Europium(III) telluride

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Europium(III) telluride
Identifiers
3D model (JSmol)
  • InChI=1S/2Eu.3Te/q2*+3;3*-2
    Key: ZJYRIAUVAHYSPF-UHFFFAOYSA-N
  • [Eu+3].[Eu+3].[Te-2].[Te-2].[Te-2]
Properties
Eu2Te3
Molar mass 686.73 g·mol−1
Appearancegrey [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Europium(III) telluride is an inorganic compound, one of the tellurides of europium, with the chemical formula Eu2Te3. In this compound, Eu is in the +3 oxidation state. [2] It can form cubic crystals. [3] It has limited solubility in lead telluride and forms a solid solution. [4]

Related Research Articles

<span class="mw-page-title-main">Europium</span> Chemical element with atomic number 63 (Eu)

Europium is a chemical element; it has symbol Eu and atomic number 63. Europium is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. It is the most chemically reactive, least dense, and softest of the lanthanide elements. It is soft enough to be cut with a knife. Europium was isolated in 1901 and named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

<span class="mw-page-title-main">Gadolinium</span> Chemical element with atomic number 64 (Gd)

Gadolinium is a chemical element; it has symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is a malleable and ductile rare-earth element. Gadolinium reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of 20 °C (68 °F) is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare earths because of their similar chemical properties.

<span class="mw-page-title-main">Lanthanum</span> Chemical element with atomic number 57 (La)

Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, its usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.

<span class="mw-page-title-main">Samarium</span> Chemical element with atomic number 62 (Sm)

Samarium is a chemical element; it has symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide.

<span class="mw-page-title-main">Tellurium</span> Chemical element with atomic number 52 (Te)

Tellurium is a chemical element; it has symbol Te and atomic number 52. It is a brittle, mildly toxic, rare, silver-white metalloid. Tellurium is chemically related to selenium and sulfur, all three of which are chalcogens. It is occasionally found in its native form as elemental crystals. Tellurium is far more common in the Universe as a whole than on Earth. Its extreme rarity in the Earth's crust, comparable to that of platinum, is due partly to its formation of a volatile hydride that caused tellurium to be lost to space as a gas during the hot nebular formation of Earth.

<span class="mw-page-title-main">Cubic crystal system</span> Crystallographic system where the unit cell is in the shape of a cube

In crystallography, the cubiccrystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.

<span class="mw-page-title-main">Europium(III) chloride</span> Chemical compound

Europium(III) chloride is an inorganic compound with the formula EuCl3. The anhydrous compound is a yellow solid. Being hygroscopic it rapidly absorbs water to form a white crystalline hexahydrate, EuCl3·6H2O, which is colourless. The compound is used in research.

<span class="mw-page-title-main">Zinc telluride</span> Chemical compound

Zinc telluride is a binary chemical compound with the formula ZnTe. This solid is a semiconductor material with a direct band gap of 2.26 eV. It is usually a p-type semiconductor. Its crystal structure is cubic, like that for sphalerite and diamond.

<span class="mw-page-title-main">Hydrogen telluride</span> Chemical compound

Hydrogen telluride is the inorganic compound with the formula H2Te. A hydrogen chalcogenide and the simplest hydride of tellurium, it is a colorless gas. Although unstable in ambient air, the gas can exist long enough to be readily detected by the odour of rotting garlic at extremely low concentrations; or by the revolting odour of rotting leeks at somewhat higher concentrations. Most compounds with Te–H bonds (tellurols) are unstable with respect to loss of H2. H2Te is chemically and structurally similar to hydrogen selenide, both are acidic. The H–Te–H angle is about 90°. Volatile tellurium compounds often have unpleasant odours, reminiscent of decayed leeks or garlic.

<span class="mw-page-title-main">Polonide</span> Chemical compound

A polonide is a chemical compound of the radioactive element polonium with any element less electronegative than polonium. Polonides are usually prepared by a direct reaction between the elements at temperatures of around 300–400 °C. They are amongst the most chemically stable compounds of polonium, and can be divided into two broad groups:

Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.

<span class="mw-page-title-main">Potassium telluride</span> Chemical compound

Potassium telluride is an inorganic compound with a chemical formula K2Te. It is formed from potassium and tellurium, making it a telluride. Potassium telluride is a white powder. Like rubidium telluride and caesium telluride, it can be used as an ultraviolet detector in space. Its crystal structure is similar to other tellurides, which have an anti-fluorite structure.

<span class="mw-page-title-main">Europium(III) hydroxide</span> Chemical compound

Europium(III) hydroxide is an inorganic compound with a chemical formula Eu(OH)3.

<span class="mw-page-title-main">Europium(II) oxide</span> Chemical compound

Europium(II) oxide (EuO) is a chemical compound which is one of the oxides of europium. In addition to europium(II) oxide, there is also europium(III) oxide and the mixed valence europium(II,III) oxide.

Tellurogallates are chemical compounds which contain anionic units of tellurium connected to gallium. They can be considered as gallates where tellurium substitutes for oxygen. Similar compounds include the thiogallates, selenogallates, telluroaluminates, telluroindates and thiostannates. They are in the category of chalcogenotrielates or more broadly tellurometallates or chalcogenometallates.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

<span class="mw-page-title-main">Europium(II) telluride</span> Chemical compound

Europium(II) telluride is an inorganic compound of europium and tellurium, with the chemical formula EuTe.

Lanthanide compounds are compounds formed by the 15 elements classed as lanthanides. The lanthanides are generally trivalent, although some, such as cerium and europium, are capable of forming compounds in other oxidation states.

References

  1. Pierre Villars; Karin Cenzual; Roman Gladyshevskii. Handbook of Inorganic Substances 2017. Walter de Gruyter GmbH & Co KG. 24 July 2017. ISBN 978-3-11-043655-6. "Eu-Te"
  2. Dziawa P, Taliashvili B, Domuchowski W, et al. (Eu, Gd) Te-MBE growth and characterization. Acta Physica Polonica A, 2004, 106(2): 215-221. (pdf)
  3. Dziawa P, Taliashvili B, Domuchowski W, et al. (Eu, Gd) Te-MBE growth and characterization. Acta Physica Polonica A, 2004, 106(2): 215-221. (pdf)
  4. Фреїк Д М, Михайльонка Р Я, Іванишин І М. Термоелектричні властивості і дефектна підсистема твердих розчинів PbTe-Eu2Te3(in Ukrainian). Фізика і хімія твердого тіла, 2001, 2(4): 637-642. (pdf)

External reading