Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, called charcoal burning, often by forming a charcoal kiln, the heat is supplied by burning part of the starting material itself, with a limited supply of oxygen. The material can also be heated in a closed retort. Modern charcoal briquettes used for outdoor cooking may contain many other additives, e.g. coal.
The history of wood charcoal production spans ancient times, rooted in the abundance of wood in various regions. The process typically involves stacking wood billets to form a conical pile, allowing air to enter through openings at the bottom, and igniting the pile gradually. Charcoal burners, skilled professionals tasked with managing the delicate operation, often lived in isolation to tend their wood piles. Throughout history, the extensive production of charcoal has been a significant contributor to deforestation, particularly in regions like Central Europe. However, various management practices, such as coppicing, aimed to maintain a steady supply of wood for charcoal production. The scarcity of easily accessible wood resources eventually led to the transition to fossil fuel equivalents like coal.
Modern methods of charcoal production involve carbonizing wood in retorts, yielding higher efficiencies compared to traditional kilning methods. The properties of charcoal depend on factors such as the material charred and the temperature of carbonization.
Charcoal finds diverse applications, including metallurgical fuel in iron and steel production, industrial fuel, cooking and heating fuel, reducing agent in chemical processes, and as a raw material in pyrotechnics. It is also utilized in cosmetics, horticulture, animal husbandry, medicine, and environmental sustainability efforts, such as carbon sequestration.
However, the production and utilization of charcoal can have adverse environmental impacts, including deforestation and emissions. Illegal and unregulated charcoal production, particularly in regions like South America and Africa, poses significant challenges to environmental conservation efforts.
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The production of wood charcoal in locations where there is an abundance of wood dates back to ancient times. It generally began with piling billets of wood on their ends to form a conical pile. Openings were left at the bottom to admit air, with a central shaft serving as a flue. The whole pile was covered with turf or moistened clay. The firing began at the bottom of the flue, and the fire gradually spread outward and upward.
The traditional method in Britain used a charcoal pile or clamp. [1] This was essentially a pile of wooden logs (e.g. seasoned oak) leaning in a circle against a chimney. The chimney consisted of 4 wooden stakes held up by some rope. In the clamp too the logs were completely covered with soil and straw allowing no air to enter. It must be lit by introducing some burning fuel into the chimney. The logs burned slowly and transformed into charcoal over a period of 5 days. If the soil covering became torn or cracked by the fire, additional soil was placed on the cracks. Once the burn was complete, the chimney was plugged to prevent air from entering.
The true art of this production method was in managing the sufficient generation of heat, by combusting part of the wood material, and the transfer of the heat to the wood in the process of being carbonized. The operation was so delicate that it was generally left to colliers (professional charcoal burners). They often lived alone in small huts to tend their wood piles. For example, in the Harz Mountains of Germany, charcoal burners lived in conical huts called Köten which still exist today.[ when? ]
The success of the operation depends upon the rate of the combustion. Under average conditions wood yields about 60% charcoal by volume, or 25% by weight; [2] small-scale production methods often yield only about 50% by volume, while large-scale methods enabled higher yields of about 90% by the 17th century. A strong disadvantage of this production method is the huge amount of emissions that are harmful to human health and the environment (emissions of unburnt methane). [3] As a result of the partial combustion of wood material, the efficiency of the traditional method is low.
The massive production of charcoal (at its height employing hundreds of thousands, mainly in Alpine and neighbouring forests) was a major cause of deforestation, especially in Central Europe. [4] [ when? ] Complaints (as early as the Stuart period) about shortages may stem from over-exploitation or the impossibility of increasing production to match growing demand. In England, many woods were managed as coppices, which were cut and regrown cyclically, so that a steady supply of charcoal was available. But the increasing scarcity of easily harvested wood was a major factor behind the switch to fossil fuel equivalents, mainly coal and brown coal for industrial use.
In Finland and Scandinavia, the charcoal was considered the by-product of wood tar production. The best tar came from pine, thus pinewoods were cut down for tar pyrolysis. The residual charcoal was widely used as substitute for metallurgical coke in blast furnaces for smelting. Tar production led to rapid local deforestation. The end of tar production at the end of the 19th century resulted in rapid re-forestation of affected areas.
The American form of the charcoal briquette was first invented and patented by Ellsworth B. A. Zwoyer of Pennsylvania in 1897 [5] and was produced by the Zwoyer Fuel Company. The process was further popularized by Henry Ford, who used wood and sawdust byproducts from automobile fabrication as a feedstock. Ford Charcoal went on to become the Kingsford Company.
The modern process of carbonizing wood, either in small pieces or as sawdust in cast iron retorts, is extensively practiced where wood is scarce, and also for the recovery of valuable byproducts (wood spirit, pyroligneous acid, wood tar), which the process permits. The question of the temperature of the carbonization is important; according to J. Percy, wood becomes brown at 220 °C (430 °F), a deep brown-black after some time at 280 °C (540 °F), and an easily powdered mass at 310 °C (590 °F). Charcoal made at 300 °C (570 °F) is brown, soft and friable, and readily inflames at 380 °C (720 °F); made at higher temperatures it is hard and brittle, and does not fire until heated to about 700 °C (1,300 °F). [2] [6]
Modern methods employ retorting technology, in which process heat is recovered from, and solely provided by, the combustion of gas released during carbonization. [7] Yields of retorting are considerably higher than those of kilning, and may reach 35%-40%.
The properties of the charcoal produced depend on the material charred. The charring temperature is also important. Charcoal contains varying amounts of hydrogen and oxygen as well as ash and other impurities that, together with the structure, determine the properties. The approximate composition of charcoal for gunpowders is sometimes empirically described as C7H4O.[ citation needed ] To obtain a coal with high purity, source material should be free of non-volatile compounds.
Wood charcoal is obtained as the residue by destructive distillation of wood such that the products are:
Charcoal has been used since earliest times for a large range of purposes including art and medicine, but by far its most important use has been as a metallurgical fuel. Charcoal is the traditional fuel of a blacksmith's forge and other applications where an intense heat is required. Charcoal was also used historically as a source of black pigment by grinding it up. In this form charcoal was important to early chemists and was a constituent of formulas for mixtures such as black powder. Due to its high surface area, charcoal can be used as a filter, catalyst, or adsorbent.
Charcoal burns at temperatures exceeding 1,100 degrees Celsius (2,010 degrees Fahrenheit). [9] By comparison, the melting point of iron is approximately 1,200 to 1,550 °C (2,190 to 2,820 °F). Due to its porosity, it is sensitive to the flow of air and the heat generated can be moderated by controlling the air flow to the fire. For this reason charcoal is still widely used by blacksmiths. Charcoal has been used for the production of iron and steel (where it also provided the necessary carbon) since at least 2000 BCE, with artifacts having been found in Proto-Hittite layers at Kaman-Kalehöyük. [10] Charcoal briquettes can burn up to approximately 1,260 °C (2,300 °F) with a forced air blower forge. [11]
In the 16th century, England had to pass laws to prevent the country from becoming completely denuded of trees due to production of iron.[ citation needed ] In the 19th century charcoal was largely replaced by coke in steel production due to cost, even though coke usually adds sulphur and sometimes other deleterious contaminants to the pig iron. Wooded metallurgical regions devoid of coal like Sweden, the Urals, or Siberia transitioned from charcoal in the early 20th century.
Prior to the Industrial Revolution, charcoal was occasionally used as a cooking fuel. It is counted as a smokeless fuel; that is, the carbon is sufficiently pure that burning it causes substantially less air pollution than burning the original uncarbonized organic material would. In the 20th century, clean-air legislation mandated smokeless fuels (mostly coke or charcoal) in many areas of Europe. In the 21st century, charcoal has been advocated as a way to improve the health of people burning raw biomass for cooking and/or heating. Modern "charcoal" briquettes, widely used for outdoor cooking, are made with charcoal but may also include coal as an energy source as well as accelerants, binders and filler.
To contain the charcoal and use it for cooking purposes, a barbecue grill may be used. A small Japanese charcoal grill is known as a shichirin . A brazier is a container used to burn charcoal or other solid fuel.
To start the charcoal burning is harder than starting a wood fire and charcoal lighter fluid may be employed. A chimney starter or electric charcoal starter are tools to help with starting to light charcoal.
Certain types of charcoal, such as wood charcoal, are used for reducing heated metallic oxides to their respective metals:[ citation needed ]
Charcoal can also be used to reduce super heated steam to hydrogen (along with the formation of carbon monoxide):[ citation needed ]
Like many other sources of carbon, charcoal can be used for the production of various syngas compositions; i.e., various CO + H2 + CO2 + N2 mixtures. The syngas is typically used as fuel, including automotive propulsion, or as a chemical feedstock.
In times of scarce petroleum, automobiles and even buses have been converted to burn wood gas: a gas mixture consisting primarily of diluting atmospheric nitrogen, but also containing combustible gasses (mostly carbon monoxide) released by burning charcoal or wood in a wood gas generator. In 1931, Tang Zhongming developed an automobile powered by charcoal, and these cars were popular in China until the 1950s, and in occupied France during World War II, where they were called gazogènes .
Charcoal is used in the production of black powder, which is used extensively in the production of fireworks. It is usually ground into a fine powder, with air float grade being the finest particle size available commercially. When used in black powder compositions, it is often ball-milled with other ingredients so that they are intimately mixed together. Certain charcoals perform better when used to make black powder; these include spruce, willow, paulownia and grapevine among others.[ citation needed ] Charcoal produces fine dark orange/golden sparks. Usually, powder with a mesh size from 10 to 325 is used to obtain showers of golden sparks in pyrotechnic compositions. [13]
Charcoal is also incorporated in multiple cosmetic products. [14] It can be produced from regular bamboo cut into small pieces and boiled in water to remove soluble compounds. [14] Raw bamboo charcoal is obtained after drying and carbonization in an oven at elevated temperature. [14] The role of charcoal in cosmetics is based on its highly effective absorbing properties at a microscopic scale. [14]
Charcoal may be used as a source of carbon in chemical reactions. One example of this is the production of carbon disulphide through the reaction of sulfur vapors with hot charcoal. In that case, the wood should be charred at high temperature to reduce the residual amounts of hydrogen and oxygen that lead to side reactions.
Charcoal may be activated to increase its effectiveness as a filter. Activated charcoal readily adsorbs a wide range of organic compounds dissolved or suspended in gases and liquids. In certain industrial processes, such as the purification of sucrose from cane sugar, impurities cause an undesirable color, which can be removed with activated charcoal. It is also used to absorb odors and toxins in gaseous solutions, as in home air purifiers and some types of gas mask. The medical use of activated charcoal is mainly the absorption of poisons. [15] Activated charcoal is available without a prescription, so it is used for a variety of health-related applications. For example, it is often used to reduce discomfort and embarrassment due to excessive gas (flatulence) in the digestive tract. [16]
Animal charcoal or bone black is the carbonaceous residue obtained by the dry distillation of bones. It contains only about 10% carbon, the remaining being calcium and magnesium phosphates (80%) and other inorganic material originally present in the bones. It is generally manufactured from the residues obtained in the glue and gelatin industries. Its bleaching power was applied in 1812 by Derosne for clarifying sugar syrup, but its use in this direction has now greatly diminished. Today it is seldom used for this purpose due to the introduction of more active and easily managed reagents, but it is still employed to some extent in laboratory practice. The bleaching action of the charcoal in solution diminishes as it adsorbs colored contaminants, and it must be reactivated periodically by separate washing and reheating. [2] While wood charcoal effectively removes some pigments and contaminants from solutions, bone charcoal is generally more effective as an adsorption filter due to its increased porosity and surface area.[ citation needed ]
Charcoal is used for drawing, making rough sketches in painting, and is one of the possible media used for making a parsemage. It usually must be preserved by the application of a fixative. Artists generally utilize charcoal in four forms:
One additional use of charcoal was rediscovered recently[ when? ] for horticulture. Although American gardeners have used charcoal for a short time, research on Terra preta soils in Amazonia has discovered the widespread use of biochar by pre-Columbian natives to ameliorate unproductive soil into soil rich in carbon. The technique may find modern application, both to improve soils and as a means of carbon sequestration. [18]
Charcoal is mixed with feed, added to litter, or used in the treatment of manure. [19] Poultry benefits from using charcoal in this manner. [20] [21]
A concern that activated charcoal might be used unscrupulously to allow livestock to tolerate low quality feed contaminated with aflatoxins resulted in the Association of American Feed Control Officials banning it in 2012 from use in commercial livestock feeds. [22]
Charcoal in the form of charcoal biscuits was consumed in the past for gastric problems. Now it can be consumed in tablet, capsule, or powder form for digestive effects. [23] Research regarding its effectiveness is controversial. [24]
Charcoal has been used in combination with saccharin in research to measure mucociliary transport time. [25]
Charcoal has also been incorporated into toothpaste formulas; however, there is no evidence to determine its safety and effectiveness. [26]
Red colobus monkeys in Africa have been observed eating charcoal for self-medication. Because their leafy diets contain high levels of cyanide, which may lead to indigestion, they learned to consume charcoal, which absorbs the cyanide and relieves discomfort. This knowledge is transmitted from mother to infant. [27]
Production and utilization of charcoal, like any use of woody biomass as fuel, typically results in emissions and can contribute to deforestation.
The use of charcoal as a smelting fuel has been experiencing a resurgence in South America resulting in severe environmental, social and medical problems. [28] [29] Charcoal production at a sub-industrial level is one of the causes of deforestation. Charcoal production is now usually illegal and nearly always unregulated, as in Brazil, where charcoal production is a large illegal industry for making pig iron. [30] [31] [32]
Massive forest destruction has been documented in areas such as Virunga National Park in the Democratic Republic of Congo, where it is considered a primary threat to the survival of the mountain gorillas. [33] Similar threats are found in Zambia. [34] In Malawi, illegal charcoal trade employs 92,800 workers and is the main source of heat and cooking fuel for 90 percent of the nation's population. [35] Some experts, such as Duncan MacQueen, Principal Researcher–Forest Team, International Institute for Environment and Development (IIED), argue that while illegal charcoal production causes deforestation, a regulated charcoal industry that required replanting and sustainable use of the forests "would give their people clean efficient energy – and their energy industries a strong competitive advantage". [35]
Recent assessments of charcoal imported to Europe have shown that many charcoal products are produced from tropical wood, often of undeclared origin. In an analysis of barbecue charcoal marketed in Germany, the World Wildlife Fund found that most products contain tropical wood. As a notable exception, reference is made to barbecue charcoal imports from Namibia, where charcoal is typically produced from surplus biomass resulting from woody plant encroachment. [36] [37] [38] Charcoal trafficking in Somalia is an economic and environmental issue with significant regional-security implications. [39]
The last section of the film Le Quattro Volte (2010) gives a good and long, if poetic, documentation of the traditional method of making charcoal. [40] The Arthur Ransome children's series Swallows and Amazons (particularly the second book, Swallowdale ) features carefully drawn vignettes of the lives and the techniques of charcoal burners at the start of the 20th century, in the Lake District of the UK. Antonín Dvořák's opera King and Charcoal Burner is based on a Czech legend about a king who gets lost in a forest and is rescued by a charcoal burner.
Coke is a grey, hard, and porous coal-based fuel with a high carbon content. It is made by heating coal or petroleum in the absence of air. Coke is an important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and forges.
Wood gas is a fuel gas that can be used for furnaces, stoves, and vehicles. During the production process, biomass or related carbon-containing materials are gasified within the oxygen-limited environment of a wood gas generator to produce a combustible mixture. In some gasifiers this process is preceded by pyrolysis, where the biomass or coal is first converted to char, releasing methane and tar rich in polycyclic aromatic hydrocarbons.
Pyrolysis is the process of thermal decomposition of materials at elevated temperatures, often in an inert atmosphere without access to oxygen.
A barbecue grill or barbeque grill is a device that cooks food by applying heat from below. There are several varieties of grills, with most falling into one of three categories: gas-fueled, charcoal, or electric. There is debate over which method yields superior results.
Solid fuel refers to various forms of solid material that can be burnt to release energy, providing heat and light through the process of combustion. Solid fuels can be contrasted with liquid fuels and gaseous fuels. Common examples of solid fuels include wood, charcoal, peat, coal, hexamine fuel tablets, dry dung, wood pellets, corn, wheat, rice, rye, and other grains. Solid fuels are extensively used in rocketry as solid propellants. Solid fuels have been used throughout human history to create fire and solid fuel is still in widespread use throughout the world in the present day.
Dry distillation is the heating of solid materials to produce gaseous products. The method may involve pyrolysis or thermolysis, or it may not.
A briquette is a compressed block of coal dust or other combustible biomass material used for fuel and kindling to start a fire. The term is a diminutive derived from the French word brique, meaning brick.
Carbonization or carbonisation is the conversion of organic matters like plants and dead animal remains into carbon through destructive distillation.
The Karrick process is a low-temperature carbonization (LTC) and pyrolysis process of carbonaceous materials. Although primarily meant for coal carbonization, it also could be used for processing of oil shale, lignite or any carbonaceous materials. These are heated at 450 °C (800 °F) to 700 °C (1,300 °F) in the absence of air to distill out synthetic fuels–unconventional oil and syngas. It could be used for a coal liquefaction as also for a semi-coke production. The process was the work of oil shale technologist Lewis Cass Karrick at the United States Bureau of Mines in the 1920s.
Smouldering or smoldering is the slow, flameless form of combustion, sustained by the heat evolved when oxygen directly attacks the surface of a condensed-phase fuel. Many solid materials can sustain a smouldering reaction, including coal, cellulose, wood, cotton, tobacco, cannabis, peat, plant litter, humus, synthetic foams, charring polymers including polyurethane foam and some types of dust. Common examples of smouldering phenomena are the initiation of residential fires on upholstered furniture by weak heat sources, and the persistent combustion of biomass behind the flaming front of wildfires.
Pyrolysis oil, sometimes also known as biocrude or bio-oil, is a synthetic fuel with few industrial application and under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 °C (900 °F) with subsequent cooling, separation from the aqueous phase and other processes. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, partial miscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading.
Biochar is charcoal, sometimes modified, that is intended for organic use, as in soil. It is the lightweight black remnants, consisting of carbon and ashes, remaining after the pyrolysis of biomass, and is a form of charcoal. Biochar is defined by the International Biochar Initiative as the "solid material obtained from the thermochemical conversion of biomass in an oxygen-limited environment".
Bamboo charcoal is charcoal made from species of bamboo. It is typically made from the culms or refuse of mature bamboo plants and burned in ovens at temperatures ranging from 600 to 1,200 °C. It is an especially porous charcoal, making it useful in the manufacture of activated carbon.
Kingsford is a brand that makes charcoal briquettes, along with related products, used for grilling. Established in 1920, the brand is owned by The Clorox Company. Currently, the Kingsford Products Company remains the leading manufacturer of charcoal in the United States, with 80% market share. More than 1 million tons of wood scraps are converted into charcoal briquettes annually.
Smokeless fuel is a type of solid fuel which either does not emit visible smoke or emits minimal amounts during combustion. These types of fuel find use where the use of fuels which produce smoke, such as coal and unseasoned or wet wood, is prohibited.
The history of gaseous fuel, important for lighting, heating, and cooking purposes throughout most of the 19th century and the first half of the 20th century, began with the development of analytical and pneumatic chemistry in the 18th century. These "synthetic fuel gases" were made by gasification of combustible materials, usually coal, but also wood and oil, by heating them in enclosed ovens with an oxygen-poor atmosphere. The fuel gases generated were mixtures of many chemical substances, including hydrogen, methane, carbon monoxide and ethylene. Coal gas also contains significant quantities of unwanted sulfur and ammonia compounds, as well as heavy hydrocarbons, and must be purified before use.
Slash-and-char is an alternative to slash-and-burn that has a lesser effect on the environment. It is the practice of charring the biomass resulting from the slashing instead of burning it. Due to incomplete combustion (pyrolysis) the resulting residue matter charcoal can be utilized as biochar to improve the soil fertility.
Biomass briquettes are a biofuel substitute made of biodegradable green waste with lower emissions of greenhouses gases and carbon dioxide than traditional fuel sources. This fuel source is used as an alternative for harmful biofuels. Briquettes are used for heating, cooking fuel, and electricity generation usually in developing countries that do not have access to more modern fuel sources. Biomass briquettes have become popular in developed countries due to the accessibility, and eco-friendly impact. The briquettes can be used in the developed countries for producing electricity from steam power by heating water in boilers.
A disposable grill is a specific barbecue grill type which is used in a single application, with the grill being recycled or disposed of after use.
Hydrothermal carbonization (HTC) is a chemical process for the conversion of organic compounds to structured carbons. It can be used to make a wide variety of nanostructured carbons, simple production of brown coal substitute, synthesis gas, liquid petroleum precursors and humus from biomass with release of energy. Technically the process imitates, within a few hours, the brown coal formation process which takes place in nature over enormously longer geological periods of 50,000 to 50 million years. It was investigated by Friedrich Bergius and first described in 1913.
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