Lutetium(III) telluride

Last updated
Lutetium(III) telluride
2.svg Lu3+.svg 3.svg Telluride ion.png
Identifiers
3D model (JSmol)
ECHA InfoCard 100.032.087 OOjs UI icon edit-ltr-progressive.svg
  • InChI=1S/2Tm.3Te/q2*+3;3*-2
    Key: HEPKJXBBYRJGCC-UHFFFAOYSA-N
  • [Lu+3].[Lu+3].[Te-2].[Te-2].[Te-2]
Properties
Lu2Te3
Molar mass 732.73 g·mol−1
Density 7.8 g/cm3 [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lutetium(III) telluride is an inorganic compound, one of the tellurides of lutetium, with the chemical formula Lu2Te3. It has the structure Sc2S3 and space group Fddd. [2] It can be obtained by arc melting with lutetium metal, and Lu7Te, Lu11Te4 or LuTe could also be obtained. [3] [4]

It is listed on the Toxic Substances Control Act of 1976. [5]

Related Research Articles

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Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, the usual oxidation state is +3, although some compounds are known with oxidation state +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

<span class="mw-page-title-main">Lutetium</span> Chemical element, symbol Lu and atomic number 71

Lutetium is a chemical element; it has symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals.

<span class="mw-page-title-main">Tellurium</span> Chemical element, symbol Te and atomic number 52

Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

<span class="mw-page-title-main">Group (periodic table)</span> Column of elements in the periodic table of the chemical elements

In chemistry, a group is a column of elements in the periodic table of the chemical elements. There are 18 numbered groups in the periodic table; the 14 f-block columns, between groups 2 and 3, are not numbered. The elements in a group have similar physical or chemical characteristics of the outermost electron shells of their atoms, because most chemical properties are dominated by the orbital location of the outermost electron.

<span class="mw-page-title-main">Group 3 element</span> Group of chemical elements

Group 3 is the first group of transition metals in the periodic table. This group is closely related to the rare-earth elements. It contains the four elements scandium (Sc), yttrium (Y), lutetium (Lu), and lawrencium (Lr). The group is also called the scandium group or scandium family after its lightest member.

<span class="mw-page-title-main">Lead(II) sulfide</span> Chemical compound

Lead(II) sulfide is an inorganic compound with the formula PbS. Galena is the principal ore and the most important compound of lead. It is a semiconducting material with niche uses.

<span class="mw-page-title-main">Copper(I) iodide</span> Chemical compound

Copper(I) iodide is the inorganic compound with the formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

<span class="mw-page-title-main">Lutetium(III) chloride</span> Chemical compound

Lutetium(III) chloride or lutetium trichloride is the chemical compound composed of lutetium and chlorine with the formula LuCl3. It forms hygroscopic white monoclinic crystals and also a hygroscopic hexahydrate LuCl3·6H2O. Anhydrous lutetium(III) chloride has the YCl3 (AlCl3) layer structure with octahedral lutetium ions.

The telluride bromides are chemical compounds that contain both telluride ions (Te2−) and bromide ions (Br). They are in the class of mixed anion compounds or chalcogenide halides.

The telluride oxides or oxytellurides are double salts that contain both telluride and oxide anions. They are in the class of mixed anion compounds.

The telluride iodides are chemical compounds that contain both telluride ions (Te2−) and iodide ions (I). They are in the class of mixed anion compounds or chalcogenide halides.

A selenite fluoride is a chemical compound or salt that contains fluoride and selenite anions. These are mixed anion compounds. Some have third anions, including nitrate, molybdate, oxalate, selenate, silicate and tellurate.

The borotellurates are heteropoly anion compounds which have tellurate groups attached to boron atoms. The ratio of tellurate to borate reflects the degree of condensation. In [TeO4(BO3)2]8- the anions are linked into a chain. In [TeO2(BO3)4]10− the structure is zero dimensional with isolated anions. These arrangements of oxygen around boron and tellurium can have forms resembling silicates. The first borotellurates to be discovered were the mixed sodium rare earth compounds in 2015.

The boroselenites are heteropoly anion chemical compounds containing selenite and borate groups linked by common oxygen atoms. They are not to be confused with the boroselenates with have a higher oxidation state for selenium, and extra oxygen. If selenium is replaced by sulfur, it would be a borosulfite. Boroselenites are distinct from selenoborates in which selenium replaces oxygen in borate, or perselenoborates which contain Se-Se bonds as well as Se-B bonds. The metal boroselenites were only discovered in 2012.

Carbide iodides are mixed anion compounds containing iodide and carbide anions. Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

<span class="mw-page-title-main">Lutetium(III) iodide</span> Chemical compound

Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.

Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Lutetium compounds are compounds formed by the lanthanide metal lutetium (Lu). In these compounds, lutetium generally exhibits the +3 oxidation state, such as LuCl3, Lu2O3 and Lu2(SO4)3. Aqueous solutions of most lutetium salts are colorless and form white crystalline solids upon drying, with the common exception of the iodide. The soluble salts, such as nitrate, sulfate and acetate form hydrates upon crystallization. The oxide, hydroxide, fluoride, carbonate, phosphate and oxalate are insoluble in water.

Thulium(III) telluride is an inorganic compound, one of the tellurides of thulium, with the chemical formula Tm2Te3. It is an orthorhombic crystal with space group Fddd. It can dissolve in lead telluride at high temperatures to form a solid solution.

References

  1. David R. Lide. CRC Handbook of Chemistry and Physics, 88th Edition. CRC Press. page 4-73.
  2. Pierre Villars; Karin Cenzual; Roman Gladyshevskii. Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. 24 July 2017. ISBN 978-3-11-043655-6. "Lu-Te"
  3. Ling Chen, John D. Corbett (2003-07-01). "Lu 8 Te and Lu 7 Te. Novel Substitutional Derivatives of Lutetium Metal". Journal of the American Chemical Society. 125 (26): 7794–7795. doi:10.1021/ja035392z. ISSN   0002-7863. PMID   12822985. Archived from the original on 2023-05-09. Retrieved 2023-06-13.
  4. Ling Chen, Sheng-Qing Xia, John D. Corbett (2005-05-01). "Metal-Rich Chalcogenides. Synthesis, Structure, and Bonding of the Layered Lu 11 Te 4 . Comparison with the Similar Sc 8 Te 3 and Ti 11 Se 4". Inorganic Chemistry. 44 (9): 3057–3062. doi:10.1021/ic0401142. ISSN   0020-1669. PMID   15847409. Archived from the original on 2023-05-12. Retrieved 2023-06-13.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  5. "TSCA Inventory". Data.gov. 2020-12-03. Archived from the original on 2023-05-30. Retrieved 2023-05-09. (List) Archived (Date missing) at epa.gov (Error: unknown archive URL) TSCAINV_022023.csv; last created: 02/2023 ID#18021.