Germanide

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A germanide is any binary compound of germanium and a more electropositive element. The composition of most germanides is analogous to that of the corresponding silicides and does not follow formal valence rules. The germanides of alkali and alkaline earth metals, are readily decomposed by water and acids to give germanium hydrides; most germanides of the transition metals resist the action of acids and alkalies. The main method of producing germanides is the melting or sintering of the components. [1] [2]

The IUPAC Red Book uses the name tetragermide for compounds containing Ge4− and instead uses the term germanide (or trihydridogermanate(1-)) for the GeH3 anion. [3]

Examples

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<span class="mw-page-title-main">Digermane</span> Chemical compound

Digermane is an inorganic compound with the chemical formula Ge2H6. One of the few hydrides of germanium, it is a colourless liquid. Its molecular geometry is similar to ethane.

Germyl, trihydridogermanate(1-), trihydrogermanide, trihydridogermyl or according to IUPAC Red Book: germanide is an anion containing germanium bounded with three hydrogens, with formula GeH−3. Germyl is the IUPAC term for the –GeH3 group. For less electropositive elements the bond can be considered covalent rather than ionic as "germanide" indicates. Germanide is the base for germane when it loses a proton.

Germanium compounds are chemical compounds formed by the element germanium (Ge). Germanium is insoluble in dilute acids and alkalis but dissolves slowly in hot concentrated sulfuric and nitric acids and reacts violently with molten alkalis to produce germanates ([GeO
3
]2−
). Germanium occurs mostly in the oxidation state +4 although many +2 compounds are known. Other oxidation states are rare: +3 is found in compounds such as Ge2Cl6, and +3 and +1 are found on the surface of oxides, or negative oxidation states in germanides, such as −4 in Mg
2
Ge
. Germanium cluster anions (Zintl ions) such as Ge42−, Ge94−, Ge92−, [(Ge9)2]6− have been prepared by the extraction from alloys containing alkali metals and germanium in liquid ammonia in the presence of ethylenediamine or a cryptand. The oxidation states of the element in these ions are not integers—similar to the ozonides O3.

References

  1. "Germanides definition of Germanides in the Free Online Encyclopedia". Encyclopedia2.thefreedictionary.com. Retrieved 2011-10-08.
  2. "germanide - Wiktionary". En.wiktionary.org. 2011-04-09. Retrieved 2011-10-08.
  3. Red Book. IUPAC. 2005. p. 298.