Exotic atom

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An exotic atom is an otherwise normal atom in which one or more sub-atomic particles have been replaced by other particles. For example, electrons may be replaced by other negatively charged particles such as muons (muonic atoms) or pions (pionic atoms). [1] [2] Because these substitute particles are usually unstable, exotic atoms typically have very short lifetimes and no exotic atom observed so far can persist under normal conditions.

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Muonic atoms

Muonic helium, made out of 2 protons, 2 neutrons, 1 muon and 1 electron. Hydrogen-4.1.svg
Muonic helium, made out of 2 protons, 2 neutrons, 1 muon and 1 electron.

In a muonic atom (previously called a mu-mesic atom, now known to be a misnomer as muons are not mesons), [3] an electron is replaced by a muon, which, like the electron, is a lepton. Since leptons are only sensitive to weak, electromagnetic and gravitational forces, muonic atoms are governed to very high precision by the electromagnetic interaction.

Since a muon is more massive than an electron, the Bohr orbits are closer to the nucleus in a muonic atom than in an ordinary atom, and corrections due to quantum electrodynamics are more important. Study of muonic atoms' energy levels as well as transition rates from excited states to the ground state therefore provide experimental tests of quantum electrodynamics.

Muon-catalyzed fusion is a technical application of muonic atoms.

Other muonic atoms can be formed when negative muons interact with ordinary matter. [4] The muon in muonic atoms can either decay or get captured by a proton. Muon capture is very important in heavier muonic atoms, thus shorten the muon's lifetime from 2.2 μs to only 0.08 μs. [4]

Muonic hydrogen

Muonic hydrogen is like normal hydrogen with the electron replaced by a negative muon—that is a proton orbited by a muon. It is important in addressing the proton radius puzzle.

Muonic helium (Hydrogen-4.1)

The symbol 4.1H (Hydrogen-4.1) has been used to describe the exotic atom muonic helium (4He-μ), which is like helium-4 in having two protons and two neutrons. [5] However one of its electrons is replaced by a muon, which also has charge –1. Because the muon's orbital radius is less than 1/200th the electron's orbital radius (due to the mass ratio), the muon can be considered as a part of the nucleus. The atom then has a nucleus with two protons, two neutrons and one muon, with total nuclear charge +1 (from two protons and one muon) and only one electron outside, so that it is effectively an isotope of hydrogen instead of an isotope of helium. A muon's weight is approximately 0.1 Da so the isotopic mass is 4.1. Since there is only one electron outside the nucleus, the hydrogen-4.1 atom can react with other atoms. Its chemical behavior behaves more like a hydrogen atom than an inert helium atom. [5] [6] [7]

Hadronic atoms

A hadronic atom is an atom in which one or more of the orbital electrons are replaced by a negatively charged hadron. [8] Possible hadrons include mesons such as the pion or kaon, yielding a pionic atom [9] or a kaonic atom (see Kaonic hydrogen), collectively called mesonic atoms; antiprotons, yielding an antiprotonic atom; and the
Σ
particle, yielding a
Σ
or sigmaonic atom. [10] [11] [12]

Unlike leptons, hadrons can interact via the strong force, so the orbitals of hadronic atoms are influenced by nuclear forces between the nucleus and the hadron. Since the strong force is a short-range interaction, these effects are strongest if the atomic orbital involved is close to the nucleus, when the energy levels involved may broaden or disappear because of the absorption of the hadron by the nucleus. [2] [11] Hadronic atoms, such as pionic hydrogen and kaonic hydrogen, thus provide experimental probes of the theory of strong interactions, quantum chromodynamics. [13]

Onium

An onium (plural: onia) is the bound state of a particle and its antiparticle. The classic onium is positronium, which consists of an electron and a positron bound together as a metastable state, with a relatively long lifetime of 142 ns in the triplet state. [14] Positronium has been studied since the 1950s to understand bound states in quantum field theory. A recent development called non-relativistic quantum electrodynamics (NRQED) used this system as a proving ground.

Pionium, a bound state of two oppositely charged pions, is useful for exploring the strong interaction. This should also be true of protonium, which is a proton–antiproton bound state. Understanding bound states of pionium and protonium is important in order to clarify notions related to exotic hadrons such as mesonic molecules and pentaquark states. Kaonium, which is a bound state of two oppositely charged kaons, has not been observed experimentally yet.

The true analogs of positronium in the theory of strong interactions, however, are not exotic atoms but certain mesons, the quarkonium states, which are made of a heavy quark such as the charm or bottom quark and its antiquark. (Top quarks are so heavy that they decay through the weak force before they can form bound states.) Exploration of these states through non-relativistic quantum chromodynamics (NRQCD) and lattice QCD are increasingly important tests of quantum chromodynamics.

Muonium, despite its name, is not an onium state containing a muon and an antimuon, because IUPAC assigned that name to the system of an antimuon bound with an electron. However, the production of a muon–antimuon bound state, which is an onium (called true muonium), has been theorized. [15] The same applies to the ditauonium (or "true tauonium") exotic QED atom. [16]

Hypernuclear atoms

Atoms may be composed of electrons orbiting a hypernucleus that includes strange particles called hyperons. Such hypernuclear atoms are generally studied for their nuclear behaviour, falling into the realm of nuclear physics rather than atomic physics.

Quasiparticle atoms

In condensed matter systems, specifically in some semiconductors, there are states called excitons, which are bound states of an electron and an electron hole.

Exotic molecules

An exotic molecule contains one or more exotic atoms.

"Exotic molecule" can also refer to a molecule having some other uncommon property such as pyramidal hexamethylbenzene and a Rydberg atom.

See also

Related Research Articles

<span class="mw-page-title-main">Hadron</span> Composite subatomic particle

In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong interaction. They are analogous to molecules, which are held together by the electric force. Most of the mass of ordinary matter comes from two hadrons: the proton and the neutron, while most of the mass of the protons and neutrons is in turn due to the binding energy of their constituent quarks, due to the strong force.

<span class="mw-page-title-main">Muon</span> Subatomic particle

A muon is an elementary particle similar to the electron, with an electric charge of −1 e and spin-1/2, but with a much greater mass. It is classified as a lepton. As with other leptons, the muon is not thought to be composed of any simpler particles.

<span class="mw-page-title-main">Muonium</span> Exotic atom made up of an antimuon and an electron

Muonium is an exotic atom made up of an antimuon and an electron, which was discovered in 1960 by Vernon W. Hughes and is given the chemical symbol Mu. During the muon's 2.2 µs lifetime, muonium can undergo chemical reactions. Because, like a proton, the antimuon's mass is vastly larger than that of the electron, muonium is more similar to atomic hydrogen than positronium. Its Bohr radius and ionization energy are within 0.5% of hydrogen, deuterium, and tritium, and thus it can usefully be considered as an exotic light isotope of hydrogen.

<span class="mw-page-title-main">Particle physics</span> Study of subatomic particles and forces

Particle physics or high-energy physics is the study of fundamental particles and forces that constitute matter and radiation. The field also studies combinations of elementary particles up to the scale of protons and neutrons, while the study of combination of protons and neutrons is called nuclear physics.

<span class="mw-page-title-main">Proton</span> Subatomic particle with positive charge

A proton is a stable subatomic particle, symbol
p
, H+, or 1H+ with a positive electric charge of +1 e (elementary charge). Its mass is slightly less than the mass of a neutron and approximately 1836 times the mass of an electron (the proton-to-electron mass ratio). Protons and neutrons, each with a mass of approximately one atomic mass unit, are jointly referred to as nucleons (particles present in atomic nuclei).

<span class="mw-page-title-main">Positronium</span> Bound state of an electron and positron

Positronium (Ps) is a system consisting of an electron and its anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annihilate each other to predominantly produce two or three gamma-rays, depending on the relative spin states. The energy levels of the two particles are similar to that of the hydrogen atom. However, because of the reduced mass, the frequencies of the spectral lines are less than half of those for the corresponding hydrogen lines.

A timeline of atomic and subatomic physics, including particle physics.

<span class="mw-page-title-main">Lepton</span> Class of elementary particles

In particle physics, a lepton is an elementary particle of half-integer spin that does not undergo strong interactions. Two main classes of leptons exist: charged leptons, including the electron, muon, and tauon, and neutral leptons, better known as neutrinos. Charged leptons can combine with other particles to form various composite particles such as atoms and positronium, while neutrinos rarely interact with anything, and are consequently rarely observed. The best known of all leptons is the electron.

<span class="mw-page-title-main">Subatomic particle</span> Particle smaller than an atom

In physics, a subatomic particle is a particle smaller than an atom. According to the Standard Model of particle physics, a subatomic particle can be either a composite particle, which is composed of other particles, or an elementary particle, which is not composed of other particles. Particle physics and nuclear physics study these particles and how they interact. Most force-carrying particles like photons or gluons are called bosons and, although they have quanta of energy, do not have rest mass or discrete diameters and are unlike the former particles that have rest mass and cannot overlap or combine which are called fermions. The W and Z bosons, however, are an exception to this rule and have relatively large rest masses at approximately 80 GeV and 90 GeV respectively.

Muon-catalyzed fusion is a process allowing nuclear fusion to take place at temperatures significantly lower than the temperatures required for thermonuclear fusion, even at room temperature or lower. It is one of the few known ways of catalyzing nuclear fusion reactions.

<span class="mw-page-title-main">Tau (particle)</span> Elementary subatomic particle with negative electric charge

The tau, also called the tau lepton, tau particle, tauon or tau electron, is an elementary particle similar to the electron, with negative electric charge and a spin of 1/2. Like the electron, the muon, and the three neutrinos, the tau is a lepton, and like all elementary particles with half-integer spin, the tau has a corresponding antiparticle of opposite charge but equal mass and spin. In the tau's case, this is the "antitau". Tau particles are denoted by the symbol
τ
and the antitaus by 
τ+
.

<span class="mw-page-title-main">Helium-4</span> Isotope of helium

Helium-4 is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consists of two protons and two neutrons.

<span class="mw-page-title-main">Protonium</span> Bound state of a proton and antiprotron

Protonium, also known as antiprotonic hydrogen, is a type of exotic atom in which a proton and an antiproton are bound to each other.

<span class="mw-page-title-main">Antiprotonic helium</span> Exotic matter with an antiproton in place of an electron

Antiprotonic helium is a three-body atom composed of an antiproton and an electron orbiting around a helium nucleus. It is thus made partly of matter, and partly of antimatter. The atom is electrically neutral, since an electron and an antiproton each have a charge of −1 e, whereas a helium nucleus has a charge of +2 e. It has the longest lifetime of any experimentally produced matter–antimatter bound state.

In quantum electrodynamics, the anomalous magnetic moment of a particle is a contribution of effects of quantum mechanics, expressed by Feynman diagrams with loops, to the magnetic moment of that particle. The magnetic moment, also called magnetic dipole moment, is a measure of the strength of a magnetic source.

Quantum electrodynamics (QED), a relativistic quantum field theory of electrodynamics, is among the most stringently tested theories in physics. The most precise and specific tests of QED consist of measurements of the electromagnetic fine-structure constant, α, in various physical systems. Checking the consistency of such measurements tests the theory.

<span class="mw-page-title-main">Onium</span> Quantum state of a particle and its antiparticle

An onium is a bound state of a particle and its antiparticle. These states are usually named by adding the suffix -onium to the name of one of the constituent particles, with one exception for "muonium"; a muon–antimuon bound pair is called "true muonium" to avoid confusion with old nomenclature.

<span class="mw-page-title-main">Atomic nucleus</span> Core of an atom; composed of nucleons (protons and neutrons)

The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in 1932, models for a nucleus composed of protons and neutrons were quickly developed by Dmitri Ivanenko and Werner Heisenberg. An atom is composed of a positively charged nucleus, with a cloud of negatively charged electrons surrounding it, bound together by electrostatic force. Almost all of the mass of an atom is located in the nucleus, with a very small contribution from the electron cloud. Protons and neutrons are bound together to form a nucleus by the nuclear force.

<span class="mw-page-title-main">True muonium</span> Predicted exotic atom

In particle physics, true muonium is a theoretically predicted exotic atom representing a bound state of an muon and an antimuon (μ+μ). The existence of true muonium is well established theoretically within the Standard Model. Its properties within the Standard Model are determined by quantum electrodynamics, and may be modified by physics beyond the Standard Model.

References

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