Niobium(V) bromide

Niobium(V) bromide

Names
Other names niobium pentabromide
Identifiers
CAS Number	13478-45-0 NbBr5 N 17633-68-0 Nb2Br10 N
3D model (JSmol)	ionic representation: Interactive image monomer: Interactive image dimer: Interactive image
ChemSpider	19388901  Y
ECHA InfoCard	100.033.420
EC Number	236-778-5
PubChem CID	83517
CompTox Dashboard (EPA)	DTXSID6065505
InChI InChI=1S/5BrH.Nb/h5*1H;/q;;;;;+5/p-5 Y Key: DSYRJFDOOSKABR-UHFFFAOYSA-I Y InChI=1/5BrH.Nb/h5*1H;/q;;;;;+5/p-5 Key: DSYRJFDOOSKABR-AACRGIKGAJ
SMILES ionic representation:[Br-].[Br-].[Br-].[Br-].[Br-].[Nb+5] monomer:Br[Nb](Br)(Br)(Br)Br dimer:Br[Nb-]1(Br)(Br)(Br)[Br+][Nb-]([Br+]1)(Br)(Br)(Br)Br
Properties
Chemical formula	NbBr5
Molar mass	492.430 g/mol
Appearance	wine red to black crystals
Density	4.417 g/cm3
Melting point	254 °C (489 °F; 527 K)
Boiling point	364 °C (687 °F; 637 K)
Solubility in water	hydrolyzes
Structure
Crystal structure	orthorhombic
Hazards
GHS labelling: [1]
Pictograms
Signal word	Danger
Hazard statements	H302, H312, H314, H332
Precautionary statements	P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P363, P405, P501
Safety data sheet (SDS)	MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N  verify  (what is  YN ?) Infobox references

Niobium(V) bromide is the inorganic compound with the formula Nb₂Br₁₀. Its name comes from the compound's empirical formula, NbBr₅. ^[2] It is a diamagnetic, orange solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two NbBr₅ units are joined by a pair of bromide bridges. There is no bond between the Nb centres. ^[3] Niobium(V) chloride, niobium(V) iodide, tantalum(V) chloride, tantalum(V) bromide, and tantalum(V) iodide all share this structural motif.

Synthesis

Niobium(V) bromide can be prepared by the reaction of bromine with niobium metal at 230–250 °C in a tube furnace. It can also be produced from the more accessible oxide by metathesis using aluminium tribromide: ^[4]

3 Nb₂O₅ + 10 AlBr₃ → 6 NbBr₅ + 5 Al₂O₃

A challenge with the latter method is the occurrence of NbOBr₃ as an impurity.

References

1. "Niobium(V) bromide". pubchem.ncbi.nlm.nih.gov. Retrieved 28 December 2021.
2. Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford: Butterworth-Heinemann. ISBN   0-7506-3365-4.
3. Hönle, Wolfgang; Furuseth, Sigrid; Schnering, Hans Georg von (1990). "Synthesis and Crystal Structure of Ordered, Orthorhombic α-NbBr₅". Zeitschrift für Naturforschung B. 45 (7): 952–956. doi: 10.1515/znb-1990-0706 . S2CID   98293250.
4. G. Brauer (1963). "Niobium(V) and Tantalum(V) Bromides". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. NY, NY: Academic Press. p. 1311.

External links

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