

The Jones oxidation is an organic reaction for the oxidation of primary and secondary alcohols to carboxylic acids and ketones, respectively. It is named after its discoverer, Sir Ewart Jones. The reaction was an early method for the oxidation of alcohols. Its use has subsided because milder, more selective reagents have been developed, e.g. Collins reagent.

Potassium hypochromate Chemical compound

Potassium hypochromate is a chemical compound with the formula K3CrO4 with the unusual Cr5+ ion. This compound is unstable in water but stable in alkaline solution and was found to have a similar crystal structure to potassium hypomanganate.

Transition metal nitrate complex Compound of nitrate ligands

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the preparation of other compounds.

Europium(III) chromate is an chemical compound composed of europium, chromium and oxygen with europium in the +3 oxidation state, chromium in the +5 oxidation state and oxygen in the -2 oxidation state. It has the chemical formula of EuCrO4.

References

  1. Lide, David R. (1998). Handbook of Chemistry and Physics (87 ed.). Boca Raton, Florida: CRC Press. pp. 4–63. ISBN   0-8493-0594-2.
  2. "Search - Archives Hub".