The fuel-characteristics of a particular gasoline-blend, which will resist igniting too early are measured as the octane rating of the fuel blend. Gasoline blends with stable octane ratings are produced in several fuel-grades for various types of motors. A low octane rated fuel may cause engine knocking and reduced efficiency in reciprocating engines. Tetraethyl lead was once widely used to increase the octane rating but are not used in modern automotive gasoline due to the health hazard. Aviation, off-road motor vehicles, and racing car motors still use leaded gasolines.[2][3]
Interest in gasoline-like fuels started with the invention of internal combustion engines suitable for use in transportation applications. The so-called Otto engines were developed in Germany during the last quarter of the 19th century. The fuel for these early engines was a relatively volatile hydrocarbon obtained from coal gas. With a boiling point near 85°C (185°F) (n-octane boils at 125.62°C (258.12°F)[4]), it was well-suited for early carburetors (evaporators). The development of a "spray nozzle" carburetor enabled the use of less volatile fuels. Further improvements in engine efficiency were attempted at higher compression ratios, but early attempts were blocked by the premature explosion of fuel, known as knocking. In 1891, the Shukhov cracking process became the world's first commercial method to break down heavier hydrocarbons in crude oil to increase the percentage of lighter products compared to simple distillation.
Commercial gasoline as well as other liquid transportation fuels are complex mixtures of hydrocarbons.[5] The performance specification also varies with season, requiring less volatile blends during summer, in order to minimize evaporative losses.
Gasoline is produced in oil refineries. Roughly 72 liters (19U.S.gal) of gasoline is derived from a 160-liter (42U.S.gal) barrel of crude oil.[6] Material separated from crude oil via distillation, called virgin or straight-run gasoline, does not meet specifications for modern engines (particularly the octane rating; see below), but can be pooled to the gasoline blend.
The bulk of a typical gasoline consists of a homogeneous mixture of hydrocarbons with between 4 and 12 carbon atoms per molecule (commonly referred to as C4–C12).[7] It is a mixture of paraffins (alkanes), olefins (alkenes), napthenes (cycloalkanes), and aromatics. The use of the term paraffin in place of the standard chemical nomenclature alkane is particular to the oil industry (which relies extensively on jargon). The composition of a gasoline depends upon:
the oil refinery that makes the gasoline, as not all refineries have the same set of processing units;
the grade of gasoline sought (in particular, the octane rating).
The various refinery streams blended to make gasoline have different characteristics. Some important streams include the following:
Straight-run gasoline, sometimes referred to as naphtha, is distilled directly from crude oil. Once the leading source of fuel, its low octane rating required lead additives. It is typically low in aromatics (depending on the grade of the crude oil stream) and contains some cycloalkanes (naphthenes) and no olefins (alkenes). Between 0 and 20 percent of this stream is pooled into the finished gasoline because the quantity of this fraction in the crude is less than fuel demand and the fraction's Research Octane Number (RON) is too low. The chemical properties (namely RON and Reid vapor pressure (RVP)) of the straight-run gasoline can be improved through reforming and isomerization. However, before feeding those units, the naphtha needs to be split into light and heavy naphtha. Straight-run gasoline can also be used as a feedstock for steam-crackers to produce olefins.
Reformate, produced from straight run gasoline in a catalytic reformer, has a high octane rating with high aromatic content and relatively low olefin content. Most of the benzene, toluene, and xylene (the so-called BTX hydrocarbons) are more valuable as chemical feedstocks and are thus removed to some extent. Also the BTX content is regulated.
Catalytic cracked gasoline, or catalytic cracked naphtha, produced with a catalytic cracker, has a moderate octane rating, high olefin content, and moderate aromatic content.
Hydrocrackate (heavy, mid, and light), produced with a hydrocracker, has a medium to low octane rating and moderate aromatic levels.
Alkylate is produced in an alkylation unit, using isobutane and C3-/C4-olefins as feedstocks. Finished alkylate contains no aromatics or olefins and has a high MON (Motor Octane Number) Alkylate was used during world war 2 in aviation fuel.[8] Since the late 1980's it is sold as a specialty fuel for (handheld) gardening and forestry tools with a combustion engine. [9][10]
Isomerate is obtained by isomerizing low-octane straight-run gasoline into iso-paraffins (non-chain alkanes, such as isooctane). Isomerate has a medium RON and MON, but no aromatics or olefins.
Butane is usually blended in the gasoline pool, although the quantity of this stream is limited by the RVP specification.
The terms above are the jargon used in the oil industry, and the terminology varies.
Currently, many countries set limits on gasoline aromatics in general, benzene in particular, and olefin (alkene) content. Such regulations have led to an increasing preference for alkane isomers, such as isomerate or alkylate, as their octane rating is higher than n-alkanes. In the European Union, the benzene limit is set at one percent by volume for all grades of automotive gasoline. This is usually achieved by avoiding feeding C6, in particular cyclohexane, to the reformer unit, where it would be converted to benzene. Therefore, only (desulfurized) heavy virgin naphtha (HVN) is fed to the reformer unit[11]
Gasoline can also contain other organic compounds, such as organic ethers (deliberately added), plus small levels of contaminants, in particular organosulfur compounds (which are usually removed at the refinery).
On average, U.S. petroleum refineries produce about 19 to 20 gallons of gasoline, 11 to 13 gallons of distillate fuel diesel fuel and 3 to 4 gallons of jet fuel from each 42 gallon (152 liters) barrel of crude oil. The product ratio depends upon the processing in an oil refinery and the crude oil assay.[12]
The specific gravity of gasoline ranges from 0.71 to 0.77,[13] with higher densities having a greater volume fraction of aromatics.[14] Finished marketable gasoline is traded (in Europe) with a standard reference of 0.755 kilograms per liter (6.30lb/U.S.gal), (7,5668 lb/ imp gal) its price is escalated or de-escalated according to its actual density.[clarification needed] Because of its low density, gasoline floats on water, and therefore water cannot generally be used to extinguish a gasoline fire unless applied in a fine mist.
Quality gasoline should be stable for six months if stored properly, but can degrade over time. Gasoline stored for a year will most likely be able to be burned in an internal combustion engine without too much trouble. However, the effects of long-term storage will become more noticeable with each passing month until a time comes when the gasoline should be diluted with ever-increasing amounts of freshly made fuel so that the older gasoline may be used up. If left undiluted, improper operation will occur and this may include engine damage from misfiring or the lack of proper action of the fuel within a fuel injection system and from an onboard computer attempting to compensate (if applicable to the vehicle). Gasoline should ideally be stored in an airtight container (to prevent oxidation or water vapor mixing in with the gas) that can withstand the vapor pressure of the gasoline without venting (to prevent the loss of the more volatile fractions) at a stable cool temperature (to reduce the excess pressure from liquid expansion and to reduce the rate of any decomposition reactions). When gasoline is not stored correctly, gums and solids may result, which can corrode system components and accumulate on wet surfaces, resulting in a condition called "stale fuel". Gasoline containing ethanol is especially subject to absorbing atmospheric moisture, then forming gums, solids, or two phases (a hydrocarbon phase floating on top of a water-alcohol phase).
The presence of these degradation products in the fuel tank or fuel lines plus a carburetor or fuel injection components makes it harder to start the engine or causes reduced engine performance [15]On resumption of regular engine use, the buildup may or may not be eventually cleaned out by the flow of fresh gasoline. The addition of a fuel stabilizer to gasoline can extend the life of fuel that is not or cannot be stored properly, though removal of all fuel from a fuel system is the only real solution to the problem of long-term storage of an engine or a machine or vehicle. Typical fuel stabilizers are proprietary mixtures containing mineral spirits, isopropyl alcohol, 1,2,4-trimethylbenzene or other additives. Fuel stabilizers are commonly used for small engines, such as lawnmower and tractor engines, especially when their use is sporadic or seasonal (little to no use for one or more seasons of the year). Users have been advised to keep gasoline containers more than half full and properly capped to reduce air exposure, to avoid storage at high temperatures, to run an engine for ten minutes to circulate the stabilizer through all components prior to storage, and to run the engine at intervals to purge stale fuel from the carburetor.[7]
Gasoline stability requirements are set by the standard ASTM D4814. This standard describes the various characteristics and requirements of automotive fuels for use over a wide range of operating conditions in ground vehicles equipped with spark-ignition engines.
Combustion energy content
A gasoline-fueled internal combustion engine obtains energy from the combustion of gasoline's various hydrocarbons with oxygen from the ambient air, yielding carbon dioxide and water as exhaust. The combustion of octane, a representative species, performs the chemical reaction:
2 C8H18 + 25 O2 → 16 CO2 + 18 H2O
By weight, combustion of gasoline releases about 46.7 megajoules per kilogram (13.0kWh/kg; 21.2MJ/lb) or by volume 33.6 megajoules per liter (9.3kWh/L; 127MJ/U.S.gal; 121,000BTU/U.S.gal), quoting the lower heating value.[16] Gasoline blends differ, and therefore actual energy content varies according to the season and producer by up to 1.75 percent more or less than the average.[17] On average, about 74 liters (20U.S.gal) of gasoline are available from a barrel of crude oil (about 46 percent by volume), varying with the quality of the crude and the grade of the gasoline. The remainder is products ranging from tar to naphtha.[18]
A high-octane-rated fuel, such as liquefied petroleum gas (LPG), has an overall lower power output at the typical 10:1 compression ratio of an engine design optimized for gasoline fuel. An engine tuned for LPG fuel via higher compression ratios (typically 12:1) improves the power output. This is because higher-octane fuels allow for a higher compression ratio without knocking, resulting in a higher cylinder temperature, which improves efficiency. Also, increased mechanical efficiency is created by a higher compression ratio through the concomitant higher expansion ratio on the power stroke, which is by far the greater effect. The higher expansion ratio extracts more work from the high-pressure gas created by the combustion process. An Atkinson cycle engine uses the timing of the valve events to produce the benefits of a high expansion ratio without the disadvantages, chiefly detonation, of a high compression ratio. A high expansion ratio is also one of the two key reasons for the efficiency of diesel engines, along with the elimination of pumping losses due to throttling of the intake airflow.
The lower energy content of LPG by liquid volume in comparison to gasoline is due mainly to its lower density. This lower density is a property of the lower molecular weight of propane (LPG's chief component) compared to gasoline's blend of various hydrocarbon compounds with heavier molecular weights than propane. Conversely, LPG's energy content by weight is higher than gasoline's due to a higher hydrogen-to-carbon ratio.
Molecular weights of the species in the representative octane combustion are 114, 32, 44, and 18 for C8H18, O2, CO2, and H2O, respectively; therefore one kilogram (2.2lb) of fuel reacts with 3.51 kilograms (7.7lb) of oxygen to produce 3.09 kilograms (6.8lb) of carbon dioxide and 1.42 kilograms (3.1lb) of water.
Spark-ignition engines are designed to burn gasoline in a controlled process called deflagration. However, the unburned mixture may autoignite by pressure and heat alone, rather than igniting from the spark plug at exactly the right time, causing a rapid pressure rise that can damage the engine. This is often referred to as engine knocking or end-gas knock. Knocking can be reduced by increasing the gasoline's resistance to autoignition, which is expressed by its octane rating.
Octane rating is measured relative to a mixture of 2,2,4-trimethylpentane (an isomer of octane) and n-heptane. There are different conventions for expressing octane ratings, so the same physical fuel may have several different octane ratings based on the measure used. One of the best known is the research octane number (RON).
The octane rating of typical commercially available gasoline varies by country. In Finland, Sweden, and Norway, 95 RON is the standard for regular unleaded gasoline and 98 RON is also available as a more expensive option.
In the United Kingdom, over 95 percent of gasoline sold has 95 RON and is marketed as Unleaded or Premium Unleaded. Super Unleaded, with 97/98 RON and branded high-performance fuels (e.g., Shell V-Power, BP Ultimate) with 99 RON make up the balance. Gasoline with 102 RON may rarely be available for racing purposes.[19][20][21]
In the U.S., octane ratings in unleaded fuels vary between 85[22] and 87 AKI (91–92 RON) for regular, 89–90 AKI (94–95 RON) for mid-grade (equivalent to European regular), up to 90–94 AKI (95–99 RON) for premium (European premium).
91
92
93
94
95
96
97
98
99
100
101
102
Scandinavian
Regular
Premium
UK
Regular
Premium
Super
High-performance
USA
Regular
Mid-grade
Premium
As South Africa's largest city, Johannesburg, is located on the Highveld at 1,753 meters (5,751ft) above sea level, the Automobile Association of South Africa recommends 95-octane gasoline at low altitude and 93-octane for use in Johannesburg because "The higher the altitude the lower the air pressure, and the lower the need for a high octane fuel as there is no real performance gain".[23]
Octane rating became important as the military sought higher output for aircraft engines in the late 1920s and the 1940s. A higher octane rating allows a higher compression ratio or supercharger boost, and thus higher temperatures and pressures, which translate to higher power output. Some scientists[who?] even predicted that a nation with a good supply of high-octane gasoline would have the advantage in air power. In 1943, the Rolls-Royce Merlin aero engine produced 980 kilowatts (1,320hp) using 100 RON fuel from a modest 27 liters (1,600cuin) displacement. By the time of Operation Overlord, both the RAF and USAAF were conducting some operations in Europe using 150 RON fuel (100/150 avgas), obtained by adding 2.5 percent aniline to 100-octane avgas.[24] By this time, the Rolls-Royce Merlin 66 was developing 1,500 kilowatts (2,000hp) using this fuel.
Gasoline, when used in high-compression internal combustion engines, tends to auto-ignite or "detonate" causing damaging engine knocking (also called "pinging" or "pinking"). To address this problem, tetraethyl lead (TEL) was widely adopted as an additive for gasoline in the 1920s. With a growing awareness of the seriousness of the extent of environmental and health damage caused by lead compounds, however, and the incompatibility of lead with catalytic converters, governments began to mandate reductions in gasoline lead.
In the U.S., the Environmental Protection Agency issued regulations to reduce the lead content of leaded gasoline over a series of annual phases, scheduled to begin in 1973 but delayed by court appeals until 1976. By 1995, leaded fuel accounted for only 0.6 percent of total gasoline sales and under 1,800 metric tons (2,000 short tons; 1,800 long tons) of lead per year. From 1 January 1996, the U.S. Clean Air Act banned the sale of leaded fuel for use in on-road vehicles in the U.S. The use of TEL also necessitated other additives, such as dibromoethane.
European countries began replacing lead-containing additives by the end of the 1980s, and by the end of the 1990s, leaded gasoline was banned within the entire European Union with an exception for Avgas 100LL for general aviation.[25] The UAE started to switch to unleaded in the early 2000s.[26]
Reduction in the average lead content of human blood may be a major cause for falling violent crime rates around the world[27] including South Africa.[28] A study found a correlation between leaded gasoline usage and violent crime (see Lead–crime hypothesis).[29][30] Other studies found no correlation.
In August 2021, the UN Environment Programme announced that leaded petrol had been eradicated worldwide, with Algeria being the last country to deplete its reserves. UN Secretary-GeneralAntónio Guterres called the eradication of leaded petrol an "international success story". He also added: "Ending the use of leaded petrol will prevent more than one million premature deaths each year from heart disease, strokes and cancer, and it will protect children whose IQs are damaged by exposure to lead". Greenpeace called the announcement "the end of one toxic era".[31] However, leaded gasoline continues to be used in aeronautic, auto racing, and off-road applications.[32] The use of leaded additives is still permitted worldwide for the formulation of some grades of aviation gasoline such as 100LL, because the required octane rating is difficult to reach without the use of leaded additives.
Lead replacement petrol (LRP) was developed for vehicles designed to run on leaded fuels and incompatible with unleaded fuels. Rather than tetraethyllead, it contains other metals such as potassium compounds or methylcyclopentadienyl manganese tricarbonyl (MMT); these are purported to buffer soft exhaust valves and seats so that they do not suffer recession due to the use of unleaded fuel.
LRP was marketed during and after the phaseout of leaded motor fuels in the United Kingdom, Australia, South Africa, and some other countries.[vague] Consumer confusion led to a widespread mistaken preference for LRP rather than unleaded,[33] and LRP was phased out 8 to 10 years after the introduction of unleaded.[34]
Leaded gasoline was withdrawn from sale in Britain after 31 December 1999, seven years after EEC regulations signaled the end of production for cars using leaded gasoline in member states. At this stage, a large percentage of cars from the 1980s and early 1990s which ran on leaded gasoline were still in use, along with cars that could run on unleaded fuel. However, the declining number of such cars on British roads saw many gasoline stations withdrawing LRP from sale by 2003.[35]
MMT
Methylcyclopentadienyl manganese tricarbonyl (MMT) is used in Canada and the U.S. to boost octane rating.[36] Its use in the U.S. has been restricted by regulations, although it is currently allowed.[37] Its use in the European Union is restricted by Article 8a of the Fuel Quality Directive[38] following its testing under the Protocol for the evaluation of effects of metallic fuel-additives on the emissions performance of vehicles.[39]
Fuel stabilizers (antioxidants and metal deactivators)
Substituted phenols and derivatives of phenylenediamine are common antioxidants used to inhibit gum formation in gasoline
Gummy, sticky resin deposits result from oxidative degradation of gasoline during long-term storage. These harmful deposits arise from the oxidation of alkenes and other minor components in gasoline[citation needed] (see drying oils). Improvements in refinery techniques have generally reduced the susceptibility of gasolines to these problems. Previously, catalytically or thermally cracked gasolines were most susceptible to oxidation. The formation of gums is accelerated by copper salts, which can be neutralized by additives called metal deactivators.
This degradation can be prevented through the addition of 5–100 ppm of antioxidants, such as phenylenediamines and other amines.[7] Hydrocarbons with a bromine number of 10 or above can be protected with the combination of unhindered or partially hindered phenols and oil-soluble strong amine bases, such as hindered phenols. "Stale" gasoline can be detected by a colorimetricenzymatic test for organic peroxides produced by oxidation of the gasoline.[40]
Gasolines are also treated with metal deactivators, which are compounds that sequester (deactivate) metal salts that otherwise accelerate the formation of gummy residues. The metal impurities might arise from the engine itself or as contaminants in the fuel.
Detergents
Gasoline, as delivered at the pump, also contains additives to reduce internal engine carbon buildups, improve combustion and allow easier starting in cold climates. High levels of detergent can be found in Top Tier Detergent Gasolines. The specification for Top Tier Detergent Gasolines was developed by four automakers: GM, Honda, Toyota, and BMW. According to the bulletin, the minimal U.S. EPA requirement is not sufficient to keep engines clean.[41] Typical detergents include alkylamines and alkyl phosphates at a level of 50–100 ppm.[7]
In the EU, 5 percent ethanol can be added within the common gasoline spec (EN 228). Discussions are ongoing to allow 10 percent blending of ethanol (available in Finnish, French and German gasoline stations). In Finland, most gasoline stations sell 95E10, which is 10 percent ethanol, and 98E5, which is 5 percent ethanol. Most gasoline sold in Sweden has 5–15 percent ethanol added. Three different ethanol blends are sold in the Netherlands—E5, E10 and hE15. The last of these differs from standard ethanol–gasoline blends in that it consists of 15 percent hydrous ethanol (i.e., the ethanol–water azeotrope) instead of the anhydrous ethanol traditionally used for blending with gasoline.
Legislation requires retailers to label fuels containing ethanol on the dispenser, and limits ethanol use to 10 percent of gasoline in Australia. Such gasoline is commonly called E10 by major brands, and it is cheaper than regular unleaded gasoline.
The federal Renewable Fuel Standard (RFS) effectively requires refiners and blenders to blend renewable biofuels (mostly ethanol) with gasoline, sufficient to meet a growing annual target of total gallons blended. Although the mandate does not require a specific percentage of ethanol, annual increases in the target combined with declining gasoline consumption have caused the typical ethanol content in gasoline to approach 10 percent. Most fuel pumps display a sticker that states that the fuel may contain up to 10 percent ethanol, an intentional disparity that reflects the varying actual percentage. In parts of the U.S., ethanol is sometimes added to gasoline without an indication that it is a component.
India
In October 2007, the Government of India decided to make five percent ethanol blending (with gasoline) mandatory. Currently, 10 percent ethanol blended product (E10) is being sold in various parts of the country.[43][44] Ethanol has been found in at least one study to damage catalytic converters.[45]
Though gasoline is a naturally colorless liquid, many gasolines are dyed in various colors to indicate their composition and acceptable uses. In Australia, the lowest grade of gasoline (RON 91) was dyed a light shade of red/orange, but is now the same color as the medium grade (RON 95) and high octane (RON 98), which are dyed yellow.[46] In the U.S., aviation gasoline (avgas) is dyed to identify its octane rating and to distinguish it from kerosene-based jet fuel, which is left colorless.[47] In Canada, the gasoline for marine and farm use is dyed red and is not subject to fuel excise tax in most provinces.[48]
Oxygenate blending
Oxygenate blending adds oxygen-bearing compounds such as MTBE, ETBE, TAME, TAEE, ethanol, and biobutanol. The presence of these oxygenates reduces the amount of carbon monoxide and unburned fuel in the exhaust. In many areas throughout the U.S., oxygenate blending is mandated by EPA regulations to reduce smog and other airborne pollutants. For example, in Southern California fuel must contain two percent oxygen by weight, resulting in a mixture of 5.6 percent ethanol in gasoline. The resulting fuel is often known as reformulated gasoline (RFG) or oxygenated gasoline, or, in the case of California, California reformulated gasoline (CARBOB). The federal requirement that RFG contain oxygen was dropped on 6 May 2006 because the industry had developed VOC-controlled RFG that did not need additional oxygen.[49]
MTBE was phased out in the U.S. due to groundwater contamination and the resulting regulations and lawsuits. Ethanol and, to a lesser extent, ethanol-derived ETBE are common substitutes. A common ethanol-gasoline mix of 10 percent ethanol mixed with gasoline is called gasohol or E10, and an ethanol-gasoline mix of 85 percent ethanol mixed with gasoline is called E85. The most extensive use of ethanol takes place in Brazil, where the ethanol is derived from sugarcane. In 2004, over 13billion liters (3.4×10^9U.S.gal) of ethanol was produced in the U.S. for fuel use, mostly from corn and sold as E10. E85 is slowly becoming available in much of the U.S., though many of the relatively few stations vending E85 are not open to the general public.[50]
The use of bioethanol and bio-methanol, either directly or indirectly by conversion of ethanol to bio-ETBE, or methanol to bio-MTBE is encouraged by the European Union Directive on the Promotion of the use of biofuels and other renewable fuels for transport. Since producing bioethanol from fermented sugars and starches involves distillation, though, ordinary people in much of Europe cannot legally ferment and distill their own bioethanol at present (unlike in the U.S., where getting a BATF distillation permit has been easy since the 1973 oil crisis).
Safety
HAZMAT class 3 gasoline
Toxicity
The safety data sheet for a 2003 Texan unleaded gasoline shows at least 15 hazardous chemicals occurring in various amounts, including benzene (up to five percent by volume), toluene (up to 35 percent by volume), naphthalene (up to one percent by volume), trimethylbenzene (up to seven percent by volume), methyl tert-butyl ether (MTBE) (up to 18 percent by volume, in some states), and about 10 others.[51] Hydrocarbons in gasoline generally exhibit low acute toxicities, with LD50 of 700–2700mg/kg for simple aromatic compounds.[52] Benzene and many antiknocking additives are carcinogenic.
People can be exposed to gasoline in the workplace by swallowing it, breathing in vapors, skin contact, and eye contact. Gasoline is toxic. The National Institute for Occupational Safety and Health (NIOSH) has also designated gasoline as a carcinogen.[53] Physical contact, ingestion, or inhalation can cause health problems. Since ingesting large amounts of gasoline can cause permanent damage to major organs, a call to a local poison control center or emergency room visit is indicated.[54]
Contrary to common misconception, swallowing gasoline does not generally require special emergency treatment, and inducing vomiting does not help, and can make it worse. According to poison specialist Brad Dahl, "even two mouthfuls wouldn't be that dangerous as long as it goes down to your stomach and stays there or keeps going". The U.S. CDC's Agency for Toxic Substances and Disease Registry says not to induce vomiting, lavage, or administer activated charcoal.[55][56]
Inhalation for intoxication
Inhaled (huffed) gasoline vapor is a common intoxicant. Users concentrate and inhale gasoline vapor in a manner not intended by the manufacturer to produce euphoria and intoxication. Gasoline inhalation has become epidemic in some poorer communities and indigenous groups in Australia, Canada, New Zealand, and some Pacific Islands.[57] The practice is thought to cause severe organ damage, along with other effects such as intellectual disability and various cancers.[58][59][60][61]
In Canada, Native children in the isolated Northern Labrador community of Davis Inlet were the focus of national concern in 1993, when many were found to be sniffing gasoline. The Canadian and provincial Newfoundland and Labrador governments intervened on several occasions, sending many children away for treatment. Despite being moved to the new community of Natuashish in 2002, serious inhalant abuse problems have continued. Similar problems were reported in Sheshatshiu in 2000 and also in Pikangikum First Nation.[62] In 2012, the issue once again made the news media in Canada.[63]
Australia has long faced a petrol (gasoline) sniffing problem in isolated and impoverished aboriginal communities. Although some sources argue that sniffing was introduced by U.S. servicemen stationed in the nation's Top End during World War II[64] or through experimentation by 1940s-era Cobourg Peninsula sawmill workers,[65] other sources claim that inhalant abuse (such as glue inhalation) emerged in Australia in the late 1960s.[66] Chronic, heavy petrol sniffing appears to occur among remote, impoverished indigenous communities, where the ready accessibility of petrol has helped to make it a common substance for abuse.
In Australia, petrol sniffing now occurs widely throughout remote Aboriginal communities in the Northern Territory, Western Australia, northern parts of South Australia, and Queensland.[67] The number of people sniffing petrol goes up and down over time as young people experiment or sniff occasionally. "Boss", or chronic, sniffers may move in and out of communities; they are often responsible for encouraging young people to take it up.[68] In 2005, the Government of Australia and BP Australia began the usage of Opal fuel in remote areas prone to petrol sniffing.[69] Opal is a non-sniffable fuel (which is much less likely to cause a high) and has made a difference in some indigenous communities.
Flammability
Uncontrolled burning of gasoline produces large quantities of soot and carbon monoxide.
Gasoline is flammable with low flash point of −23°C (−9°F). Gasoline has a lower explosive limit of 1.4 percent by volume and an upper explosive limit of 7.6 percent. If the concentration is below 1.4 percent, the air-gasoline mixture is too lean and does not ignite. If the concentration is above 7.6 percent, the mixture is too rich and also does not ignite. However, gasoline vapor rapidly mixes and spreads with air, making unconstrained gasoline quickly flammable.
Gasoline exhaust
The exhaust gas generated by burning gasoline is harmful to both the environment and to human health. After CO is inhaled into the human body, it readily combines with hemoglobin in the blood, and its affinity is 300 times that of oxygen. Therefore, the hemoglobin in the lungs combines with CO instead of oxygen, causing the human body to be hypoxic, causing headaches, dizziness, vomiting, and other poisoning symptoms. In severe cases, it may lead to death.[70][71] Hydrocarbons only affect the human body when their concentration is quite high, and their toxicity level depends on the chemical composition. The hydrocarbons produced by incomplete combustion include alkanes, aromatics, and aldehydes. Among them, a concentration of methane and ethane over 35g/m3 (0.035oz/cuft) will cause loss of consciousness or suffocation, a concentration of pentane and hexane over 45g/m3 (0.045oz/cuft) will have an anesthetic effect, and aromatic hydrocarbons will have more serious effects on health, blood toxicity, neurotoxicity, and cancer. If the concentration of benzene exceeds 40 ppm, it can cause leukemia, and xylene can cause headache, dizziness, nausea, and vomiting. Human exposure to large amounts of aldehydes can cause eye irritation, nausea, and dizziness. In addition to carcinogenic effects, long-term exposure can cause damage to the skin, liver, kidneys, and cataracts.[72] After NOx enters the alveoli, it has a severe stimulating effect on the lung tissue. It can irritate the conjunctiva of the eyes, cause tearing, and cause pink eyes. It also has a stimulating effect on the nose, pharynx, throat, and other organs. It can cause acute wheezing, breathing difficulties, red eyes, sore throat, and dizziness causing poisoning.[72][73]Fine particulates are also dangerous to health.[74]
Environmental impact
The air pollution in many large cities has changed from coal-burning pollution to "motor vehicle pollution". In the U.S., transportation is the largest source of carbon emissions, accounting for 30 percent of the total carbon footprint of the U.S.[75] Combustion of gasoline produces 2.35 kilograms per liter (19.6lb/U.S.gal) of carbon dioxide, a greenhouse gas.[76][77]
Unburnt gasoline and evaporation from the tank, when in the atmosphere, react in sunlight to produce photochemical smog. Vapor pressure initially rises with some addition of ethanol to gasoline, but the increase is greatest at 10 percent by volume.[78] At higher concentrations of ethanol above 10 percent, the vapor pressure of the blend starts to decrease. At a 10 percent ethanol by volume, the rise in vapor pressure may potentially increase the problem of photochemical smog. This rise in vapor pressure could be mitigated by increasing or decreasing the percentage of ethanol in the gasoline mixture. The chief risks of such leaks come not from vehicles, but gasoline delivery truck accidents and leaks from storage tanks. Because of this risk, most (underground) storage tanks now have extensive measures in place to detect and prevent any such leaks, such as monitoring systems (Veeder-Root, Franklin Fueling).
Production of gasoline consumes 1.5 liters per kilometer (0.63U.S.gal/mi) of water by driven distance.[79]
Gasoline use causes a variety of deleterious effects to the human population and to the climate generally. The harms imposed include a higher rate of premature death and ailments, such as asthma, caused by air pollution, higher healthcare costs for the public generally, decreased crop yields, missed work and school days due to illness, increased flooding and other extreme weather events linked to global climate change, and other social costs. The costs imposed on society and the planet are estimated to be $3.80 per gallon of gasoline, in addition to the price paid at the pump by the user. The damage to the health and climate caused by a gasoline-powered vehicle greatly exceeds that caused by electric vehicles.[80][81]
Gasoline can be released into the Earth's environment as an uncombusted liquid fuel, as a flammable liquid, or as a vapor by way of leakages occurring during its production, handling, transport and delivery.[82] Gasoline contains known carcinogens,[83][84][85] and gasoline exhaust is a health risk.[74] Gasoline is often used as a recreational inhalant and can be harmful or fatal when used in such a manner.[86] When burned, one liter (0.26U.S.gal) of gasoline emits about 2.3 kilograms (5.1lb) of CO2, a greenhouse gas, contributing to human-caused climate change.[87][88] Oil products, including gasoline, were responsible for about 32% of CO2 emissions worldwide in 2021.[89]
Carbon dioxide
About 2.353 kilograms per liter (19.64lb/U.S.gal) of carbon dioxide (CO2) are produced from burning gasoline that does not contain ethanol.[77] Most of the retail gasoline now sold in the U.S. contains about 10 percent fuel ethanol (or E10) by volume.[77] Burning E10 produces about 2.119 kilograms per liter (17.68lb/U.S.gal) of CO2 that is emitted from the fossil fuel content. If the CO2 emissions from ethanol combustion are considered, then about 2.271 kilograms per liter (18.95lb/U.S.gal) of CO2 are produced when E10 is combusted.[77]
Worldwide 7 liters of gasoline are burnt for every 100km driven by cars and vans.[90]
In 2021, the International Energy Agency stated, "To ensure fuel economy and CO2 emissions standards are effective, governments must continue regulatory efforts to monitor and reduce the gap between real-world fuel economy and rated performance."[90]
Contamination of soil and water
Gasoline enters the environment through the soil, groundwater, surface water, and air. Therefore, humans may be exposed to gasoline through methods such as breathing, eating, and skin contact. For example, using gasoline-filled equipment, such as lawnmowers, drinking gasoline-contaminated water close to gasoline spills or leaks to the soil, working at a gasoline station, inhaling gasoline volatile gas when refueling at a gasoline station is the easiest way to be exposed to gasoline.[91]
The International Energy Agency said in 2021 that "road fuels should be taxed at a rate that reflects their impact on people's health and the climate".[90]
Europe
Countries in Europe impose substantially higher taxes on fuels such as gasoline when compared to the U.S. The price of gasoline in Europe is typically higher than that in the U.S. due to this difference.[92]
U.S.
This section needs to be updated. Please help update this article to reflect recent events or newly available information.(April 2016)
From 1998 to 2004, the price of gasoline fluctuated between $0.26 and $0.53 per liter ($1 and $2/U.S.gal).[93] After 2004, the price increased until the average gasoline price reached a high of $1.09 per liter ($4.11/U.S.gal) in mid-2008 but receded to approximately $0.69 per liter ($2.60/U.S.gal) by September 2009.[93] The U.S. experienced an upswing in gasoline prices through 2011,[94] and, by 1 March 2012, the national average was $0.99 per liter ($3.74/U.S.gal). California prices are higher because the California government mandates unique California gasoline formulas and taxes.[95]
In the U.S., most consumer goods bear pre-tax prices, but gasoline prices are posted with taxes included. Taxes are added by federal, state, and local governments. As of 2009[update], the federal tax was $0.049 per liter ($0.184/U.S.gal) for gasoline and $0.064 per liter ($0.244/U.S.gal) for diesel (excluding red diesel).[96]
About nine percent of all gasoline sold in the U.S. in May 2009 was premium grade, according to the Energy Information Administration. Consumer Reports magazine says, "If [your owner's manual] says to use regular fuel, do so—there's no advantage to a higher grade."[97] The Associated Press said premium gas—which has a higher octane rating and costs more per gallon than regular unleaded—should be used only if the manufacturer says it is "required".[98] Cars with turbocharged engines and high compression ratios often specify premium gasoline because higher octane fuels reduce the incidence of "knock", or fuel pre-detonation.[99] The price of gasoline varies considerably between the summer and winter months.[100]
There is a considerable difference between summer oil and winter oil in gasoline vapor pressure (Reid Vapor Pressure, RVP), which is a measure of how easily the fuel evaporates at a given temperature. The higher the gasoline volatility (the higher the RVP), the easier it is to evaporate. The conversion between the two fuels occurs twice a year, once in autumn (winter mix) and the other in spring (summer mix). The winter blended fuel has a higher RVP because the fuel must be able to evaporate at a low temperature for the engine to run normally. If the RVP is too low on a cold day, the vehicle will be difficult to start; however, the summer blended gasoline has a lower RVP. It prevents excessive evaporation when the outdoor temperature rises, reduces ozone emissions, and reduces smog levels. At the same time, vapor lock is less likely to occur in hot weather.[101]
The compression ratio is the ratio between the volume of the cylinder and combustion chamber in an internal combustion engine at their maximum and minimum values.
Diesel fuel, also called diesel oil, heavy oil (historically) or simply diesel, is any liquid fuel specifically designed for use in a diesel engine, a type of internal combustion engine in which fuel ignition takes place without a spark as a result of compression of the inlet air and then injection of fuel. Therefore, diesel fuel needs good compression ignition characteristics.
Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb(C2H5)4. It was widely used as a fuel additive for much of the 20th century, first being mixed with gasoline beginning in the 1920s. This "leaded gasoline" had an increased octane rating that allowed engine compression to be raised substantially and in turn increased vehicle performance and fuel economy. TEL was first synthesised by German chemist Carl Jacob Löwig in 1853. American chemical engineer Thomas Midgley Jr., who was working for the U.S. corporation General Motors, was the first to discover its effectiveness as an antiknock agent in 1921, after spending several years attempting to find an additive that was both highly effective and inexpensive.
An octane rating, or octane number, is a standard measure of a fuel's ability to withstand compression in an internal combustion engine without causing engine knocking. The higher the octane number, the more compression the fuel can withstand before detonating. Octane rating does not relate directly to the power output or the energy content of the fuel per unit mass or volume, but simply indicates the resistance to detonating under pressure without a spark.
Avgas is an aviation fuel used in aircraft with spark-ignited internal combustion engines. Avgas is distinguished from conventional gasoline (petrol) used in motor vehicles, which is termed mogas in an aviation context. Unlike motor gasoline, which has been formulated without lead since the 1970s to allow the use of catalytic converters for pollution reduction, the most commonly used grades of avgas still contain tetraethyl lead, a toxic lead containing additive used to aid in lubrication of the engine, increase octane rating, and prevent engine knocking. There are ongoing efforts to reduce or eliminate the use of lead in aviation gasoline.
A fuel tax is an excise tax imposed on the sale of fuel. In most countries the fuel tax is imposed on fuels which are intended for transportation. Fuel tax receipts are often dedicated or hypothecated to transportation projects, in which case the fuel tax can be considered a user fee. In other countries, the fuel tax is a source of general revenue. Sometimes, a fuel tax is used as an ecotax, to promote ecological sustainability. Fuel taxes are often considered by government agencies such as the Internal Revenue Service as regressive taxes.
Ethanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline.
Aviation fuels are petroleum-based fuels, or petroleum and synthetic fuel blends, used to power aircraft. They have more stringent requirements than fuels used for ground use, such as heating and road transport, and contain additives to enhance or maintain properties important to fuel performance or handling. They are kerosene-based for gas turbine-powered aircraft. Piston-engined aircraft use leaded gasoline and those with diesel engines may use jet fuel (kerosene). By 2012, all aircraft operated by the U.S. Air Force had been certified to use a 50-50 blend of kerosene and synthetic fuel derived from coal or natural gas as a way of stabilizing the cost of fuel.
Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable instead of the fluid. Most liquid fuels in widespread use are derived from fossil fuels; however, there are several types, such as hydrogen fuel, ethanol, and biodiesel, which are also categorized as a liquid fuel. Many liquid fuels play a primary role in transportation and the economy.
Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol (CH3OH) is less expensive to sustainably produce than ethanol fuel, although it is more toxic than ethanol and has a lower energy density than gasoline. Methanol is safer for the environment than gasoline, is an anti-freeze agent, prevents dirt and grime buildup within the engine, has a higher ignition temperature and can withstand compression equivalent to that of super high-octane gasoline. It can readily be used in most modern engines. To prevent vapor lock due to being a simple, pure fuel, a small percentage of other fuel or certain additives can be included. Methanol may be made from fossil fuels or renewable resources, in particular natural gas and coal, or biomass respectively. In the case of the latter, it can be synthesized from CO2 (carbon dioxide) and hydrogen. The vast majority of methanol produced globally is currently made with gas and coal. However, projects, investments, and the production of green-methanol has risen steadily into 2023. Methanol fuel is currently used by racing cars in many countries and has seen increasing adoption by the maritime industry.
Shell V-Power is the brand name given to Shell's enhanced high specification fuels for road motor vehicles including "Shell V-Power Nitro+" and "Shell V-Power Diesel". Introduced in Italy in 2001, Shell relaunched the fuel in March 2008, under the name Nitrogen-Enriched Shell V-Power, with nitrogen-containing detergents.
Ethanol, an alcohol fuel, is an important fuel for the operation of internal combustion engines that are used in cars, trucks, and other kinds of machinery.
Methylcyclopentadienyl manganese tricarbonyl (MMT or MCMT) is an organomanganese compound with the formula (C5H4CH3)Mn(CO)3. Initially marketed as a supplement for use in leaded gasoline, MMT was later used in unleaded gasoline to increase the octane rating. Following the implementation of the Clean Air Act (United States) (CAA) in 1970, MMT continued to be used alongside tetraethyl lead (TEL) in the US as leaded gasoline was phased out (prior to TEL finally being banned from US gasoline in 1995), and was also used in unleaded gasoline until 1977. Ethyl Corporation obtained a waiver from the U.S. EPA (Environmental Protection Agency) in 1995, which allows the use of MMT in US unleaded gasoline (not including reformulated gasoline) at a treat rate equivalent to 8.3 mg Mn/L (manganese per liter).
E85 is an abbreviation typically referring to an ethanol fuel blend of 85% ethanol fuel and 15% gasoline or other hydrocarbon by volume.
Several common ethanol fuel mixtures are in use around the world. The use of pure hydrous or anhydrous ethanol in internal combustion engines (ICEs) is only possible if the engines are designed or modified for that purpose, and used only in automobiles, light-duty trucks and motorcycles. Anhydrous ethanol can be blended with gasoline (petrol) for use in gasoline engines, but with high ethanol content only after engine modifications to meter increased fuel volume since pure ethanol contains only 2/3 of the BTUs of an equivalent volume of pure gasoline. High percentage ethanol mixtures are used in some racing engine applications as the very high octane rating of ethanol is compatible with very high compression ratios.
Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is CnH2n+1OH.
An antiknock agent is a gasoline additive used to reduce engine knocking and increase the fuel's octane rating by raising the temperature and pressure at which auto-ignition occurs. The mixture known as gasoline or petrol, when used in high compression internal combustion engines, has a tendency to knock and/or to ignite early before the correctly timed spark occurs.
N-Methylaniline (NMA) is an aniline derivative. It is an organic compound with the chemical formula C6H5NH(CH3). The substance is a colorless viscous liquid, Samples turn brown when exposed to air. The chemical is insoluble in water. It is used as a latent and coupling solvent and is also used as an intermediate for dyes, agrochemicals and other organic products manufacturing. NMA is toxic and exposure can cause damage to the central nervous system and can also cause liver and kidney failure.
The history of gasoline started around the invention of internal combustion engines suitable for use in transportation applications. The so-called Otto engines were developed in Germany during the last quarter of the 19th century. The fuel for these early engines was a relatively volatile hydrocarbon obtained from coal gas. With a boiling point near 85 °C (185 °F), it was well-suited for early carburetors (evaporators). The development of a "spray nozzle" carburetor enabled the use of less volatile fuels. Further improvements in engine efficiency were attempted at higher compression ratios, but early attempts were blocked by the premature explosion of fuel, known as knocking.
References
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