Ocean stratification

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Ocean stratification is the natural separation of an ocean's water into horizontal layers by density. This is generally stable stratification, because warm water floats on top of cold water, and heating is mostly from the sun, which reinforces that arrangement. Stratification is reduced by wind-forced mechanical mixing, but reinforced by convection (warm water rising, cold water sinking). Stratification occurs in all ocean basins and also in other water bodies. Stratified layers are a barrier to the mixing of water, which impacts the exchange of heat, carbon, oxygen and other nutrients. [1] The surface mixed layer is the uppermost layer in the ocean and is well mixed by mechanical (wind) and thermal (convection) effects. Climate change is causing the upper ocean stratification to increase. [1] [ clarification needed ]

Contents

Due to upwelling and downwelling, which are both wind-driven, mixing of different layers can occur through the rise of cold nutrient-rich and sinking of warm water, respectively. Generally, layers are based on water density: heavier, and hence denser, water is below the lighter water, representing a stable stratification. For example, the pycnocline is the layer in the ocean where the change in density is largest compared to that of other layers in the ocean. The thickness of the thermocline is not constant everywhere and depends on a variety of variables.[ clarification needed ]

Between 1960 and 2018, upper ocean stratification increased between 0.7-1.2% per decade due to climate change. [1] This means that the differences in density of the layers in the oceans increase, leading to larger mixing barriers and other effects.[ clarification needed ] In the last few decades,[ when? ] stratification in all ocean basins has increased due to effects of climate change on oceans. Global upper-ocean stratification has continued its increasing trend in 2022. [2] The southern oceans (south of 30°S) experienced the strongest rate of stratification since 1960, followed by the Pacific, Atlantic, and the Indian Oceans. [1] Increasing stratification is predominantly affected by changes in ocean temperature; salinity only plays a role locally. [1]

Density of water in the oceans

The density of water in the ocean, which is defined as mass per unit of volume, has a complicated dependence on temperature (), salinity () and pressure (), which in turn is a function of the density and depth of the overlying water, and is denoted as . The dependence on pressure is not significant, since seawater is almost perfectly incompressible. [3] A change in the temperature of the water impacts on the distance between water parcels directly.[ clarification needed ] When the temperature of the water increases, the distance between water parcels will increase and hence the density will decrease. Salinity is a measure of the mass of dissolved solids, which consist mainly of salt. Increasing the salinity will increase the density. Just like the pycnocline defines the layer with a fast change in density, similar layers can be defined for a fast change in temperature and salinity: the thermocline and the halocline. Since the density depends on both the temperature and the salinity, the pycno-, thermo-, and haloclines have similar shapes. The difference is that the density increases with depth, whereas the salinity and temperature decrease with depth.

The halo-, thermo-, and pycnocline at 10E, 30S. For this image the annual means of the year 2000 from the GODAS Data has been used. CLINES1.png
The halo-, thermo-, and pycnocline at 10E, 30S. For this image the annual means of the year 2000 from the GODAS Data has been used.

In the ocean, a specific range of temperature and salinity occurs. Using the GODAS Data, [4] a temperature-salinity plot can show the possibilities and occurrences of the different combinations of salinity and potential temperature.

Potential temperature - salinity plot. This plot was generated using the GODAS Data of 2020. ST-plot oceans.png
Potential temperature - salinity plot. This plot was generated using the GODAS Data of 2020.
Occurrences of combinations of potential temperature and salinity in the ocean. This plot was generated using the GODAS Data of 2020. Occurences of Pottemp and salinity.png
Occurrences of combinations of potential temperature and salinity in the ocean. This plot was generated using the GODAS Data of 2020.

The density of ocean water is described by the UNESCO formula as: [5] The terms in this formula, density when the pressure is zero, , and a term involving the compressibility of water, , are both heavily dependent on the temperature and less dependent on the salinity:

The surface temperature, surface salinity and surface potential density calculated and plotted using the annual mean over the year 2000 of the GODAS Data. Densittydependence2.png
The surface temperature, surface salinity and surface potential density calculated and plotted using the annual mean over the year 2000 of the GODAS Data.

with:andIn these formulas, all of the small letters, and are constants that are defined in Appendix A of a book on Internal Gravity Waves, published in 2015. [5] [ clarification needed ]

The density depends more on the temperature than on the salinity, as can be deduced from the exact formula and can be shown in plots using the GODAS Data. [4] In the plots regarding surface temperature, salinity and density, it can be seen that locations with the coldest water, at the poles, are also the locations with the highest densities. The regions with the highest salinity, on the other hand, are not the regions with the highest density, meaning that temperature contributes mostly to the density in the oceans. A specific example is the Arabian Sea.

Quantification

Ocean stratification can be defined and quantified by the change in density with depth. The Buoyancy frequency, also called the Brunt-Väisälä frequency, can be used as direct representation of stratification in combination with observations on temperature and salinity.

The Buoyancy frequency, , represents the intrinsic frequency of internal gravity waves. [1] This means that water that is vertically displaced tends to bounce up and down with that frequency.

The Buoyancy frequency is defined as follows:Here, is the gravitational constant, is a reference density and is the potential density depending on temperature and salinity as discussed earlier. Water is considered to have a stable stratification for , leading to a real value of . The ocean is typically stable and the corresponding -values in the ocean lie between approximately in the abyssal ocean and in the upper parts of the ocean. The Buoyancy period is defined as . Corresponding to the previous values, this period typically takes values between approximately 10 and 100 minutes. [6] In some parts of the ocean unstable stratification appears, leading to convection.

If the stratification in a water column increases, implying an increase of the value , turbulent mixing and hence the eddy viscosity will decrease. [7] Furthermore, an increase of , implies an increase of , meaning that the difference in densities in this water column increase as well. Throughout the year, the oceanic stratification is not constant, since the stratification depends on density, and therefore on temperature and salinity. The interannual fluctuations in tropical Pacific Ocean stratification are dominated by El Niño, which can be linked with the strong variations in the thermocline depth in the eastern equatorial Pacific. [1]

Furthermore, tropical storms are sensitive to the conditions on the stratification and hence on its change. [8] On the other hand, mixing from tropical storms also tends to reduce stratification differences among layers.

Observations on increasing stratification

Temperature and salinity changes due to global warming and climate change alter the ocean density and lead to changes in vertical stratification. [2] The stratified configuration of the ocean can act as a barrier to water mixing, which impacts the efficiency of vertical exchanges of heat, carbon, oxygen, and other constituents. Thus, stratification is a central element of Earth's climate system. Global upper-ocean stratification continued its increasing trend in 2022 and was among the top seven on record. [2]

In the last few decades, the stratification in all of the ocean basins has increased. Furthermore, the southern oceans (south of 30°S) experienced the strongest rate of stratification since 1960, followed by the Pacific Ocean, the Atlantic Ocean, and the Indian Ocean. [1] When the upper ocean becomes more stratified, the mixed layer of surface water with homogeneous temperature may get shallower, but projected changes to mixed-layer depth by the end of the 21st century remain contested. [9] The regions with the currently deepest mixed layers are associated with the greatest mixed layer shoaling, particularly the North Atlantic and Southern Ocean basin. [9]

By looking at the GODAS Data [4] provided by the NOAA/OAR/ESRL PSL, the Buoyancy frequencies can be found from January 1980 up to and including March 2021. Since a change in stratification is mostly visible in the upper 500 meters of the ocean, very specific data is necessary in order to see this in a plot. The resulting plots from the GODAS Data might indicate that there is also a decrease in stratification looking at the differences of the stratification between the years 1980, 2000 and 2020. It is possible to see that the change in stratification is indeed the biggest in the first 500 meters of the ocean. From approximately 1000 meters into the ocean, the stratification converges toward a stable value and the change in stratification becomes almost non-existent.

Annual and latitudinal means of
N
2
{\displaystyle N^{2}}
for different ocean basins. This plot was generated using the GODAS Data of 1980, 2000 and 2020. Change of mean N^2.png
Annual and latitudinal means of for different ocean basins. This plot was generated using the GODAS Data of 1980, 2000 and 2020.
Change in annual and latitudinal means of
N
2
{\displaystyle N^{2}}
for different ocean basins. This plot was generated using the GODAS Data of 1980, 2000 and 2020. N2Change.png
Change in annual and latitudinal means of for different ocean basins. This plot was generated using the GODAS Data of 1980, 2000 and 2020.

In many scientific articles, magazines and blogs, it is claimed that the stratification has increased in all of the ocean basins (e.g in Ecomagazine.com [10] and NCAR & UCAR News [11] ). In the figure below, the trends of the change in stratification in all of the ocean basins have been plotted. [1] This data shows that over the years the stratification has drastically increased. The changes in stratification are greatest in the Southern Ocean, followed by the Pacific Ocean. In the Pacific Ocean, the increase of stratification in the eastern equatorial has found to be greater than in the western equatorial. [1] This is likely to be linked to the weakening of the trade winds and reduced upwelling in the eastern Pacific, which can be explained by the weakening of the Walker circulation. [1]

This figure shows the global change in stratification
N
2
{\displaystyle N^{2}}
since the year 1960 until 2018 from 0 to 2000 meters. (a) Global, (b) Pacific Ocean, (c) Atlantic Ocean, (d) Indian Ocean and (e) Southern oceans. The thin grey lines indicate the interannual variations. The small plot in (a) shows the rates of
N
2
{\displaystyle N^{2}}
for the global case and for the basins. This is calculated by centered differences of the smooth time series (Glb: Global, Pac: Pacific, Atl: Atlantic, So: Southern, Ind: Indian). The trends have been plotted for various datasets, indicated by the different lines. Schermafbeelding 2021-06-03 om 14.33.42.png
This figure shows the global change in stratification since the year 1960 until 2018 from 0 to 2000 meters. (a) Global, (b) Pacific Ocean, (c) Atlantic Ocean, (d) Indian Ocean and (e) Southern oceans. The thin grey lines indicate the interannual variations. The small plot in (a) shows the rates of for the global case and for the basins. This is calculated by centered differences of the smooth time series (Glb: Global, Pac: Pacific, Atl: Atlantic, So: Southern, Ind: Indian). The trends have been plotted for various datasets, indicated by the different lines.

Causes and consequences

Temperature and mixing

The change in temperature dominates the increasing stratification, while salinity only plays a role locally. [1] The ocean has an extraordinary ability of storing and transporting large amounts of heat, carbon and fresh water. [12] Even though approximately 70% of the Earth's surface consists of water, more than 75% of the water exchange between the Earth's surface and the atmosphere occurs over the oceans. The ocean absorbs part of the energy from sunlight as heat and is initially absorbed by the surface. [13] Eventually a part of this heat also spreads to deeper water. Greenhouse gases absorb extra energy from the sun, which is again absorbed by the oceans, leading to an increase in the amount of heat stored by the oceans. The increase of temperature of the oceans goes rather slow, compared to the atmosphere.

However, the ocean heat uptake has doubled since 1993 and oceans have absorbed over 90% of the extra heat of the Earth since 1955. [13] The temperature in the ocean, up to approximately 700 meters deep into the ocean, has been rising almost all over the globe. [12] The increased warming in the upper ocean reduces the density of the upper ~500 m of water, while deeper water does not experience as much warming and as great a decrease in density. Thus, the stratification in the upper layers will change more than in the lower layers, and these strengthening vertical density gradients act as barriers limiting mixing between the upper layers and deep-water.

There is limited evidence that seasonal differences in stratification have grown larger over the years. [9]

Salinity

The salinity is associated with the difference between evaporation and precipitation. [1] Ocean currents are important in moving fresh and saline waters around and in keeping a balance.

Evaporation causes the water to become more saline, and hence denser. Precipitation has the opposite effect, since it decreases the density of the surface water. Hence, it can be stated that salinity plays a more local role in the increase of stratification, even though it is less present compared to the influence of the temperature. For example, salinity plays an important role in the subtropical gyre, North (-East) Pacific, North Atlantic and Arctic regions. [1] [14]

In the Arctic, the decrease of salinity, and hence density, can be explained by the input of freshwater from melting glaciers and ice sheets. This process and the increase of stratification in the Arctic will continue with the current carbon emissions. [1]

De-oxygenation

A decline in dissolved oxygen, and hence in the oxygen supply to the ocean interior, is a likely effect of the increase in stratification in the upper ocean. [15] Since oxygen plays a direct and important role in the cycles of carbon, nitrogen and many other elements such as phosphorus, iron and magnesium, de-oxygenation will have large consequences. It plays a vital role for many organisms and the variety of ocean animals of all kinds.

The de-oxygenation in subsurface waters is due to the decrease in ocean mixing, which is caused by the increase of stratification in the upper ocean. [1] To illustrate, in the period between 1970 and 1990, approximately 15% of the de-oxygenation can be explained by an increase of temperature and the rest by reduced transport due to stratification. [12] In the period between 1967 and 2000 the decrease in oxygen concentration in the shallow waters, between 0 and 300 meters, was 10 times faster in the coastal ocean compared to the open ocean. [12] This has led to an increase of hypoxic zones, which can lead to a change in behavior of the aquatic flora and fauna. The increase of stratification in the upper ocean during the second half of the 21st century can lead to a decoupling between the surface and the deeper oceans. [14] This decoupling can cause de-oxygenation in the deeper ocean as well, since the decoupling makes it less likely for the oxygen to reach the deeper oceans.

Nevertheless, the change in oxygen concentration can also be influenced by changes in circulation and winds. And even though oxygen has decreased in many areas of the oceans, it can also increase locally, due to a variety of influences on the oxygen. For example, between 1990 and 2000, the oxygen in the thermocline of the Indian Ocean and South Pacific Ocean has increased. [12]

Mixed layer depth (MLD)

The surface mixed layer is the uppermost layer in the ocean and is well mixed by mechanical (wind) and thermal (convection) effects. Turbulence in this layer occurs through surface processes, for example wind stirring, surface heat fluxes and evaporation, The mixed layer is inherently the layer most connected to the atmosphere and affects and is affected by all weather systems, especially those with strong winds such as hurricanes. [16]   Heat stored in the mixed layer in the tropical western Pacific plays a vital role in El Nino development.

The depth of the mixed layer is associated with physical, chemical and biological systems and is one of the most important quantities in the upper ocean. [16] Throughout the year, the depth of the mixed layer varies. The thickness of the layer increases in wintertime and decreases in the summer. If the mixed layer is really deep, less light can reach the phytoplankton. Phytoplankton have been shown to be important in the global carbon cycle. [17] Furthermore, since phytoplankton are at the bottom of the food chain, a decrease in phytoplankton can have consequences on a very large scale.

An exact relation between an increase in stratification and a change in the mixed layer depth has not yet been determined and remains uncertain. Although some studies suggest that a thinner mixed layer should accompany a more stratified upper ocean, [18] [19] [20] other work reports seasonal deepening of the mixed layer since 1970. [21] There is literature substantiating the statement that in the years from 1970 to 2018, the stratification in the basis of the mixed layer as well as the depth of the mixed layer have increased. Contradicting this result, other literature states a decrease of the depth of the mixed layer partly as a result of the increase of upper-ocean stratification. [22] It has been found that the mixed layer in the extension of the Kuroshio Current, at the west side of the North Pacific, has decreased more than 30 meters. This shoaling is caused by weakening of wind and a reduction of seasonal vertical mixing. Furthermore, there exists research stating that heating of the surface of the ocean, and hence an increase in stratification, does not necessarily mean an increase nor decrease in the mixed layer depth. [23] Using the GODAS Data [4] it can be seen that the depth of the mixed layer has increased as well as decreased over time.

Between 1970 and 2018, the summertime mixed-layer depth (MLD) deepened by 2.9 ± 0.5% per decade (or 5 to 10 m per decade, depending on the region), and the Southern Ocean experienced the greatest deepening. [21] [23] However, there is limited observational evidence that the mixed layer is globally deepening, and only under strong greenhouse gas emissions scenarios do global mixed-layer depths shoal in the 21st century. [9] Although it is virtually certain that upper ocean stratification will increase through the 21st century, scientists express low confidence in how the mixed-layer depth will evolve. [9]

Annual means and change in annual means of the mixed layer depth of 1980, 2000 and 2020. This plot was generated using the GODAS Data. MixedLayerDepth(1980-2020).png
Annual means and change in annual means of the mixed layer depth of 1980, 2000 and 2020. This plot was generated using the GODAS Data.
Identification of regions with increase and decrease of annual means of the mixed layer depth of 1980, 2000 and 2020. This plot was generated using the GODAS Data. MixedLayerDepthChanges(1980-2020).png
Identification of regions with increase and decrease of annual means of the mixed layer depth of 1980, 2000 and 2020. This plot was generated using the GODAS Data.

See also

Related Research Articles

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<span class="mw-page-title-main">Internal wave</span> Type of gravity waves that oscillate within a fluid medium

Internal waves are gravity waves that oscillate within a fluid medium, rather than on its surface. To exist, the fluid must be stratified: the density must change with depth/height due to changes, for example, in temperature and/or salinity. If the density changes over a small vertical distance, the waves propagate horizontally like surface waves, but do so at slower speeds as determined by the density difference of the fluid below and above the interface. If the density changes continuously, the waves can propagate vertically as well as horizontally through the fluid.

In atmospheric dynamics, oceanography, asteroseismology and geophysics, the Brunt–Väisälä frequency, or buoyancy frequency, is a measure of the stability of a fluid to vertical displacements such as those caused by convection. More precisely it is the frequency at which a vertically displaced parcel will oscillate within a statically stable environment. It is named after David Brunt and Vilho Väisälä. It can be used as a measure of atmospheric stratification.

<span class="mw-page-title-main">Mixed layer</span> Layer in which active turbulence has homogenized some range of depths

The oceanic or limnological mixed layer is a layer in which active turbulence has homogenized some range of depths. The surface mixed layer is a layer where this turbulence is generated by winds, surface heat fluxes, or processes such as evaporation or sea ice formation which result in an increase in salinity. The atmospheric mixed layer is a zone having nearly constant potential temperature and specific humidity with height. The depth of the atmospheric mixed layer is known as the mixing height. Turbulence typically plays a role in the formation of fluid mixed layers.

The potential density of a fluid parcel at pressure is the density that the parcel would acquire if adiabatically brought to a reference pressure , often 1 bar. Whereas density changes with changing pressure, potential density of a fluid parcel is conserved as the pressure experienced by the parcel changes. The concept is used in oceanography and atmospheric science.

Spice, spiciness, or spicity, symbol τ, is a term in oceanography referring to variations in the temperature and salinity of seawater over space or time, whose combined effects leave the water's density unchanged. For a given spice, any change in temperature is offset by a change in salinity to maintain unchanged density. An increase in temperature decreases density, but an increase in salinity increases density. Such density-compensated thermohaline variability is ubiquitous in the upper ocean. Warmer, saltier water is more spicy while cooler, less salty water is more minty. For a density ratio of 1, all the thermohaline variability is spice, and there are no density fluctuations.

Ocean dynamics define and describe the flow of water within the oceans. Ocean temperature and motion fields can be separated into three distinct layers: mixed (surface) layer, upper ocean, and deep ocean.

<span class="mw-page-title-main">Double diffusive convection</span> Convection with two density gradients

Double diffusive convection is a fluid dynamics phenomenon that describes a form of convection driven by two different density gradients, which have different rates of diffusion.

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<span class="mw-page-title-main">Sea ice growth processes</span>

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<span class="mw-page-title-main">Barrier layer (oceanography)</span> Layer of water separating the well-mixed surface layer from the thermocline

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The density ratio of a column of seawater is a measure of the relative contributions of temperature and salinity in determining the density gradient. At a density ratio of 1, temperature and salinity are said to be compensated: their density signatures cancel, leaving a density gradient of zero. The formula for the density ratio, , is:

<span class="mw-page-title-main">Stratification (water)</span> Layering of a body of water due to density variations

Stratification in water is the formation in a body of water of relatively distinct and stable layers by density. It occurs in all water bodies where there is stable density variation with depth. Stratification is a barrier to the vertical mixing of water, which affects the exchange of heat, carbon, oxygen and nutrients. Wind-driven upwelling and downwelling of open water can induce mixing of different layers through the stratification, and force the rise of denser cold, nutrient-rich, or saline water and the sinking of lighter warm or fresher water, respectively. Layers are based on water density: denser water remains below less dense water in stable stratification in the absence of forced mixing.

<span class="mw-page-title-main">Turner angle</span>

The Turner angleTu, introduced by Ruddick(1983) and named after J. Stewart Turner, is a parameter used to describe the local stability of an inviscid water column as it undergoes double-diffusive convection. The temperature and salinity attributes, which generally determine the water density, both respond to the water vertical structure. By putting these two variables in orthogonal coordinates, the angle with the axis can indicate the importance of the two in stability. Turner angle is defined as:

Open ocean convection is a process in which the mesoscale ocean circulation and large, strong winds mix layers of water at different depths. Fresher water lying over the saltier or warmer over the colder leads to the stratification of water, or its separation into layers. Strong winds cause evaporation, so the ocean surface cools, weakening the stratification. As a result, the surface waters are overturned and sink while the "warmer" waters rise to the surface, starting the process of convection. This process has a crucial role in the formation of both bottom and intermediate water and in the large-scale thermohaline circulation, which largely determines global climate. It is also an important phenomena that controls the intensity of the Atlantic Meridional Overturning Circulation (AMOC).

The Haline contraction coefficient, abbreviated as β, is a coefficient that describes the change in ocean density due to a salinity change, while the potential temperature and the pressure are kept constant. It is a parameter in the Equation Of State (EOS) of the ocean. β is also described as the saline contraction coefficient and is measured in [kg]/[g] in the EOS that describes the ocean. An example is TEOS-10. This is the thermodynamic equation of state.

Thermohaline staircases are patterns that form in oceans and other bodies of salt water, characterised by step-like structures observed in vertical temperature and salinity profiles; the patterns are formed and maintained by double diffusion of heat and salt. The ocean phenomenon consists of well-mixed layers of ocean water stacked on top of each other. The well-mixed layers are separated by high-gradient interfaces, which can be several meters thick. The total thickness of staircases ranges typically from tens to hundreds of meters.

<span class="mw-page-title-main">Faroe-Bank Channel overflow</span> Overflow current from Nordic Seas towards North Atlantic Ocean

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Oceanic freshwater fluxes are defined as the transport of non saline water between the oceans and the other components of the Earth's system. These fluxes have an impact on the local ocean properties, as well as on the large scale circulation patterns.

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