Pentaoxidane

Last updated
Pentaoxidane
Pentaoxidane.svg
Names
IUPAC name
Pentaoxidane
Other names
Hydrogen pentoxide, dihydrogen pentoxide
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/H2O5/c1-3-5-4-2/h1-2H
    Key: KUGRPPRAQNPSQD-UHFFFAOYSA-N
  • OOOOO
Properties
H2O5
Molar mass 82.011 g·mol−1
Related compounds
Related compounds
Pentoxolane, Tetraoxidane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pentaoxidane is an inorganic compound of hydrogen and oxygen with the chemical formula H2O5. [1] This is one of the most unstable hydrogen polyoxides. [2] [3] [4]

Synthesis

Related Research Articles

<span class="mw-page-title-main">Hydrogen peroxide</span> Chemical compound

Hydrogen peroxide is a chemical compound with the formula H2O2. In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry.

The quinones are a class of organic compounds that are formally "derived from aromatic compounds [such as benzene or naphthalene] by conversion of an even number of –CH= groups into –C(=O)– groups with any necessary rearrangement of double bonds", resulting in "a fully conjugated cyclic dione structure". The archetypical member of the class is 1,4-benzoquinone or cyclohexadienedione, often called simply "quinone". Other important examples are 1,2-benzoquinone (ortho-quinone), 1,4-naphthoquinone and 9,10-anthraquinone.

<span class="mw-page-title-main">Hypochlorite</span> Anion

In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite and calcium hypochlorite. The Cl-O distance in ClO is 1.69 Å.

<span class="mw-page-title-main">Sodium borohydride</span> Chemical compound

Sodium borohydride, also known as sodium tetrahydridoborate and sodium tetrahydroborate, is an inorganic compound with the formula NaBH4. It is a white crystalline solid, usually encountered as an aqueous basic solution. Sodium borohydride is a reducing agent that finds application in papermaking and dye industries. It is also used as a reagent in organic synthesis.

<span class="mw-page-title-main">Cyanate</span> Anion with formula OCN and charge –1

The cyanate ion is an anion with the chemical formula OCN. It is a resonance of three forms: [O−C≡N] (61%) ↔ [O=C=N] (30%) ↔ [O+≡C−N2−] (4%).

<span class="mw-page-title-main">Organic peroxides</span> Organic compounds of the form R–O–O–R’

In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group. If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article. The O−O bond of peroxides easily breaks, producing free radicals of the form RO. Thus, organic peroxides are useful as initiators for some types of polymerization, such as the acrylic, unsaturated polyester, and vinyl ester resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can explosively combust. Organic peroxides, like their inorganic counterparts, are often powerful bleaching agents.

<span class="mw-page-title-main">Ozonide</span> Polyatomic ion (O3, charge –1), or cyclic compounds made from ozone and alkenes

Ozonide is the polyatomic anion O−3. Cyclic organic compounds formed by the addition of ozone to an alkene are also called ozonides.

Sodium perborate is chemical compound whose chemical formula may be written NaH2BO4, Na2H4B2O8, or, more properly, [Na+]2[B2O4(OH)4]2−. Its name is sometimes abbreviated as PBS.

<span class="mw-page-title-main">Hydroperoxide</span> Class of chemical compounds

Hydroperoxides or peroxols are compounds of the form ROOH, where R stands for any group, typically organic, which contain the hydroperoxy functional group. Hydroperoxide also refers to the hydroperoxide anion and its salts, and the neutral hydroperoxyl radical (•OOH) consist of an unbond hydroperoxy group. When R is organic, the compounds are called organic hydroperoxides. Such compounds are a subset of organic peroxides, which have the formula ROOR. Organic hydroperoxides can either intentionally or unintentionally initiate explosive polymerisation in materials with unsaturated chemical bonds.

<span class="mw-page-title-main">Trioxidane</span> Chemical compound

Trioxidane, also called hydrogen trioxide is an inorganic compound with the chemical formula H[O]
3
H
. It is one of the unstable hydrogen polyoxides. In aqueous solutions, trioxidane decomposes to form water and singlet oxygen:

<span class="mw-page-title-main">Barium peroxide</span> Chemical compound

Barium peroxide is an inorganic compound with the formula BaO2. This white solid is one of the most common inorganic peroxides, and it was the first peroxide compound discovered. Being an oxidizer and giving a vivid green colour upon ignition, it finds some use in fireworks; historically, it was also used as a precursor for hydrogen peroxide.

<span class="mw-page-title-main">Trimethylphosphine</span> Chemical compound

Trimethylphosphine is an organophosphorus compound with the formula P(CH3)3, commonly abbreviated as PMe3. This colorless liquid has a strongly unpleasant odor, characteristic of alkylphosphines. The compound is a common ligand in coordination chemistry.

<span class="mw-page-title-main">Thiourea dioxide</span> Chemical compound

Thiourea dioxide or thiox is an organosulfur compound that is used in the textile industry. It functions as a reducing agent. It is a white solid, and exhibits tautomerism in solution.

<span class="mw-page-title-main">Hydrogen polyoxide</span> Chemical compound

Hydrogen polyoxides are chemical compounds that consist only of hydrogen and oxygen atoms, are bonded exclusively by single bonds, and are acyclic. They can therefore be classed as hydrogen chalcogenides.

Dihydroxydisulfane or hypodithionous acid is a reduced sulfur oxyacid with sulfur in a formal oxidation state of +1, but the valence of sulfur is 2. The structural formula is HO−S−S−OH, with all atoms arranged in a chain. It is an isomer of thiosulfurous acid but is lower in energy. Other isomers include HOS(=O)SH, HOS(=S)OH, and HS(=O)2SH. Disulfur monoxide, S2O, can be considered as the anhydride. Unlike many of these other reduced sulfur acids, dihydroxydisulfane can be formed in a pure state by reacting hydrogen sulfide with sulfur dioxide at −70 °C in dichlorodifluoromethane.

<span class="mw-page-title-main">Metal peroxide</span> Metal-containing compounds with peroxide (O2) ions/groups

In chemistry, metal peroxides are metal-containing compounds with ionically- or covalently-bonded peroxide groups. This large family of compounds can be divided into ionic and covalent peroxide. The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid. In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character.

<span class="mw-page-title-main">Caesium peroxide</span> Chemical compound

Caesium peroxide or cesium peroxide is an inorganic compound of caesium and oxygen with the chemical formula Cs2O2. It can be formed from caesium metal by adding a stoichiometric amount in ammonia solution, or oxidizing the solid metal directly.

Rhenium compounds are compounds formed by the transition metal rhenium (Re). Rhenium can form in many oxidation states, and compounds are known for every oxidation state from -3 to +7 except -2, although the oxidation states +7, +4, and +3 are the most common. Rhenium is most available commercially as salts of perrhenate, including sodium and ammonium perrhenates. These are white, water-soluble compounds. The tetrathioperrhenate anion [ReS4] is possible.

Tetraoxidane is an inorganic compound of hydrogen and oxygen with the chemical formula H
2
O
4
. This is one of the unstable hydrogen polyoxides.

References

  1. The Chemistry of Peroxides, Volume 3. John Wiley & Sons. 20 April 2015. p. 8. ISBN   978-1-118-41271-8 . Retrieved 16 May 2023.
  2. "Selected ATcT [1, 2] enthalpy of formation based on version 1.122 of the Thermochemical Network [3]". atct.anl.gov. Retrieved 15 May 2023.
  3. Denis, Pablo A. (5 October 2013). "Theoretical characterization of hydrogen pentoxide, H 2 O 5". International Journal of Quantum Chemistry . 113 (19): 2206–2212. doi:10.1002/qua.24432 . Retrieved 16 May 2023.
  4. Patai, Saul (1983). The Chemistry of Peroxides. Wiley. p. 485. ISBN   978-0-471-10218-2 . Retrieved 16 May 2023.
  5. Xu, Xin; Goddard, William A. III (November 2002). "Peroxone chemistry: Formation of H2O3 and ring-(HO2)(HO3) from O3/H2O2". Proceedings of the National Academy of Sciences. 99 (24): 15308–15312. Bibcode:2002PNAS...9915308X. doi: 10.1073/pnas.202596799 . PMC   137712 . PMID   12438699.
  6. Levanov, Alexander V.; Sakharov, Dmitri V.; Dashkova, Anna V.; Antipenko, Ewald E.; Lunin, Valeri V. (November 2011). "Synthesis of Hydrogen Polyoxides H 2 O 4 and H 2 O 3 and Their Characterization by Raman Spectroscopy". European Journal of Inorganic Chemistry . 2011 (33): 5144–5150. doi:10.1002/ejic.201100767. ISSN   1434-1948 . Retrieved 16 May 2023.