Landfill gas is a mix of different gases created by the action of microorganisms within a landfill as they decompose organic waste, including for example, food waste and paper waste. Landfill gas is approximately forty to sixty percent methane, with the remainder being mostly carbon dioxide. Trace amounts of other volatile organic compounds (VOCs) comprise the remainder (<1%). These trace gases include a large array of species, mainly simple hydrocarbons. [1]
Landfill gases have an influence on climate change. The major components are CO2 and methane, both of which are greenhouse gases. Methane in the atmosphere is a far more potent greenhouse gas, with each molecule having twenty-five times the effect of a molecule of carbon dioxide. Methane itself however accounts for less composition of the atmosphere than does carbon dioxide. Landfills are the third-largest source of methane in the US. [2]
Because of the significant negative effects of these gases, regulatory regimes have been set up to monitor landfill gas, reduce the amount of biodegradable content in municipal waste, and to create landfill gas utilization strategies, which include gas flaring or capture for electricity generation.
Landfill gases are the result of three processes: [1]
The first two depend strongly on the nature of the waste. The dominant process in most landfills is the third process whereby anaerobic bacteria decompose organic waste to produce biogas, which consists of methane and carbon dioxide together with traces of other compounds. [3] Despite the heterogeneity of waste, the evolution of gases follows well defined kinetic pattern. Formation of methane and CO2 commences about six months after depositing the landfill material. The evolution of gas reaches a maximum at about 20 years, then declines over the course of decades. [1]
Conditions and changes within the landfill can be observed with electrical resistivity tomography (ERT) to detect sources of landfill gas, [4] and leachate movements and pathways. [5] Conditions at different locations, such as temperature, moisture levels and fraction of biodegradable material can be inferred and this information can be used to improve gas production with optimal well locations over hotspots and interventions such as heap irrigation.
When landfill gas permeates through a soil cover, a fraction of the methane in the gas is oxidized microbially to CO2. [6]
Because gases produced by landfills are both valuable and sometimes hazardous, monitoring techniques have been developed. Flame ionization detectors can be used to measure methane levels as well as total VOC levels. Surface monitoring and sub-surface monitoring as well as monitoring of the ambient air is carried out. In the U.S., under the Clean Air Act of 1990, it is required that many large landfills install gas collection and control systems, which means that at the very least the facilities must collect and flare the gas.
U.S. Federal regulations under Subtitle D of RCRA formed in October 1979 regulate the siting, design, construction, operation, monitoring, and closure of MSW landfills. Subtitle D now requires controls on the migration of methane in landfill gas. Monitoring requirements must be met at landfills during their operation, and for an additional 30 years after. The landfills affected by Subtitle D of RCRA are required to control gas by establishing a way to check for methane emissions periodically and therefore prevent off-site migration. Landfill owners and operators must make sure the concentration of methane gas does not exceed 25% of the LEL for methane in the facilities' structures and the LEL for methane at the facility boundary. [7]
The gases produced within a landfill can be collected and used in various ways. The landfill gas can be utilized directly on-site by a boiler or any type of combustion system, providing heat. Electricity can also be generated on-site through the use of microturbines, steam turbines, or fuel cells. [8] The landfill gas can also be sold off-site and sent into natural gas pipelines. This approach requires the gas to be processed into pipeline quality, e.g., by removing various contaminants and components. [9] Landfill gas can also be used to evaporate leachate, another byproduct of the landfill process. This application displaces another fuel that was previously used for the same thing. [10]
The efficiency of gas collection at landfills directly impacts the amount of energy that can be recovered - closed landfills (those no longer accepting waste) collect gas more efficiently than open landfills (those that are still accepting waste). A comparison of collection efficiency at closed and open landfills found about a 17 percentage point difference between the two. [11]
Capture and use of landfill gas can be expensive. Some environmental groups claim that the projects do not produce "renewable power" because trash (their source) is not renewable. The Sierra Club opposes government subsidies for such projects. [12] The Natural Resources Defense Council (NRDC) argues that government incentives should be directed more towards solar, wind, and energy-efficiency efforts. [12]
Landfill gas emissions can lead to environmental, hygiene and security problems in the landfill. [13] [14] Several accidents have occurred, for example at Loscoe, England in 1986, [15] where migrating landfill gas accumulated and partially destroyed a property. An accident causing two deaths occurred from an explosion in a house adjacent to Skellingsted landfill in Denmark in 1991. [16] Due to the risk presented by landfill gas, there is a clear need to monitor gas produced by landfills. In addition to the risk of fire and explosion, gas migration in the subsurface can result in contact with landfill gas with groundwater. This, in turn, can result in contamination of groundwater by organic compounds present in nearly all landfill gas. [17]
Although usually evolved only in trace amounts, landfills do release some aromatics and chlorocarbons.
Landfill gas migration, due to pressure differentials and diffusion, can occur. This can create an explosion hazard if the gas reaches sufficiently high concentrations in adjacent buildings.
A United States Environmental Protection Agency (EPA) report indicates that as of 2016, counts of operational municipal solid waste landfills range between 1,900 and 2,000. In a nationwide study done by the Environmental Research and Education Foundation in 2013, only 1,540 operational municipal solid waste landfills were counted throughout the United States. Decomposing waste in these landfills produces landfill gas, which is a mixture of about half methane and half carbon dioxide. Landfills are the third-largest source of methane emissions in the United States, with municipal solid waste landfills representing 95 percent of this fraction. [18] [19]
In the U.S., the number of landfill gas projects increased from 399 in 2005, to 594 in 2012 [20] according to the Environmental Protection Agency. These projects are popular because they control energy costs and reduce greenhouse gas emissions. These projects collect the methane gas and treat it, so it can be used for electricity or upgraded to pipeline-grade gas. (Methane gas has twenty-one times the global warming potential of carbon dioxide). [21] For example, in the U.S., Waste Management uses landfill gas as an energy source at 110 landfill gas-to-energy facilities. This energy production offsets almost two million tons of coal per year, creating energy equivalent to that needed by four hundred thousand homes. These projects also reduce greenhouse gas emissions into the atmosphere. [22]
The EPA, which estimates that hundreds of landfills could support gas to energy projects, has also established the Landfill Methane Outreach Program. This program was developed to reduce methane emissions from landfills in a cost-effective manner by encouraging the development of environmentally and economically beneficial landfill gas-to-energy projects. [23]Biogas is a gaseous renewable energy source produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste, wastewater, and food waste. Biogas is produced by anaerobic digestion with anaerobic organisms or methanogens inside an anaerobic digester, biodigester or a bioreactor. The gas composition is primarily methane and carbon dioxide and may have small amounts of hydrogen sulfide, moisture and siloxanes. The gases methane and hydrogen can be combusted or oxidized with oxygen. This energy release allows biogas to be used as a fuel; it can be used in fuel cells and for heating purpose, such as in cooking. It can also be used in a gas engine to convert the energy in the gas into electricity and heat.
A landfill site, also known as a tip, dump, rubbish dump, garbage dump, trash dump, or dumping ground, is a site for the disposal of waste materials. Landfill is the oldest and most common form of waste disposal, although the systematic burial of the waste with daily, intermediate and final covers only began in the 1940s. In the past, refuse was simply left in piles or thrown into pits; in archeology this is known as a midden.
Anaerobic digestion is a sequence of processes by which microorganisms break down biodegradable material in the absence of oxygen. The process is used for industrial or domestic purposes to manage waste or to produce fuels. Much of the fermentation used industrially to produce food and drink products, as well as home fermentation, uses anaerobic digestion.
The Global Methane Initiative (GMI) is a voluntary, international partnership that brings together national governments, private sector entities, development banks, NGOs and other interested stakeholders in a collaborative effort to reduce methane gas emissions and advance methane recovery and use as a clean energy source. National governments are encouraged to join GMI as Partner Countries, while other non-State organizations may join GMI's extensive Project Network. As a public-private initiative, GMI creates an international platform to build capacity, development methane abatement strategies, engage in technology transfer, and remove political and economic barriers to project development for emissions reduction.
A gas flare, alternatively known as a flare stack, flare boom, ground flare, or flare pit, is a gas combustion device used in places such as petroleum refineries, chemical plants and natural gas processing plants, oil or gas extraction sites having oil wells, gas wells, offshore oil and gas rigs and landfills.
Renewable natural gas (RNG), also known as biomethane, is a biogas which has been upgraded to a quality similar to fossil natural gas and has a methane concentration of 90% or greater. By removing CO2 and other impurities from biogas, and increasing the concentration of methane to a level similar to fossil natural gas, it becomes possible to distribute RNG via existing gas pipeline infrastructure. RNG can be used in existing appliances, including vehicles with natural gas burning engines (natural gas vehicles).
Waste-to-energy (WtE) or energy-from-waste (EfW) is the process of generating energy in the form of electricity and/or heat from the primary treatment of waste, or the processing of waste into a fuel source. WtE is a form of energy recovery. Most WtE processes generate electricity and/or heat directly through combustion, or produce a combustible fuel commodity, such as methane, methanol, ethanol or synthetic fuels, often derived from the product syngas.
Landfills are the primary method of waste disposal in many parts of the world, including United States and Canada. Bioreactor landfills are expected to reduce the amount of and costs associated with management of leachate, to increase the rate of production of methane for commercial purposes and reduce the amount of land required for land-fills. Bioreactor landfills are monitored and manipulate oxygen and moisture levels to increase the rate of decomposition by microbial activity.
Biodegradable waste includes any organic matter in waste which can be broken down into carbon dioxide, water, methane, compost, humus, and simple organic molecules by micro-organisms and other living things by composting, aerobic digestion, anaerobic digestion or similar processes. It mainly includes kitchen waste, ash, soil, dung and other plant matter. In waste management, it also includes some inorganic materials which can be decomposed by bacteria. Such materials include gypsum and its products such as plasterboard and other simple sulfates which can be decomposed by sulfate reducing bacteria to yield hydrogen sulfide in anaerobic land-fill conditions.
Landfill gas monitoring is the process by which gases that are collected or released from landfills are electronically monitored. Landfill gas may be measured as it escapes the landfill or may be measured as it is collected and redirected to a power plant or flare.
An emission inventory is an accounting of the amount of pollutants discharged into the atmosphere. An emission inventory usually contains the total emissions for one or more specific greenhouse gases or air pollutants, originating from all source categories in a certain geographical area and within a specified time span, usually a specific year.
The United States produced 5.2 billion metric tons of carbon dioxide equivalent greenhouse gas (GHG) emissions in 2020, the second largest in the world after greenhouse gas emissions by China and among the countries with the highest greenhouse gas emissions per person. In 2019 China is estimated to have emitted 27% of world GHG, followed by the United States with 11%, then India with 6.6%. In total the United States has emitted a quarter of world GHG, more than any other country. Annual emissions are over 15 tons per person and, amongst the top eight emitters, is the highest country by greenhouse gas emissions per person. However, the IEA estimates that the richest decile in the US emits over 55 tonnes of CO2 per capita each year. Because coal-fired power stations are gradually shutting down, in the 2010s emissions from electricity generation fell to second place behind transportation which is now the largest single source. In 2020, 27% of the GHG emissions of the United States were from transportation, 25% from electricity, 24% from industry, 13% from commercial and residential buildings and 11% from agriculture. In 2021, the electric power sector was the second largest source of U.S. greenhouse gas emissions, accounting for 25% of the U.S. total. These greenhouse gas emissions are contributing to climate change in the United States, as well as worldwide.
Fugitive emissions are leaks and other irregular releases of gases or vapors from a pressurized containment – such as appliances, storage tanks, pipelines, wells, or other pieces of equipment – mostly from industrial activities. In addition to the economic cost of lost commodities, fugitive emissions contribute to local air pollution and may cause further environmental harm. Common industrial gases include refrigerants and natural gas, while less common examples are perfluorocarbons, sulfur hexafluoride, and nitrogen trifluoride.
The environmental impact of the energy industry is significant, as energy and natural resource consumption are closely related. Producing, transporting, or consuming energy all have an environmental impact. Energy has been harnessed by human beings for millennia. Initially it was with the use of fire for light, heat, cooking and for safety, and its use can be traced back at least 1.9 million years. In recent years there has been a trend towards the increased commercialization of various renewable energy sources. Scientific consensus on some of the main human activities that contribute to global warming are considered to be increasing concentrations of greenhouse gases, causing a warming effect, global changes to land surface, such as deforestation, for a warming effect, increasing concentrations of aerosols, mainly for a cooling effect.
The environmental impact of the petroleum industry is extensive and expansive due to petroleum having many uses. Crude oil and natural gas are primary energy and raw material sources that enable numerous aspects of modern daily life and the world economy. Their supply has grown quickly over the last 150 years to meet the demands of the rapidly increasing human population, creativity, knowledge, and consumerism.
Municipal solid waste (MSW) – more commonly known as trash or garbage – consists of everyday items people use and then throw away, such as product packaging, grass clippings, furniture, clothing, bottles, food scraps and papers. In 2018, Americans generated about 265.3 million tonnes of waste. In the United States, landfills are regulated by the Environmental Protection Agency (EPA) and the states' environmental agencies. Municipal solid waste landfills (MSWLF) are required to be designed to protect the environment from contaminants that may be present in the solid waste stream.
Landfill gas utilization is a process of gathering, processing, and treating the methane or another gas emitted from decomposing garbage to produce electricity, heat, fuels, and various chemical compounds. After fossil fuel and agriculture, landfill gas is the third largest human generated source of methane. Compared to CO2, methane is 25 times more potent as a greenhouse gas. It is important not only to control its emission but, where conditions allow, use it to generate energy, thus offsetting the contribution of two major sources of greenhouse gases towards climate change. The number of landfill gas projects, which convert the gas into power, went from 399 in 2005 to 519 in 2009 in the United States, according to the US Environmental Protection Agency. These projects are popular because they control energy costs and reduce greenhouse gas emissions. These projects collect the methane gas and treat it, so it can be used for electricity or upgraded to pipeline-grade gas. These projects power homes, buildings, and vehicles.
Source-separated organics (SSO) is the system by which waste generators segregate compostable materials from other waste streams at the source for separate collection.
Increasing methane emissions are a major contributor to the rising concentration of greenhouse gases in Earth's atmosphere, and are responsible for up to one-third of near-term global heating. During 2019, about 60% of methane released globally was from human activities, while natural sources contributed about 40%. Reducing methane emissions by capturing and utilizing the gas can produce simultaneous environmental and economic benefits.
Home composting is the process of using household waste to make compost at home. Composting is the biological decomposition of organic waste by recycling food and other organic materials into compost. Home composting can be practiced within households for various environmental advantages, such as increasing soil fertility, reduce landfill and methane contribution, and limit food waste.
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