Lutetium(III) bromide

Last updated
Lutetium(III) bromide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.034.935 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 238-446-5
PubChem CID
  • InChI=1S/3BrH.Lu/h3*1H;/q;;;+3/p-3
    Key: DWHGOINJUKABSY-UHFFFAOYSA-K
  • [Lu+3].[Br-].[Br-].[Br-]
Properties
LuBr3
Molar mass 414.68 [1]
AppearanceWhite Powder
Density 1.025 [2]
Melting point 1,400 °C (2,550 °F; 1,670 K) [2]
Will dissolve [2]
Structure
Rhombohedric FeCl3 like [3]
Thermochemistry
66.9 J/mol K [3]
48.8 kJ/mol [3]
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H315, H319, H335 [1]
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501 [4]
NFPA 704 (fire diamond)
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lutetium(III) bromide is a crystalline compound made of one lutetium atom and three bromine atoms. [2] It takes the form of a white powder at room temperature. [1] It is hygroscopic. [2] It is odorless. [5]

Contents

Properties

Reactions

Lutetium(III) bromide can be synthesized through the following reaction: [6]

2 Lu(s) + 3 Br2(g) → 2 LuBr3(s)

If burned, lutetium(III) bromide may produce hydrogen bromide and metal oxide fumes. [5]

Lutetium(III) bromide reacts to strong oxidizing agents. [5]

Solubility

An experiment by T. Mioduski showed that the solubility of LuBr3 in tetrahydrofuran at 21-23 °C was 0.30 g per 100 ml of solution. [7]

Related Research Articles

Bromine Chemical element, symbol Br and atomic number 35

Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest halogen and is a volatile red-brown liquid at room temperature that evaporates readily to form a similarly coloured vapour. Its properties are intermediate between those of chlorine and iodine. Isolated independently by two chemists, Carl Jacob Löwig and Antoine Jérôme Balard, its name was derived from the Ancient Greek βρῶμος, referring to its sharp and pungent smell.

Halogen Group of chemical elements

The halogens are a group in the periodic table consisting of five or six chemically related elements: fluorine (F), chlorine (Cl), bromine (Br), iodine (I), and astatine (At). The artificially created element 117, tennessine (Ts), may also be a halogen. In the modern IUPAC nomenclature, this group is known as group 17.

Lutetium Chemical element, symbol Lu and atomic number 71

Lutetium is a chemical element with the symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earths. Lutetium is generally considered the first element of the 6th-period transition metals by those who study the matter, although there has been some dispute on this point.

Lawrencium Chemical element, symbol Lr and atomic number 103

Lawrencium is a synthetic chemical element with the symbol Lr and atomic number 103. It is named in honor of Ernest Lawrence, inventor of the cyclotron, a device that was used to discover many artificial radioactive elements. A radioactive metal, lawrencium is the eleventh transuranic element and the last member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles. Fourteen isotopes of lawrencium are currently known; the most stable is 266Lr with half-life 11 hours, but the shorter-lived 260Lr is most commonly used in chemistry because it can be produced on a larger scale.

Ytterbium Chemical element, symbol Yb and atomic number 70

Ytterbium is a chemical element with the symbol Yb and atomic number 70. It is the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. However, like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density and melting and boiling points differ significantly from those of most other lanthanides.

Group 3 element Group of chemical elements

Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. Although some controversy exists regarding the composition and placement of this group, it is generally agreed among those who study the matter that this group contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.

Lutetium(III) oxide Chemical compound

Lutetium(III) oxide, a white solid, is a cubic compound of lutetium sometimes used in the preparation of specialty glasses. It is also called lutecia. It is a lanthanide oxide, also known as a rare earth.

Gold(III) bromide Chemical compound

Gold(III) bromide is a dark-red to black crystalline solid. It has the empirical formula AuBr3, but exists primarily as a dimer with the molecular formula Au2Br6 in which two gold atoms are bridged by two bromine atoms. It is commonly referred to as gold(III) bromide, gold tribromide, and rarely but traditionally auric bromide, and sometimes as digold hexabromide. As is similar with the other gold halides, this compound is unique for being a coordination complex of a group 11 transition metal that is stable in an oxidation state of +3 whereas copper or silver complexes persist in oxidation states of +1 or +2.

Tin(II) bromide is a chemical compound of tin and bromine with a chemical formula of SnBr2. Tin is in the +2 oxidation state. The stability of tin compounds in this oxidation state is attributed to the inert pair effect.

Indium(III) bromide Chemical compound

Indium(III) bromide, (indium tribromide), InBr3, is a chemical compound of indium and bromine. It is a Lewis acid and has been used in organic synthesis.

There are three sets of gallium halides, the trihalides where gallium has oxidation state +3, the intermediate halides containing gallium in oxidation states +1, +2 and +3 and some unstable monohalides, where gallium has oxidation state +1.

Cobalt(II) bromide Chemical compound

Cobalt(II) bromide (CoBr2) is an inorganic compound. In its anhydrous form, it is a green solid that is soluble in water, used primarily as a catalyst in some processes.

Praseodymium(III) bromide is a crystalline compound of one praseodymium atom and three bromine atoms.

Neodymium(III) bromide Chemical compound

Neodymium(III) bromide is an inorganic salt of bromine and neodymium the formula NdBr3. The anhydrous compound is an off-white to pale green solid at room temperature, with an orthorhombic PuBr3-type crystal structure. The material is hydroscopic and forms a hexahydrate in water (NdBr3· 6H2O), similar to the related neodymium(III) chloride.

Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature. The compound has a crystal structure isotypic to that of plutonium(III) bromide.

Europium(II) bromide Chemical compound

Europium(II) bromide is a crystalline compound of one europium atom and two bromine atoms. Europium(II) bromide is a white powder at room temperature, and odorless. Europium dibromide is hygroscopic.

Europium(III) bromide is a crystalline compound, a salt, made of one europium and three bromine atoms. Europium tribromide is a grey powder at room temperature. It is odorless. Europium tribromide is hygroscopic.

Holmium(III) bromide is a crystalline compound made of one holmium atom and three bromine atoms. Holmium bromide is a yellow powder at room temperature. Holmium bromide is hygroscopic. Holmium bromide is odorless.

Thulium(III) bromide is a crystalline compound of one thulium atom and three bromine atoms. The salt is a white powder at room temperature. It is hygroscopic.

Lutetium(III) iodide Chemical compound

Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.

References

  1. 1 2 3 Elements, American. "Lutetium Bromide". American Elements. Retrieved 22 December 2016.
  2. 1 2 3 4 5 Phillips, Sidney L.; Perry, Dale L. (1995). Handbook of inorganic compounds. Boca Raton: CRC Press. p. 232. ISBN   9780849386718.
  3. 1 2 3 L., Rycerz; M., Gaune-Escard (2008). "Lanthanide(III) halides: Thermodynamic properties and their correlation with crystal structure". Journal of Alloys and Compounds. 450 (1–2): 167–174. doi:10.1016/j.jallcom.2006.12.096 . Retrieved 22 December 2016.
  4. "Lutetium bromide | Br3Lu - PubChem". pubchem.ncbi.nlm.nih.gov. Retrieved 22 December 2016.
  5. 1 2 3 "Lutetian bromide" (PDF). SDS. Retrieved 22 December 2016.
  6. Winter, Mark. "Lutetium»reactions of elements [WebElements Periodic Table]". www.webelements.com. Retrieved 22 December 2016.
  7. "Lutetium Bromide" (PDF). Srdata. Retrieved 22 December 2016.