Pine tar

Last updated
Pine tar
Wood tar.jpg
Names
Other names
Pine tar oil, Wood tar oil
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.029.429 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 232-374-8
KEGG
PubChem CID
UNII
Properties
AppearanceBlackish-brown viscous liquid
Density 1.01–1.06
Boiling point 150 to 400 °C (302 to 752 °F; 423 to 673 K)
Slightly
Solubility alc, chloroform, ether, acetone, glacial acetic acid, fixed/volatile oils, solutions of caustic alkalies
Pharmacology
Topical
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H317, H412
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point 90 °C (194 °F; 363 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Pine tar is a form of wood tar produced by the high temperature carbonization of pine wood in anoxic conditions (dry distillation or destructive distillation). The wood is rapidly decomposed by applying heat and pressure in a closed container; the primary resulting products are charcoal and pine tar.

Contents

Pine tar consists primarily of aromatic hydrocarbons, tar acids, and tar bases. Components of tar vary according to the pyrolytic process (e.g. method, duration, temperature) and origin of the wood (e.g. age of pine trees, type of soil, and moisture conditions during tree growth). The choice of wood, design of kiln, burning, and collection of the tar can vary. Only pine stumps and roots are used in the traditional production of pine tar.[ citation needed ]

Pine tar has a long history as a wood preservative, as a wood sealant for maritime use, in roofing construction and maintenance, in soaps, and in the treatment of carbuncles and skin diseases, such as psoriasis, eczema, and rosacea. It is used in baseball to enhance the grip of a hitter's bat; it is also sometimes used by pitchers to improve their grip on the ball, in violation of the rules. [1]

History

Nordic Iron Age

Based on chemical analysis of organic residues, there are strong indications that cone-shaped pits discovered north of Uppsala, Sweden, have been used for pine tar production. Three of the pits have been radiocarbon dated. The oldest dates back to 540–380 BCE, which would make it the world's oldest known, still existing tar production facility. The other dates from 230–390 CE. [2]

Classical antiquity

In his encyclopedic work Natural History (Latin : Naturalis Historia) the Roman naturalist and author Pliny the Elder (23/24–79 CE) describes how, in Europe, tar is produced through the destructive distillation of pine wood. The wood was chopped into small pieces (billets) and heated in a furnace. The tar was used "for coating ships and for many other useful purposes." [3]

17th century

Finland

Pine tar has long been used in Nordic nations as a preservative for wood which may be exposed to harsh conditions, including outdoor furniture and ship decking and rigging. Tar demand surged in the 17th century as European nations began constructing naval and merchant fleets that required tar and pitch for ship waterproofing and caulking. In Finland, then a part of Sweden, large-scale tar production began in the early 17th century. By the late 17th century, tar was Sweden's third most valuable export commodity.

North American colonies

Tar and pitch for maritime use was in such demand that it became an important export for the American colonies, which had extensive pine forests. North Carolinians became known as "Tar Heels."[ citation needed ]

18th–19th century

Sweden

In present-day Sweden, large-scale tar production started around 1700. Swedish pine tar was often called "Stockholm tar" [4] since, for many years, a single company held a royal monopoly on its export out of Stockholm, Sweden. [5] It was also known as "Archangel Tar". [6] Stockholm tar became synonymous with top-quality tar. Tar production peaked around the mid-1850s and gradually declined thereafter, largely due to new shipbuilding materials reducing the need for tar as a waterproofing agent, and to the decreasing use of hemp rope as sailing ships were phased out.

Use

Pine tar was used as a preservative on the bottoms of traditional Nordic-style skis until modern synthetic materials replaced wood in their construction. It also helped waxes adhere, which aided such skis’ grip and glide.

Pine tar is widely used as a veterinary care product, [7] particularly as an antiseptic and hoof care treatment for horses and cattle. [7] It also has been used when chickens start pecking the low hen. [8] Applying a smear of pine tar on the hens' wound acts as a natural germicidal/antibacterial agent that discourages continued attacks on the affected hen due to its foreign texture. [8]

Pine tar is used as a softening solvent in the rubber industry, for treating and fabricating construction materials, and in special paints.

As a wood preservative

Pine tar is combined with gum turpentine and boiled linseed oil to create a wood preservative. First, a thin coat is applied using a mixture with a greater proportion of turpentine. This allows it to permeate deeper into the oakum and fibre of the wood and lets the tar seep into any pinholes and larger gaps that might be in the planks. The tar weeps out to the exterior and indicates where the boat needs the most attention.[ how? ] This is followed with a thicker standard mix. Such treatments, while effective, must be continually reapplied.

Weatherproofing rope

Traditionally, hemp and other natural fibers were the norm for rope production. Such rope would quickly rot when exposed to rain, and was typically tarred to preserve it. The tar would stain the hands of ship's crews, and British Navy seamen became known as "tars."

Baseball

George Brett's pine tar bat at left, from a 2006 exhibit at The Henry Ford in Dearborn, Michigan Pine-tar bat.jpg
George Brett's pine tar bat at left, from a 2006 exhibit at The Henry Ford in Dearborn, Michigan

Pine tar is applied to the handles of baseball bats to improve a batter's grip.

Rule 1.10(c) of the 2002 Official rules of Major League Baseball restricts application to the lower 18 inches of a bat. The most famous example of the rule being applied is the Pine Tar Incident, which occurred during the July 24, 1983 game between the Kansas City Royals and New York Yankees which resulted in a George Brett go-ahead home run in the ninth inning being nullified and the game being protested.

Pine tar is also sometimes used illegally by pitchers to improve their grip on the ball in cold weather. This is not allowed due to a regulation prohibiting the application of any foreign substance to a ball (except grip-improving baseball rubbing mud applied by the umpires).

Medical

Pine tar has historically been used for treating skin conditions, usually as an additive in cold process solid soap or lotions. [9] Due to the high presence of phenol in the early manufacturing of pine tar, it was deemed carcinogenic. However, now much of the phenol has been removed. Pine tar was banned by the FDA along with many other ingredients categorized as over the counter drugs, due to a lack of evidence of safety and effectiveness for the specific uses named. [10] However, clinical tests in Australia in 2017 demonstrated that the greatest risk comes from acute sensitivity for those with severe dermatological conditions, and if it comes in contact with the eyes. [9] The number of positive reactions for wood tars was not significantly greater than those for other common allergens. In addition, the concentration of pine tar in topical products available in Australia is up to 2.3%, which is up to four times less than that tested in these studies.

Pine tar has been used to cover peck wounds in captive bird flocks such as chickens, to prevent continued pecking on a wound and cannibalism. [11] Pine tar is also used in veterinary medicine as an expectorant and an antiseptic in chronic skin conditions. [12]

See also

Related Research Articles

Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and used in the surfacing of roads. Coal tar was listed as a known human carcinogen in the first Report on Carcinogens from the U.S. Federal Government, issued in 1980.

<span class="mw-page-title-main">Phenol</span> Organic compound (C6H5OH)

Phenol is an aromatic organic compound with the molecular formula C6H5OH. It is a white crystalline solid that is volatile. The molecule consists of a phenyl group bonded to a hydroxy group. Mildly acidic, it requires careful handling because it can cause chemical burns.

<span class="mw-page-title-main">Creosote</span> Tar distillation byproduct used as wood preservative

Creosote is a category of carbonaceous chemicals formed by the distillation of various tars and pyrolysis of plant-derived material, such as wood, or fossil fuel. They are typically used as preservatives or antiseptics.

<span class="mw-page-title-main">Cedar oil</span> Essential oil

Cedar oil, also known as cedarwood oil, is an essential oil derived from various types of conifers, most in the pine or cypress botanical families. It is produced from the foliage, and sometimes the wood, roots, and stumps left after logging of trees for timber. It has many uses in art, industry, and perfumery, and while the characteristics of oils derived from various species may vary, all have some degree of pesticidal effects.

<span class="mw-page-title-main">Turpentine</span> Liquid distilled from pine resin

Turpentine is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Principally used as a specialized solvent, it is also a source of material for organic syntheses.

<span class="mw-page-title-main">Beak trimming</span> Trimming of a birds beak, usually performed on domesticated birds

Beak trimming, or beak conditioning, is the partial removal of the beak of poultry, especially layer hens and turkeys, although it is also be performed on some quail and ducks. When multiple birds are confined in small spaces due to farming practices, they are more likely to hurt each other through pecking. Beak trimming aims to avoid damage done by pecking, although the practice is criticized by animal welfare organizations and banned in several European countries. Beak trimming is most common in egg-laying strains of chickens. In some countries, such as the United States, turkeys routinely have their beaks trimmed. In the UK, only 10% of turkeys are beak trimmed.

<span class="mw-page-title-main">Rosin</span> Solid form of resin

Rosin, also known as colophony or Greek pitch, is a solid form of resin obtained from pine trees and other plants, mostly conifers, primarily through heating fresh liquid resin to vaporize the volatile liquid terpene components. Used widely in various industries and arts, rosin appears as a semi-transparent, brittle substance that ranges in color from yellow to black and melts at stove-top temperatures. Rosin consists mainly of resin acids, especially abietic acid, and is soluble in alcohol, ether, benzene, and chloroform.

<span class="mw-page-title-main">Wood preservation</span> Treatment or process aimed at extending the service life of wood structures

Wood easily degrades without sufficient preservation. Apart from structural wood preservation measures, there are a number of different chemical preservatives and processes that can extend the life of wood, timber, and their associated products, including engineered wood. These generally increase the durability and resistance from being destroyed by insects or fungi.

<span class="mw-page-title-main">Dry distillation</span> Heating of solids to produce gases

Dry distillation is the heating of solid materials to produce gaseous products. The method may involve pyrolysis or thermolysis, or it may not.

<span class="mw-page-title-main">White spirit</span> Petroleum-derived clear, transparent liquid

White spirit (AU, UK and Ireland) or mineral spirits (US, Canada), also known as mineral turpentine (AU/NZ/ZA), turpentine substitute, and petroleum spirits, is a petroleum-derived clear liquid used as a common organic solvent in painting. There are also terms for specific kinds of white spirit, including Stoddard solvent and solvent naphtha (petroleum). White spirit is often used as a paint thinner, or as a component thereof, though paint thinner is a broader category of solvent. Odorless mineral spirits (OMS) have been refined to remove the more toxic aromatic compounds, and are recommended for applications such as oil painting.

<span class="mw-page-title-main">Pentachlorophenol</span> Chemical compound

Pentachlorophenol (PCP) is an organochlorine compound used as a pesticide and a disinfectant. First produced in the 1930s, it is marketed under many trade names. It can be found as pure PCP, or as the sodium salt of PCP, the latter of which dissolves easily in water. It can be biodegraded by some bacteria, including Sphingobium chlorophenolicum.

<span class="mw-page-title-main">Liquid smoke</span> Edible chemical compound

Liquid smoke is a water-soluble yellow to red liquid used as a flavoring as a substitute for cooking with wood smoke while retaining a similar flavor. It can be used to flavor any meat or vegetable. It is available as pure condensed smoke from various types of wood, and as derivative formulas containing additives.

<span class="mw-page-title-main">Destructive distillation</span> Chemical process

Destructive distillation is a chemical process in which decomposition of unprocessed material is achieved by heating it to a high temperature; the term generally applies to processing of organic material in the absence of air or in the presence of limited amounts of oxygen or other reagents, catalysts, or solvents, such as steam or phenols. It is an application of pyrolysis. The process breaks up or 'cracks' large molecules. Coke, coal gas, gaseous carbon, coal tar, ammonia liquor, and coal oil are examples of commercial products historically produced by the destructive distillation of coal.

<span class="mw-page-title-main">Tar</span> Dark viscous organic liquid

Tar is a dark brown or black viscous liquid of hydrocarbons and free carbon, obtained from a wide variety of organic materials through destructive distillation. Tar can be produced from coal, wood, petroleum, or peat.

<span class="mw-page-title-main">Pine oil</span> Chemical compound

Pine oil is an essential oil obtained from a variety of species of pine, particularly Pinus sylvestris. Typically, parts of the trees that are not used for lumber — stumps, etc. — are ground and subjected to steam distillation. As of 1995, synthetic pine oil was the "biggest single turpentine derivative." Synthetic pine oils accounted for 90% of sales as of 2000.

<span class="mw-page-title-main">Worm, parcel and serve</span>

To worm, parcel and serve a line is to apply a multi-layered protection against chafe and deterioration to standing rigging. It is a technique not usually used on modern small boats, but is found extensively on traditionally-rigged sailing ships. Worming, parcelling and serving —referred to collectively as "service"— is traditionally applied only to traditional twisted rope, either natural fiber or steel wire-rope, not the braided line almost exclusively used on modern vessels, but some traditional vessels now use modern high modulus braided lines in place of wire rope and serve the line to maintain the traditional appearance. It can be applied to the entire length of a line, such as a shroud, or selectively, to specific parts of a line, such as over the spliced ends of a stay, where the chafe on the middle section of the stay precludes complete protection.

<span class="mw-page-title-main">Tarring (rope)</span> Coating fibers with pine tar or coal tar

Tarring is protecting some types of natural fibre and wire rope by coating it with tar. Hemp rope, which was typically used for standing rigging, requires tarring. Manila and cotton ropes were used for running rigging and were not tarred as this would make the rope too stiff to run easily through blocks. Regular tarring at sea was required when sailing ships used hemp rope - once every 6 months for a ship on a long voyage.

Pyrolysis oil, sometimes also known as biocrude or bio-oil, is a synthetic fuel with few industrial application and under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about 500 °C (900 °F) with subsequent cooling, separation from the aqueous phase and other processes. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, partial miscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading.

<span class="mw-page-title-main">Birch bark tar</span> Substance derived from birch tree bark

Birch bark tar is a substance that is synthesized by dry distillation of birch tree bark.

Creolin is a generic name for disinfectants whose composition varies according to origin. It is extracted from the dry distillation of wood. The residue remaining in the autoclave vessel is a dark, syrupy mass called creosote, which is composed mainly of phenolic acid and cresylic acid. The original composition of creolin is a creosote tar oil, caustic soda, soaps, and very little water. It is of low technology and a very powerful disinfectant.

References

  1. Matthews, Wallace (April 24, 2014). "Michael Pineda suspended 10 games". ESPN.com. Retrieved June 12, 2021.
  2. Björck, Niclas; Appelgren, Katarina (2005). Boplats och gravar från äldre järnålder i Fyrisåns dalgång [Settlements and graves from the early Iron Age in the Fyris valley]. UV GAL, Rapport 2005:5 (in Swedish). Riksantikvarieämbetet, Avdelningen för arkeologiska undersökningar. pp. 16, 26.
  3. Pliny the Elder (1855) [Pliny published the first 10 books in 77 CE. The rest was published posthumously by Pliny the Younger]. "XVI.21(11)". The Natural History of Pliny: Translated, with Copious Notes and Illustrations. Vol. III. Translated by Bostock, John; Riley, Henry Thomas. Henry G. Bohn.
  4. "Stockholm Tar". MedicAnimal.com. Archived from the original on 19 April 2014. Retrieved 23 September 2012.
  5. Theodore P. Kaye. "Pine Tar; History And Uses". San Francisco Maritime Park Association. Retrieved 2010-08-01.
  6. Chisholm, Hugh, ed. (1911). "Tar"  . Encyclopædia Britannica . Vol. 26 (11th ed.). Cambridge University Press. p. 414: see second para. Wood Tar.—Wood tar, known also as Stockholm and as Archangel tar, is....."
  7. 1 2 Wickstrom, Mark. "Phenols and Related Compounds". The Merck Veterinary Manual. Merck Manuals. Retrieved 16 April 2015.
  8. 1 2 Laura Bryant. Chickens: A Step-by-Step Guide to Raising and Keeping Hens. Cedar Fort, Inc. ISBN   9781462103409 . Retrieved 2018-02-26.
  9. 1 2 Barnes, Tanya M.; Greive, Kerryn A. (2017). "Topical pine tar: History, properties and use as a treatment for common skin conditions". Australasian Journal of Dermatology. 58 (2): 80–85. doi:10.1111/ajd.12427. ISSN   1440-0960. PMC   5434829 . PMID   26790564.
  10. Drug products containing certain active ingredients offered over-the-counter (OTC) for certain uses. 14CFR310.545
  11. Gail Damerow (1 January 2010). Guide to Raising Chickens . Storey Publishing, LLC. p.  121. ISBN   978-1-60342-469-1.
  12. Merck Index, 11th Edition, 7417. p. 1182