Xenon dichloride

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Xenon dichloride
Xenon dichloride.png
Names
IUPAC name
Dichloroxenon
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/Cl2Xe/c1-3-2
    Key: ZDICFBIJLKDJAQ-UHFFFAOYSA-N
  • Cl[Xe]Cl
Properties
XeCl2
Molar mass 202.199 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Xenon dichloride (XeCl2) is a xenon compound and the only known stable chloride of xenon. The compound can be prepared by using microwave discharges towards the mixture of xenon and chlorine, and it can be isolated from a condensate trap. One experiment[ which? ] tried to use xenon, chlorine and boron trichloride to produce XeCl2·BCl3, but only generated xenon dichloride. [1]

However, it is still doubtful whether xenon dichloride is a true compound or a Van der Waals molecule composed of a xenon atom and a chlorine molecule connected by a secondary bond. [2]

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2
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2
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Xenon tetrachloride is an unstable inorganic compound with the chemical formula XeCl4. Unlike other noble gas/halide compounds, it cannot be synthesized by simply combining the elements, by using a more-active halogenating agent, or by substitution of other halides on tetrahaloxenon compounds. Instead, a decay technique can be used, starting with K129ICl4. The iodine-129 atom of the 129
ICl
4
covalent cluster is radioactive and undergoes beta decay to become xenon-129. The resulting XeCl4 molecule has a square planar molecular geometry analogous to xenon tetrafluoride.

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References

  1. 张青莲 [Zhang Qingliang] (November 1991). 稀有气体、氢、碱金属[Noble Gases, Hydrogen, and the Alkali Metals]. 无机化学丛书 [Inorganic Chemistry] (in Simplified Chinese). Vol. 1. Beijing: Science Press. p. 72. ISBN   7-03-002238-6.
  2. Proserpio, Davide M.; Hoffmann, Roald; Janda, Kenneth C. (1991). "The xenon-chlorine conundrum: van der Waals complex or linear molecule?". Journal of the American Chemical Society. 113 (19): 7184. doi:10.1021/ja00019a014.