Iron(II) chromite

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Iron(II) chromite
Names
IUPAC name
Iron(2+) chromite
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.782 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-159-3
PubChem CID
RTECS number
  • GB4000000
UNII
  • InChI=1S/2Cr.Fe.4O/q;;+2;;;2*-1
    Key: VUIWSEWFMMYPHW-UHFFFAOYSA-N
  • O=[Cr][O-].O=[Cr][O-].[Fe+2]
Properties
FeCr2O4
Molar mass 223.83 g/mol
AppearanceBrown-black solid
Density 4.97 g/cm3
Melting point 2,190 to 2,270 °C (3,970 to 4,120 °F; 2,460 to 2,540 K)
insoluble
Solubility Slightly soluble in acid
2.16
Structure
cubic
Hazards
GHS labelling:
GHS-pictogram-pollu.svg
H317
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Iron(II) chromite is an inorganic compound with the chemical formula FeCr2O4.

Contents

Preparation

It is created by the sintering of chromium(III) oxide and iron(II) oxide at 1600 °C. It also occurs in nature as the mineral chromite, though with many impurities.

Uses

Chromite, a
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FeCr2O4 containing mineral ChromiteUSGOV.jpg
Chromite, a FeCr2O4 containing mineral

It is used as a commercial source of chromium and its compounds. [1] It is also used as a catalyst in the synthesis of hydrogen (H2) from the reaction between carbon monoxide and water vapor.

Safety

Its dust particles may cause irritation; inhalation and ingestion of its dust should be avoided. Swallowing larger amounts may cause injury.

Related Research Articles

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<span class="mw-page-title-main">Group 6 element</span> Group of chemical elements

Group 6, numbered by IUPAC style, is a group of elements in the periodic table. Its members are chromium (Cr), molybdenum (Mo), tungsten (W), and seaborgium (Sg). These are all transition metals and chromium, molybdenum and tungsten are refractory metals.

<span class="mw-page-title-main">Ferric</span> The element iron in its +3 oxidation state

In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe2+. The word ferric is derived from the Latin word ferrum, meaning "iron".

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<span class="mw-page-title-main">Chromate and dichromate</span> Chromium(VI) anions

Chromate salts contain the chromate anion, CrO2−
4
. Dichromate salts contain the dichromate anion, Cr
2
O2−
7
. They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible.

<span class="mw-page-title-main">Chromite</span> Crystalline mineral

Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (MgCr2O4). Substitution of the element aluminium can also occur, leading to hercynite (FeAl2O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (FeCr), which is an iron-chromium alloy.

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In materials science, a refractory is a material that is resistant to decomposition by heat or chemical attack and that retains its strength and rigidity at high temperatures. They are inorganic, non-metallic compounds that may be porous or non-porous, and their crystallinity varies widely: they may be crystalline, polycrystalline, amorphous, or composite. They are typically composed of oxides, carbides or nitrides of the following elements: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium. Many refractories are ceramics, but some such as graphite are not, and some ceramics such as clay pottery are not considered refractory. Refractories are distinguished from the refractory metals, which are elemental metals and their alloys that have high melting temperatures.

<span class="mw-page-title-main">Potassium dichromate</span> Chemical compound

Potassium dichromate, K2Cr2O7, is a common inorganic chemical reagent, most commonly used as an oxidizing agent in various laboratory and industrial applications. As with all hexavalent chromium compounds, it is acutely and chronically harmful to health. It is a crystalline ionic solid with a very bright, red-orange color. The salt is popular in laboratories because it is not deliquescent, in contrast to the more industrially relevant salt sodium dichromate.

<span class="mw-page-title-main">Chromium(III) oxide</span> Chemical compound

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2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

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Copper chromite often refers to inorganic compounds with the formula Cu2Cr2Ox. They are black solids. Cu2Cr2O4 is a well-defined material. The other copper chromite often is described as Cu2Cr2O5. It is used to catalyze reactions in organic chemistry.

<span class="mw-page-title-main">Chromium(IV) oxide</span> Chemical compound

Chromium dioxide or chromium(IV) oxide is an inorganic compound with the formula CrO2. It is a black synthetic magnetic solid. It once was widely used in magnetic tape emulsion. With the increase in popularity of CDs and DVDs and more recently digital media, the use of chromium(IV) oxide has declined. However, it is still used in data tape applications for enterprise-class storage systems. It is still considered by many oxide and tape manufacturers to have been one of the best magnetic recording particulates ever invented.

Non-metallic inclusions are chemical compounds and nonmetals that are present in steel and other alloys. They are the product of chemical reactions, physical effects, and contamination that occurs during the melting and pouring process. These inclusions are categorized by origin as either endogenous or exogenous. Endogenous inclusions, also known as indigenous, occur within the metal and are the result of chemical reactions. These products precipitate during cooling and are typically very small. Exogenous inclusions are caused by the entrapment of nonmetals. Their size varies greatly and their source can include slag, dross, flux residues, and pieces of the mold.

<span class="mw-page-title-main">Chromium compounds</span> Chemical compounds containing chromium

Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals. The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist.

<span class="mw-page-title-main">Chromium(III) sulfate</span> Chemical compound

Chromium(III) sulfate usually refers to the inorganic compounds with the formula Cr2(SO4)3.x(H2O), where x can range from 0 to 18. Additionally, ill-defined but commercially important "basic chromium sulfates" are known. These salts are usually either violet or green solids that are soluble in water. It is commonly used in tanning leather.

<span class="mw-page-title-main">Sodium chromate</span> Chemical compound

Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores.

<span class="mw-page-title-main">Glass coloring and color marking</span> Production methods of colored glass

Glass coloring and color marking may be obtained in several ways.

  1. by the addition of coloring ions,
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    Ancient Roman enamelled glass, 1st century, Treasure of Begram
  3. by colored inclusions
  4. by light scattering
  5. by dichroic coatings, or
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<span class="mw-page-title-main">Chromite (compound)</span>

In chemistry the term chromite has been used in two contexts. Under IUPAC naming conventions, chromate(III) is preferred to chromite.

  1. For compounds containing an oxyanion of chromium in oxidation state of +3
  2. For other compounds of chromium(III) as a means of distinguishing a chemical species such as hexacyanochromite(III). [Cr(CN)6]3− from an analogous compound in which chromium is a different oxidation state.
<span class="mw-page-title-main">Chromium cycle</span> Biogeochemical cycle

The chromium cycle is the biogeochemical cycle of chromium through the atmosphere, hydrosphere, biosphere and lithosphere.

Europium(III) chromate is a chemical compound composed of europium, chromium and oxygen with europium in the +3 oxidation state, chromium in the +5 oxidation state and oxygen in the −2 oxidation state. It has the chemical formula of EuCrO4.

References