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Nickel nitrate is the inorganic compound Ni(NO3)2 or any hydrate thereof. The anhydrous form is not commonly encountered, thus "nickel nitrate" usually refers to nickel(II) nitrate hexahydrate. The formula for this species is written in two ways: Ni(NO3)2.6H2O and, more descriptively [Ni(H2O)6](NO3)2. The latter formula indicates that the nickel(II) center is surrounded by six water molecules in this hydrated salt. In the hexahydrate, the nitrate anions are not bonded to nickel. Also known are three other hydrates: Ni(NO3)2.9H2O, Ni(NO3)2.4H2O, and Ni(NO3)2.2H2O. Anhydrous Ni(NO3)2 is also known.
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References
- ↑ Hathaway, B. J.; Slade, R. C. (1966). "The properties of trirubidium pentanitronickelate(II)". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1485. doi:10.1039/J19660001485.
- 1 2 3 4 Goodgame, David M. L.; Hitchman, M. A. (April 1967). "Spectroscopic studies of some compounds with octahedral polynitrite anions". Inorganic Chemistry. 6 (4): 813–816. doi:10.1021/ic50050a034.
- 1 2 Green, RW; Bell, B (1973). "Complex nickel nitrites. I. Complexes of N-substituted Propane-1,3-diamines". Australian Journal of Chemistry. 26 (8): 1663. doi:10.1071/CH9731663.
- 1 2 Grey, Ian E.; Hitchman, Michael A.; Rowbottom, Graham L.; Scarlett, Nicola V. Y.; Wilson, Jenny (1994-01-01). "Crystal and molecular structure and spectra of K4[Ni(NO2)6]·H2O and K3[Ni(NO2)4(O2N)]". Journal of the Chemical Society, Dalton Transactions (4): 595–601. doi:10.1039/DT9940000595. ISSN 1364-5447.
- ↑ Hathaway, B. J.; Slade, R. C. (1968). "The influence of cations on the properties of the hexanitrometallate anions in the K2MIIMII(NO2)6 type of complex of the nickel(II) and copper(II) ions". Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 85. doi:10.1039/J19680000085.
- ↑ Takagi, S.; Joesten, M. D.; Lenhert, P. G. (15 August 1976). "Potassium strontium hexanitrocuprate(II) and potassium strontium hexanitronickelate(II)". Acta Crystallographica Section B. 32 (8): 2524–2526. doi:10.1107/S0567740876008121.
- ↑ Takagi, S.; Joesten, M. D.; Lenhert, P. G. (15 July 1975). "Potassium barium hexanitronickelate(II)". Acta Crystallographica Section B. 31 (7): 1970–1972. doi:10.1107/S0567740875006590.
- ↑ Takagi, S.; Joesten, M. D.; Lenhert, P. G. (15 July 1975). "Potassium lead hexanitronickelate(II)". Acta Crystallographica Section B. 31 (7): 1968–1970. doi:10.1107/S0567740875006589.
- ↑ Chou, Liang-Kuei; Abboud, Khalil A.; Talham, Daniel R.; Kim, W. W.; Meisel, Mark W. (November 1994). "Structure- and Orientation-Dependent Magnetic Susceptibility of Tetramethylammonium Nickel Nitrite, (CH3)4N[Ni(NO2)3]: An S = 1 One-Dimensional Heisenberg Antiferromagnet". Chemistry of Materials. 6 (11): 2051–2055. doi:10.1021/cm00047a026.
- ↑ Kong, Li-Hui; Fu, Da-Wei; Ye, Qiong; Ye, Heng-Yun; Zhang, Yi; Xiong, Ren-Gen (June 2014). "Iso-structural phase transition in tetramethylammonium nickel(II) nitrite [(CH3)4N][Ni(NO2)3]". Chinese Chemical Letters. 25 (6): 844–848. doi:10.1016/j.cclet.2014.05.028.