Transmittance

Last updated March 23, 2024

In optical physics, transmittance of the surface of a material is its effectiveness in transmitting radiant energy. It is the fraction of incident electromagnetic power that is transmitted through a sample, in contrast to the transmission coefficient, which is the ratio of the transmitted to incident electric field.^[2]

Mathematical definitions

Hemispherical transmittance

Hemispherical transmittance of a surface, denoted T, is defined as^[3]

T={\frac {\Phi _{\mathrm {e} }^{\mathrm {t} }}{\Phi _{\mathrm {e} }^{\mathrm {i} }}},

where

Φ_e^t is the radiant flux transmitted by that surface;
Φ_eⁱ is the radiant flux received by that surface.

Spectral hemispherical transmittance

Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted T_ν and T_λ respectively, are defined as^[3]

T_{\nu }={\frac {\Phi _{\mathrm {e} ,\nu }^{\mathrm {t} }}{\Phi _{\mathrm {e} ,\nu }^{\mathrm {i} }}},

T_{\lambda }={\frac {\Phi _{\mathrm {e} ,\lambda }^{\mathrm {t} }}{\Phi _{\mathrm {e} ,\lambda }^{\mathrm {i} }}},

where

Φ_e,ν^t is the spectral radiant flux in frequency transmitted by that surface;
Φ_e,νⁱ is the spectral radiant flux in frequency received by that surface;
Φ_e,λ^t is the spectral radiant flux in wavelength transmitted by that surface;
Φ_e,λⁱ is the spectral radiant flux in wavelength received by that surface.

Directional transmittance

Directional transmittance of a surface, denoted T_Ω, is defined as^[3]

T_{\Omega }={\frac {L_{\mathrm {e} ,\Omega }^{\mathrm {t} }}{L_{\mathrm {e} ,\Omega }^{\mathrm {i} }}},

where

L_e,Ω^t is the radiance transmitted by that surface;
L_e,Ωⁱ is the radiance received by that surface.

Spectral directional transmittance

Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted T_ν,Ω and T_λ,Ω respectively, are defined as^[3]

T_{\nu ,\Omega }={\frac {L_{\mathrm {e} ,\Omega ,\nu }^{\mathrm {t} }}{L_{\mathrm {e} ,\Omega ,\nu }^{\mathrm {i} }}},

T_{\lambda ,\Omega }={\frac {L_{\mathrm {e} ,\Omega ,\lambda }^{\mathrm {t} }}{L_{\mathrm {e} ,\Omega ,\lambda }^{\mathrm {i} }}},

where

L_e,Ω,ν^t is the spectral radiance in frequency transmitted by that surface;
L_e,Ω,νⁱ is the spectral radiance received by that surface;
L_e,Ω,λ^t is the spectral radiance in wavelength transmitted by that surface;
L_e,Ω,λⁱ is the spectral radiance in wavelength received by that surface.

Luminous transmittance

In the field of photometry (optics), the luminous transmittance of a filter is a measure of the amount of luminous flux or intensity transmitted by an optical filter. It is generally defined in terms of a standard illuminant (e.g. Illuminant A, Iluminant C, or Illuminant E). The luminous transmittance with respect to the standard illuminant is defined as:

T_{lum}={\frac {\int _{0}^{\infty }I(\lambda )T(\lambda )V(\lambda )d\lambda }{\int _{0}^{\infty }I(\lambda )V(\lambda )d\lambda }}

where:

$I(\lambda )$ is the spectral radiant flux or intensity of the standard illuminant (unspecified magnitude).
$T(\lambda )$ is the spectral transmittance of the filter
$V(\lambda )$ is the luminous efficiency function

The luminous transmittance is independent of the magnitude of the flux or intensity of the standard illuminant used to measure it, and is a dimensionless quantity.

Beer–Lambert law

By definition, internal transmittance is related to optical depth and to absorbance as

T=e^{-\tau }=10^{-A},

where

τ is the optical depth;
A is the absorbance.

The Beer–Lambert law states that, for N attenuating species in the material sample,

T=e^{-\sum _{i=1}^{N}\sigma _{i}\int _{0}^{\ell }n_{i}(z)\mathrm {d} z}=10^{-\sum _{i=1}^{N}\varepsilon _{i}\int _{0}^{\ell }c_{i}(z)\mathrm {d} z},

or equivalently that

\tau =\sum _{i=1}^{N}\tau _{i}=\sum _{i=1}^{N}\sigma _{i}\int _{0}^{\ell }n_{i}(z)\,\mathrm {d} z,

A=\sum _{i=1}^{N}A_{i}=\sum _{i=1}^{N}\varepsilon _{i}\int _{0}^{\ell }c_{i}(z)\,\mathrm {d} z,

where

σ_i is the attenuation cross section of the attenuating species i in the material sample;
n_i is the number density of the attenuating species i in the material sample;
ε_i is the molar attenuation coefficient of the attenuating species i in the material sample;
c_i is the amount concentration of the attenuating species i in the material sample;
ℓ is the path length of the beam of light through the material sample.

Attenuation cross section and molar attenuation coefficient are related by

\varepsilon _{i}={\frac {\mathrm {N_{A}} }{\ln {10}}}\,\sigma _{i},

and number density and amount concentration by

c_{i}={\frac {n_{i}}{\mathrm {N_{A}} }},

where N_A is the Avogadro constant.

In case of uniform attenuation, these relations become^[4]

T=e^{-\sum _{i=1}^{N}\sigma _{i}n_{i}\ell }=10^{-\sum _{i=1}^{N}\varepsilon _{i}c_{i}\ell },

or equivalently

\tau =\sum _{i=1}^{N}\sigma _{i}n_{i}\ell ,

A=\sum _{i=1}^{N}\varepsilon _{i}c_{i}\ell .

Cases of non-uniform attenuation occur in atmospheric science applications and radiation shielding theory for instance.

Other radiometric coefficients

Radiometry coefficients
v
t
e
Quantity		SI units	Notes
Name	Sym.	SI units	Notes
Hemispherical emissivity	$ε$	—	Radiant exitance of a surface, divided by that of a black body at the same temperature as that surface.
Spectral hemispherical emissivity	$ε ν$ $ε λ$	—	Spectral exitance of a surface, divided by that of a black body at the same temperature as that surface.
Directional emissivity	$ε Ω$	—	Radiance emitted by a surface, divided by that emitted by a black body at the same temperature as that surface.
Spectral directional emissivity	$ε Ω, ν$ $ε Ω, λ$	—	Spectral radiance emitted by a surface, divided by that of a black body at the same temperature as that surface.
Hemispherical absorptance	$A$	—	Radiant flux absorbed by a surface, divided by that received by that surface. This should not be confused with "absorbance".
Spectral hemispherical absorptance	$A ν$ $A λ$	—	Spectral flux absorbed by a surface, divided by that received by that surface. This should not be confused with "spectral absorbance".
Directional absorptance	$A Ω$	—	Radiance absorbed by a surface, divided by the radiance incident onto that surface. This should not be confused with "absorbance".
Spectral directional absorptance	$A Ω, ν$ $A Ω, λ$	—	Spectral radiance absorbed by a surface, divided by the spectral radiance incident onto that surface. This should not be confused with "spectral absorbance".
Hemispherical reflectance	$R$	—	Radiant flux reflected by a surface, divided by that received by that surface.
Spectral hemispherical reflectance	$R ν$ $R λ$	—	Spectral flux reflected by a surface, divided by that received by that surface.
Directional reflectance	$R Ω$	—	Radiance reflected by a surface, divided by that received by that surface.
Spectral directional reflectance	$R Ω, ν$ $R Ω, λ$	—	Spectral radiance reflected by a surface, divided by that received by that surface.
Hemispherical transmittance	$T$	—	Radiant flux transmitted by a surface, divided by that received by that surface.
Spectral hemispherical transmittance	$T ν$ $T λ$	—	Spectral flux transmitted by a surface, divided by that received by that surface.
Directional transmittance	$T Ω$	—	Radiance transmitted by a surface, divided by that received by that surface.
Spectral directional transmittance	$T Ω,ν$ $T Ω, λ$	—	Spectral radiance transmitted by a surface, divided by that received by that surface.
Hemispherical attenuation coefficient	$μ$	m⁻¹	Radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral hemispherical attenuation coefficient	$μ ν$ $μ λ$	m⁻¹	Spectral radiant flux absorbed and scattered by a volume per unit length, divided by that received by that volume.
Directional attenuation coefficient	$μ Ω$	m⁻¹	Radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.
Spectral directional attenuation coefficient	$μ Ω, ν$ $μ Ω, λ$	m⁻¹	Spectral radiance absorbed and scattered by a volume per unit length, divided by that received by that volume.

Related Research Articles

The Beer-Lambert law is commonly applied to chemical analysis measurements to determine the concentration of chemical species that absorb light. It is often referred to as Beer's law. In physics, the Bouguer–Lambert law is an empirical law which relates the extinction or attenuation of light to the properties of the material through which the light is travelling. It had its first use in astronomical extinction. The fundamental law of extinction is sometimes called the Beer-Bouguer-Lambert law or the Bouguer-Beer-Lambert law or merely the extinction law. The extinction law is also used in understanding attenuation in physical optics, for photons, neutrons, or rarefied gases. In mathematical physics, this law arises as a solution of the BGK equation.

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In physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to transmitted radiant power through a material. Thus, the larger the optical depth, the smaller the amount of transmitted radiant power through the material. Spectral optical depth or spectral optical thickness is the natural logarithm of the ratio of incident to transmitted spectral radiant power through a material. Optical depth is dimensionless, and in particular is not a length, though it is a monotonically increasing function of optical path length, and approaches zero as the path length approaches zero. The use of the term "optical density" for optical depth is discouraged.

Radiometry is a set of techniques for measuring electromagnetic radiation, including visible light. Radiometric techniques in optics characterize the distribution of the radiation's power in space, as opposed to photometric techniques, which characterize the light's interaction with the human eye. The fundamental difference between radiometry and photometry is that radiometry gives the entire optical radiation spectrum, while photometry is limited to the visible spectrum. Radiometry is distinct from quantum techniques such as photon counting.

<span class="mw-page-title-main">Reflectance</span> Capacity of an object to reflect light

The reflectance of the surface of a material is its effectiveness in reflecting radiant energy. It is the fraction of incident electromagnetic power that is reflected at the boundary. Reflectance is a component of the response of the electronic structure of the material to the electromagnetic field of light, and is in general a function of the frequency, or wavelength, of the light, its polarization, and the angle of incidence. The dependence of reflectance on the wavelength is called a reflectance spectrum or spectral reflectance curve.

In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature $T$ , when there is no net flow of matter or energy between the body and its environment.

Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample ". Alternatively, for samples which scatter light, absorbance may be defined as "the negative logarithm of one minus absorptance, as measured on a uniform sample". The term is used in many technical areas to quantify the results of an experimental measurement. While the term has its origin in quantifying the absorption of light, it is often entangled with quantification of light which is “lost” to a detector system through other mechanisms. What these uses of the term tend to have in common is that they refer to a logarithm of the ratio of a quantity of light incident on a sample or material to that which is detected after the light has interacted with the sample.

In radiometry, radiance is the radiant flux emitted, reflected, transmitted or received by a given surface, per unit solid angle per unit projected area. Radiance is used to characterize diffuse emission and reflection of electromagnetic radiation, and to quantify emission of neutrinos and other particles. The SI unit of radiance is the watt per steradian per square metre. It is a directional quantity: the radiance of a surface depends on the direction from which it is being observed.

In radiometry, irradiance is the radiant flux received by a surface per unit area. The SI unit of irradiance is the watt per square metre (W⋅m⁻²). The CGS unit erg per square centimetre per second (erg⋅cm⁻²⋅s⁻¹) is often used in astronomy. Irradiance is often called intensity, but this term is avoided in radiometry where such usage leads to confusion with radiant intensity. In astrophysics, irradiance is called radiant flux.

In radiometry, radiant intensity is the radiant flux emitted, reflected, transmitted or received, per unit solid angle, and spectral intensity is the radiant intensity per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. These are directional quantities. The SI unit of radiant intensity is the watt per steradian, while that of spectral intensity in frequency is the watt per steradian per hertz and that of spectral intensity in wavelength is the watt per steradian per metre —commonly the watt per steradian per nanometre. Radiant intensity is distinct from irradiance and radiant exitance, which are often called intensity in branches of physics other than radiometry. In radio-frequency engineering, radiant intensity is sometimes called radiation intensity.

In computer graphics, the rendering equation is an integral equation in which the equilibrium radiance leaving a point is given as the sum of emitted plus reflected radiance under a geometric optics approximation. It was simultaneously introduced into computer graphics by David Immel et al. and James Kajiya in 1986. The various realistic rendering techniques in computer graphics attempt to solve this equation.

Etendue or étendue is a property of light in an optical system, which characterizes how "spread out" the light is in area and angle. It corresponds to the beam parameter product (BPP) in Gaussian beam optics. Other names for etendue include acceptance, throughput, light grasp, light-gathering power, optical extent, and the AΩ product. Throughput and AΩ product are especially used in radiometry and radiative transfer where it is related to the view factor. It is a central concept in nonimaging optics.

In radiometry, radiant flux or radiant power is the radiant energy emitted, reflected, transmitted, or received per unit time, and spectral flux or spectral power is the radiant flux per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of radiant flux is the watt (W), one joule per second, while that of spectral flux in frequency is the watt per hertz and that of spectral flux in wavelength is the watt per metre —commonly the watt per nanometre.

In radiometry, radiant exitance or radiant emittance is the radiant flux emitted by a surface per unit area, whereas spectral exitance or spectral emittance is the radiant exitance of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. This is the emitted component of radiosity. The SI unit of radiant exitance is the watt per square metre, while that of spectral exitance in frequency is the watt per square metre per hertz (W·m⁻²·Hz⁻¹) and that of spectral exitance in wavelength is the watt per square metre per metre (W·m⁻³)—commonly the watt per square metre per nanometre. The CGS unit erg per square centimeter per second is often used in astronomy. Radiant exitance is often called "intensity" in branches of physics other than radiometry, but in radiometry this usage leads to confusion with radiant intensity.

<span class="mw-page-title-main">Penetration depth</span> The depth light can penetrate into a material

Penetration depth is a measure of how deep light or any electromagnetic radiation can penetrate into a material. It is defined as the depth at which the intensity of the radiation inside the material falls to 1/e of its original value at the surface.

In radiometry, radiosity is the radiant flux leaving a surface per unit area, and spectral radiosity is the radiosity of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of radiosity is the watt per square metre, while that of spectral radiosity in frequency is the watt per square metre per hertz (W·m⁻²·Hz⁻¹) and that of spectral radiosity in wavelength is the watt per square metre per metre (W·m⁻³)—commonly the watt per square metre per nanometre. The CGS unit erg per square centimeter per second is often used in astronomy. Radiosity is often called intensity in branches of physics other than radiometry, but in radiometry this usage leads to confusion with radiant intensity.

The linear attenuation coefficient, attenuation coefficient, or narrow-beam attenuation coefficient characterizes how easily a volume of material can be penetrated by a beam of light, sound, particles, or other energy or matter. A coefficient value that is large represents a beam becoming 'attenuated' as it passes through a given medium, while a small value represents that the medium had little effect on loss. The (derived) SI unit of attenuation coefficient is the reciprocal metre (m⁻¹). Extinction coefficient is another term for this quantity, often used in meteorology and climatology. Most commonly, the quantity measures the exponential decay of intensity, that is, the value of downward e-folding distance of the original intensity as the energy of the intensity passes through a unit thickness of material, so that an attenuation coefficient of 1 m⁻¹ means that after passing through 1 metre, the radiation will be reduced by a factor of e, and for material with a coefficient of 2 m⁻¹, it will be reduced twice by e, or e². Other measures may use a different factor than e, such as the decadic attenuation coefficient below. The broad-beam attenuation coefficient counts forward-scattered radiation as transmitted rather than attenuated, and is more applicable to radiation shielding. The mass attenuation coefficient is the attenuation coefficient normalized by the density of the material.

In the study of heat transfer, absorptance of the surface of a material is its effectiveness in absorbing radiant energy. It is the ratio of the absorbed to the incident radiant power.

In fluid dynamics, a flow with periodic variations is known as pulsatile flow, or as Womersley flow. The flow profiles was first derived by John R. Womersley (1907–1958) in his work with blood flow in arteries. The cardiovascular system of chordate animals is a very good example where pulsatile flow is found, but pulsatile flow is also observed in engines and hydraulic systems, as a result of rotating mechanisms pumping the fluid.

In radiometry, radiant exposure or fluence is the radiant energy received by a surface per unit area, or equivalently the irradiance of a surface, integrated over time of irradiation, and spectral exposure is the radiant exposure per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of radiant exposure is the joule per square metre, while that of spectral exposure in frequency is the joule per square metre per hertz and that of spectral exposure in wavelength is the joule per square metre per metre —commonly the joule per square metre per nanometre.

References

↑ "Electronic warfare and radar systems engineering handbook". Archived from the original on September 13, 2001.{{cite web}}: CS1 maint: unfit URL (link)
↑ IUPAC , Compendium of Chemical Terminology , 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) " Transmittance ". doi : 10.1351/goldbook.T06484
1 2 3 4 "Thermal insulation — Heat transfer by radiation — Physical quantities and definitions". ISO 9288:1989. ISO catalogue. 1989. Retrieved 2015-03-15.
↑ IUPAC , Compendium of Chemical Terminology , 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) " Beer–Lambert law ". doi : 10.1351/goldbook.B00626

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[1] "Electronic warfare and radar systems engineering handbook". Archived from the original on September 13, 2001.{{cite web}}: CS1 maint: unfit URL (link)

[GoldBook-2] IUPAC , Compendium of Chemical Terminology , 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) " Transmittance ". doi : 10.1351/goldbook.T06484

[ISO_9288-1989-3] 1 2 3 4 "Thermal insulation — Heat transfer by radiation — Physical quantities and definitions". ISO 9288:1989. ISO catalogue. 1989. Retrieved 2015-03-15.

[GoldBook2-4] IUPAC , Compendium of Chemical Terminology , 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) " Beer–Lambert law ". doi : 10.1351/goldbook.B00626

[2]

[3]

[4]

Transmittance

Contents

Mathematical definitions

Hemispherical transmittance

Spectral hemispherical transmittance

Directional transmittance

Spectral directional transmittance

Luminous transmittance

Beer–Lambert law

Other radiometric coefficients

See also

Related Research Articles

References