Xenon hexafluororhodate

Last updated
Xenon hexafluororhodate
Xenon-hexafluororhodate-3D-vdW.png
Identifiers
  • none
3D model (JSmol)
  • InChI=1S/FXe.5FH.Rh/c1-2;;;;;;/h;5*1H;/q+1;;;;;;+4/p-5
    Key: NFSSTTHKJSXWRM-UHFFFAOYSA-I
  • F[Xe+].F[Rh-1](F)(F)(F)F
Properties
XeRhF6
Molar mass 348.1855 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Xenon hexafluororhodate (XeRhF6) is a deep-red noble gas compound first synthesised in 1963 by Neil Bartlett. [1] [2] [3] It is analogous to xenon hexafluoroplatinate. [1]

Synthesis

Xenon hexafluororhodate is produced by the direct combination of xenon and rhodium hexafluoride: [3]

Xe + RhF6 → XeRhF6

References

  1. 1 2 Bartlett, Neil (1963). "New Compounds of Noble Gases: The Fluorides of Xenon and Radon". American Scientist . 51 (1): 114–118. JSTOR   27838621.
  2. ↑ "Rare Gas Studies Lead to XeF". Chemical & Engineering News . 41 (5): 36–39. 1963. doi:10.1021/cen-v041n005.p036.
  3. 1 2 Pauling, Linus (1970). General Chemistry (3rd ed.). San Francisco: Dover. p. 250.
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