Yttrium aluminium garnet | |
---|---|
General | |
Category | synthetic mineral |
Formula (repeating unit) | Y3Al5O12 |
Crystal system | Cubic |
Identification | |
Color | Usually colorless, but may be pink, red, orange, yellow, green, blue, purple |
Cleavage | None |
Fracture | Conchoidal to uneven |
Mohs scale hardness | 8.5 |
Luster | Vitreous to subadamantine |
Specific gravity | 4.5–4.6 |
Polish luster | Vitreous to subadamantine |
Optical properties | Single refractive |
Refractive index | 1.833±0.010 |
Birefringence | None |
Pleochroism | None |
Dispersion | 0.028 |
Ultraviolet fluorescence | Colorless stones - inert to moderate orange in long wave, inert to weak orange in short wave; blue and pink stones - inert; yellow-green stones - very strong yellow in long and short wave also phosphoresces; green stones - strong red in long wave, weak red in short wave |
References | [1] |
Yttrium aluminium garnet (YAG, Y 3 Al 5 O 12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP [2] ) in a hexagonal or an orthorhombic, perovskite-like form, and the monoclinic Y4Al2O9 (YAM [3] ). [4]
Due to its broad optical transparency, [5] low internal stress, high hardness, chemical and heat resistance, YAG is used for a variety of optics. [6] Its lack of birefringence (unlike sapphire) makes it an interesting material for high-energy/high-power laser systems. Laser damage levels of YAG ranged from 1.1 to 2.2 kJ/cm2 (1064 nm, 10 ns). [7]
YAG, like garnet and sapphire, has no uses as a laser medium when pure. However, after being doped with an appropriate ion, YAG is commonly used as a host material in various solid-state lasers. [8] Rare earth elements such as neodymium and erbium can be doped into YAG as active laser ions, yielding Nd:YAG and Er:YAG lasers, respectively. Cerium-doped YAG (Ce:YAG) is used as a phosphor in cathode ray tubes and white light-emitting diodes, and as a scintillator.
YAG for a period[ when? ] was used in jewelry as a diamond and other gemstone simulant. Colored variants and their doping elements include: [1] green (chromium), blue (cobalt), red (manganese), yellow (titanium), blue/pink/purple (neodymium, depending on light source), pink, and orange. As faceted gems they are valued (as synthetics) for their clarity, durability, high refractive index and dispersion, and occasionally properties like simulating alexandrite's color-changing property. The critical angle of YAG is 33 degrees. YAG cuts like natural garnet, with polishing being performed with alumina or diamond (50,000 or 100,000 grit) on common polishing laps. YAG has low heat sensitivity. [9]
As a synthetic gemstone YAG has numerous varietal and trade names, as well as a number of misnomers. Synonymous names include: alexite, amamite, circolite, dia-bud, diamite, diamogem, diamonair, diamone, diamonique, diamonite, diamonte, di'yag, geminair, gemonair, kimberly, Linde simulated diamond, nier-gem, regalair, replique, somerset, triamond, YAIG, and yttrium garnet. Production for the gem trade decreased after the introduction of synthetic cubic zirconia; as of 1995 [update] there was little production. [1] Some demand exists as synthetic garnet, and for designs where the very high refractive index of cubic zirconia is not desirable.[ citation needed ]
This section needs additional citations for verification .(April 2013) |
Neodymium-doped YAG (Nd:YAG) was developed in the early 1960s, and the first working Nd:YAG laser was invented in 1964. Neodymium-YAG is the most widely used active laser medium in solid-state lasers, being used for everything from low-power continuous-wave lasers to high-power Q-switched (pulsed) lasers with power levels measured in the kilowatts. [10] The thermal conductivity of Nd:YAG is higher and its fluorescence lifetime is about twice as long as that of Nd:YVO4 crystals, however it is not as efficient and is less stable, requiring more precisely controlled temperatures. The best absorption band of Nd:YAG for pumping the laser is centered at 807.5 nm, and is 1 nm wide. [11]
Most Nd:YAG lasers produce infrared light at a wavelength of 1064 nm. Light at this wavelength is rather dangerous to vision, since it can be focused by the eye's lens onto the retina, but the light is invisible and does not trigger the blink reflex. Nd:YAG lasers can also be used with frequency doubling or frequency tripling crystals, to produce green light with a wavelength of 532 nm or ultraviolet light at 355 nm, respectively.
The dopant concentration in commonly used Nd:YAG crystals usually varies between 0.5 and 1.4 molar percent. Higher dopant concentration is used for pulsed lasers; lower concentration is suitable for continuous-wave lasers. Nd:YAG is pinkish-purple, with lighter-doped rods being less intensely colored than heavier-doped ones. Since its absorption spectrum is narrow, the hue depends on the light under which it is observed.
YAG doped with neodymium and chromium (Nd:Cr:YAG or Nd/Cr:YAG) has absorption characteristics which are superior to Nd:YAG. This is because energy is absorbed by the broad absorption bands of the Cr3+ dopant and then transferred to Nd3+ by dipole-dipole interactions. [12] This material has been suggested for use in solar-pumped lasers, which could form part of a solar power satellite system. [13]
Erbium-doped YAG (Er:YAG) is an active laser medium lasing at 2940 nm. Its absorption bands suitable for pumping are wide and located between 600 and 800 nm, allowing for efficient flashlamp pumping. The dopant concentration used is high: about 50% of the yttrium atoms are replaced. The Er:YAG laser wavelength couples well into water and body fluids, making this laser especially useful for medicine and dentistry uses; it is used for treatment of tooth enamel and in cosmetic surgery. Er:YAG is used for noninvasive monitoring of blood sugar. The mechanical properties of Er:YAG are essentially the same as Nd:YAG. Er:YAG operates at wavelengths where the threshold for eye damage is relatively high (since the light is absorbed before striking the retina), works well at room temperature, and has high slope efficiency. Er:YAG is pink. [14]
Ytterbium-doped YAG (Yb:YAG) is an active laser medium lasing at 1030 nm, with a broad, 18 nm wide absorption band at 940 nm. [15] It is one of the most useful media for high-power diode-pumped solid state lasers. The dopant levels used range between 0.2% and 30% of replaced yttrium atoms. Yb:YAG has very low fractional heating, very high slope efficiency, [16] and no excited-state absorption or up-conversion, high mechanical strength and high thermal conductivity. Yb:YAG can be pumped by reliable InGaAs laser diodes at 940 or 970 nm.
Yb:YAG is a good substitute for 1064 nm Nd:YAG in high-power applications, and its frequency-doubled 515 nm version can replace the 514 nm argon lasers.
Neodymium-cerium double-doped YAG (Nd:Ce:YAG, or Nd,Ce:YAG) is an active laser medium material very similar to Nd:YAG. The added cerium atoms strongly absorb in the ultraviolet region and transfer their energy to the neodymium atoms, increasing the pumping efficiency; the result is lower thermal distortion and higher power output than Nd:YAG at the same pumping level. The lasing wavelength, 1064 nm, is the same as for Nd:YAG. The material has a good resistance to damage caused by UV from the pump source, and low lasing threshold. Usually 1.1–1.4% of Y atoms are replaced with Nd, and 0.05–0.1% with Ce.
Holmium-chromium-thulium triple-doped YAG (Ho:Cr:Tm:YAG, or Ho,Cr,Tm:YAG) is an active laser medium material with high efficiency. It lases at 2080 nm and can be pumped by a flashlamp or a laser diode. [17] It is widely used in military, medicine, and meteorology. It works well at room temperature, has high slope efficiency, and operates at a wavelength where the threshold for eye damage is relatively high. When pumped by a diode, the 785 nm band for Tm3+ ion can be used. [17] Other major pump bands are located between 400 and 800 nm. The dopant levels used are 0.35 atom.% Ho, 5.8 atom.% Tm, and 1.5 at.% Cr. The rods have green color, imparted by chromium(III).
Thulium-doped YAG (Tm:YAG) is an active laser medium that operates between 1930 and 2040 nm. It is suitable for diode pumping. A dual-mode Tm:YAG laser emits two frequencies separated by 1 GHz.
Chromium (IV)-doped YAG (Cr:YAG) provides a large absorption cross section in the 0.9-1.2 micrometer spectral region, which makes it an attractive choice as a passive Q-switch for Nd-doped lasers. The resulting devices are solid-state, compact and low-cost. Cr:YAG has high damage threshold, good thermal conductivity, good chemical stability, resists ultraviolet radiation, and is easily machinable. It is replacing more traditional Q-switching materials like lithium fluoride and organic dyes. The dopant levels used range between 0.5 and 3 percent (molar). Cr:YAG can be used for passive Q-switching of lasers that operate at wavelengths between 1000 and 1200 nm, such as those based on Nd:YAG, Nd:YLF, Nd:YVO4, and Yb:YAG.
Cr:YAG can be also used as a laser gain medium itself, producing tunable lasers with outputs adjustable between 1350 and 1550 nm. The Cr:YAG laser can generate ultrashort pulses (in the femtoseconds range) when it is pumped at 1064 nm by a Nd:YAG laser. [18]
Cr:YAG has been demonstrated in an application of non-linear optics as a self-pumped phase-conjugate mirror in a Nd:YAG "loop resonator".[ citation needed ] Such a mirror provides compensation of both phase and polarization aberrations induced into the loop resonator.
Dysprosium-doped YAG (Dy:YAG) is a temperature-sensitive phosphor used in temperature measurements. [19] The phosphor is excited by a laser pulse and its temperature-dependent fluorescence is observed. Dy:YAG is sensitive in ranges of 300–1700 K. [20] The phosphor can be applied directly to the measured surface, or to an end of an optical fiber. It has also been studied as a single-phase white emitting phosphor in phosphor-converted white light-emitting diodes. [21]
Samarium-doped YAG (Sm:YAG) is a temperature-sensitive phosphor similar to Dy:YAG.
Terbium-doped YAG (Tb:YAG) is a phosphor used in cathode ray tubes. It emits at yellow-green color, at 544 nm.
Cerium(III)-doped YAG (Ce:YAG or YAG:Ce) is a phosphor, or a scintillator when in pure single-crystal form, with a wide range of uses. It emits yellow light when subjected to blue or ultraviolet light or to x-rays. [22] It is used in white light-emitting diodes as a coating on a high-brightness blue InGaN diode, converting part of the blue light into yellow, which together then appear as white. Such an arrangement gives less than ideal color rendering. The output brightness decreases with increasing temperature, further altering device color output.[ citation needed ]
Ce:YAG is also used in some mercury-vapor lamps as one of the phosphors, often together with Eu:Y(P,V)O4 (yttrium phosphate-vanadate). It is also used as a phosphor in cathode ray tubes, where it emits green (530 nm) to yellow-green (550 nm) light. When excited by electrons, it has virtually no afterglow (70 ns decay time). It is suitable for use in photomultipliers.
Ce:YAG is used in PET scanners, high-energy gamma radiation and charged particle detectors, and high-resolution imaging screens for gamma, x-rays, beta radiation and ultraviolet radiation.
Ce:YAG can be further doped with gadolinium.
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word laser is an anacronym that originated as an acronym for light amplification by stimulated emission of radiation. The first laser was built in 1960 by Theodore Maiman at Hughes Research Laboratories, based on theoretical work by Charles H. Townes and Arthur Leonard Schawlow.
A laser is constructed from three principal parts:
Neodymium is a chemical element; it has symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes in air and moisture. When oxidized, neodymium reacts quickly producing pink, purple/blue and yellow compounds in the +2, +3 and +4 oxidation states. It is generally regarded as having one of the most complex spectra of the elements. Neodymium was discovered in 1885 by the Austrian chemist Carl Auer von Welsbach, who also discovered praseodymium. It is present in significant quantities in the minerals monazite and bastnäsite. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Neodymium is fairly common—about as common as cobalt, nickel, or copper—and is widely distributed in the Earth's crust. Most of the world's commercial neodymium is mined in China, as is the case with many other rare-earth metals.
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.
A laser diode is a semiconductor device similar to a light-emitting diode in which a diode pumped directly with electrical current can create lasing conditions at the diode's junction.
Nd:YAG (neodymium-doped yttrium aluminum garnet; Nd:Y3Al5O12) is a crystal that is used as a lasing medium for solid-state lasers. The dopant, neodymium in the +3 oxidation state, Nd(III), typically replaces a small fraction (1%) of the yttrium ions in the host crystal structure of the yttrium aluminum garnet (YAG), since the two ions are of similar size. It is the neodymium ion which provides the lasing activity in the crystal, in the same fashion as red chromium ion in ruby lasers.
A diode-pumped solid-state laser (DPSSL) is a solid-state laser made by pumping a solid gain medium, for example, a ruby or a neodymium-doped YAG crystal, with a laser diode.
Many ceramic materials, both glassy and crystalline, have found use as optically transparent materials in various forms from bulk solid-state components to high surface area forms such as thin films, coatings, and fibers. Such devices have found widespread use for various applications in the electro-optical field including: optical fibers for guided lightwave transmission, optical switches, laser amplifiers and lenses, hosts for solid-state lasers and optical window materials for gas lasers, and infrared (IR) heat seeking devices for missile guidance systems and IR night vision. In commercial and general knowledge domains, it is commonly accepted that transparent ceramics or ceramic glass are varieties of strengthened glass, such as those used for the screen glass on an iPhone.
Neodymium-doped yttrium orthovanadate (Nd:YVO4) is a crystalline material formed by adding neodymium ions to yttrium orthovanadate. It is commonly used as an active laser medium for diode-pumped solid-state lasers. It comes as a transparent blue-tinted material. It is birefringent, therefore rods made of it are usually rectangular.
Yttrium oxide, also known as yttria, is Y2O3. It is an air-stable, white solid substance.
A blue laser emits electromagnetic radiation with a wavelength between 400 and 500 nanometers, which the human eye sees in the visible spectrum as blue or violet.
A solid-state laser is a laser that uses a gain medium that is a solid, rather than a liquid as in dye lasers or a gas as in gas lasers. Semiconductor-based lasers are also in the solid state, but are generally considered as a separate class from solid-state lasers, called laser diodes.
Laser pumping is the act of energy transfer from an external source into the gain medium of a laser. The energy is absorbed in the medium, producing excited states in its atoms. When for a period of time the number of particles in one excited state exceeds the number of particles in the ground state or a less-excited state, population inversion is achieved. In this condition, the mechanism of stimulated emission can take place and the medium can act as a laser or an optical amplifier. The pump power must be higher than the lasing threshold of the laser.
This is a list of acronyms and other initialisms used in laser physics and laser applications.
A ruby laser is a solid-state laser that uses a synthetic ruby crystal as its gain medium. The first working laser was a ruby laser made by Theodore H. "Ted" Maiman at Hughes Research Laboratories on May 16, 1960.
Lutetium aluminum garnet (commonly abbreviated LuAG, molecular formula Lu3Al5O12) is an inorganic compound with a unique crystal structure primarily known for its use in high-efficiency laser devices. LuAG is also useful in the synthesis of transparent ceramics.
Neodymium-doped yttrium lithium fluoride (Nd:YLF) is a lasing medium for arc lamp-pumped and diode-pumped solid-state lasers. The YLF crystal (LiYF4) is naturally birefringent, and commonly used laser transitions occur at 1047 nm and 1053 nm.
A dopant is a small amount of a substance added to a material to alter its physical properties, such as electrical or optical properties. The amount of dopant is typically very low compared to the material being doped.
Lightwave Electronics Corporation was a developer and manufacturer of diode-pumped solid-state lasers, and was a significant contributor to the creation and maturation of this technology. Lightwave Electronics was a technology-focused company, with diverse markets, including science and micromachining. Inventors employed by Lightwave Electronics received 51 US patents, and Lightwave Electronics products were referenced by non-affiliated inventors in 91 US patents.
A Pr:YLF laser (or Pr3+:LiYF4 laser) is a solid state laser that uses a praseodymium doped yttrium-lithium-fluoride crystal as its gain medium. The first Pr:YLF laser was built in 1977 and emitted pulses at 479 nm. Pr:YLF lasers can emit in many different wavelengths in the visible spectrum of light, making them potentially interesting for RGB applications and materials processing. Notable emission wavelengths are 479 nm, 523 nm, 607 nm and 640 nm.
Yttrium aluminum garnet (YAG) is an important optical ceramic material, especially when doped with Nd and Er, when it exhibits a specific color. For instance, Er:YAG is pink and Nd:YAG is a light reddish purple