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Gadolinium is a chemical element; it has symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is a malleable and ductile rare-earth element. Gadolinium reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of 20 °C (68 °F) is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare-earths because of their similar chemical properties.
Lutetium is a chemical element; it has symbol Lu and atomic number 71. It is a silvery white metal, which resists corrosion in dry air, but not in moist air. Lutetium is the last element in the lanthanide series, and it is traditionally counted among the rare earth elements; it can also be classified as the first element of the 6th-period transition metals.
The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.
Ytterbium is a chemical element; it has symbol Yb and atomic number 70. It is a metal, the fourteenth and penultimate element in the lanthanide series, which is the basis of the relative stability of its +2 oxidation state. Like the other lanthanides, its most common oxidation state is +3, as in its oxide, halides, and other compounds. In aqueous solution, like compounds of other late lanthanides, soluble ytterbium compounds form complexes with nine water molecules. Because of its closed-shell electron configuration, its density, melting point and boiling point are much lower than those of most other lanthanides.
Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in their oxidation states.
A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.
Nd:YAG (neodymium-doped yttrium aluminum garnet; Nd:Y3Al5O12) is a crystal that is used as a lasing medium for solid-state lasers. The dopant, triply ionized neodymium, Nd(III), typically replaces a small fraction (1%) of the yttrium ions in the host crystal structure of the yttrium aluminum garnet (YAG), since the two ions are of similar size. It is the neodymium ion which provides the lasing activity in the crystal, in the same fashion as red chromium ion in ruby lasers.
In semiconductor production, doping is the intentional introduction of impurities into an intrinsic (undoped) semiconductor for the purpose of modulating its electrical, optical and structural properties. The doped material is referred to as an extrinsic semiconductor.
Yttrium aluminium garnet (YAG, Y3Al5O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM).
Neodymium-doped yttrium orthovanadate (Nd:YVO4) is a crystalline material formed by adding neodymium ions to yttrium orthovanadate. It is commonly used as an active laser medium for diode-pumped solid-state lasers. It comes as a transparent blue-tinted material. It is birefringent, therefore rods made of it are usually rectangular.
Yttrium oxide, also known as yttria, is Y2O3. It is an air-stable, white solid substance.
Gadolinium oxysulfide (Gd2O2S), also called gadolinium sulfoxylate, GOS or Gadox, is an inorganic compound, a mixed oxide-sulfide of gadolinium.
Yttrium is a chemical element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.
Yttrium boride refers to a crystalline material composed of different proportions of yttrium and boron, such as YB2, YB4, YB6, YB12, YB25, YB50 and YB66. They are all gray-colored, hard solids having high melting temperatures. The most common form is the yttrium hexaboride YB6. It exhibits superconductivity at relatively high temperature of 8.4 K and, similar to LaB6, is an electron cathode. Another remarkable yttrium boride is YB66. It has a large lattice constant (2.344 nm), high thermal and mechanical stability, and therefore is used as a diffraction grating for low-energy synchrotron radiation (1–2 keV).
Lutetium tantalate is a chemical compound of lutetium, tantalum and oxygen with the formula LuTaO4. With a density of 9.81 g/cm3, this salt is the densest known white stable material. (Although thorium dioxide ThO2 is also white and has a higher density of 10 g/cm3, it is radioactively unstable; while not radioactive enough to make it unstable as a material, even its low rate of decay is still too much for certain uses such as phosphors for detecting ionising radiation.) The white color and high density of LuTaO4 make it ideal for phosphor applications, though the high cost of lutetium is a hindrance.
A dopant is a small amount of a substance added to a material to alter its physical properties, such as electrical or optical properties. The amount of dopant is typically very low compared to the material being doped.
Gadolinium Gallium Garnet is a synthetic crystalline material of the garnet group, with good mechanical, thermal, and optical properties. It is typically colorless. It has a cubic lattice, a density of 7.08 g/cm3 and its Mohs hardness is variously noted as 6.5 and 7.5. Its crystals are produced with the Czochralski method. During production, various dopants can be added for colour modification. The material is also used in fabrication of various optical components and as a substrate material for magneto–optical films. It also finds use in jewelry as a diamond simulant. GGG can also be used as a seed substrate for the growth of other garnets such as yttrium iron garnet.
Lutetium–yttrium oxyorthosilicate, also known as LYSO, is an inorganic chemical compound with main use as a scintillator crystal for gamma radiation detection. Its chemical formula is Lu2(1-x)Y2xSiO5. The percentage of yttrium varies considerably, with values in the literature ranging from 5% to 70%. It is commonly used to build screens and electromagnetic calorimeters in particle physics. LYSO crystals have the advantages of high light output and density, quick decay time, excellent energy resolution. The crystals are often grown in boules using the Czochralski process, and cutting or polishing can be challenging because LYSO is brittle and hard.
References
- 1 2 3 4 5 Moore, Cheryl (2015). "Towards a Greater Understanding of Hydrothermally Grown Garnets and Sesquioxide Crystals for Laser Applications". Clemson University Tiger Prints. Bibcode:2015PhDT.......308M.
- 1 2 "Lutetium Aluminum Garnet - LuAG - Lu3Al5O12". scientificmaterials.com. Retrieved 2016-04-29.
- ↑ Kiss, Z. J.; Pressley, R. J. (1966-10-01). "Crystalline Solid Lasers". Applied Optics. 5 (10): 1474–86. Bibcode:1966ApOpt...5.1474K. doi:10.1364/ao.5.001474. ISSN 1539-4522. PMID 20057583.
- ↑ Kuwano, Yasuhiko; Suda, Katsumi; Ishizawa, Nobuo; Yamada, Toyoaki (2004-01-02). "Crystal growth and properties of (Lu,Y)3Al5O12". Journal of Crystal Growth. 260 (1–2): 159–165. Bibcode:2004JCrGr.260..159K. doi:10.1016/j.jcrysgro.2003.08.060.
- 1 2 Yoshikawa, A.; Chani, V.; Nikl, M. (2013). "Czochralski Growth and Properties of Scintillating Crystals". Acta Physica Polonica A. 124 (2): 250–264. Bibcode:2013AcPPA.124..250Y. doi: 10.12693/aphyspola.124.250 .