Lead(II) hydroxide

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Lead(II) hydroxide
Hydroxid olovnaty.PNG
Names
IUPAC name
Lead(II) hydroxide
Other names
  • Lead hydroxide
  • Plumbous hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.039.358 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 243-310-3
PubChem CID
  • InChI=1S/2H2O.Pb/h2*1H2;/q;;+2/p-2 Yes check.svgY
    Key: VNZYIVBHUDKWEO-UHFFFAOYSA-L Yes check.svgY
  • InChI=1/2H2O.Pb/h2*1H2;/q;;+2/p-2
    Key: VNZYIVBHUDKWEO-NUQVWONBAE
  • [OH-].[OH-].[Pb+2]
Properties
Pb(OH)2
Molar mass 241.2 g·mol−1
AppearanceWhite amorphous powder
Density 7.41 g/cm3 [1]
Melting point 135 °C (275 °F; 408 K) (decomposes)
0.0155 g/(100 mL) (20 °C) [2]
10−19.85 to 10−14.9 [3]
Solubility Soluble in dilute aqueous solutions of acids and alkalis
Insoluble in acetone and acetic acid [1]
Hazards
GHS labelling:
GHS-pictogram-skull.svg GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg
Danger
H302, H332, H351, H360, H373, H410
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Related compounds
Other cations
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
X mark.svgN  verify  (what is  Yes check.svgYX mark.svgN ?)

Lead(II) hydroxide, (Pb(OH)2), is a hydroxide of lead, with lead in oxidation state +2.

Contents

Preparation

When a hydroxide is added to a solution of a lead(II) salt, a hydrated lead oxide PbO·xH2O (with x < 1) is obtained. Careful hydrolysis of lead(II) acetate solution yields a crystalline product with a formula 6PbO·2H2O or Pb6O4(OH)4. [4] This material is a cluster compound, consisting of an octahedron of Pb centers, each face of which is capped by an oxide or a hydroxide. The structure is reminiscent of the Mo6S8 subunit of the Chevrel phases. [5] The following formula can also prepare it:
Pb(NO₃)₂ + NaOH = NaNO₃ + Pb(OH)₂

Reactions

In aqueous solution, lead(II) hydroxide is a somewhat weak base, forming lead(II) ion, Pb2+, under weakly acidic conditions. This cation hydrolyzes and, under progressively increasing alkaline conditions, it becomes somewhat weak acid, and it forms Pb(OH)+, Pb(OH)2(aqueous), Pb(OH)3, and other species, including several polynuclear species, e.g., Pb4(OH)4+4, Pb3(OH)2+4, Pb6O(OH)4+6. [4] Upon heating to decomposition temperatures, it forms lead oxide (PbO) in the yellow form, litharge.

History

The name lead hydrate has sometimes been used in the past but it is unclear whether this refers to Pb(OH)2 or PbO·xH2O. [6] [7] In 1964 it was believed that such a simple compound did not exist, as lead basic carbonate (2PbCO3·Pb(OH)2) or lead(II) oxide (PbO) was encountered where lead hydroxide was expected. [8] This has been a subject of considerable confusion in the past. However, subsequent research has demonstrated that lead(II) hydroxide does indeed exist as one of a series of lead hydroxides. [9]

Related Research Articles

<span class="mw-page-title-main">Hydroxide</span> Chemical compound

Hydroxide is a diatomic anion with chemical formula OH. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

In chemistry, an amphoteric compound is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used.

<span class="mw-page-title-main">Basic copper carbonate</span> Chemical compound

Basic copper carbonate is a chemical compound, more properly called copper(II) carbonate hydroxide. It can be classified as a coordination polymer or a salt. It consists of copper(II) bonded to carbonate and hydroxide with formula Cu2(CO3)(OH)2. It is a green solid that occurs in nature as the mineral malachite. It has been used since antiquity as a pigment, and it is still used as such in artist paints, sometimes called verditer, green bice, or mountain green.

<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

<span class="mw-page-title-main">Zinc chloride</span> Chemical compound

Zinc chloride is an inorganic chemical compound with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride.

<span class="mw-page-title-main">Copper(II) oxide</span> Chemical compound – an oxide of copper with formula CuO

Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or sometimes black copper. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

<span class="mw-page-title-main">Lead(II,IV) oxide</span> Chemical compound

Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula Pb3O4. A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed valence compound, being composed of both Pb(II) and Pb(IV) in the ratio of two to one.

<span class="mw-page-title-main">Tin(II) oxide</span> Chemical compound, stannous oxide (SnO)

Tin(II) oxide is a compound with the formula SnO. It is composed of tin and oxygen where tin has the oxidation state of +2. There are two forms, a stable blue-black form and a metastable red form.

<span class="mw-page-title-main">Telluric acid</span> Chemical compound (Te(OH)6)

Telluric acid, or more accurately orthotelluric acid, is a chemical compound with the formula Te(OH)6, often written as H6TeO6. It is a white crystalline solid made up of octahedral Te(OH)6 molecules which persist in aqueous solution. In the solid state, there are two forms, rhombohedral and monoclinic, and both contain octahedral Te(OH)6 molecules, containing one hexavalent tellurium (Te) atom in the +6 oxidation state, attached to six hydroxyl (–OH) groups, thus, it can be called tellurium(VI) hydroxide. Telluric acid is a weak acid which is dibasic, forming tellurate salts with strong bases and hydrogen tellurate salts with weaker bases or upon hydrolysis of tellurates in water. It is used as tellurium-source in the synthesis of oxidation catalysts.

In chemistry, a plumbate often refers to compounds that can be viewed as derivatives of the hypothetical PbO2−3 anion.

<span class="mw-page-title-main">Lithium bromide</span> Chemical compound

Lithium bromide (LiBr) is a chemical compound of lithium and bromine. Its extreme hygroscopic character makes LiBr useful as a desiccant in certain air conditioning systems.

<span class="mw-page-title-main">Ferrate(VI)</span> Ion

Ferrate(VI) is the inorganic anion with the chemical formula [FeO4]2−. It is photosensitive, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a weak base, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high pH. It is similar to the somewhat more stable permanganate.

<span class="mw-page-title-main">Silver oxide</span> Chemical compound

Silver oxide is the chemical compound with the formula Ag2O. It is a fine black or dark brown powder that is used to prepare other silver compounds.

<span class="mw-page-title-main">Nickel(II) carbonate</span> Chemical compound

Nickel(II) carbonate describes one or a mixture of inorganic compounds containing nickel and carbonate. From the industrial perspective, an important nickel carbonate is basic nickel carbonate with the formula Ni4CO3(OH)6(H2O)4. Simpler carbonates, ones more likely encountered in the laboratory, are NiCO3 and its hexahydrate. All are paramagnetic green solids containing Ni2+ cations. The basic carbonate is an intermediate in the hydrometallurgical purification of nickel from its ores and is used in electroplating of nickel.

<span class="mw-page-title-main">Lead(II) fluoride</span> Chemical compound

Lead(II) fluoride is the inorganic compound with the formula PbF2. It is a white solid. The compound is polymorphic, at ambient temperatures it exists in orthorhombic (PbCl2 type) form, while at high temperatures it is cubic (Fluorite type).

<span class="mw-page-title-main">Cobalt(II) hydroxide</span> Chemical compound

Cobalt(II) hydroxide or cobaltous hydroxide is the inorganic compound with the formula Co(OH)
2
, consisting of divalent cobalt cations Co2+
and hydroxide anions OH
. The pure compound, often called the "beta form" is a pink solid insoluble in water.

<span class="mw-page-title-main">Lead compounds</span> Type of compound

Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.

Cobalt compounds are chemical compounds formed by cobalt with other elements.

<span class="mw-page-title-main">Bismuthyl (ion)</span> Chemical compound

Bismuthyl is an inorganic oxygen-containing singly charged ion with the chemical formula BiO+, and is an oxycation of bismuth in the +3 oxidation state. Most often it is formed during the hydrolysis of trivalent bismuth salts, primarily nitrate, chloride and other halides. In chemical compounds, bismuthyl plays the role of a monovalent cation.

References

  1. 1 2 Patnaik, Pradyot (2002). Handbook of Inorganic Chemicals. New York, NY: McGraw-Hill. p. 471. ISBN   9780070494398.
  2. Handbook of Chemistry and Physics, 1st edition, 2000, CRC Press ISBN   0-8493-0740-6
  3. Internal Corrosion of Water Distribution Systems (2nd ed.). American Water Works Association. 1996. p. 178. ISBN   978-1-61300-170-7.
  4. 1 2 Von Egon Wiberg, Nils Wiberg, Arnold Frederick Holleman, "Inorganic Chemistry", Academic Press, 2001 (Google books).
  5. R. A. Howie; W. Moser (1968). "Structure of Tin(II) "Hydroxide" and Lead(II) "Hydroxide". Nature. 219 (5152): 372–373. Bibcode:1968Natur.219..372H. doi:10.1038/219372a0. S2CID   45007541.
  6. "Process of treating lead hydrate produced by electrolysis".
  7. "Process of manufacturing white lead".
  8. G. Todd and E. Parry (1964). "Character of Lead Hydroxide and Basic Lead Carbonate". Nature . 202 (4930): 386–387. Bibcode:1964Natur.202..386T. doi:10.1038/202386a0. S2CID   44941178.
  9. W. Nimal Perera, Glenn Hefter, and Pal M. Sipos (2001). "An Investigation of the Lead(II)−Hydroxide System". Inorganic Chemistry. 40 (16): 3974–3978. doi:10.1021/ic001415o. PMID   11466056.{{cite journal}}: CS1 maint: multiple names: authors list (link)