Tire recycling, or rubber recycling, is the process of recycling waste tires that are no longer suitable for use on vehicles due to wear or irreparable damage. These tires are a challenging source of waste, due to the large volume produced, the durability of the tires, and the components in the tire that are ecologically problematic. [1]
Because tires are highly durable and non-biodegradable, they can consume valuable space in landfills. [1] If waste tires are improperly managed they may cause rubber pollution. In 1990, it was estimated that over 1 billion scrap tires were in stockpiles in the United States. As of 2015, only 67 million tires remain in stockpiles. [2] From 1994 to 2010, the European Union increased the amount of tires recycled from 25% of annual discards to nearly 95%, with roughly half of the end-of-life tires used for energy, mostly in cement manufacturing. [3] [4]
Pyrolysis and devulcanization could facilitate recycling. Aside from use as fuel, the main end use for tires remains ground crumb rubber. [2] [5] In 2017, 13% of U.S. tires removed from their primary use were sold in the used tire market. Of the tires that were scrapped, 43% were burnt as tire-derived fuel, with cement manufacturing the largest user, another 25% were used to make ground rubber, 8% were used in civil engineering projects, 17% were disposed of in landfills and 8% had other uses. [6] Globally, tire graveyards are a common environmental hazard, with significant pollutants and other challenges. For example, the Sulaibiya tire graveyard in Kuwait has had repeat highly toxic fires. [7]
The tire life cycle can be recognized through the following steps:
Tires are not desired at landfills, due to their large volumes and 75% void space. [9] Tires can trap methane gases, causing them to become buoyant, or bubble to the surface. This 'bubbling' effect can damage landfill liners that have been installed to help keep landfill contaminants from polluting local surface and ground water. [8] The EU Landfill Directive prohibits the disposal of used tires in landfill. [10]
Shredded tires are now being used in landfills, replacing other construction materials, for a lightweight back-fill in gas venting systems, leachate collection systems, and operational liners. Shredded tire material may also be used to cap, close, or daily cover landfill sites. [11] Scrap tires as a back-fill and cover material are also more cost-effective, since tires can be shredded on-site instead of hauling in other fill materials.
Tire stockpiles create a great health and safety risk. Tire fires can easily occur, burning for long periods, up to a month and also creating substantial pollution in the air and ground. Recycling helps to reduce the number of tires in storage. An additional health risk, tire piles provide harborage for vermin and a breeding ground for mosquitoes that may carry diseases. Illegal dumping of scrap tires pollutes ravines, woods, deserts, and empty lots; which has led many states to pass scrap tire regulations requiring proper management. Tire amnesty day events, in which community members can deposit a limited number of waste tires free of charge, can be funded by state scrap tire programs, helping decrease illegal dumping and improper storage of scrap tires.
Tire storage and recycling are sometimes linked with illegal activities and lack of environmental awareness. [12]
Although tires are usually burnt, not recycled, efforts are continuing to find value. Tires can be reclaimed into, among other things, the hot melt asphalt, typically as crumb rubber modifier—recycled asphalt pavement (CRM—RAP), [13] [14] and as an aggregate in Portland cement concrete [15] Efforts have been made to use recycled tires as raw material for new tires, but such tires may integrate recycled materials no more than 5% by weight, and tires that contain recycled material are inferior to new tires, [5] suffering from reduced tread life and lower traction. [16] Tires have also been cut up and used in garden beds as bark mulch to hold in the water and to prevent weeds from growing. Some "green" buildings, both private and public, have been made from old tires.
Pyrolysis can be used to reprocess the tires into fuel gas, oils, solid residue (char), and low-grade carbon black, which cannot be used in tire manufacture. A pyrolysis method which produces activated carbon and high-grade carbon black has been suggested. [17]
Old tires can be used as an alternative fuel in the manufacturing of Portland cement, a key ingredient in concrete. Whole tires are commonly introduced into cement kilns, by rolling them into the upper end of a preheater kiln, or by dropping them through a slot midway along a long wet kiln. In either case, the high gas temperatures (1000–1200 °C) cause almost instantaneous, complete and smokeless combustion of the tire. Alternatively, tires are chopped into 5–10 mm chips, in which form they can be injected into a precalciner combustion chamber. Some iron input is required in manufacturing cement, so the iron content of steel-belted tires is beneficial to the process. [18]
Tires can be reused in many ways, although most used tires are burnt for their fuel value. [19] In a 2003 report cited by the U.S. EPA, it is stated that markets ("both recycling and beneficial use") existed for 80.4% of scrap tires, about 233 million tires per year. Assuming 22.5 pounds (10.2 kg) per tire, the 2003 report predicts a total weight of about 2.62 million tonnes (2,580,000 long tons; 2,890,000 short tons) from tires. [20]
New products derived from waste tires generate more economic activity than combustion or other low multiplier production, while reducing waste stream without generating excessive pollution and emissions from recycling operations. [8]
The pyrolysis method for recycling used tires is a technique which heats whole or shredded tires in a reactor vessel containing an oxygen-free atmosphere. In the reactor, the rubber is softened after which the rubber polymers break down into smaller molecules. These smaller molecules eventually vaporize and exit from the reactor. These vapors can be burned directly to produce power or condensed into an oily type liquid, generally used as a fuel. Some molecules are too small to condense. They remain as a gas which can be burned as fuel. The minerals that were part of the tire, about 40% by weight, are removed as solid ashes. When performed properly, the tire pyrolysis process is a clean operation and produces little emissions or waste; however, concerns about air pollution due to incomplete combustion as is the case with tire fires has been documented. [22]
The properties of the gas, liquid, and solid output are determined by the type of feed-stock used and the process conditions. For instance whole tires contain fibers and steel. Shredded tires have most of the steel and sometimes most of the fiber removed. Processes can be either batch or continuous. The energy required to drive the decomposition of the rubber include using directly fired fuel (like a gas oven), electrical induction (like an electrically heated oven) or by microwaves (like a microwave oven). Sometimes a catalyst is used to accelerate the decomposition. The choice of feed-stock and process can affect the value of the finished products.
The historical issue of tire pyrolysis has been the solid mineral stream, which accounts for about 40% of the output. The steel can be removed from the solid stream with magnets for recycling. The remaining solid material, often referred to as "char", has had little or no value other than possibly as a low grade carbon fuel. Char is the destroyed remains of the original carbon black used to reinforce and provide abrasion resistance to the tire. The solid stream also includes the minerals used in rubber manufacturing. This high volume component of tire pyrolysis is a major impediment, although this theme continues to be a source of innovation.
Tires can be frozen using cryogens, or super-cold fluids, then broken down and made into a material called "crumb," which can be used in asphalt road beds, agricultural hoses, and truck bed liners.
Aside from recycling old tires, the old tire can be put to a new use.
Old tires are sometimes converted into a swing for play. The innovative use allows for an easy way to find a purpose for an existing old tire not suitable for road use. [23]
Used tires are also employed as exercise equipment for athletic programs such as American football. [24] One classic conditioning drill that hones players' speed and agility is the "Tire Run" where tires are laid out side by side, with each tire on the left a few inches ahead of the tire on the right in a zigzag pattern. Athletes then run through the tire pattern by stepping in the center of each tire. The drill forces athletes to lift their feet above the ground higher than normal to avoid tripping. [25] Other athletic uses include tire flipping (tractor or large truck tires typically used) or for upper cardio conditioning by hitting a tire repetitively with a sledge hammer. [26]
Re-purposed tires can also be harnessed as an affordable alternative building material used in the framework of rammed Earth thermal mass dwellings. [27] This is beneficial across scales of production such as individually sustainable housing. [28]
Rows of stacks of tires are often used as barriers in motor racing circuits as a method of dissipating kinetic energy over a longer period of time during a crash, comparatively to striking a less malleable material such as a concrete or steel wall.
Many cattle farmers re-purpose old tractor tires as water troughs for their cattle by placing them over natural springs or by piping stream water into them. These tires contain the water and allow it to pool for the cattle without any additional interaction from the farmer. Most farmers also include a drainage pipe near the top or in the center of the tire so excess water can drain off to prevent overflow and erosion around the outside of the tire where the cattle would be. [29]
Repurposing as an elastic base for multipurpurposes uses, such as holding advertisement boards, static or swinging. This is an application still under development and at a prototype stage. [30]
Rubber shingle roofs are typically made from 95% recycled material from a variety of sources including recycled tires. They last twice as long as asphalt shingles but are about twice the price as asphalt. They are more quiet than most roofs, hail resistant, and a high wind rating if there is a tongue and groove fitting at the front edge of the rubber shingle design. [31] [32]
Due to their heavy metal and other pollutant content, tires pose a risk for the leaching of toxins into the groundwater when placed in wet soils. Research has shown that very little leaching occurs when shredded tires are used as light fill material; however, limitations have been put on use of this material; each site should be individually assessed determining if this product is appropriate for given conditions. [9]
For both above and below water table applications, the preponderance of evidence shows that TDA (tire derived aggregate, or shredded tires) will not cause primary drinking water standards to be exceeded for metals. Moreover, TDA is unlikely to increase levels of metals with primary drinking water standards above naturally occurring background levels. [33]
Waste management or waste disposal includes the processes and actions required to manage waste from its inception to its final disposal. This includes the collection, transport, treatment, and disposal of waste, together with monitoring and regulation of the waste management process and waste-related laws, technologies, and economic mechanisms.
Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalyzed or un-catalyzed and is distinct from other forms of depolymerization which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy.
Pyrolysis is the process of thermal decomposition of materials at elevated temperatures, often in an inert atmosphere without access to oxygen.
Asphalt concrete is a composite material commonly used to surface roads, parking lots, airports, and the core of embankment dams. Asphalt mixtures have been used in pavement construction since the beginning of the twentieth century. It consists of mineral aggregate bound together with bitumen, laid in layers, and compacted.
Plastic recycling is the processing of plastic waste into other products. Recycling can reduce dependence on landfill, conserve resources and protect the environment from plastic pollution and greenhouse gas emissions. Recycling rates lag behind those of other recoverable materials, such as aluminium, glass and paper. From the start of plastic production through to 2015, the world produced around 6.3 billion tonnes of plastic waste, only 9% of which has been recycled and only ~1% has been recycled more than once. Of the remaining waste, 12% was incinerated and 79% was either sent to landfills or lost to the environment as pollution.
Crumb rubber is recycled rubber produced from automotive and truck scrap tires. During the recycling process, steel and tire cord (fluff) are removed, leaving tire rubber with a granular consistency. Continued processing with a granulator or cracker mill, possibly with the aid of cryogenics or by mechanical means, reduces the size of the particles further. The particles are sized and classified based on various criteria including color. The granulate is sized by passing through a screen, the size based on a dimension or mesh. Crumb rubber is often used in artificial turf as cushioning.
Retread, also known as "recap", or a "remold" is a re-manufacturing process for tires that replace the tread on worn tires. Retreading is applied to casings of spent tires that have been inspected and repaired. It preserves about 90% of the material in spent tires and the material cost is about 20% compared to manufacturing a new one.
Aluminium recycling is the process in which secondary commercial aluminium is created from scrap or other forms of end-of-life or otherwise unusable aluminium. It involves re-melting the metal, which is cheaper and more energy-efficient than the production of virgin aluminium by electrolysis of alumina (Al2O3) refined from raw bauxite by use of the Bayer and Hall–Héroult processes.
Rubber mulch is a type of mulch used in gardening and landscaping that is made from recycled rubber, most often crumb rubber sourced from waste tires.
Construction aggregate, or simply aggregate, is a broad category of coarse- to medium-grained particulate material used in construction, including sand, gravel, crushed stone, slag, recycled concrete and geosynthetic aggregates. Aggregates are the most mined materials in the world. Aggregates are a component of composite materials such as concrete and asphalt; the aggregate serves as reinforcement to add strength to the overall composite material. Due to the relatively high hydraulic conductivity value as compared to most soils, aggregates are widely used in drainage applications such as foundation and French drains, septic drain fields, retaining wall drains, and roadside edge drains. Aggregates are also used as base material under foundations, roads, and railroads. In other words, aggregates are used as a stable foundation or road/rail base with predictable, uniform properties, or as a low-cost extender that binds with more expensive cement or asphalt to form concrete. Although most kinds of aggregate require a form of binding agent, there are types of self-binding aggregate which require no form of binding agent.
The shredding of automobiles and major household appliances is a process where a hammermill acts as a giant tree chipper by grinding the materials fed into it to fist-size pieces. The shredding of automobiles results in a mixture of ferrous metal, non-ferrous metal and shredder waste, called automotive shredder residue or automobile shredder residue (ASR). ASR consists of glass, fiber, rubber, automobile liquids, plastics and dirt. ASR is sometimes differentiated into shredder light fraction and dust. Sometimes these residual materials are called "car-fluff".
There is no national law in the United States that mandates recycling. State and local governments often introduce their own recycling requirements. In 2014, the recycling/composting rate for municipal solid waste in the U.S. was 34.6%. A number of U.S. states, including California, Connecticut, Delaware, Hawaii, Iowa, Maine, Massachusetts, Michigan, New York, Oregon, and Vermont have passed laws that establish deposits or refund values on beverage containers while other jurisdictions rely on recycling goals or landfill bans of recyclable materials.
Rubberized asphalt concrete (RAC), also known as asphalt rubber or just rubberized asphalt, is noise reducing pavement material that consists of regular asphalt concrete mixed with crumb rubber made from recycled tires. Asphalt rubber is the largest single market for ground rubber in the United States, consuming an estimated 220,000,000 pounds (100,000,000 kg), or approximately 12 million tires annually.
Tire-derived fuel (TDF) is composed of shredded scrap tires. Tires may be mixed with coal or other fuels, such as wood or chemical wastes, to be burned in concrete kilns, power plants, or paper mills. An EPA test program concluded that, with the exception of zinc emissions, potential emissions from TDF are not expected to be very much different from other conventional fossil fuels, as long as combustion occurs in a well-designed, well-operated and well-maintained combustion device.
Demolition waste is waste debris from destruction of buildings, roads, bridges, or other structures. Debris varies in composition, but the major components, by weight, in the US include concrete, wood products, asphalt shingles, brick and clay tile, steel, and drywall. There is the potential to recycle many elements of demolition waste.
Recycling can be carried out on various raw materials. Recycling is an important part of creating more sustainable economies, reducing the cost and environmental impact of raw materials. Not all materials are easily recycled, and processing recyclable into the correct waste stream requires considerable energy. Some particular manufactured goods are not easily separated, unless specially process therefore have unique product-based recycling processes.
Products made from a variety of materials can be recycled using a number of processes.
Micronized rubber powder (MRP) is classified as fine, dry, powdered elastomeric crumb rubber in which a significant proportion of particles are less than 100 μm and free of foreign particulates. MRP particle size distributions typically range from 180 μm to 10 μm. Narrower distributions can be achieved depending on the classification technology.
Tire recycling in the United States is the disposal and reuse of waste tires.
Tire-derived aggregate (TDA) is a building material made of recycled tires, which are shredded into pieces of varying sizes. It is commonly used in construction projects because it is sustainable and lightweight, along with being less expensive than many competing available materials. In 2007, an estimated 561.6 thousand tons of TDA were produced. This accounted for about 12 percent of the total recycled tire material used. Particle sizes less than 12mm are considered crumb rubber.