Polydymite

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Polydymite
Polydymite-614287.jpg
General
Category Sulfide mineral
Thiospinel group
Spinel structural group
Formula
(repeating unit)
Ni3S4
IMA symbol Pld [1]
Strunz classification 2.DA.05
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Fd3m
Unit cell a = 9.48 Å; Z = 8
Identification
ColorPale to steel-gray
Crystal habit As octahedral crystals, massive, granular to compact
Twinning Twinning on {111}
Cleavage Indistinct on {001}
Fracture Conchoidal to uneven
Mohs scale hardness4.5 – 5.5
Luster Metallic
Streak Black gray
Diaphaneity Opaque
Specific gravity 4.5 – 4.8
Alters toTarnishes to copper-red
References [2] [3] [4] [5]

Polydymite, Ni2+Ni23+S4, is a supergene thiospinel sulfide mineral associated with the weathering of primary pentlandite nickel sulfide.

Contents

Polydymite crystallises in the isometric system, with a hardness of 4.5 to 5.5 and a specific gravity of about 4, is dark violet gray to copper-red, often with verdigris and patina from associated copper and arsenic sulfides, and is typically in amorphous to massive infill of lower saprolite ultramafic lithologies.

Polydymite is the nickel equivalent of violarite and in many cases these two minerals are formed together, potentially in solid solution.

Common contaminants of polydymite are cobalt and iron. Polydymite forms a series with linnaeite, Co+2Co+32S4. [6]

Paragenesis

Polydymite is formed by oxidisation of primary sulfide assemblages in nickel sulfide mineralisation. The process of formation involves oxidation of Ni2+ and Fe2+ which is contained within the primary pentlandite-pyrrhotite-pyrite assemblage.

Continued oxidation of polydymite leads to replacement by goethite and formation of a gossanous boxwork, with nickel tending to remain as impurities within the goethite or hematite, or rarely as carbonate minerals.

Occurrence

Polydymite is reported widely from the oxidised regolith above primary nickel sulfide ore systems worldwide. It is less common than related violarite, due to the high iron content of most primary sulfides.

Economic importance

Polydymite is an important transitional ore in many nickel sulfide mines, as it has increased nickel tenor (Ni% as a total of sulfide) and occupies a position within the mineralised profile where it must be extracted to pay for development down to the more valuable primary (hypogene) mineralisation.

Related Research Articles

Ore Rock with valuable metals, minerals and elements

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Pentlandite Iron–nickel sulfide

Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of weight.

Nickeline Nickel arsenide mineral

Nickeline or niccolite is a mineral consisting of nickel arsenide (NiAs) containing 43.9% nickel and 56.1% arsenic.

Pyrrhotite Magnetic iron sulfide mineral

Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.

Trevorite

Trevorite is a rare nickel iron oxide mineral belonging to the spinel group. It has the chemical formula NiFe3+2O4. It is a black mineral with the typical spinel properties of crystallising in the cubic system, black streaked, infusible and insoluble in most acids.

Ore genesis How the various types of mineral deposits form within the Earths crust

Various theories of ore genesis explain how the various types of mineral deposits form within the Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.

Kambalda type komatiitic nickel ore deposits are a class of magmatic iron-nickel-copper-platinum-group element ore deposit in which the physical processes of komatiite volcanology serve to deposit, concentrate and enrich a Fe-Ni-Cu-(PGE) sulfide melt within the lava flow environment of an erupting komatiite volcano.

In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene enrichment occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surface waters.

Gaspéite

Gaspéite, a very rare nickel carbonate mineral, with the formula (Ni,Fe,Mg)CO3, is named for the place it was first described, in the Gaspé Peninsula, Québec, Canada.

Kambaldaite

Kambaldaite, NaNi4(CO3)3(OH)3·3H2O, is an extremely rare hydrated sodium nickel carbonate mineral described from gossanous material associated with Kambalda type komatiitic nickel ore deposits at Kambalda, Western Australia, and Widgie Townsite nickel gossan, Widgiemooltha, Western Australia.

Violarite (Fe2+Ni23+S4) is a supergene sulfide mineral associated with the weathering and oxidation of primary pentlandite nickel sulfide ore minerals.

Mineral redox buffer

In geology, a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently, oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history. Iron, sulfur, and manganese are three of the relatively abundant elements in the Earth's crust that occur in more than one oxidation state. For instance, iron, the fourth most abundant element in the crust, exists as native iron, ferrous iron (Fe2+), and ferric iron (Fe3+). The redox state of a rock affects the relative proportions of the oxidation states of these elements and hence may determine both the minerals present and their compositions. If a rock contains pure minerals that constitute a redox buffer, then the oxygen fugacity of equilibration is defined by one of the curves in the accompanying fugacity-temperature diagram.

The Widgiemooltha Komatiite is a formation of komatiite in the Yilgarn Craton of Western Australia.

Carrollite

Carrollite, CuCo2S4, is a sulfide of copper and cobalt, often with substantial substitution of nickel for the metal ions, and a member of the linnaeite group. It is named after the type locality in Carroll County, Maryland, US, at the Patapsco mine, Sykesville.

Linnaeite is a cobalt sulfide mineral with the composition Co+2Co+32S4. It was discovered in 1845 in Västmanland, Sweden, and was named to honor Carl Linnaeus (1707–1778).

Cattierite

Cattierite (CoS2) is a cobalt sulfide mineral found in the Democratic Republic of Congo. It was discovered together with the nickel sulfide vaesite by Johannes F. Vaes, a Belgian mineralologist and named after Felicien Cattier, who was chairman of the board of the Union Miniere du Haut Katanga.

Cubanite

Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system. Cubanite is chemically similar to chalcopyrite, however it is the less common copper iron sulfide mineral due to crystallization requirements.

Iron oxide copper gold ore deposits (IOCG) are important and highly valuable concentrations of copper, gold and uranium ores hosted within iron oxide dominant gangue assemblages which share a common genetic origin.

Saprolite Chemically weathered rock

Saprolite is a chemically weathered rock. Saprolites form in the lower zones of soil profiles and represent deep weathering of the bedrock surface. In most outcrops its color comes from ferric compounds. Deeply weathered profiles are widespread on the continental landmasses between latitudes 35°N and 35°S.

Millerite Nickel sulfide mineral

Millerite is a nickel sulfide mineral, NiS. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85: 291–320.
  2. Mineralienatlas
  3. Polydymite on Mindat.org
  4. Polydymite in the Handbook of Mineralogy
  5. Polydymite data on Webmineral
  6. Linnaeite-Polydymite Series