Carbon dioxide sensor

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A carbon dioxide sensor or CO2 sensor is an instrument for the measurement of carbon dioxide gas. The most common principles for CO2 sensors are infrared gas sensors (NDIR) and chemical gas sensors. Measuring carbon dioxide is important in monitoring indoor air quality, [1] the function of the lungs in the form of a capnograph device, and many industrial processes.

Contents

Nondispersive infrared (NDIR) CO2 sensors

CO2 concentration meter using a nondispersive infrared sensor CO2Mini monitor TFA Dostmann.jpg
CO2 concentration meter using a nondispersive infrared sensor

NDIR sensors are spectroscopic sensors to detect CO2 in a gaseous environment by its characteristic absorption. The key components are an infrared source, a light tube, an interference (wavelength) filter, and an infrared detector. The gas is pumped or diffuses into the light tube, and the electronics measure the absorption of the characteristic wavelength of light. NDIR sensors are most often used for measuring carbon dioxide. [2] The best of these have sensitivities of 20–50 PPM. [2] Typical NDIR sensors cost in the (US) $100 to $1000 range.

NDIR CO2 sensors are also used for dissolved CO2 for applications such as beverage carbonation, pharmaceutical fermentation and CO2 sequestration applications. In this case they are mated to an ATR (attenuated total reflection) optic and measure the gas in situ. New developments include using microelectromechanical systems (MEMS) IR sources to bring down the costs of this sensor and to create smaller devices (for example for use in air conditioning applications). [3]

Another method (Henry's Law) also can be used to measure the amount of dissolved CO2 in a liquid, if the amount of foreign gases is insignificant.[ further explanation needed ]

Photoacoustic sensors

CO2 can be measured using photoacoustic spectroscopy. Concentration of CO2 can be measured by subjecting a sample to pulses of electromagnetic energy (such as from a distributed feedback laser [4] ) that is tuned specifically to the absorption wavelength of CO2. With each pulse of energy, the CO2 molecules within the sample will absorb and generate pressure waves via the photoacoustic effect. These pressure waves are then detected with an acoustic detector and converted to a usable CO2 reading through a computer or microprocessor. [5]

Chemical CO2 sensors

Chemical CO2 gas sensors with sensitive layers based on polymer- or heteropolysiloxane have the principal advantage of very low energy consumption, and that they can be reduced in size to fit into microelectronic-based systems. On the downside, short and long term drift effects, as well as a rather low overall lifetime, are major obstacles when compared with the NDIR measurement principle. [6] Most CO2 sensors are fully calibrated prior to shipping from the factory. Over time, the zero point of the sensor needs to be calibrated to maintain the long term stability of the sensor. [7]

Estimated CO2 sensor

For indoor environments such as offices or gyms where the principal source of CO2 is human respiration, rescaling some easier-to-measure quantities such as volatile organic compound (VOC) and hydrogen gas (H2) concentrations provides a good-enough estimator of the real CO2 concentration for ventilation and occupancy purposes.[ citation needed ] Furthermore, inasmuch as ventilation is a factor in the spread of respiratory viruses, [8] CO2 levels are a rough metric for COVID-19 risk; the worse the ventilation, the better for viruses and vice versa. [9] [10] Sensors for these substances can be made using cheap (~$20) Microelectromechanical systems (MEMS) metal oxide semiconductor (MOS) technology. The reading they generate is called estimated CO2 (eCO2) [11] or CO2 equivalent (CO2eq). [12] Although the readings tend to be good enough in the long run, introducing non-respiration sources of VOC or CO2, such as peeling fruits or using perfume, will undermine their reliability. H2-based sensors are less susceptible as they are more specific to human breathing, although the very health conditions the hydrogen breath test is set to diagnose will also disrupt them. [12]

Applications

See also

Related Research Articles

<span class="mw-page-title-main">Carbon dioxide</span> Chemical compound with formula CO₂

Carbon dioxide is a chemical compound with the chemical formula CO2. It is made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature, and as the source of available carbon in the carbon cycle, atmospheric CO2 is the primary carbon source for life on Earth. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. When carbon dioxide dissolves in water, it forms carbonate and mainly bicarbonate, which causes ocean acidification as atmospheric CO2 levels increase.

<span class="mw-page-title-main">Global warming potential</span> Potential heat absorbed by a greenhouse gas

Global warming potential or greenhouse warming potential (GWP) is a measure of how much infrared thermal radiation a greenhouse gas added to the atmosphere would absorb over a given time frame, as a multiple of the radiation that would be absorbed by the same mass of added carbon dioxide. GWP is 1 for CO2. For other gases it depends on how strongly the gas absorbs infrared thermal radiation, how quickly the gas leaves the atmosphere, and the time frame being considered. The carbon dioxide equivalent is calculated from GWP. For any gas, it is the mass of CO2 that would warm the earth as much as the mass of that gas. Thus it provides a common scale for measuring the climate effects of different gases. It is calculated as GWP times mass of the other gas.

<span class="mw-page-title-main">Indoor air quality</span> Air quality within and around buildings and structures

Indoor air quality (IAQ) is the air quality within and around buildings and structures. IAQ is known to affect the health, comfort, and well-being of building occupants. Poor indoor air quality has been linked to sick building syndrome, reduced productivity, and impaired learning in schools. Common pollutants of indoor air include: secondhand tobacco smoke, air pollutants from indoor combustion, radon, molds and other allergens, carbon monoxide, volatile organic compounds, legionella and other bacteria, asbestos fibers, carbon dioxide, ozone and particulates. Source control, filtration, and the use of ventilation to dilute contaminants are the primary methods for improving indoor air quality.

<span class="mw-page-title-main">Absorption spectroscopy</span> Spectroscopic techniques that measure the absorption of radiation

Absorption spectroscopy is spectroscopy that involves techniques that measure the absorption of electromagnetic radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.

<span class="mw-page-title-main">Ventilation (architecture)</span> Intentional introduction of outside air into a space

Ventilation is the intentional introduction of outdoor air into a space. Ventilation is mainly used to control indoor air quality by diluting and displacing indoor pollutants; it can also be used to control indoor temperature, humidity, and air motion to benefit thermal comfort, satisfaction with other aspects of the indoor environment, or other objectives.

<span class="mw-page-title-main">Keeling Curve</span> Graph of atmospheric CO2 from 1958 to the present

The Keeling Curve is a graph of the accumulation of carbon dioxide in the Earth's atmosphere based on continuous measurements taken at the Mauna Loa Observatory on the island of Hawaii from 1958 to the present day. The curve is named for the scientist Charles David Keeling, who started the monitoring program and supervised it until his death in 2005.

Photoacoustic spectroscopy is the measurement of the effect of absorbed electromagnetic energy on matter by means of acoustic detection. The discovery of the photoacoustic effect dates to 1880 when Alexander Graham Bell showed that thin discs emitted sound when exposed to a beam of sunlight that was rapidly interrupted with a rotating slotted disk. The absorbed energy from the light causes local heating, generating a thermal expansion which creates a pressure wave or sound. Later Bell showed that materials exposed to the non-visible portions of the solar spectrum can also produce sounds.

<span class="mw-page-title-main">Total organic carbon</span> Concentration of organic carbon in a sample

Total organic carbon (TOC) is an analytical parameter representing the concentration of organic carbon in a sample. TOC determinations are made in a variety of application areas. For example, TOC may be used as a non-specific indicator of water quality, or TOC of source rock may be used as one factor in evaluating a petroleum play. For marine surface sediments average TOC content is 0.5% in the deep ocean, and 2% along the eastern margins.

<span class="mw-page-title-main">Nondispersive infrared sensor</span> Infrared detector without diffracting element dispersing the IR wave lengths

A nondispersive infrared sensor is a simple spectroscopic sensor often used as a gas detector. It is non-dispersive in the fact that no dispersive element is used to separate out the broadband light into a narrow spectrum suitable for gas sensing. The majority of NDIR sensors use a broadband lamp source and an optical filter to select a narrow band spectral region that overlaps with the absorption region of the gas of interest. In this context narrow may be 50-300nm bandwidth. Modern NDIR sensors may use Microelectromechanical systems (MEMs) or mid IR LED sources, with or without an optical filter.

<span class="mw-page-title-main">Hydrogen sensor</span> Gas Detector

A hydrogen sensor is a gas detector that detects the presence of hydrogen. They contain micro-fabricated point-contact hydrogen sensors and are used to locate hydrogen leaks. They are considered low-cost, compact, durable, and easy to maintain as compared to conventional gas detecting instruments.

<span class="mw-page-title-main">Occupancy sensor</span>

An occupancy sensor is an indoor device used to detect the presence of a person. Applications include automatic adjustment of lights or temperature or ventilation systems in response to the quantity of people present. The sensors typically use infrared, ultrasonic, microwave, or other technology. The term encompasses devices as different as PIR sensors, hotel room keycard locks and smart meters. Occupancy sensors are typically used to save energy, provide automatic control, and comply with building codes.

A gas detector is a device that detects the presence of gases in an area, often as part of a safety system. A gas detector can sound an alarm to operators in the area where the leak is occurring, giving them the opportunity to leave. This type of device is important because there are many gases that can be harmful to organic life, such as humans or animals.

A flame detector is a sensor designed to detect and respond to the presence of a flame or fire, allowing flame detection. Responses to a detected flame depend on the installation, but can include sounding an alarm, deactivating a fuel line, and activating a fire suppression system. When used in applications such as industrial furnaces, their role is to provide confirmation that the furnace is working properly; it can be used to turn off the ignition system though in many cases they take no direct action beyond notifying the operator or control system. A flame detector can often respond faster and more accurately than a smoke or heat detector due to the mechanisms it uses to detect the flame.

<span class="mw-page-title-main">Infrared gas analyzer</span> Scientific equipment to analyse gas composition using absorption of infrared radiation

An infrared gas analyzer measures trace gases by determining the absorption of an emitted infrared light source through a certain air sample. Trace gases found in the Earth's atmosphere become excited under specific wavelengths found in the infrared range. The concept behind the technology can be understood as testing how much of the light is absorbed by the air. Different molecules in the air absorb different frequencies of light. Air with much of a certain gas will absorb more of a certain frequency, allowing the sensor to report a high concentration of the corresponding molecule.

The photoacoustic effect or optoacoustic effect is the formation of sound waves following light absorption in a material sample. In order to obtain this effect the light intensity must vary, either periodically or as a single flash. The photoacoustic effect is quantified by measuring the formed sound with appropriate detectors, such as microphones or piezoelectric sensors. The time variation of the electric output from these detectors is the photoacoustic signal. These measurements are useful to determine certain properties of the studied sample. For example, in photoacoustic spectroscopy, the photoacoustic signal is used to obtain the actual absorption of light in either opaque or transparent objects. It is useful for substances in extremely low concentrations, because very strong pulses of light from a laser can be used to increase sensitivity and very narrow wavelengths can be used for specificity. Furthermore, photoacoustic measurements serve as a valuable research tool in the study of the heat evolved in photochemical reactions, particularly in the study of photosynthesis.

Demand controlled ventilation (DCV) is a feedback control method to maintain indoor air quality that automatically adjusts the ventilation rate provided to a space in response to changes in conditions such as occupant number or indoor pollutant concentration. The control strategy is mainly intended to reduce the energy use by heating, cooling, and ventilation systems compared to buildings that use open-loop controls with constant ventilation rates.

<span class="mw-page-title-main">Air pollution measurement</span>

Air pollution measurement is the process of collecting and measuring the components of air pollution, notably gases and particulates. The earliest devices used to measure pollution include rain gauges, Ringelmann charts for measuring smoke, and simple soot and dust collectors known as deposit gauges. Modern air pollution measurement is largely automated and carried out using many different devices and techniques. These range from simple absorbent test tubes known as diffusion tubes through to highly sophisticated chemical and physical sensors that give almost real-time pollution measurements, which are used to generate air quality indexes.

<span class="mw-page-title-main">Gasera</span> Finnish technology company

Gasera Ltd. is a Finnish high-tech company focused on the analysis of gases, liquids and solid materials. The main focus of Gasera is measuring harmful air pollutants in order to protect humans and the environment. Other applications include e.g. greenhouse gas monitoring, automotive and ship emissions monitoring, dissolved gas analysis in transformer oil, CWA and TIC detection, material identification and food production and safety.

<span class="mw-page-title-main">Exhaust gas analyzer</span>

An exhaust gas analyser or exhaust carbon monoxide (CO) analyser is an instrument for the measurement of carbon monoxide among other gases in the exhaust, caused by an incorrect combustion, the Lambda coefficient measurement is the most common.

<span class="mw-page-title-main">Orbiting Carbon Observatory 3</span>

The Orbiting Carbon Observatory-3 (OCO-3) is a NASA-JPL instrument designed to measure carbon dioxide in Earth's atmosphere. The instrument is mounted on the Japanese Experiment Module-Exposed Facility on board the International Space Station (ISS). OCO-3 was scheduled to be transported to space by a SpaceX Dragon from a Falcon 9 rocket on 30 April 2019, but the launch was delayed to 3 May, due to problems with the space station's electrical power system. This launch was further delayed to 4 May due to electrical issues aboard Of Course I Still Love You (OCISLY), the barge used to recover the Falcon 9’s first stage. OCO-3 was launched as part of CRS-17 on 4 May 2019 at 06:48 UTC. The nominal mission lifetime is ten years.

References

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