Light-emitting diode

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Light-emitting diode
RBG-LED.jpg
Blue, green, and red LEDs in 5 mm diffused cases. There are many different variants of LEDs.
Working principle Electroluminescence
Inventor
First production October 1962;62 years ago (1962-10)
Pin names Anode and cathode
Electronic symbol
IEEE 315-1975 (1993) 8.5.4.2.svg
Parts of a conventional LED. The flat bottom surfaces of the anvil and post embedded inside the epoxy act as anchors, to prevent the conductors from being forcefully pulled out via mechanical strain or vibration. LED, 5mm, green (en).svg
Parts of a conventional LED. The flat bottom surfaces of the anvil and post embedded inside the epoxy act as anchors, to prevent the conductors from being forcefully pulled out via mechanical strain or vibration.
Close-up image of a surface-mount LED Surface mount LED close up image.png
Close-up image of a surface-mount LED
Close-up of an LED with the voltage being increased and decreased to show a detailed view of its operation
A bulb-shaped modern retrofit LED lamp with aluminum heat sink, a light diffusing dome and E27 screw base, using a built-in power supply working on mains voltage Br20 1.jpg
A bulb-shaped modern retrofit LED lamp with aluminum heat sink, a light diffusing dome and E27 screw base, using a built-in power supply working on mains voltage

A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corresponding to the energy of the photons) is determined by the energy required for electrons to cross the band gap of the semiconductor. [5] White light is obtained by using multiple semiconductors or a layer of light-emitting phosphor on the semiconductor device. [6]

Contents

Appearing as practical electronic components in 1962, the earliest LEDs emitted low-intensity infrared (IR) light. [7] Infrared LEDs are used in remote-control circuits, such as those used with a wide variety of consumer electronics. The first visible-light LEDs were of low intensity and limited to red.

Early LEDs were often used as indicator lamps, replacing small incandescent bulbs, and in seven-segment displays. Later developments produced LEDs available in visible, ultraviolet (UV), and infrared wavelengths with high, low, or intermediate light output, for instance, white LEDs suitable for room and outdoor lighting. LEDs have also given rise to new types of displays and sensors, while their high switching rates are useful in advanced communications technology with applications as diverse as aviation lighting, fairy lights, strip lights, automotive headlamps, advertising, general lighting, traffic signals, camera flashes, lighted wallpaper, horticultural grow lights, and medical devices. [8]

LEDs have many advantages over incandescent light sources, including lower power consumption, a longer lifetime, improved physical robustness, smaller sizes, and faster switching. In exchange for these generally favorable attributes, disadvantages of LEDs include electrical limitations to low voltage and generally to DC (not AC) power, the inability to provide steady illumination from a pulsing DC or an AC electrical supply source, and a lesser maximum operating temperature and storage temperature.

LEDs are transducers of electricity into light. They operate in reverse of photodiodes, which convert light into electricity.

History

The first LED was created by Soviet inventor Oleg Losev [9] in 1927, but electroluminescence was already known for 20 years, and relied on a diode made of silicon carbide.

Commercially viable LEDs only became available after Texas Instruments engineers patented efficient near-infrared emission from a diode based on GaAs in 1962.

From 1968, commercial LEDs were extremely costly and saw no practical use. Monstanto and Hewlett-Packard led the development of LEDs to the point where, in the 1970s, a unit cost less than five cents. [10]

Physics of light production and emission

In a light-emitting diode, the recombination of electrons and electron holes in a semiconductor produces light (be it infrared, visible or UV), a process called "electroluminescence". The wavelength of the light depends on the energy band gap of the semiconductors used. Since these materials have a high index of refraction, design features of the devices such as special optical coatings and die shape are required to efficiently emit light. [11]

Unlike a laser, the light emitted from an LED is neither spectrally coherent nor even highly monochromatic. Its spectrum is sufficiently narrow that it appears to the human eye as a pure (saturated) color. [12] [13] Also unlike most lasers, its radiation is not spatially coherent, so it cannot approach the very high intensity characteristic of lasers.

Single-color LEDs

Blue LEDs Blue light emitting diodes over a proto-board.jpg
Blue LEDs
External videos
Herb Maruska original blue LED College of New Jersey Sarnoff Collection.png
Nuvola apps kaboodle.svg "The Original Blue LED", Science History Institute

By selection of different semiconductor materials, single-color LEDs can be made that emit light in a narrow band of wavelengths from near-infrared through the visible spectrum and into the ultraviolet range. The required operating voltages of LEDs increase as the emitted wavelengths become shorter (higher energy, red to blue), because of their increasing semiconductor band gap.

Blue LEDs have an active region consisting of one or more InGaN quantum wells sandwiched between thicker layers of GaN, called cladding layers. By varying the relative In/Ga fraction in the InGaN quantum wells, the light emission can in theory be varied from violet to amber.

Aluminium gallium nitride (AlGaN) of varying Al/Ga fraction can be used to manufacture the cladding and quantum well layers for ultraviolet LEDs, but these devices have not yet reached the level of efficiency and technological maturity of InGaN/GaN blue/green devices. If unalloyed GaN is used in this case to form the active quantum well layers, the device emits near-ultraviolet light with a peak wavelength centred around 365 nm. Green LEDs manufactured from the InGaN/GaN system are far more efficient and brighter than green LEDs produced with non-nitride material systems, but practical devices still exhibit efficiency too low for high-brightness applications.[ citation needed ]

With AlGaN and AlGaInN, even shorter wavelengths are achievable. Near-UV emitters at wavelengths around 360–395 nm are already cheap and often encountered, for example, as black light lamp replacements for inspection of anti-counterfeiting UV watermarks in documents and bank notes, and for UV curing. Substantially more expensive, shorter-wavelength diodes are commercially available for wavelengths down to 240 nm. [14] As the photosensitivity of microorganisms approximately matches the absorption spectrum of DNA, with a peak at about 260 nm, UV LED emitting at 250–270 nm are expected in prospective disinfection and sterilization devices. Recent research has shown that commercially available UVA LEDs (365 nm) are already effective disinfection and sterilization devices. [15] UV-C wavelengths were obtained in laboratories using aluminium nitride (210 nm), [16] boron nitride (215 nm) [17] [18] and diamond (235 nm). [19]

White LEDs

There are two primary ways of producing white light-emitting diodes. One is to use individual LEDs that emit three primary colors—red, green and blue—and then mix all the colors to form white light. The other is to use a phosphor material to convert monochromatic light from a blue or UV LED to broad-spectrum white light, similar to a fluorescent lamp. The yellow phosphor is cerium-doped YAG crystals suspended in the package or coated on the LED. This YAG phosphor causes white LEDs to appear yellow when off, and the space between the crystals allow some blue light to pass through in LEDs with partial phosphor conversion. Alternatively, white LEDs may use other phosphors like manganese(IV)-doped potassium fluorosilicate (PFS) or other engineered phosphors. PFS assists in red light generation, and is used in conjunction with conventional Ce:YAG phosphor.

In LEDs with PFS phosphor, some blue light passes through the phosphors, the Ce:YAG phosphor converts blue light to green and red (yellow) light, and the PFS phosphor converts blue light to red light. The color, emission spectrum or color temperature of white phosphor converted and other phosphor converted LEDs can be controlled by changing the concentration of several phosphors that form a phosphor blend used in an LED package. [20] [21] [22] [23]

The 'whiteness' of the light produced is engineered to suit the human eye. Because of metamerism, it is possible to have quite different spectra that appear white. The appearance of objects illuminated by that light may vary as the spectrum varies. This is the issue of color rendition, quite separate from color temperature. An orange or cyan object could appear with the wrong color and much darker as the LED or phosphor does not emit the wavelength it reflects. The best color rendition LEDs use a mix of phosphors, resulting in less efficiency and better color rendering.[ citation needed ]

The first white light-emitting diodes (LEDs) were offered for sale in the autumn of 1996. [24] Nichia made some of the first white LEDs which were based on blue LEDs with Ce:YAG phosphor. [25] Ce:YAG is often grown using the Czochralski method. [26]

RGB systems

Combined spectral curves for blue, yellow-green, and high-brightness red solid-state semiconductor LEDs. FWHM spectral bandwidth is approximately 24-27 nm for all three colors. RGB LED Spectrum.svg
Combined spectral curves for blue, yellow-green, and high-brightness red solid-state semiconductor LEDs. FWHM spectral bandwidth is approximately 24–27 nm for all three colors.
An RGB LED projecting red, green, and blue onto a surface RGB-Led-projection.jpg
An RGB LED projecting red, green, and blue onto a surface

Mixing red, green, and blue sources to produce white light needs electronic circuits to control the blending of the colors. Since LEDs have slightly different emission patterns, the color balance may change depending on the angle of view, even if the RGB sources are in a single package, so RGB diodes are seldom used to produce white lighting. Nonetheless, this method has many applications because of the flexibility of mixing different colors, [27] and in principle, this mechanism also has higher quantum efficiency in producing white light. [28]

There are several types of multicolor white LEDs: di-, tri-, and tetrachromatic white LEDs. Several key factors that play among these different methods include color stability, color rendering capability, and luminous efficacy. Often, higher efficiency means lower color rendering, presenting a trade-off between the luminous efficacy and color rendering. For example, the dichromatic white LEDs have the best luminous efficacy (120 lm/W), but the lowest color rendering capability. Although tetrachromatic white LEDs have excellent color rendering capability, they often have poor luminous efficacy. Trichromatic white LEDs are in between, having both good luminous efficacy (>70 lm/W) and fair color rendering capability. [29]

One of the challenges is the development of more efficient green LEDs. The theoretical maximum for green LEDs is 683 lumens per watt but as of 2010 few green LEDs exceed even 100 lumens per watt. The blue and red LEDs approach their theoretical limits.[ citation needed ]

Multicolor LEDs offer a means to form light of different colors. Most perceivable colors can be formed by mixing different amounts of three primary colors. This allows precise dynamic color control. Their emission power decays exponentially with rising temperature, [30] resulting in a substantial change in color stability. Such problems inhibit industrial use. Multicolor LEDs without phosphors cannot provide good color rendering because each LED is a narrowband source. LEDs without phosphor, while a poorer solution for general lighting, are the best solution for displays, either backlight of LCD, or direct LED based pixels.

Dimming a multicolor LED source to match the characteristics of incandescent lamps is difficult because manufacturing variations, age, and temperature change the actual color value output. To emulate the appearance of dimming incandescent lamps may require a feedback system with color sensor to actively monitor and control the color. [31]

Phosphor-based LEDs

Spectrum of a white LED showing blue light directly emitted by the GaN-based LED (peak at about 465 nm) and the more broadband Stokes-shifted light emitted by the Ce :YAG phosphor, which emits at roughly 500-700 nm White LED.png
Spectrum of a white LED showing blue light directly emitted by the GaN-based LED (peak at about 465 nm) and the more broadband Stokes-shifted light emitted by the Ce :YAG phosphor, which emits at roughly 500–700 nm

This method involves coating LEDs of one color (mostly blue LEDs made of InGaN) with phosphors of different colors to form white light; the resultant LEDs are called phosphor-based or phosphor-converted white LEDs (pcLEDs). [32] A fraction of the blue light undergoes the Stokes shift, which transforms it from shorter wavelengths to longer. Depending on the original LED's color, various color phosphors are used. Using several phosphor layers of distinct colors broadens the emitted spectrum, effectively raising the color rendering index (CRI). [33]

Phosphor-based LEDs have efficiency losses due to heat loss from the Stokes shift and also other phosphor-related issues. Their luminous efficacies compared to normal LEDs depend on the spectral distribution of the resultant light output and the original wavelength of the LED itself. For example, the luminous efficacy of a typical YAG yellow phosphor based white LED ranges from 3 to 5 times the luminous efficacy of the original blue LED because of the human eye's greater sensitivity to yellow than to blue (as modeled in the luminosity function).

Due to the simplicity of manufacturing, the phosphor method is still the most popular method for making high-intensity white LEDs. The design and production of a light source or light fixture using a monochrome emitter with phosphor conversion is simpler and cheaper than a complex RGB system, and the majority of high-intensity white LEDs presently on the market are manufactured using phosphor light conversion.[ citation needed ]

1 watt 9 volt three chips SMD phosphor based white LED 1 watt 9 volt SMD LED.jpg
1 watt 9 volt three chips SMD phosphor based white LED

Among the challenges being faced to improve the efficiency of LED-based white light sources is the development of more efficient phosphors. As of 2010, the most efficient yellow phosphor is still the YAG phosphor, with less than 10% Stokes shift loss. Losses attributable to internal optical losses due to re-absorption in the LED chip and in the LED packaging itself account typically for another 10% to 30% of efficiency loss. Currently, in the area of phosphor LED development, much effort is being spent on optimizing these devices to higher light output and higher operation temperatures. For instance, the efficiency can be raised by adapting better package design or by using a more suitable type of phosphor. Conformal coating process is frequently used to address the issue of varying phosphor thickness.[ citation needed ]

Some phosphor-based white LEDs encapsulate InGaN blue LEDs inside phosphor-coated epoxy. Alternatively, the LED might be paired with a remote phosphor, a preformed polycarbonate piece coated with the phosphor material. Remote phosphors provide more diffuse light, which is desirable for many applications. Remote phosphor designs are also more tolerant of variations in the LED emissions spectrum. A common yellow phosphor material is cerium-doped yttrium aluminium garnet (Ce3+:YAG).[ citation needed ]

White LEDs can also be made by coating near-ultraviolet (NUV) LEDs with a mixture of high-efficiency europium-based phosphors that emit red and blue, plus copper and aluminium-doped zinc sulfide (ZnS:Cu, Al) that emits green. This is a method analogous to the way fluorescent lamps work. This method is less efficient than blue LEDs with YAG:Ce phosphor, as the Stokes shift is larger, so more energy is converted to heat, but yields light with better spectral characteristics, which render color better. Due to the higher radiative output of the ultraviolet LEDs than of the blue ones, both methods offer comparable brightness. A concern is that UV light may leak from a malfunctioning light source and cause harm to human eyes or skin.[ citation needed ]

A new style of wafers composed of gallium-nitride-on-silicon (GaN-on-Si) is being used to produce white LEDs using 200-mm silicon wafers. This avoids the typical costly sapphire substrate in relatively small 100- or 150-mm wafer sizes. [34] The sapphire apparatus must be coupled with a mirror-like collector to reflect light that would otherwise be wasted. It was predicted that since 2020, 40% of all GaN LEDs are made with GaN-on-Si. Manufacturing large sapphire material is difficult, while large silicon material is cheaper and more abundant. LED companies shifting from using sapphire to silicon should be a minimal investment. [35]

Mixed white LEDs

Tunable white LED array in a floodlight Led Lights Panel.jpg
Tunable white LED array in a floodlight

There are RGBW LEDs that combine RGB units with a phosphor white LED on the market. Doing so retains the extremely tunable color of RGB LED, but allows color rendering and efficiency to be optimized when a color close to white is selected. [36]

Some phosphor white LED units are "tunable white", blending two extremes of color temperatures (commonly 2700K and 6500K) to produce intermediate values. This feature allows users to change the lighting to suit the current use of a multifunction room. [37] As illustrated by a straight line on the chromaticity diagram, simple two-white blends will have a pink bias, becoming most severe in the middle. A small amount of green light, provided by another LED, could correct the problem. [38] Some products are RGBWW, i.e. RGBW with tunable white. [39]

A final class of white LED with mixed light is dim-to-warm. These are ordinary 2700K white LED bulbs with a small red LED that turns on when the bulb is dimmed. Doing so makes the color warmer, emulating an incandescent light bulb. [39]

Other white LEDs

Another method used to produce experimental white light LEDs used no phosphors at all and was based on homoepitaxially grown zinc selenide (ZnSe) on a ZnSe substrate that simultaneously emitted blue light from its active region and yellow light from the substrate. [40]

Organic light-emitting diodes (OLEDs)

In an organic light-emitting diode (OLED), the electroluminescent material composing the emissive layer of the diode is an organic compound. The organic material is electrically conductive due to the delocalization of pi electrons caused by conjugation over all or part of the molecule, and the material therefore functions as an organic semiconductor. [41] The organic materials can be small organic molecules in a crystalline phase, or polymers. [42]

The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color gamut. [43] Polymer LEDs have the added benefit of printable and flexible displays. [44] [45] [46] OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, lighting and televisions. [42] [43]

Types

LEDs are produced in a variety of shapes and sizes. The color of the plastic lens is often the same as the actual color of light emitted, but not always. For instance, purple plastic is often used for infrared LEDs, and most blue devices have colorless housings. Modern high-power LEDs such as those used for lighting and backlighting are generally found in surface-mount technology (SMT) packages (not shown). Verschiedene LEDs.jpg
LEDs are produced in a variety of shapes and sizes. The color of the plastic lens is often the same as the actual color of light emitted, but not always. For instance, purple plastic is often used for infrared LEDs, and most blue devices have colorless housings. Modern high-power LEDs such as those used for lighting and backlighting are generally found in surface-mount technology (SMT) packages (not shown).
A variety of different diffused 5 mm THT-LEDs
Red, 650 - 625nm
Orange, 600 - 610nm
Yellow, 587 - 591nm
Green, 570 - 575nm
Blue, 465 - 467nm
Purple, 395 - 400nm LED Rainbow Pack - 5mm PTH 12903-01 new aranged.jpg
A variety of different diffused 5 mm THT-LEDs
  • Red, 650 – 625nm
  • Orange, 600 – 610nm
  • Yellow, 587 – 591nm
  • Green, 570 – 575nm
  • Blue, 465 – 467nm
  • Purple, 395 – 400nm

LEDs are made in different packages for different applications. A single or a few LED junctions may be packed in one miniature device for use as an indicator or pilot lamp. An LED array may include controlling circuits within the same package, which may range from a simple resistor, blinking or color changing control, or an addressable controller for RGB devices. Higher-powered white-emitting devices will be mounted on heat sinks and will be used for illumination. Alphanumeric displays in dot matrix or bar formats are widely available. Special packages permit connection of LEDs to optical fibers for high-speed data communication links.

Miniature

Image of miniature surface mount LEDs in most common sizes. They can be much smaller than a traditional 5 mm lamp type LED, shown on the upper left corner. Single and multicolor surface mount miniature LEDs in most common sizes.jpg
Image of miniature surface mount LEDs in most common sizes. They can be much smaller than a traditional 5 mm lamp type LED, shown on the upper left corner.
Very small (1.6x1.6x0.35 mm) red, green, and blue surface mount miniature LED package with gold wire bonding details Very small 1.6x1.6x0.35 mm RGB Surface Mount LED EAST1616RGBA2.jpg
Very small (1.6×1.6×0.35 mm) red, green, and blue surface mount miniature LED package with gold wire bonding details

These are mostly single-die LEDs used as indicators, and they come in various sizes from 1.8 mm to 10 mm, through-hole and surface mount packages. [47] Typical current ratings range from around 1 mA to above 20 mA. LED's can be soldered to a flexible PCB strip to form LED tape popularly used for decoration.

Common package shapes include round, with a domed or flat top, rectangular with a flat top (as used in bar-graph displays), and triangular or square with a flat top. The encapsulation may also be clear or tinted to improve contrast and viewing angle. Infrared devices may have a black tint to block visible light while passing infrared radiation, such as the Osram SFH 4546. [48]

5 V and 12 V LEDs are ordinary miniature LEDs that have a series resistor for direct connection to a 5 V or 12 V supply. [49]

High-power

High-power light-emitting diodes attached to an LED star base (Luxeon, Lumileds) 2007-07-24 High-power light emitting diodes (Luxeon, Lumiled).jpg
High-power light-emitting diodes attached to an LED star base (Luxeon, Lumileds)

High-power LEDs (HP-LEDs) or high-output LEDs (HO-LEDs) can be driven at currents from hundreds of mA to more than an ampere, compared with the tens of mA for other LEDs. Some can emit over a thousand lumens. [50] [51] LED power densities up to 300 W/cm2 have been achieved. Since overheating is destructive, the HP-LEDs must be mounted on a heat sink to allow for heat dissipation. If the heat from an HP-LED is not removed, the device fails in seconds. One HP-LED can often replace an incandescent bulb in a flashlight, or be set in an array to form a powerful LED lamp.

Some HP-LEDs in this category are the Nichia 19 series, Lumileds Rebel Led, Osram Opto Semiconductors Golden Dragon, and Cree X-lamp. As of September 2009, some HP-LEDs manufactured by Cree exceed 105 lm/W. [52]

Examples for Haitz's law—which predicts an exponential rise in light output and efficacy of LEDs over time—are the CREE XP-G series LED, which achieved 105 lm/W in 2009 [52] and the Nichia 19 series with a typical efficacy of 140 lm/W, released in 2010. [53]

AC-driven

LEDs developed by Seoul Semiconductor can operate on AC power without a DC converter. For each half-cycle, part of the LED emits light and part is dark, and this is reversed during the next half-cycle. The efficiency of this type of HP-LED is typically 40 lm/W. [54] A large number of LED elements in series may be able to operate directly from line voltage. In 2009, Seoul Semiconductor released a high DC voltage LED, named 'Acrich MJT', capable of being driven from AC power with a simple controlling circuit. The low-power dissipation of these LEDs affords them more flexibility than the original AC LED design. [55]

Strip

Several LED spots being reflected as continuous lighting strip Passenger Experience Week 2018, Hamburg (1X7A3748).jpg
Several LED spots being reflected as continuous lighting strip

An LED strip, tape, or ribbon light is a flexible circuit board populated by surface-mount light-emitting diodes (SMD LEDs) and other components that usually comes with an adhesive backing. Traditionally, strip lights had been used solely in accent lighting, backlighting, task lighting, and decorative lighting applications, such as cove lighting.

LED strip lights originated in the early 2000s. Since then, increased luminous efficacy and higher-power SMDs have allowed them to be used in applications such as high brightness task lighting, fluorescent and halogen lighting fixture replacements, indirect lighting applications, ultraviolet inspection during manufacturing processes, set and costume design, and growing plants.

Application-specific

RGB-SMD-LED RGB-SMD-LED.jpg
RGB-SMD-LED
Composite image of an 11 x 44 LED matrix lapel name tag display using 1608/0603-type SMD LEDs. Top: A little over half of the 21 x 86 mm display. Center: Close-up of LEDs in ambient light. Bottom: LEDs in their own red light. Macro photo of LED matrix.jpg
Composite image of an 11 × 44 LED matrix lapel name tag display using 1608/0603-type SMD LEDs. Top: A little over half of the 21 × 86 mm display. Center: Close-up of LEDs in ambient light. Bottom: LEDs in their own red light.
Flashing
Flashing LEDs are used as attention seeking indicators without requiring external electronics. Flashing LEDs resemble standard LEDs but they contain an integrated voltage regulator and a multivibrator circuit that causes the LED to flash with a typical period of one second. In diffused lens LEDs, this circuit is visible as a small black dot. Most flashing LEDs emit light of one color, but more sophisticated devices can flash between multiple colors and even fade through a color sequence using RGB color mixing. Flashing SMD LEDs in the 0805 and other size formats have been available since early 2019.
Flickering
Integrated electronics Simple electronic circuits integrated into the LED package have been around since at least 2011 which produce a random LED intensity pattern reminiscent of a flickering candle. [56] Reverse engineering in 2024 has suggested that some flickering LEDs with automatic sleep and wake modes might be using an integrated 8-bit microcontroller for such functionally. [57]
Bi-color
Bi-color LEDs contain two different LED emitters in one case. There are two types of these. One type consists of two dies connected to the same two leads antiparallel to each other. Current flow in one direction emits one color, and current in the opposite direction emits the other color. The other type consists of two dies with separate leads for both dies and another lead for common anode or cathode so that they can be controlled independently. The most common bi-color combination is red/traditional green. Others include amber/traditional green, red/pure green, red/blue, and blue/pure green.
RGB tri-color
Tri-color LEDs contain three different LED emitters in one case. Each emitter is connected to a separate lead so they can be controlled independently. A four-lead arrangement is typical with one common lead (anode or cathode) and an additional lead for each color. Others have only two leads (positive and negative) and have a built-in electronic controller. RGB LEDs consist of one red, one green, and one blue LED. [58] By independently adjusting each of the three, RGB LEDs are capable of producing a wide color gamut. Unlike dedicated-color LEDs, these do not produce pure wavelengths. Modules may not be optimized for smooth color mixing.
Decorative-multicolor
Decorative-multicolor LEDs incorporate several emitters of different colors supplied by only two lead-out wires. Colors are switched internally by varying the supply voltage.
Alphanumeric
Alphanumeric LEDs are available in seven-segment, starburst, and dot-matrix format. Seven-segment displays handle all numbers and a limited set of letters. Starburst displays can display all letters. Dot-matrix displays typically use 5×7 pixels per character. Seven-segment LED displays were in widespread use in the 1970s and 1980s, but rising use of liquid crystal displays, with their lower power needs and greater display flexibility, has reduced the popularity of numeric and alphanumeric LED displays.
Digital RGB
Digital RGB addressable LEDs contain their own "smart" control electronics. In addition to power and ground, these provide connections for data-in, data-out, clock and sometimes a strobe signal. These are connected in a daisy chain, which allows individual LEDs in a long LED strip light to be easily controlled by a microcontroller. Data sent to the first LED of the chain can control the brightness and color of each LED independently of the others. They are used where a combination of maximum control and minimum visible electronics are needed such as strings for Christmas and LED matrices. Some even have refresh rates in the kHz range, allowing for basic video applications. These devices are known by their part number (WS2812 being common) or a brand name such as NeoPixel.
Filament
An LED filament consists of multiple LED chips connected in series on a common longitudinal substrate that forms a thin rod reminiscent of a traditional incandescent filament. [59] These are being used as a low-cost decorative alternative for traditional light bulbs that are being phased out in many countries. The filaments use a rather high voltage, allowing them to work efficiently with mains voltages. Often a simple rectifier and capacitive current limiting are employed to create a low-cost replacement for a traditional light bulb without the complexity of the low voltage, high current converter that single die LEDs need. [60] Usually, they are packaged in bulb similar to the lamps they were designed to replace, and filled with inert gas at slightly lower than ambient pressure to remove heat efficiently and prevent corrosion.
Chip-on-board arrays
Surface-mounted LEDs are frequently produced in chip on board (COB) arrays, allowing better heat dissipation than with a single LED of comparable luminous output. [61] The LEDs can be arranged around a cylinder, and are called "corn cob lights" because of the rows of yellow LEDs. [62]

Considerations for use

Power sources

Simple LED circuit with resistor for current limiting LED circuit.svg
Simple LED circuit with resistor for current limiting

The current in an LED or other diodes rises exponentially with the applied voltage (see Shockley diode equation), so a small change in voltage can cause a large change in current. Current through the LED must be regulated by an external circuit such as a constant current source to prevent damage. Since most common power supplies are (nearly) constant-voltage sources, LED fixtures must include a power converter, or at least a current-limiting resistor. In some applications, the internal resistance of small batteries is sufficient to keep current within the LED rating.[ citation needed ]

LEDs are sensitive to voltage. They must be supplied with a voltage above their threshold voltage and a current below their rating. Current and lifetime change greatly with a small change in applied voltage. They thus require a current-regulated supply (usually just a series resistor for indicator LEDs). [65]

Efficiency droop: The efficiency of LEDs decreases as the electric current increases. Heating also increases with higher currents, which compromises LED lifetime. These effects put practical limits on the current through an LED in high power applications. [66]

Electrical polarity

Unlike a traditional incandescent lamp, an LED will light only when voltage is applied in the forward direction of the diode. No current flows and no light is emitted if voltage is applied in the reverse direction. If the reverse voltage exceeds the breakdown voltage, which is typically about five volts, a large current flows and the LED will be damaged. If the reverse current is sufficiently limited to avoid damage, the reverse-conducting LED is a useful noise diode.[ citation needed ]

By definition, the energy band gap of any diode is higher when reverse-biased than when forward-biased. Because the band gap energy determines the wavelength of the light emitted, the color cannot be the same when reverse-biased. The reverse breakdown voltage is sufficiently high that the emitted wavelength cannot be similar enough to still be visible. Though dual-LED packages exist that contain a different color LED in each direction, it is not expected that any single LED element can emit visible light when reverse-biased.[ citation needed ]

It is not known if any zener diode could exist that emits light only in reverse-bias mode. Uniquely, this type of LED would conduct when connected backwards.

Appearance

Light properties

Reliability

Manufacturing

LED manufacturing involves multiple steps, including epitaxy, chip processing, chip separation, and packaging. [76]

In a typical LED manufacturing process, encapsulation is performed after probing, dicing, die transfer from wafer to package, and wire bonding or flip chip mounting, [77] perhaps using indium tin oxide, a transparent electrical conductor. In this case, the bond wire(s) are attached to the ITO film that has been deposited in the LEDs.

Flip chip circuit on board (COB) is a technique that can be used to manufacture LEDs. [78]

Colors and materials

Conventional LEDs are made from a variety of inorganic semiconductor materials, the following table shows the available colors with wavelength range, voltage drop and material:

Color Wavelength (nm)Voltage (V)Semiconductor Material
Infrared λ > 760 Δ V < 1.9 Gallium arsenide (GaAs)

Aluminium gallium arsenide (AlGaAs)

Red 610 < λ < 7601.63 < ΔV < 2.03 Aluminium gallium arsenide (AlGaAs)

Gallium arsenide phosphide (GaAsP) Aluminium gallium indium phosphide (AlGaInP) Gallium(III) phosphide (GaP)

Orange 590 < λ < 6102.03 < ΔV < 2.10 Gallium arsenide phosphide (GaAsP)

Aluminium gallium indium phosphide (AlGaInP) Gallium(III) phosphide (GaP)

Yellow 570 < λ < 5902.10 < ΔV < 2.18 Gallium arsenide phosphide (GaAsP)

Aluminium gallium indium phosphide (AlGaInP) Gallium(III) phosphide (GaP)

Green 500 < λ < 5701.9 [79] < ΔV < 4.0 Indium gallium nitride (InGaN) / Gallium(III) nitride (GaN)

Gallium(III) phosphide (GaP) Aluminium gallium indium phosphide (AlGaInP) Aluminium gallium phosphide (AlGaP)

Blue 450 < λ < 5002.48 < ΔV < 3.7 Zinc selenide (ZnSe)

Indium gallium nitride (InGaN) Silicon carbide (SiC) as substrate Silicon (Si) as substrate — (under development)

Violet 400 < λ < 4502.76 < ΔV < 4.0 Indium gallium nitride (InGaN)
Purple multiple types2.48 < ΔV < 3.7Dual blue/red LEDs,

blue with red phosphor, or white with purple plastic

Ultraviolet λ < 4003.1 < ΔV < 4.4 Diamond (235 nm) [80]

Boron nitride (215 nm) [81] [82] Aluminium nitride (AlN) (210 nm) [83]

Aluminium gallium nitride (AlGaN) Aluminium gallium indium nitride (AlGaInN) — (down to 210 nm) [84]

WhiteBroad spectrum2.7 < ΔV < 3.5Blue diode with yellow phosphor or violet/UV diode with multi-color phosphor  

Applications

Daytime running light LEDs of an automobile LED DaytimeRunningLights.jpg
Daytime running light LEDs of an automobile

LED uses fall into five major categories:

The application of LEDs in horticulture has revolutionized plant cultivation by providing energy-efficient, customizable lighting solutions that optimize plant growth and development. [91] LEDs offer precise control over light spectra, intensity, and photoperiods, enabling growers to tailor lighting conditions to the specific needs of different plant species and growth stages. This technology enhances photosynthesis, improves crop yields, and reduces energy costs compared to traditional lighting systems. Additionally, LEDs generate less heat, allowing closer placement to plants without risking thermal damage, and contribute to sustainable farming practices by lowering carbon footprints and extending growing seasons in controlled environments. [92] Light spectrum affects growth, metabolite profile, and resistance against fungal phytopathogens of Solanum lycopersicum seedlings. [93] LEDs can also be used in micropropagation. [94]

Indicators and signs

The low energy consumption, low maintenance and small size of LEDs has led to uses as status indicators and displays on a variety of equipment and installations. Large-area LED displays are used as stadium displays, dynamic decorative displays, and dynamic message signs on freeways. Thin, lightweight message displays are used at airports and railway stations, and as destination displays for trains, buses, trams, and ferries.

Red and green LED traffic signals Red and green traffic signals, Stamford Road, Singapore - 20111210.jpg
Red and green LED traffic signals

One-color light is well suited for traffic lights and signals, exit signs, emergency vehicle lighting, ships' navigation lights, and LED-based Christmas lights

Because of their long life, fast switching times, and visibility in broad daylight due to their high output and focus, LEDs have been used in automotive brake lights and turn signals. The use in brakes improves safety, due to a great reduction in the time needed to light fully, or faster rise time, about 0.1 second faster[ citation needed ] than an incandescent bulb. This gives drivers behind more time to react. In a dual intensity circuit (rear markers and brakes) if the LEDs are not pulsed at a fast enough frequency, they can create a phantom array, where ghost images of the LED appear if the eyes quickly scan across the array. White LED headlamps are beginning to appear. Using LEDs has styling advantages because LEDs can form much thinner lights than incandescent lamps with parabolic reflectors.

Due to the relative cheapness of low output LEDs, they are also used in many temporary uses such as glowsticks and throwies. Artists have also used LEDs for LED art.

Lighting

With the development of high-efficiency and high-power LEDs, it has become possible to use LEDs in lighting and illumination. To encourage the shift to LED lamps and other high-efficiency lighting, in 2008 the US Department of Energy created the L Prize competition. The Philips Lighting North America LED bulb won the first competition on August 3, 2011, after successfully completing 18 months of intensive field, lab, and product testing. [95]

Efficient lighting is needed for sustainable architecture. As of 2011, some LED bulbs provide up to 150 lm/W and even inexpensive low-end models typically exceed 50 lm/W, so that a 6-watt LED could achieve the same results as a standard 40-watt incandescent bulb. The lower heat output of LEDs also reduces demand on air conditioning systems. Worldwide, LEDs are rapidly adopted to displace less effective sources such as incandescent lamps and CFLs and reduce electrical energy consumption and its associated emissions. Solar powered LEDs are used as street lights and in architectural lighting.

The mechanical robustness and long lifetime are used in automotive lighting on cars, motorcycles, and bicycle lights. LED street lights are employed on poles and in parking garages. In 2007, the Italian village of Torraca was the first place to convert its street lighting to LEDs. [96]

Cabin lighting on recent[ when? ] Airbus and Boeing jetliners uses LED lighting. LEDs are also being used in airport and heliport lighting. LED airport fixtures currently include medium-intensity runway lights, runway centerline lights, taxiway centerline and edge lights, guidance signs, and obstruction lighting.

LEDs are also used as a light source for DLP projectors, and to backlight newer LCD television (referred to as LED TV), computer monitor (including laptop) and handheld device LCDs, succeeding older CCFL-backlit LCDs although being superseded by OLED screens. RGB LEDs raise the color gamut by as much as 45%. Screens for TV and computer displays can be made thinner using LEDs for backlighting. [97]

LEDs are small, durable and need little power, so they are used in handheld devices such as flashlights. LED strobe lights or camera flashes operate at a safe, low voltage, instead of the 250+ volts commonly found in xenon flashlamp-based lighting. This is especially useful in cameras on mobile phones, where space is at a premium and bulky voltage-raising circuitry is undesirable.

LEDs are used for infrared illumination in night vision uses including security cameras. A ring of LEDs around a video camera, aimed forward into a retroreflective background, allows chroma keying in video productions.

LED for miners, to increase visibility inside mines LED for mines.jpg
LED for miners, to increase visibility inside mines
Los Angeles Vincent Thomas Bridge illuminated with blue LEDs Los Angeles Bridge.jpg
Los Angeles Vincent Thomas Bridge illuminated with blue LEDs

LEDs are used in mining operations, as cap lamps to provide light for miners. Research has been done to improve LEDs for mining, to reduce glare and to increase illumination, reducing risk of injury to the miners. [98]

LEDs are increasingly finding uses in medical and educational applications, for example as mood enhancement. [99] NASA has even sponsored research for the use of LEDs to promote health for astronauts. [100]

Data communication and other signalling

Light can be used to transmit data and analog signals. For example, lighting white LEDs can be used in systems assisting people to navigate in closed spaces while searching necessary rooms or objects. [101]

Assistive listening devices in many theaters and similar spaces use arrays of infrared LEDs to send sound to listeners' receivers. Light-emitting diodes (as well as semiconductor lasers) are used to send data over many types of fiber optic cable, from digital audio over TOSLINK cables to the very high bandwidth fiber links that form the Internet backbone. For some time, computers were commonly equipped with IrDA interfaces, which allowed them to send and receive data to nearby machines via infrared.

Because LEDs can cycle on and off millions of times per second, very high data bandwidth can be achieved. [102] For that reason, visible light communication (VLC) has been proposed as an alternative to the increasingly competitive radio bandwidth. [103] VLC operates in the visible part of the electromagnetic spectrum, so data can be transmitted without occupying the frequencies of radio communications.

Machine vision systems

Machine vision systems often require bright and homogeneous illumination, so features of interest are easier to process. LEDs are often used.

Barcode scanners are the most common example of machine vision applications, and many of those scanners use red LEDs instead of lasers. Optical computer mice use LEDs as a light source for the miniature camera within the mouse.

LEDs are useful for machine vision because they provide a compact, reliable source of light. LED lamps can be turned on and off to suit the needs of the vision system, and the shape of the beam produced can be tailored to match the system's requirements.

Biological detection

The discovery of radiative recombination in aluminum gallium nitride (AlGaN) alloys by U.S. Army Research Laboratory (ARL) led to the conceptualization of UV light-emitting diodes (LEDs) to be incorporated in light-induced fluorescence sensors used for biological agent detection. [104] [105] [106] In 2004, the Edgewood Chemical Biological Center (ECBC) initiated the effort to create a biological detector named TAC-BIO. The program capitalized on semiconductor UV optical sources (SUVOS) developed by the Defense Advanced Research Projects Agency (DARPA). [106]

UV-induced fluorescence is one of the most robust techniques used for rapid real-time detection of biological aerosols. [106] The first UV sensors were lasers lacking in-field-use practicality. In order to address this, DARPA incorporated SUVOS technology to create a low-cost, small, lightweight, low-power device. The TAC-BIO detector's response time was one minute from when it sensed a biological agent. It was also demonstrated that the detector could be operated unattended indoors and outdoors for weeks at a time. [106]

Aerosolized biological particles fluoresce and scatter light under a UV light beam. Observed fluorescence is dependent on the applied wavelength and the biochemical fluorophores within the biological agent. UV induced fluorescence offers a rapid, accurate, efficient and logistically practical way for biological agent detection. This is because the use of UV fluorescence is reagentless, or a process that does not require an added chemical to produce a reaction, with no consumables, or produces no chemical byproducts. [106]

Additionally, TAC-BIO can reliably discriminate between threat and non-threat aerosols. It was claimed to be sensitive enough to detect low concentrations, but not so sensitive that it would cause false positives. The particle-counting algorithm used in the device converted raw data into information by counting the photon pulses per unit of time from the fluorescence and scattering detectors, and comparing the value to a set threshold. [107]

The original TAC-BIO was introduced in 2010, while the second-generation TAC-BIO GEN II, was designed in 2015 to be more cost-efficient, as plastic parts were used. Its small, light-weight design allows it to be mounted to vehicles, robots, and unmanned aerial vehicles. The second-generation device could also be utilized as an environmental detector to monitor air quality in hospitals, airplanes, or even in households to detect fungus and mold. [108] [109]

Other applications

LED costume for stage performers LED Costume by Beo Beyond.jpg
LED costume for stage performers
LED wallpaper by Meystyle Digitally printed LED wallpaper Dolomites.jpg
LED wallpaper by Meystyle
A large LED display behind a disc jockey LED screen behind Tsach Zimroni in Tel Aviv Israel.jpg
A large LED display behind a disc jockey
Seven-segment display that can display four digits and points LED Digital Display.jpg
Seven-segment display that can display four digits and points
LED panel light source used in an early experiment on potato growth during Shuttle mission STS-73 to investigate the potential for growing food on future long duration missions LED panel and plants.jpg
LED panel light source used in an early experiment on potato growth during Shuttle mission STS-73 to investigate the potential for growing food on future long duration missions

The light from LEDs can be modulated very quickly so they are used extensively in optical fiber and free space optics communications. This includes remote controls, such as for television sets, where infrared LEDs are often used. Opto-isolators use an LED combined with a photodiode or phototransistor to provide a signal path with electrical isolation between two circuits. This is especially useful in medical equipment where the signals from a low-voltage sensor circuit (usually battery-powered) in contact with a living organism must be electrically isolated from any possible electrical failure in a recording or monitoring device operating at potentially dangerous voltages. An optoisolator also lets information be transferred between circuits that do not share a common ground potential.

Many sensor systems rely on light as the signal source. LEDs are often ideal as a light source due to the requirements of the sensors. The Nintendo Wii's sensor bar uses infrared LEDs. Pulse oximeters use them for measuring oxygen saturation. Some flatbed scanners use arrays of RGB LEDs rather than the typical cold-cathode fluorescent lamp as the light source. Having independent control of three illuminated colors allows the scanner to calibrate itself for more accurate color balance, and there is no need for warm-up. Further, its sensors only need be monochromatic, since at any one time the page being scanned is only lit by one color of light.

Since LEDs can also be used as photodiodes, they can be used for both photo emission and detection. This could be used, for example, in a touchscreen that registers reflected light from a finger or stylus. [110] Many materials and biological systems are sensitive to, or dependent on, light. Grow lights use LEDs to increase photosynthesis in plants, [111] and bacteria and viruses can be removed from water and other substances using UV LEDs for sterilization. [15] LEDs of certain wavelengths have also been used for light therapy treatment of neonatal jaundice and acne. [112]

UV LEDs, with spectra range of 220 nm to 395 nm, have other applications, such as water/air purification, surface disinfection, glue curing, free-space non-line-of-sight communication, high performance liquid chromatography, UV curing dye printing, phototherapy (295nm Vitamin D, 308nm Excimer lamp or laser replacement), medical/ analytical instrumentation, and DNA absorption. [105] [113]

LEDs have also been used as a medium-quality voltage reference in electronic circuits. The forward voltage drop (about 1.7 V for a red LED or 1.2V for an infrared) can be used instead of a Zener diode in low-voltage regulators. Red LEDs have the flattest I/V curve above the knee. Nitride-based LEDs have a fairly steep I/V curve and are useless for this purpose. Although LED forward voltage is far more current-dependent than a Zener diode, Zener diodes with breakdown voltages below 3 V are not widely available.

The progressive miniaturization of low-voltage lighting technology, such as LEDs and OLEDs, suitable to incorporate into low-thickness materials has fostered experimentation in combining light sources and wall covering surfaces for interior walls in the form of LED wallpaper.

Research and development

Key challenges

LEDs require optimized efficiency to hinge on ongoing improvements such as phosphor materials and quantum dots. [114]

The process of down-conversion (the method by which materials convert more-energetic photons to different, less energetic colors) also needs improvement. For example, the red phosphors that are used today are thermally sensitive and need to be improved in that aspect so that they do not color shift and experience efficiency drop-off with temperature. Red phosphors could also benefit from a narrower spectral width to emit more lumens and becoming more efficient at converting photons. [115]

In addition, work remains to be done in the realms of current efficiency droop, color shift, system reliability, light distribution, dimming, thermal management, and power supply performance. [114]

Early suspicions were that the LED droop was caused by elevated temperatures. Scientists showed that temperature was not the root cause of efficiency droop. [116] The mechanism causing efficiency droop was identified in 2007 as Auger recombination, which was taken with mixed reaction. [66] A 2013 study conclusively identified Auger recombination as the cause. [117]

Potential technology

A new family of LEDs are based on the semiconductors called perovskites. In 2018, less than four years after their discovery, the ability of perovskite LEDs (PLEDs) to produce light from electrons already rivaled those of the best performing OLEDs. [118] They have a potential for cost-effectiveness as they can be processed from solution, a low-cost and low-tech method, which might allow perovskite-based devices that have large areas to be made with extremely low cost. Their efficiency is superior by eliminating non-radiative losses, in other words, elimination of recombination pathways that do not produce photons; or by solving outcoupling problem (prevalent for thin-film LEDs) or balancing charge carrier injection to increase the EQE (external quantum efficiency). The most up-to-date PLED devices have broken the performance barrier by shooting the EQE above 20%. [119]

In 2018, Cao et al. and Lin et al. independently published two papers on developing perovskite LEDs with EQE greater than 20%, which made these two papers a mile-stone in PLED development. Their device have similar planar structure, i.e. the active layer (perovskite) is sandwiched between two electrodes. To achieve a high EQE, they not only reduced non-radiative recombination, but also utilized their own, subtly different methods to improve the EQE. [119]

In the work of Cao et al., [120] researchers targeted the outcoupling problem, which is that the optical physics of thin-film LEDs causes the majority of light generated by the semiconductor to be trapped in the device. [121] To achieve this goal, they demonstrated that solution-processed perovskites can spontaneously form submicrometre-scale crystal platelets, which can efficiently extract light from the device. These perovskites are formed via the introduction of amino acid additives into the perovskite precursor solutions. In addition, their method is able to passivate perovskite surface defects and reduce nonradiative recombination. Therefore, by improving the light outcoupling and reducing nonradiative losses, Cao and his colleagues successfully achieved PLED with EQE up to 20.7%. [120]

Lin and his colleague used a different approach to generate high EQE. Instead of modifying the microstructure of perovskite layer, they chose to adopt a new strategy for managing the compositional distribution in the device—an approach that simultaneously provides high luminescence and balanced charge injection. In other words, they still used flat emissive layer, but tried to optimize the balance of electrons and holes injected into the perovskite, so as to make the most efficient use of the charge carriers. Moreover, in the perovskite layer, the crystals are perfectly enclosed by MABr additive (where MA is CH3NH3). The MABr shell passivates the nonradiative defects that would otherwise be present perovskite crystals, resulting in reduction of the nonradiative recombination. Therefore, by balancing charge injection and decreasing nonradiative losses, Lin and his colleagues developed PLED with EQE up to 20.3%. [122]

Health and safety

Certain blue LEDs and cool-white LEDs can exceed safe limits of the so-called blue-light hazard as defined in eye safety specifications such as "ANSI/IESNA RP-27.1–05: Recommended Practice for Photobiological Safety for Lamp and Lamp Systems". [123] One study showed no evidence of a risk in normal use at domestic illuminance, [124] and that caution is only needed for particular occupational situations or for specific populations. [125] In 2006, the International Electrotechnical Commission published IEC 62471 Photobiological safety of lamps and lamp systems, replacing the application of early laser-oriented standards for classification of LED sources. [126]

While LEDs have the advantage over fluorescent lamps, in that they do not contain mercury, they may contain other hazardous metals such as lead and arsenic. [127]

In 2016 the American Medical Association (AMA) issued a statement concerning the possible adverse influence of blueish street lighting on the sleep-wake cycle of city-dwellers. Critics in the industry claim exposure levels are not high enough to have a noticeable effect. [128]

Environmental issues

See also

Related Research Articles

<span class="mw-page-title-main">Electroluminescence</span> Optical and electrical phenomenon

Electroluminescence (EL) is an optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emission resulting from heat (incandescence), chemical reactions (chemiluminescence), reactions in a liquid (electrochemiluminescence), sound (sonoluminescence), or other mechanical action (mechanoluminescence), or organic electroluminescence.

<span class="mw-page-title-main">Phosphor</span> Luminescent substance

A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.

<span class="mw-page-title-main">Fluorescent lamp</span> Lamp using fluorescence to produce light

A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, to produce ultraviolet and make a phosphor coating in the lamp glow. Fluorescent lamps convert electrical energy into useful light much more efficiently than incandescent lamps, but are less efficient than most LED lamps. The typical luminous efficacy of fluorescent lamps is 50–100 lumens per watt, several times the efficacy of incandescent bulbs with comparable light output.

<span class="mw-page-title-main">Lighting</span> Deliberate use of light to achieve practical or aesthetic effects

Lighting or illumination is the deliberate use of light to achieve practical or aesthetic effects. Lighting includes the use of both artificial light sources like lamps and light fixtures, as well as natural illumination by capturing daylight. Daylighting is sometimes used as the main source of light during daytime in buildings. This can save energy in place of using artificial lighting, which represents a major component of energy consumption in buildings. Proper lighting can enhance task performance, improve the appearance of an area, or have positive psychological effects on occupants.

<span class="mw-page-title-main">Flashlight</span> Portable hand-held electric light

A flashlight or electric torch, usually shortened to torch, is a portable hand-held electric lamp. Formerly, the light source typically was a miniature incandescent light bulb, but these have been displaced by light-emitting diodes (LEDs) since the early 2000s. A typical flashlight consists of the light source mounted in a reflector, a transparent cover to protect the light source and reflector, a battery, and a switch, all enclosed in a case.

<span class="mw-page-title-main">Neon lamp</span> Light source based on gas discharge

A neon lamp is a miniature gas-discharge lamp. The lamp typically consists of a small glass capsule that contains a mixture of neon and other gases at a low pressure and two electrodes. When sufficient voltage is applied and sufficient current is supplied between the electrodes, the lamp produces an orange glow discharge. The glowing portion in the lamp is a thin region near the cathode; the larger and much longer neon signs are also glow discharges, but they use the positive column which is not present in the ordinary neon lamp. Neon glow lamps were widely used as indicator lamps in the displays of electronic instruments and appliances. They are still sometimes used for their electrical simplicity in high-voltage circuits.

<span class="mw-page-title-main">Blacklight</span> Light fixture that emits long-wave ultraviolet light and very little visible light

A blacklight, also called a UV-A light, Wood's lamp, or ultraviolet light, is a lamp that emits long-wave (UV-A) ultraviolet light and very little visible light. One type of lamp has a violet filter material, either on the bulb or in a separate glass filter in the lamp housing, which blocks most visible light and allows through UV, so the lamp has a dim violet glow when operating. Blacklight lamps which have this filter have a lighting industry designation that includes the letters "BLB". This stands for "blacklight blue". A second type of lamp produces ultraviolet but does not have the filter material, so it produces more visible light and has a blue color when operating. These tubes are made for use in "bug zapper" insect traps, and are identified by the industry designation "BL". This stands for "blacklight".

<span class="mw-page-title-main">High-intensity discharge lamp</span> Type of electric lamp/bulb

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<span class="mw-page-title-main">Mercury-vapor lamp</span> Light source using an electric arc through mercury vapor

A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate glass bulb. The outer bulb may be clear or coated with a phosphor; in either case, the outer bulb provides thermal insulation, protection from the ultraviolet radiation the light produces, and a convenient mounting for the fused quartz arc tube.

<span class="mw-page-title-main">Germicidal lamp</span> Ultraviolet C light-emitting device

A germicidal lamp is an electric light that produces ultraviolet C (UVC) light. This short-wave ultraviolet light disrupts DNA base pairing, causing formation of pyrimidine dimers, and leads to the inactivation of bacteria, viruses, and protozoans. It can also be used to produce ozone for water disinfection. They are used in ultraviolet germicidal irradiation (UVGI).

<span class="mw-page-title-main">Compact fluorescent lamp</span> Fluorescent lamps with folded tubes, often with built-in ballast

A compact fluorescent lamp (CFL), also called compact fluorescent light, energy-saving light and compact fluorescent tube, is a fluorescent lamp designed to replace an incandescent light bulb; some types fit into light fixtures designed for incandescent bulbs. The lamps use a tube that is curved or folded to fit into the space of an incandescent bulb, and a compact electronic ballast in the base of the lamp.

<span class="mw-page-title-main">Blue laser</span> Laser which emits light with blue wavelengths

A blue laser emits electromagnetic radiation with a wavelength between 400 and 500 nanometers, which the human eye sees in the visible spectrum as blue or violet.

<span class="mw-page-title-main">Solid-state lighting</span> Lighting technology

Solid-state lighting (SSL) is a type of lighting that uses semiconductor light-emitting diodes (LEDs), organic light-emitting diodes (OLED), or polymer light-emitting diodes (PLED) as sources of illumination rather than electrical filaments, plasma, or gas.

Nichia Corporation is a Japanese chemical engineering and manufacturing company headquartered in Anan, Japan with global subsidiaries. It specializes in the manufacturing and distribution of phosphors, including light-emitting diodes (LEDs), laser diodes, battery materials, and calcium chloride.

<span class="mw-page-title-main">LED lamp</span> Electric light that produces light using LEDs

An LED lamp or LED light is an electric light that produces light using light-emitting diodes (LEDs). LED lamps are significantly more energy-efficient than equivalent incandescent lamps and fluorescent lamps. The most efficient commercially available LED lamps have efficiencies exceeding 200 lumens per watt (lm/W) and convert more than half the input power into light. Commercial LED lamps have a lifespan several times longer than both incandescent and fluorescent lamps.

<span class="mw-page-title-main">Holiday lighting technology</span> Decorative lighting for festivities

Holiday lighting technology has been subject to considerable development and variation since the replacement of candles by electric lights. While originally used during the Christmas holidays as Christmas lights, modern electric light arrays have become popular around the world in many cultures and are used both during religious festivals and for other purposes unconnected to any festivities.

<span class="mw-page-title-main">Dental curing light</span> Dental equipment

A dental curing light is a piece of dental equipment that is used for polymerization of light-cure resin-based composites. It can be used on several different dental materials that are curable by light. The light used falls under the visible blue light spectrum. This light is delivered over a range of wavelengths and varies for each type of device. There are four basic types of dental curing light sources: tungsten halogen, light-emitting diodes (LED), plasma arcs, and lasers. The two most common are halogen and LEDs.

<span class="mw-page-title-main">LED filament</span>

A LED filament light bulb is a LED lamp which is designed to resemble a traditional incandescent light bulb with visible filaments for aesthetic and light distribution purposes, but with the high efficiency of light-emitting diodes (LEDs). The name comes from their strings of many close-spaced series-connected diodes, which resemble the filaments of incandescent light bulbs much closer than previous bulbs with many LEDs. They are made as direct replacements for conventional incandescent bulbs, as they are made in the same shapes, they use the same bases that fit the same sockets, and they work at the same supply voltage. They may be used for their appearance, similar when lit to a clear incandescent bulb, or for their wide angle of light distribution, typically 300°. They are also more efficient than many other LED lamps.

Light-emitting diodes (LEDs) produce light by the recombination of electrons and electron holes in a semiconductor, a process called "electroluminescence". The wavelength of the light produced depends on the energy band gap of the semiconductors used. Since these materials have a high index of refraction, design features of the devices such as special optical coatings and die shape are required to efficiently emit light. A LED is a long-lived light source, but certain mechanisms can cause slow loss of efficiency of the device or sudden failure. The wavelength of the light emitted is a function of the band gap of the semiconductor material used; materials such as gallium arsenide, and others, with various trace doping elements, are used to produce different colors of light. Another type of LED uses a quantum dot which can have its properties and wavelength adjusted by its size. Light-emitting diodes are widely used in indicator and display functions, and white LEDs are displacing other technologies for general illumination purposes.

<span class="mw-page-title-main">History of the LED</span> History of semiconductor light source

The first Light-Emitting Diode (LED) was created in 1927 by Russian inventor Oleg Losev, and used silicon carbide as a semiconductor. However, electroluminescence as a phenomenon was discovered twenty years earlier by the English experimenter Henry Joseph Round of Marconi Labs, using the same crystal and a cat's-whisker detector. Despite having distributed his report in Soviet, German and British scientific journals, Losev's LED found no practical use for several decades, partly due to the very inefficient light-producing properties the semiconductor used.

References

  1. "HJ Round was a pioneer in the development of the LED". www.myledpassion.com. Archived from the original on October 28, 2020. Retrieved April 11, 2017.
  2. "The life and times of the LED — a 100-year history" (PDF). The Optoelectronics Research Centre, University of Southampton. April 2007. Archived from the original (PDF) on September 15, 2012. Retrieved September 4, 2012.
  3. US Patent 3293513, "Semiconductor Radiant Diode", James R. Biard and Gary Pittman, Filed on Aug. 8th, 1962, Issued on Dec. 20th, 1966.
  4. "Inventor of Long-Lasting, Low-Heat Light Source Awarded $500,000 Lemelson-MIT Prize for Invention". Washington, D.C. Massachusetts Institute of Technology. April 21, 2004. Archived from the original on October 9, 2011. Retrieved December 21, 2011.
  5. Edwards, Kimberly D. "Light Emitting Diodes" (PDF). University of California, Irvine . p. 2. Archived from the original (PDF) on February 14, 2019. Retrieved January 12, 2019.
  6. Lighting Research Center. "How is white light made with LEDs?". Rensselaer Polytechnic Institute . Archived from the original on May 2, 2021. Retrieved January 12, 2019.
  7. Okon, Thomas M.; Biard, James R. (2015). "The First Practical LED" (PDF). EdisonTechCenter.org. Edison Tech Center . Retrieved February 2, 2016.
  8. Peláez, E. A; Villegas, E. R (2007). "LED power reduction trade-offs for ambulatory pulse oximetry". 2007 29th Annual International Conference of the IEEE Engineering in Medicine and Biology Society. Vol. 2007. pp. 2296–9. doi:10.1109/IEMBS.2007.4352784. ISBN   978-1-4244-0787-3. ISSN   1557-170X. PMID   18002450. S2CID   34626885.
  9. Lossev, O.V. (November 1928). "CII. Luminous carborundum detector and detection effect and oscillations with crystals". The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science. 6 (39): 1024–1044. doi:10.1080/14786441108564683. ISSN   1941-5982.
  10. Yao, H. Walter; Schubert, E. Fred; United States; AIXTRON, Inc; Society of Photo-optical Instrumentation Engineers, eds. (2001). Light-emitting diodes: research, manufacturing, and applications V: 24-25 January 2001, San Jose, USA. SPIE proceedings series. Bellingham, Wash: SPIE. ISBN   978-0-8194-3956-7. OCLC   47203707.
  11. Pearsall, Thomas (2010). Photonics Essentials, 2nd edition. McGraw-Hill. ISBN   978-0-07-162935-5. Archived from the original on August 17, 2021. Retrieved February 25, 2021.
  12. "LED Basics | Department of Energy". www.energy.gov. Retrieved October 22, 2018.
  13. "LED Spectral Distribution". optiwave.com. July 25, 2013. Retrieved June 20, 2017.
  14. Cooke, Mike (April–May 2010). "Going Deep for UV Sterilization LEDs" (PDF). Semiconductor Today. 5 (3): 82. Archived from the original (PDF) on May 15, 2013.
  15. 1 2 Mori, M.; Hamamoto, A.; Takahashi, A.; Nakano, M.; Wakikawa, N.; Tachibana, S.; Ikehara, T.; Nakaya, Y.; Akutagawa, M.; Kinouchi, Y. (2007). "Development of a new water sterilization device with a 365 nm UV-LED". Medical & Biological Engineering & Computing. 45 (12): 1237–1241. doi: 10.1007/s11517-007-0263-1 . PMID   17978842. S2CID   2821545.
  16. Taniyasu, Y.; Kasu, M.; Makimoto, T. (2006). "An aluminium nitride light-emitting diode with a wavelength of 210 nanometres". Nature. 441 (7091): 325–328. Bibcode:2006Natur.441..325T. doi:10.1038/nature04760. PMID   16710416. S2CID   4373542.
  17. Kubota, Y.; Watanabe, K.; Tsuda, O.; Taniguchi, T. (2007). "Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure". Science. 317 (5840): 932–934. Bibcode:2007Sci...317..932K. doi: 10.1126/science.1144216 . PMID   17702939.
  18. Watanabe, K.; Taniguchi, T.; Kanda, H. (2004). "Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal". Nature Materials. 3 (6): 404–409. Bibcode:2004NatMa...3..404W. doi:10.1038/nmat1134. PMID   15156198. S2CID   23563849.
  19. Koizumi, S.; Watanabe, K.; Hasegawa, M.; Kanda, H. (2001). "Ultraviolet Emission from a Diamond pn Junction". Science. 292 (5523): 1899–1901. Bibcode:2001Sci...292.1899K. doi:10.1126/science.1060258. PMID   11397942. S2CID   10675358.
  20. "Seeing Red with PFS Phosphor".
  21. "GE Lighting manufactures PFS red phosphor for LED display backlight applications". March 31, 2015.
  22. Murphy, James E.; Garcia-Santamaria, Florencio; Setlur, Anant A.; Sista, Srinivas (2015). "62.4: PFS, K2SiF6:Mn4+: The Red-line Emitting LED Phosphor behind GE's TriGain Technology™ Platform". Sid Symposium Digest of Technical Papers. 46: 927–930. doi:10.1002/sdtp.10406.
  23. Dutta, Partha S.; Liotta, Kathryn M. (2018). "Full Spectrum White LEDs of Any Color Temperature with Color Rendering Index Higher Than 90 Using a Single Broad-Band Phosphor". ECS Journal of Solid State Science and Technology. 7: R3194–R3198. doi: 10.1149/2.0251801jss . S2CID   103600941.
  24. Cho, Jaehee; Park, Jun Hyuk; Kim, Jong Kyu; Schubert, E. Fred (2017). "White light-emitting diodes: History, progress, and future". Laser & Photonics Reviews. 11 (2): 1600147. Bibcode:2017LPRv...1100147C. doi:10.1002/lpor.201600147. ISSN   1863-8880. S2CID   53645208.
  25. Light-Emitting Diodes (3rd Edition, 2018). E. Fred Schubert. February 3, 2018. ISBN   978-0-9863826-6-6.
  26. Additive Manufacturing and Strategic Technologies in Advanced Ceramics. John Wiley & Sons. August 16, 2016. ISBN   978-1-119-23600-9.
  27. Moreno, I.; Contreras, U. (2007). "Color distribution from multicolor LED arrays". Optics Express. 15 (6): 3607–3618. Bibcode:2007OExpr..15.3607M. doi: 10.1364/OE.15.003607 . PMID   19532605. S2CID   35468615.
  28. Yeh, Dong-Ming; Huang, Chi-Feng; Lu, Chih-Feng; Yang, Chih-Chung. "Making white-light-emitting diodes without phosphors | SPIE Homepage: SPIE". spie.org. Retrieved April 7, 2019.
  29. Cabrera, Rowan (2019). Electronic Devices and Circuits. EDTECH. ISBN   978-1839473838.
  30. Schubert, E. Fred; Kim, Jong Kyu (2005). "Solid-State Light Sources Getting Smart" (PDF). Science. 308 (5726): 1274–1278. Bibcode:2005Sci...308.1274S. doi:10.1126/science.1108712. PMID   15919985. S2CID   6354382. Archived from the original (PDF) on February 5, 2016.
  31. Nimz, Thomas; Hailer, Fredrik; Jensen, Kevin (November 2012). "Sensors and Feedback Control of Multicolor LED Systems". Led Professional Review: Trends & Technologie for Future Lighting Solutions (34). LED Professional: 2–5. ISSN   1993-890X. Archived from the original (PDF) on April 29, 2014.
  32. Tanabe, S.; Fujita, S.; Yoshihara, S.; Sakamoto, A.; Yamamoto, S. (2005). "YAG glass-ceramic phosphor for white LED (II): Luminescence characteristics" (PDF). In Ferguson, Ian T; Carrano, John C; Taguchi, Tsunemasa; Ashdown, Ian E (eds.). Fifth International Conference on Solid State Lighting. Vol. 5941. p. 594112. Bibcode:2005SPIE.5941..193T. doi:10.1117/12.614681. S2CID   38290951. Archived from the original (PDF) on May 11, 2011.{{cite book}}: |journal= ignored (help)
  33. Ohno, Y. (2004). Ferguson, Ian T; Narendran, Nadarajah; Denbaars, Steven P; Carrano, John C (eds.). "Color rendering and luminous efficacy of white LED spectra" (PDF). Proc. SPIE. Fourth International Conference on Solid State Lighting. 5530: 89. Bibcode:2004SPIE.5530...88O. doi:10.1117/12.565757. S2CID   122777225. Archived from the original (PDF) on May 11, 2011.
  34. Next-Generation GaN-on-Si White LEDs Suppress Costs, Electronic Design, 19 November 2013
  35. GaN-on-Silicon LEDs Forecast to Increase Market Share to 40 Percent by 2020, iSuppli, 4 December 2013
  36. "All You Want to Know about RGBW LED Light". AGC Lighting.
  37. "Tunable White Application Note". enlightedinc.com.
  38. "2021 How Green Light Can Maximize the Quality of Tunable White – LEDucation".
  39. 1 2 "Understanding LED Color-Tunable Products". Energy.gov.
  40. Whitaker, Tim (December 6, 2002). "Joint venture to make ZnSe white LEDs" . Retrieved January 3, 2009.
  41. Burroughes, J. H.; Bradley, D. D. C.; Brown, A. R.; Marks, R. N.; MacKay, K.; Friend, R. H.; Burns, P. L.; Holmes, A. B. (1990). "Light-emitting diodes based on conjugated polymers". Nature. 347 (6293): 539–541. Bibcode:1990Natur.347..539B. doi:10.1038/347539a0. S2CID   43158308.
  42. 1 2 Kho, Mu-Jeong; Javed, T.; Mark, R.; Maier, E.; David, C (March 4, 2008). Final Report: OLED Solid State Lighting. Kodak European Research. Cambridge Science Park, Cambridge, UK.
  43. 1 2 Bardsley, J. N. (2004). "International OLED Technology Roadmap". IEEE Journal of Selected Topics in Quantum Electronics. 10 (1): 3–4. Bibcode:2004IJSTQ..10....3B. doi:10.1109/JSTQE.2004.824077. S2CID   30084021.
  44. Hebner, T. R.; Wu, C. C.; Marcy, D.; Lu, M. H.; Sturm, J. C. (1998). "Ink-jet printing of doped polymers for organic light emitting devices". Applied Physics Letters. 72 (5): 519. Bibcode:1998ApPhL..72..519H. doi:10.1063/1.120807. S2CID   119648364.
  45. Bharathan, J.; Yang, Y. (1998). "Polymer electroluminescent devices processed by inkjet printing: I. Polymer light-emitting logo". Applied Physics Letters. 72 (21): 2660. Bibcode:1998ApPhL..72.2660B. doi:10.1063/1.121090. S2CID   44128025.
  46. Gustafsson, G.; Cao, Y.; Treacy, G. M.; Klavetter, F.; Colaneri, N.; Heeger, A. J. (1992). "Flexible light-emitting diodes made from soluble conducting polymers". Nature. 357 (6378): 477–479. Bibcode:1992Natur.357..477G. doi:10.1038/357477a0. S2CID   4366944.
  47. LED-design. Elektor.com. Retrieved on March 16, 2012. Archived August 31, 2012, at the Wayback Machine
  48. "OSRAM Radial T1 3/4, SFH 4546 IR LEDs - ams-osram - ams". ams-osram. Retrieved September 19, 2024.
  49. "LED Through Hole 5mm (T-1 3/4) Red Built-in resistor 635 nm 4500 mcd 12V". VCC. Retrieved September 19, 2024.
  50. "Luminus Products". Luminus Devices. Archived from the original on July 25, 2008. Retrieved October 21, 2009.
  51. "Luminus Products CST-90 Series Datasheet" (PDF). Luminus Devices. Archived from the original (PDF) on March 31, 2010. Retrieved October 25, 2009.
  52. 1 2 "Xlamp Xp-G Led". Cree.com. Cree, Inc. Archived from the original on March 13, 2012. Retrieved March 16, 2012.
  53. High Power Point Source White Led NVSx219A Archived July 29, 2021, at the Wayback Machine . Nichia.co.jp, November 2, 2010.
  54. "Seoul Semiconductor launches AC LED lighting source Acrich". LEDS Magazine. November 17, 2006. Archived from the original on October 15, 2007. Retrieved February 17, 2008.
  55. 1 2 Visibility, Environmental, and Astronomical Issues Associated with Blue-Rich White Outdoor Lighting (PDF). International Dark-Sky Association. May 4, 2010. Archived from the original (PDF) on January 16, 2013.
  56. Oskay, Windell (June 22, 2011). "Does this LED sound funny to you?". Evil Mad Scientist Laboratories. Archived from the original on September 24, 2023. Retrieved January 30, 2024.
  57. Tim's Blog (January 14, 2024). "Revisiting Candle Flicker-LEDs: Now with integrated Timer". cpldcpu.wordpress.com. Archived from the original on January 29, 2024. Retrieved January 30, 2024.
  58. Ting, Hua-Nong (June 17, 2011). 5th Kuala Lumpur International Conference on Biomedical Engineering 2011: BIOMED 2011, 20–23 June 2011, Kuala Lumpur, Malaysia. Springer Science & Business Media. ISBN   9783642217296.
  59. "The Next Generation of LED Filament Bulbs". LEDInside.com. Trendforce. Retrieved October 26, 2015.
  60. Archived at Ghostarchive and the Wayback Machine : "LED Filaments". YouTube . April 5, 2015. Retrieved October 26, 2015.
  61. Handbook on the Physics and Chemistry of Rare Earths: Including Actinides. Elsevier Science. August 1, 2016. p. 89. ISBN   978-0-444-63705-5.
  62. "Corn Lamps: What Are They & Where Can I Use Them?". Shine Retrofits. September 1, 2016. Retrieved December 30, 2018.
  63. "Solid-State Lighting: Comparing LEDs to Traditional Light Sources". eere.energy.gov. Archived from the original on May 5, 2009.
  64. "Dialight Micro LED SMD LED "598 SERIES" Datasheet" (PDF). Dialight.com. Archived from the original (PDF) on February 5, 2009.
  65. The LED Museum. Retrieved on March 16, 2012.
  66. 1 2 Stevenson, Richard (August 2009), "The LED's Dark Secret: Solid-state lighting will not supplant the lightbulb until it can overcome the mysterious malady known as droop". IEEE Spectrum.
  67. Worthey, James A. "How White Light Works". LRO Lighting Research Symposium, Light and Color. Retrieved October 6, 2007.
  68. Narra, Prathyusha; Zinger, D.S. (2004). "An effective LED dimming approach". Conference Record of the 2004 IEEE Industry Applications Conference, 2004. 39th IAS Annual Meeting. Vol. 3. pp. 1671–1676. doi:10.1109/IAS.2004.1348695. ISBN   978-0-7803-8486-6. S2CID   16372401.
  69. "Data Sheet — HLMP-1301, T-1 (3 mm) Diffused LED Lamps". Avago Technologies. Retrieved May 30, 2010.
  70. Hecht, E. (2002). Optics (4 ed.). Addison Wesley. p.  591. ISBN   978-0-19-510818-7.
  71. "LED Light Bars For Off Road Illumination". Larson Electronics.
  72. "LED Design Forum: Avoiding thermal runaway when driving multiple LED strings". LEDs Magazine. April 20, 2009. Retrieved January 17, 2019.
  73. "Lifetime of White LEDs". Archived from the original on April 10, 2009. Retrieved 2009-04-10., US Department of Energy
  74. Lifetime of White LEDs Archived May 28, 2016, at the Wayback Machine . US Department of Energy. (PDF). Retrieved on March 16, 2012.
  75. "In depth: Advantages of LED Lighting". energy.ltgovernors.com. Archived from the original on November 14, 2017. Retrieved July 27, 2012.
  76. Stern, Maike Lorena; Schellenberger, Martin (March 31, 2020). "Fully convolutional networks for chip-wise defect detection employing photoluminescence images". Journal of Intelligent Manufacturing. 32 (1): 113–126. arXiv: 1910.02451 . doi:10.1007/s10845-020-01563-4. ISSN   0956-5515. S2CID   254655125.
  77. Hoque, Md Ashraful; Bradley, Robert Kelley; Fan, Jiajie; Fan, Xuejun (2019). "Effects of humidity and phosphor on silicone/Phosphor composite in white light-emitting diode package". Journal of Materials Science: Materials in Electronics. 30 (23): 20471–20478. doi: 10.1007/s10854-019-02393-8 .
  78. "3-Pad LED Flip Chip COB". LED professional - LED Lighting Technology, Application Magazine. Retrieved February 15, 2024.
  79. OSRAM: green LED
  80. Koizumi, S.; Watanabe, K; Hasegawa, M; Kanda, H (2001). "Ultraviolet Emission from a Diamond pn Junction". Science. 292 (5523): 1899–2701. Bibcode:2001Sci...292.1899K. doi:10.1126/science.1060258. PMID   11397942.
  81. Kubota, Y.; Watanabe, K.; Tsuda, O.; Taniguchi, T. (2007). "Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure". Science. 317 (5840): 932–934. Bibcode:2007Sci...317..932K. doi:10.1126/science.1144216. PMID   17702939.
  82. Watanabe, Kenji; Taniguchi, Takashi; Kanda, Hisao (2004). "Direct-bandgap properties and evidence for ultraviolet lasing of hexagonal boron nitride single crystal". Nature Materials. 3 (6): 404–409. Bibcode:2004NatMa...3..404W. doi:10.1038/nmat1134. PMID   15156198.
  83. Taniyasu, Yoshitaka; Kasu, Makoto; Makimoto, Toshiki (2006). "An aluminium nitride light-emitting diode with a wavelength of 210 nanometres". Nature. 441 (7091): 325–328. Bibcode:2006Natur.441..325T. doi:10.1038/nature04760. PMID   16710416.
  84. "LEDs move into the ultraviolet". physicsworld.com. May 17, 2006. Retrieved August 13, 2007.
  85. European Photonics Industry Consortium (EPIC). This includes use in data communications over fiber optics as well as "broadcast" data or signaling.
  86. Mims, Forrest M. III. "An Inexpensive and Accurate Student Sun Photometer with Light-Emitting Diodes as Spectrally Selective Detectors".
  87. "Water Vapor Measurements with LED Detectors". cs.drexel.edu (2002).
  88. Dziekan, Mike (February 6, 2009) "Using Light-Emitting Diodes as Sensors". soamsci.or. Archived May 31, 2013, at the Wayback Machine
  89. Ben-Ezra, Moshe; Wang, Jiaping; Wilburn, Bennett; Xiaoyang Li; Le Ma (2008). "An LED-only BRDF measurement device". 2008 IEEE Conference on Computer Vision and Pattern Recognition. pp. 1–8. CiteSeerX   10.1.1.165.484 . doi:10.1109/CVPR.2008.4587766. ISBN   978-1-4244-2242-5. S2CID   206591080.
  90. Bantis, Filippos, Sonia Smirnakou, Theoharis Ouzounis, Athanasios Koukounaras, Nikolaos Ntagkas, and Kalliopi Radoglou. "Current status and recent achievements in the field of horticulture with the use of light-emitting diodes (LEDs)." Scientia horticulturae 235 (2018): 437-451.
  91. Miler N., Kulus D., Woźny A., Rymarz D., Hajzer M., Wierzbowski K., Nelke R., Szeffs L., 2019. Application of wide-spectrum light-emitting diodes in micropropagation of popular ornamental plant species: A study on plant quality and cost reduction. In Vitro Cellular and Developmental Biology – Plant 55: 99-108. https://doi.org/10.1007/s11627-018-9939-5
  92. Tymoszuk A., Kulus D., Błażejewska A., Nadolan K., Kulpińska A., Pietrzykowski K., 2023. Application of wide-spectrum light-emitting diodes in the indoor production of cucumber and tomato seedlings. Acta Agrobotanica 76: 762. https://doi.org/10.5586/aa.762
  93. Tymoszuk A., Kulus D., Kowalska J., Kulpińska A., Pańka D., Jeske M., Antkowiak M. 2024. Light spectrum affects growth, metabolite profile, and resistance against fungal phytopathogens of Solanum lycopersicum L. seedlings. Journal of Plant Protection Research 64(2). https://doi.org/10.24425/jppr.2024.150247
  94. Kulus D., Woźny A., 2020. Influence of light conditions on the morphogenetic and biochemical response of selected ornamental plant species under in vitro conditions: A mini-review. BioTechnologia 101(1): 75-83. http://doi.org/10.5114/bta.2020.92930
  95. "L-Prize U.S. Department of Energy", L-Prize Website, August 3, 2011
  96. LED There Be Light, Scientific American, March 18, 2009
  97. Eisenberg, Anne (June 24, 2007). "In Pursuit of Perfect TV Color, With L.E.D.'s and Lasers" . New York Times. Retrieved April 4, 2010.
  98. "CDC – NIOSH Publications and Products – Impact: NIOSH Light-Emitting Diode (LED) Cap Lamp Improves Illumination and Decreases Injury Risk for Underground Miners". cdc.gov. 2011. doi: 10.26616/NIOSHPUB2011192 . Retrieved May 3, 2013.{{cite journal}}: Cite journal requires |journal= (help)
  99. Janeway, Kimberly (December 12, 2014). "LED lightbulbs that promise to help you sleep". Consumer Reports. Retrieved May 10, 2018.
  100. "LED Device Illuminates New Path to Healing" (Press release). nasa.gov. Archived from the original on October 13, 2008. Retrieved January 30, 2012.
  101. Fudin, M. S.; Mynbaev, K. D.; Aifantis, K. E.; Lipsanen H.; Bougrov, V. E.; Romanov, A. E. (2014). "Frequency characteristics of modern LED phosphor materials". Scientific and Technical Journal of Information Technologies, Mechanics and Optics. 14 (6).
  102. Green, Hank (October 9, 2008). "Transmitting Data Through LED Light Bulbs". EcoGeek. Archived from the original on December 12, 2008. Retrieved February 15, 2009.
  103. Dimitrov, Svilen; Haas, Harald (2015). Principles of LED Light Communications: Towards Networked Li-Fi. Cambridge: Cambridge University Press. doi:10.1017/cbo9781107278929. ISBN   978-1-107-04942-0.
  104. Sampath, A. V.; Reed, M. L.; Moe, C.; Garrett, G. A.; Readinger, E. D.; Sarney, W. L.; Shen, H.; Wraback, M.; Chua, C. (December 1, 2009), "The effects of increasing AlN mole fraction on the performance of AlGaN active regions containing nanometer scale compositionally imhomogeneities", Advanced High Speed Devices, Selected Topics in Electronics and Systems, vol. 51, World Scientific, pp. 69–76, doi:10.1142/9789814287876_0007, ISBN   9789814287869
  105. 1 2 Liao, Yitao; Thomidis, Christos; Kao, Chen-kai; Moustakas, Theodore D. (February 21, 2011). "AlGaN based deep ultraviolet light emitting diodes with high internal quantum efficiency grown by molecular beam epitaxy". Applied Physics Letters. 98 (8): 081110. Bibcode:2011ApPhL..98h1110L. doi: 10.1063/1.3559842 . ISSN   0003-6951.
  106. 1 2 3 4 5 Cabalo, Jerry; DeLucia, Marla; Goad, Aime; Lacis, John; Narayanan, Fiona; Sickenberger, David (October 2, 2008). Carrano, John C.; Zukauskas, Arturas (eds.). "Overview of the TAC-BIO detector". Optically Based Biological and Chemical Detection for Defence IV. 7116. International Society for Optics and Photonics: 71160D. Bibcode:2008SPIE.7116E..0DC. doi:10.1117/12.799843. S2CID   108562187.
  107. Poldmae, Aime; Cabalo, Jerry; De Lucia, Marla; Narayanan, Fiona; Strauch III, Lester; Sickenberger, David (September 28, 2006). Carrano, John C.; Zukauskas, Arturas (eds.). "Biological aerosol detection with the tactical biological (TAC-BIO) detector". Optically Based Biological and Chemical Detection for Defence III. 6398. SPIE: 63980E. doi:10.1117/12.687944. S2CID   136864366.
  108. "Army advances bio-threat detector". www.army.mil. January 22, 2015. Retrieved October 10, 2019.
  109. Kesavan, Jana; Kilper, Gary; Williamson, Mike; Alstadt, Valerie; Dimmock, Anne; Bascom, Rebecca (February 1, 2019). "Laboratory validation and initial field testing of an unobtrusive bioaerosol detector for health care settings". Aerosol and Air Quality Research. 19 (2): 331–344. doi: 10.4209/aaqr.2017.10.0371 . ISSN   1680-8584.
  110. Dietz, P. H.; Yerazunis, W. S.; Leigh, D. L. (2004). "Very Low-Cost Sensing and Communication Using Bidirectional LEDs".{{cite journal}}: Cite journal requires |journal= (help)
  111. Goins, G. D.; Yorio, N. C.; Sanwo, M. M.; Brown, C. S. (1997). "Photomorphogenesis, photosynthesis, and seed yield of wheat plants grown under red light-emitting diodes (LEDs) with and without supplemental blue lighting". Journal of Experimental Botany. 48 (7): 1407–1413. doi: 10.1093/jxb/48.7.1407 . PMID   11541074.
  112. Li, Jinmin; Wang, Junxi; Yi, Xiaoyan; Liu, Zhiqiang; Wei, Tongbo; Yan, Jianchang; Xue, Bin (August 31, 2020). III-Nitrides Light Emitting Diodes: Technology and Applications. Springer Nature. p. 248. ISBN   978-981-15-7949-3.
  113. Gaska, R.; Shur, M. S.; Zhang, J. (October 2006). "Physics and Applications of Deep UV LEDs". 2006 8th International Conference on Solid-State and Integrated Circuit Technology Proceedings. pp. 842–844. doi:10.1109/ICSICT.2006.306525. ISBN   1-4244-0160-7. S2CID   17258357.
  114. 1 2 "LED R&D Challenges". Energy.gov. Retrieved March 13, 2019.
  115. "JULY 2015 POSTINGS". Energy.gov. Retrieved March 13, 2019.
  116. Identifying the Causes of LED Efficiency Droop Archived 13 December 2013 at the Wayback Machine , By Steven Keeping, Digi-Key Corporation Tech Zone
  117. Iveland, Justin; et al. (April 23, 2013). "Cause of LED Efficiency Droop Finally Revealed". Physical Review Letters, 2013.
  118. Di, Dawei; Romanov, Alexander S.; Yang, Le; Richter, Johannes M.; Rivett, Jasmine P. H.; Jones, Saul; Thomas, Tudor H.; Abdi Jalebi, Mojtaba; Friend, Richard H.; Linnolahti, Mikko; Bochmann, Manfred (April 14, 2017). "High-performance light-emitting diodes based on carbene-metal-amides" (PDF). Science. 356 (6334): 159–163. arXiv: 1606.08868 . Bibcode:2017Sci...356..159D. doi:10.1126/science.aah4345. ISSN   0036-8075. PMID   28360136. S2CID   206651900.
  119. 1 2 Armin, Ardalan; Meredith, Paul (October 2018). "LED technology breaks performance barrier". Nature. 562 (7726): 197–198. Bibcode:2018Natur.562..197M. doi: 10.1038/d41586-018-06923-y . PMID   30305755.
  120. 1 2 Cao, Yu; Wang, Nana; Tian, He; Guo, Jingshu; Wei, Yingqiang; Chen, Hong; Miao, Yanfeng; Zou, Wei; Pan, Kang; He, Yarong; Cao, Hui (October 2018). "Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures". Nature. 562 (7726): 249–253. Bibcode:2018Natur.562..249C. doi: 10.1038/s41586-018-0576-2 . ISSN   1476-4687. PMID   30305742.
  121. Cho, Sang-Hwan; Song, Young-Woo; Lee, Joon-gu; Kim, Yoon-Chang; Lee, Jong Hyuk; Ha, Jaeheung; Oh, Jong-Suk; Lee, So Young; Lee, Sun Young; Hwang, Kyu Hwan; Zang, Dong-Sik (August 18, 2008). "Weak-microcavity organic light-emitting diodes with improved light out-coupling". Optics Express. 16 (17): 12632–12639. Bibcode:2008OExpr..1612632C. doi: 10.1364/OE.16.012632 . ISSN   1094-4087. PMID   18711500.
  122. Lin, Kebin; Xing, Jun; Quan, Li Na; de Arquer, F. Pelayo García; Gong, Xiwen; Lu, Jianxun; Xie, Liqiang; Zhao, Weijie; Zhang, Di; Yan, Chuanzhong; Li, Wenqiang (October 2018). "Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent". Nature. 562 (7726): 245–248. Bibcode:2018Natur.562..245L. doi:10.1038/s41586-018-0575-3. hdl: 10356/141016 . ISSN   1476-4687. PMID   30305741. S2CID   52958604.
  123. "Blue LEDs: A health hazard?". texyt.com. January 15, 2007. Retrieved September 3, 2007.
  124. Some evidences that white LEDs are toxic for human at domestic radiance?. Radioprotection (2017-09-12). Retrieved on 2018-07-31.
  125. Point, S. and Barlier-Salsi, A. (2018) LEDs lighting and retinal damage, technical information sheets, SFRP
  126. "LED Based Products Must Meet Photobilogical Safety Standards: Part 2". ledsmagazine.com. November 29, 2011. Retrieved January 9, 2022.
  127. Lim, S. R.; Kang, D.; Ogunseitan, O. A.; Schoenung, J. M. (2011). "Potential Environmental Impacts of Light-Emitting Diodes (LEDs): Metallic Resources, Toxicity, and Hazardous Waste Classification". Environmental Science & Technology. 45 (1): 320–327. Bibcode:2011EnST...45..320L. doi:10.1021/es101052q. PMID   21138290.
  128. "Response to the AMA Statement on High Intensity Street Lighting". ledroadwaylighting.com. Archived from the original on January 19, 2019. Retrieved January 17, 2019.
  129. Stokstad, Erik (October 7, 2014). "LEDs: Good for prizes, bad for insects". Science. Retrieved October 7, 2014.
  130. Pawson, S. M.; Bader, M. K.-F. (2014). "LED Lighting Increases the Ecological Impact of Light Pollution Irrespective of Color Temperature". Ecological Applications. 24 (7): 1561–1568. Bibcode: 2014EcoAp..24.1561P . doi: 10.1890/14-0468.1 . PMID   29210222.
  131. Polakovic, Gary (June 12, 2018). "Scientist's new database can help protect wildlife from harmful hues of LED lights". USC News. Archived from the original on May 19, 2020. Retrieved December 16, 2019.
  132. "Information About Sea Turtles: Threats from Artificial Lighting". Sea Turtle Conservancy. Retrieved December 16, 2019.
  133. "Stoplights' Unusual, Potentially Deadly Winter Problem". ABC News. January 8, 2010. Archived from the original on December 12, 2023.
  134. Markley, Stephen (December 17, 2009). "LED Traffic Lights Can't Melt Snow, Ice". Cars.com. Archived from the original on June 6, 2019.

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