Tetraoxidane

Last updated
Tetraoxidane
Tetraoxidane.svg
Tetraoxidane-3D-vdW.png
Names
IUPAC name
Tetraoxidane
Other names
Hydroxyperoxide, dihydrogen tetroxide, diperoxide, bisperoxide
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/H2O4/c1-3-4-2/h1-2H
    Key: RSPISYXLHRIGJD-UHFFFAOYSA-N
  • OOOO
Properties
H2O4
Molar mass 66.012 g·mol−1
Density 1.8±0.1 g/cm3
Related compounds
Related compounds
Pentaoxidane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tetraoxidane is an inorganic compound of hydrogen and oxygen with the chemical formula H
2
O
4
. [1] [2] [3] This is one of the unstable hydrogen polyoxides. [4]

Contents

Synthesis

The compound is prepared by a chemical reaction between hydroperoxyl radicals (HO2) at low temperatures: [5] [6]

Physical properties

This is the fourth member of the polyoxidanes. The first three are water [(mon)oxidane], hydrogen peroxide (dioxidane), and trioxidane. Tetroxidane is more unstable than the previous compounds. The term "tetraoxidane" extends beyond the parent compound to several daughter compounds of the general formula R
2
O
4
, where R can be hydrogen, halogen atoms, or various inorganic and organic monovalent radicals. The two Rs together can be replaced by a divalent radical, so heterocyclic tetroxidanes also exist. [7]

Ionization

Tetroxidane autoionizes when in liquid form:

Related Research Articles

<span class="mw-page-title-main">Hydrogen peroxide</span> Chemical compound

Hydrogen peroxide is a chemical compound with the formula H2O2. In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution in water for consumer use and in higher concentrations for industrial use. Concentrated hydrogen peroxide, or "high-test peroxide", decomposes explosively when heated and has been used as both a monopropellant and an oxidizer in rocketry.

In chemistry, a superoxide is a compound that contains the superoxide ion, which has the chemical formula O−2. The systematic name of the anion is dioxide(1−). The reactive oxygen ion superoxide is particularly important as the product of the one-electron reduction of dioxygen O2, which occurs widely in nature. Molecular oxygen (dioxygen) is a diradical containing two unpaired electrons, and superoxide results from the addition of an electron which fills one of the two degenerate molecular orbitals, leaving a charged ionic species with a single unpaired electron and a net negative charge of −1. Both dioxygen and the superoxide anion are free radicals that exhibit paramagnetism. Superoxide was historically also known as "hyperoxide".

<span class="mw-page-title-main">Hypochlorite</span> Anion

In chemistry, hypochlorite, or chloroxide is an anion with the chemical formula ClO. It combines with a number of cations to form hypochlorite salts. Common examples include sodium hypochlorite and calcium hypochlorite. The Cl-O distance in ClO is 1.69 Å.

In chemistry, disproportionation, sometimes called dismutation, is a redox reaction in which one compound of intermediate oxidation state converts to two compounds, one of higher and one of lower oxidation state. The reverse of disproportionation, such as when a compound in an intermediate oxidation state is formed from precursors of lower and higher oxidation states, is called comproportionation, also known as symproportionation.

<span class="mw-page-title-main">Peroxymonosulfuric acid</span> Powerful oxidizing agent

Peroxymonosulfuric acid, also known as persulfuric acid, peroxysulfuric acid is the inorganic compound with the formula H2SO5. It is a white solid. It is a component of Caro's acid, which is a solution of peroxymonosulfuric acid in sulfuric acid containing small amounts of water. Peroxymonosulfuric acid is a very strong oxidant.

<span class="mw-page-title-main">Dioxygen difluoride</span> Chemical compound

Dioxygen difluoride is a compound of fluorine and oxygen with the molecular formula O2F2. It can exist as an orange-red colored solid which melts into a red liquid at −163 °C (110 K). It is an extremely strong oxidant and decomposes into oxygen and fluorine even at −160 °C (113 K) at a rate of 4% per dayits lifetime at room temperature is thus extremely short. Dioxygen difluoride reacts vigorously with nearly every chemical it encounters (including ordinary ice) leading to its onomatopoeic nickname FOOF (a play on its chemical structure and its explosive tendencies).

<span class="mw-page-title-main">Organic peroxides</span> Organic compounds of the form R–O–O–R’

In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group. If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article. The O−O bond of peroxides easily breaks, producing free radicals of the form RO. Thus, organic peroxides are useful as initiators for some types of polymerization, such as the acrylic, unsaturated polyester, and vinyl ester resins used in glass-reinforced plastics. MEKP and benzoyl peroxide are commonly used for this purpose. However, the same property also means that organic peroxides can explosively combust. Organic peroxides, like their inorganic counterparts, are often powerful bleaching agents.

In chemistry, phosphorus oxoacid is a generic name for any acid whose molecule consists of atoms of phosphorus, oxygen, and hydrogen. There is a potentially infinite number of such compounds. Some of them are unstable and have not been isolated, but the derived anions and organic groups are present in stable salts and esters. The most important ones—in biology, geology, industry, and chemical research—are the phosphoric acids, whose esters and salts are the phosphates.

<span class="mw-page-title-main">Hydroperoxyl</span> Chemical compound

The hydroperoxyl radical, also known as the hydrogen superoxide, is the protonated form of superoxide with the chemical formula HO2, also written HOO. This species plays an important role in the atmosphere and as a reactive oxygen species in cell biology.

<span class="mw-page-title-main">Trioxidane</span> Chemical compound

Trioxidane, also called hydrogen trioxide is an inorganic compound with the chemical formula H[O]
3
H
. It is one of the unstable hydrogen polyoxides. In aqueous solutions, trioxidane decomposes to form water and singlet oxygen:

<span class="mw-page-title-main">Oxygen compounds</span> Different oxidation states of Oxygen

The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides. Compounds containing oxygen in other oxidation states are very uncommon: −12 (superoxides), −13 (ozonides), 0, +12 (dioxygenyl), +1, and +2.

<span class="mw-page-title-main">Radical (chemistry)</span> Atom, molecule, or ion that has an unpaired valence electron; typically highly reactive

In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes.

<span class="mw-page-title-main">Hydrogen polyoxide</span> Chemical compound

Hydrogen polyoxides are chemical compounds that consist only of hydrogen and oxygen atoms, are bonded exclusively by single bonds, and are acyclic. They can therefore be classed as hydrogen chalcogenides.

Iron(II) hydride, systematically named iron dihydride and poly(dihydridoiron) is solid inorganic compound with the chemical formula (FeH
2
)
n
(also written ([FeH
2
]
)n or FeH
2
). ). It is kinetically unstable at ambient temperature, and as such, little is known about its bulk properties. However, it is known as a black, amorphous powder, which was synthesised for the first time in 2014.

Hydrogen chalcogenides are binary compounds of hydrogen with chalcogen atoms. Water, the first chemical compound in this series, contains one oxygen atom and two hydrogen atoms, and is the most common compound on the Earth's surface.

Silver hyponitrite is an ionic compound with formula Ag2N2O2 or (Ag+
)2[ON=NO]2−, containing monovalent silver cations and hyponitrite anions. It is a bright yellow solid practically insoluble in water and most organic solvents, including DMF and DMSO.

<span class="mw-page-title-main">Neptunium(IV) fluoride</span> Chemical compound

Neptunium(IV) fluoride or neptunium tetrafluoride is a inorganic compound with the formula NpF4. It is a green salt and is isostructural with UF4.

<span class="mw-page-title-main">Metal peroxide</span> Metal-containing compounds with peroxide (O2) ions/groups

In chemistry, metal peroxides are metal-containing compounds with ionically- or covalently-bonded peroxide groups. This large family of compounds can be divided into ionic and covalent peroxide. The first class mostly contains the peroxides of the alkali and alkaline earth metals whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid. In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metals have a more covalent character.

In chemistry and particularly biochemistry, an energy-rich species or high-energy species is a chemical species which reacts, potentially with other species found in the environment, to release chemical energy.

Pentaoxidane is an inorganic compound of hydrogen and oxygen with the chemical formula H2O5. This is one of the most unstable hydrogen polyoxides.

References

  1. Mckay, Daniel J.; Wright, James S. (1 February 1998). "How Long Can You Make an Oxygen Chain?". Journal of the American Chemical Society . 120 (5): 1003–1013. doi:10.1021/ja971534b. ISSN   0002-7863 . Retrieved 16 May 2023.
  2. "hydroxyperoxide". ChemScr. Retrieved 15 May 2023.
  3. The Chemistry of Peroxides, Volume 3. John Wiley & Sons. 20 April 2015. p. 198. ISBN   978-1-118-41271-8 . Retrieved 15 May 2023.
  4. "Selected ATcT [1, 2] enthalpy of formation based on version 1.122 of the Thermochemical Network [3]". atct.anl.gov. Retrieved 15 May 2023.
  5. Levanov, Alexander V.; Sakharov, Dmitri V.; Dashkova, Anna V.; Antipenko, Ewald E.; Lunin, Valeri V. (2011). "Synthesis of Hydrogen Polyoxides H2O4 and H2O3 and Their Characterization by Raman Spectroscopy". European Journal of Inorganic Chemistry . 2011 (33): 5144–5150. doi:10.1002/ejic.201100767.
  6. Möller, Detlev (19 February 2019). Fundamentals and Processes. Walter de Gruyter GmbH & Co KG. p. 276. ISBN   978-3-11-056126-5 . Retrieved 15 May 2023.
  7. Curutchet, Antton; Colinet, Pauline; Michel, Carine; Steinmann, Stephan N.; Le Bahers, Tangui (2020). "Two-sites are better than one: revisiting the OER mechanism on CoOOH by DFT with electrode polarization" (PDF). Physical Chemistry Chemical Physics . 22 (13): 7031–7038. Bibcode:2020PCCP...22.7031C. doi:10.1039/D0CP00281J. PMID   32195492. S2CID   213191538 . Retrieved 15 May 2023.