Automotive oil recycling involves the recycling of used oils and the creation of new products from the recycled oils, and includes the recycling of motor oil and hydraulic oil. Oil recycling also benefits the environment: [1] increased opportunities for consumers to recycle oil lessens the likelihood of used oil being dumped on lands and in waterways. For example, one gallon of motor oil dumped into waterways has the potential to pollute one million gallons of water. [2] [3]
Recycled motor oil can be combusted as fuel, usually in plant boilers, space heaters, or industrial heating applications such as blast furnaces and cement kilns. [4] When used motor oil is burned as fuel it must be burned at high temperatures to avoid gaseous pollution. [5] Alternatively, waste motor oil can be distilled into diesel fuel or marine fuel in a process similar to oil re-refining, but without the final hydrotreating process. [ citation needed ] The lubrication properties of motor oil persist, even in used oil, and it can be recycled indefinitely. [3]
Used oil re-refining is the process of restoring used oil to new oil by removing chemical impurities, heavy metals and dirt. [2] Used industrial and automotive oil is recycled at re-refineries. The used oil is first tested to determine suitability for re-refining, after which it is dehydrated and the water distillate is treated before being released into the environment. Dehydrating also removes the residual light fuel that can be used to power the refinery, and additionally captures ethylene glycol for re-use in recycled antifreeze.
Next, industrial fuel is separated out of the used oil then vacuum distillation removes the lube cut (that is, the fraction suitable for reuse as lubricating oil) leaving a heavy oil that contains the used oil's additives and other by-products such as asphalt extender. The lube cut next undergoes hydro treating, or catalytic hydrogenation to remove residual polymers and other chemical compounds, and saturate carbon chains with hydrogen for greater stability.
Final oil separation, or fractionating, separates the oil into three different oil grades: Light viscosity lubricants suitable for general lubricant applications, low viscosity lubricants for automotive and industrial applications, and high viscosity lubricants for heavy-duty applications. The oil that is produced in this step is referred to as re-refined base oil (RRBL).
The final step is blending additives into these three grades of oil products to produce final products with the right detergent and anti-friction qualities. Then each product is tested again for quality and purity before being released for sale to the public. [6] [7] [8]
The sludge ("residue") associated with engine oil recycling, which collects at the bottom of re-refining vacuum distillation towers, is known by various names, including "re-refined engine oil bottoms" (abbreviated "REOB" or "REOBs"). [9]
A report from the U.S. Federal Highway Administration (FHWA) states that:
Some producers of asphalt for paving have—openly or secretly—incorporated REOBs into their asphalt, creating some controversy and concern in the traffic engineering community, with some experts suggesting it reduces the durability of the resulting pavement. [9]
Bitumen is an immensely viscous constituent of petroleum. Depending on its exact composition it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In the U.S., the material is commonly referred to as asphalt. Whether found in natural deposits or refined from petroleum, the substance is classed as a pitch. Prior to the 20th century the term asphaltum was in general use. The word derives from the ancient Greek ἄσφαλτος ásphaltos, which referred to natural bitumen or pitch. The largest natural deposit of bitumen in the world is the Pitch Lake of southwest Trinidad, which is estimated to contain 10 million tons.
A lubricant is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.
Motor oil, engine oil, or engine lubricant is any one of various substances used for the lubrication of internal combustion engines. They typically consist of base oils enhanced with various additives, particularly antiwear additives, detergents, dispersants, and, for multi-grade oils, viscosity index improvers. The main function of motor oil is to reduce friction and wear on moving parts and to clean the engine from sludge and varnish (detergents). It also neutralizes acids that originate from fuel and from oxidation of the lubricant (detergents), improves the sealing of piston rings, and cools the engine by carrying heat away from moving parts.
Synthetic oil is a lubricant consisting of chemical compounds that are artificially modified or synthesised. Synthetic lubricants can be manufactured using chemically modified petroleum components rather than whole crude oil, but can also be synthesized from other raw materials. The base material, however, is still overwhelmingly crude oil that is distilled and then modified physically and chemically. The actual synthesis process and composition of additives is generally a commercial trade secret and will vary among producers.
Gear oil is a lubricant made specifically for transmissions, transfer cases, and differentials in automobiles, trucks, and other machinery. It has high viscosity and usually contains organosulfur compounds. Some modern automatic transaxles do not use a heavy oil at all but lubricate with the lower viscosity hydraulic fluid, which is available at pressure within the automatic transmission. Gear oils account for about 20% of the lubricant market.
Petroleum products are materials derived from crude oil (petroleum) as it is processed in oil refineries. Unlike petrochemicals, which are a collection of well-defined usually pure organic compounds, petroleum products are complex mixtures. Most petroleum is converted into petroleum products, which include several classes of fuels.
AMSOIL Inc. is an American corporation based in Superior, Wisconsin that primarily formulates and packages synthetic lubricants, fuel additives, and filters. Company founder Albert J. Amatuzio developed several synthetic motor oil formulations throughout the mid-to-late 1960s. He was commercially selling synthetic motor oil by 1968. In 1972, AMSOIL 10W-40 Synthetic Motor Oil became the world's first synthetic motor oil to meet American Petroleum Institute requirements, which prompted the company to adopt "The First in Synthetics®" as its tagline. The company introduced several other synthetic lubricants that represented industry firsts throughout the 1970s and early 1980s. It distributes products in North America via a network of independent dealers paid commissions on sales.
The viscosity index (VI) is an arbitrary, unit-less measure of a fluid's change in viscosity relative to temperature change. It is mostly used to characterize the viscosity-temperature behavior of lubricating oils. The lower the VI, the more the viscosity is affected by changes in temperature. The higher the VI, the more stable the viscosity remains over some temperature range. The VI was originally measured on a scale from 0 to 100; however, advancements in lubrication science have led to the development of oils with much higher VIs.
Calumet Specialty Products Partners, L.P. is a publicly traded U.S.-based company that was incorporated in 1919. It specializes in the manufacture of lubricating oils, solvents, waxes, packaged and synthetic specialty products, fuels and fuel-related products. The company operates 12 production, blending, and packaging facilities across North America. This includes locations in Princeton, Cotton Valley, and Shreveport, Louisiana; Burnham, Illinois; Dickinson, Texas; Muncie, Indiana; Karns City, Pennsylvania; and Great Falls, Montana. Calumet's specialized hydrocarbon products are distributed around the world to approximately 2,700 global customers.
Grease is a solid or semisolid lubricant formed as a dispersion of thickening agents in a liquid lubricant. Grease generally consists of a soap emulsified with mineral or vegetable oil.
Extreme pressure additives, or EP additives, are additives for lubricants with a role to decrease wear of the parts of the gears exposed to very high pressures. They are also added to cutting fluids for machining of metals.
The Dura Lube Corporation was formed in 1986, originally intended as an engine additive for heavy duty trucks. The company gained wide exposure in the mid-1990s through infomercials and wide retail distribution of its engine and fuel additives.
Friction modifiers are added to lubricants in order to reduce friction and wear in machine components. They are particularly important in the boundary lubrication regime, where they can prevent solid surfaces from coming into direct contact, substantially reducing friction and wear.
Shell Rotella is a line of heavy-duty engine lubrication products produced by Shell plc. The line includes engine oils, gear oils and coolants. The oil carries both the American Petroleum Institute (API) diesel "C" rating as well as the API gasoline engine "S" rating. Ratings differ based on the oil. Rotella oils, like the T3 15W-40, meet both the API CJ-4 and SM specifications, and may be used in both gasoline and diesel engines. However, it is formulated specifically for vehicles without catalytic converters, containing phosphorus levels beyond the 600–800 ppm range. Therefore, Rotella is not recommended for gasoline vehicles with catalytic converters due to the higher risk of damaging these emission controls. Newer formulations of Rotella T6 however are API SM rated as safe for pre-2011 gasoline vehicles.
Oil additives are chemical compounds that improve the lubricant performance of base oil. The manufacturer of many different oils can utilize the same base stock for each formulation and can choose different additives for each specific application. Additives comprise up to 5% by weight of some oils.
Corinth Refinery is an oil refining complex in Greece, the largest industrial complex in the country with a capacity of 380,000 barrels per day (60,000 m3/d), and it is operated by Motor Oil Hellas.
Nynas AB is a Swedish manufacturer of specialty naphthenic oils and bitumen products. Founded in 1928 as a national oil company with a traditional range of products, the company today supplies specialist products and niche markets.
Behran Oil Company is an oil refining company with headquarters in Tehran. Its products are exported to more than 40 countries.
Base oils are used to manufacture products including lubricating greases, motor oil and metal processing fluids. Different products require different compositions and properties in the oil. One of the most important factors is the liquid’s viscosity at various temperatures. Whether or not a crude oil is suitable to be made into a base oil is determined by the concentration of base oil molecules as well as how easily these can be extracted.
Infineum International Limited is a joint venture between ExxonMobil and Shell plc through each companies' chemical divisions. Its headquarters are located in Abingdon, England and it has operating centers throughout the United Kingdom, United States, Germany, France, Italy, China, Singapore.
