Semiheavy water

Not to be confused with Heavy water.

Semiheavy water

Spacefill model of water
Names
IUPAC name (2H1)Water
Other names Deuterium hydrogen monoxide Deuterium hydrogen oxide, Water-d1, Water-d
Identifiers
CAS Number	14940-63-7
3D model (JSmol)	Interactive image
ChEBI	CHEBI:33806
ChemSpider	123344
Gmelin Reference	115
PubChem CID	139859
CompTox Dashboard (EPA)	DTXSID50164262
InChI InChI=1S/H2O/h1H2/i/hD Key: XLYOFNOQVPJJNP-DYCDLGHISA-N
SMILES [2H]O
Properties
Chemical formula	H2HO or HDO
Molar mass	19.0214 g mol−1
Appearance	Very pale blue, transparent liquid, very similar to regular water
Density	1.054 g cm−3
Melting point	3.81 °C (38.86 °F; 276.96 K)
Boiling point	100.74 °C (213.33 °F; 373.89 K)
Solubility in water	miscible
log P	−0.65
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N  verify  (what is  YN ?) Infobox references

Semiheavy water (HDO) is a naturally occurring chemical variant of water. Other variants include heavy water (D₂O), and H₂O. It shares most of its properties with common water (¹H₂O), with its distinguishing feature being a single hydrogen atom per water molecule being of the heavier isotope deuterium (²H or D), as opposed to the far more common protium (¹H). This difference of one more neutron in one of the hydrogen atoms does not notably change its chemical properties, as these are mostly dictated by the number of valence electrons an atom has. The only notable difference to common water is a larger mass, as a result of the extra neutron per atom.

In an amount of water, about 1 molecule in 3,200 is HDO (one hydrogen in 6,400 is ²H). By comparison, heavy water (D₂O) ^[1] occurs at a proportion of about 1 molecule in 41 million (i.e., 1 in 6,400²). This makes semiheavy water far more common than heavy water.

Semiheavy water (HDO) cannot be isolated in its pure liquid form since, owing to hydrogen exchange in water, it is in equilibrium with H₂O and D₂O. ^[2] If however it were possible to weigh the same volume of HDO and H₂O, the HDO would be heavier, lending it its name.

The freezing point of semiheavy water is close to the freezing point of heavy water at 3.81°C, with the freezing point of heavy water being 3.82°C.

Production

HDO may be separated from normal water by distillation or electrolysis, or by various chemical exchange processes, all of which exploit a kinetic isotope effect. Partial enrichment also occurs in natural bodies of water under certain evaporation conditions. ^[3] (For more information about the distribution of deuterium in water, see Vienna Standard Mean Ocean Water and Hydrogen isotope biogeochemistry.)

See also

• Deuterium-depleted water

References

1. "Heavy water | chemical compound". Encyclopedia Britannica. Retrieved 2019-04-24.
2. §I (Introduction), "Isotope effects in liquid water by infrared spectroscopy. II. Factor analysis of the temperature effect on H₂O and D₂O", Pascal Larouche, Jean-Joseph Max, and Camille Chapados, The Journal of Chemical Physics 129 (2008), 064503, doi : 10.1063/1.2960583.
3. Craig, H.; Gordon, L. I.; Horibe, Y. (1963). "Isotopic exchange effects in the evaporation of water: 1. Low-temperature experimental results". Journal of Geophysical Research. 68 (17): 5079–5087. Bibcode:1963JGR....68.5079C. doi:10.1029/JZ068i017p05079.

Further reading

• Schwarzer D, Lindner J, Vöhringer P (October 2005). "Energy relaxation versus spectral diffusion of the OH-stretching vibration of HOD in liquid-to-supercritical deuterated water". The Journal of Chemical Physics. 123 (16) 161105. Bibcode:2005JChPh.123p1105S. doi:10.1063/1.2110087. hdl: 11858/00-001M-0000-0012-E7B7-2 . PMID   16268674.