# Heat engine

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In thermodynamics and engineering, a heat engine is a system that converts heat to mechanical energy, which can then be used to do mechanical work.   It does this by bringing a working substance from a higher state temperature to a lower state temperature. A heat source generates thermal energy that brings the working substance to the high temperature state. The working substance generates work in the working body of the engine while transferring heat to the colder sink until it reaches a low temperature state. During this process some of the thermal energy is converted into work by exploiting the properties of the working substance. The working substance can be any system with a non-zero heat capacity, but it usually is a gas or liquid. During this process, some heat is normally lost to the surroundings and is not converted to work. Also, some energy is unusable because of friction and drag.

## Contents

In general, an engine converts energy to mechanical work. Heat engines distinguish themselves from other types of engines by the fact that their efficiency is fundamentally limited by Carnot's theorem.  Although this efficiency limitation can be a drawback, an advantage of heat engines is that most forms of energy can be easily converted to heat by processes like exothermic reactions (such as combustion), nuclear fission, absorption of light or energetic particles, friction, dissipation and resistance. Since the heat source that supplies thermal energy to the engine can thus be powered by virtually any kind of energy, heat engines cover a wide range of applications.

Heat engines are often confused with the cycles they attempt to implement. Typically, the term "engine" is used for a physical device and "cycle" for the models.

## Overview

In thermodynamics, heat engines are often modeled using a standard engineering model such as the Otto cycle. The theoretical model can be refined and augmented with actual data from an operating engine, using tools such as an indicator diagram. Since very few actual implementations of heat engines exactly match their underlying thermodynamic cycles, one could say that a thermodynamic cycle is an ideal case of a mechanical engine. In any case, fully understanding an engine and its efficiency requires a good understanding of the (possibly simplified or idealised) theoretical model, the practical nuances of an actual mechanical engine and the discrepancies between the two.

In general terms, the larger the difference in temperature between the hot source and the cold sink, the larger is the potential thermal efficiency of the cycle. On Earth, the cold side of any heat engine is limited to being close to the ambient temperature of the environment, or not much lower than 300 Kelvin, so most efforts to improve the thermodynamic efficiencies of various heat engines focus on increasing the temperature of the source, within material limits. The maximum theoretical efficiency of a heat engine (which no engine ever attains) is equal to the temperature difference between the hot and cold ends divided by the temperature at the hot end, each expressed in absolute temperature (Kelvin).

The efficiency of various heat engines proposed or used today has a large range:

The efficiency of these processes is roughly proportional to the temperature drop across them. Significant energy may be consumed by auxiliary equipment, such as pumps, which effectively reduces efficiency.

## Examples

It is important to note that although some cycles have a typical combustion location (internal or external), they often can be implemented with the other. For example, John Ericsson  developed an external heated engine running on a cycle very much like the earlier Diesel cycle. In addition, externally heated engines can often be implemented in open or closed cycles. In a closed cycle the working fluid is retained within the engine at the completion of the cycle whereas is an open cycle the working fluid is either exchanged with the environment together with the products of combustion in the case of the internal combustion engine or simply vented to the environment in the case of external combustion engines like steam engines and turbines.

### Everyday examples

Everyday examples of heat engines include the thermal power station, internal combustion engine, firearms, fireworks, refrigerators and heat pumps. Power stations are examples of heat engines run in a forward direction in which heat flows from a hot reservoir and flows into a cool reservoir to produce work as the desired product. Refrigerators, air conditioners and heat pumps are examples of heat engines that are run in reverse, i.e. they use work to take heat energy at a low temperature and raise its temperature in a more efficient way than the simple conversion of work into heat (either through friction or electrical resistance). Refrigerators remove heat from within a thermally sealed chamber at low temperature and vent waste heat at a higher temperature to the environment and heat pumps take heat from the low temperature environment and 'vent' it into a thermally sealed chamber (a house) at higher temperature.

In general heat engines exploit the thermal properties associated with the expansion and compression of gases according to the gas laws or the properties associated with phase changes between gas and liquid states.

### Earth's heat engine

Earth's atmosphere and hydrosphere—Earth's heat engine—are coupled processes that constantly even out solar heating imbalances through evaporation of surface water, convection, rainfall, winds and ocean circulation, when distributing heat around the globe. 

A Hadley cell is an example of a heat engine. It involves the rising of warm and moist air in the earth's equatorial region and the descent of colder air in the subtropics creating a thermally driven direct circulation, with consequent net production of kinetic energy. 

### Phase-change cycles

In these cycles and engines, the working fluids are gases and liquids. The engine converts the working fluid from a gas to a liquid, from liquid to gas, or both, generating work from the fluid expansion or compression.

### Gas-only cycles

In these cycles and engines the working fluid is always a gas (i.e., there is no phase change):

### Liquid-only cycles

In these cycles and engines the working fluid are always like liquid:

### Cycles used for refrigeration

A domestic refrigerator is an example of a heat pump: a heat engine in reverse. Work is used to create a heat differential. Many cycles can run in reverse to move heat from the cold side to the hot side, making the cold side cooler and the hot side hotter. Internal combustion engine versions of these cycles are, by their nature, not reversible.

Refrigeration cycles include:

### Evaporative heat engines

The Barton evaporation engine is a heat engine based on a cycle producing power and cooled moist air from the evaporation of water into hot dry air.

### Mesoscopic heat engines

Mesoscopic heat engines are nanoscale devices that may serve the goal of processing heat fluxes and perform useful work at small scales. Potential applications include e.g. electric cooling devices. In such mesoscopic heat engines, work per cycle of operation fluctuates due to thermal noise. There is exact equality that relates average of exponents of work performed by any heat engine and the heat transfer from the hotter heat bath.  This relation transforms the Carnot's inequality into exact equality. This relation is also a Carnot cycle equality

## Efficiency

The efficiency of a heat engine relates how much useful work is output for a given amount of heat energy input.

From the laws of thermodynamics, after a completed cycle:

$W\ =\ Q_{c}\ -\ (-Q_{h})$ where
$W=-\oint PdV$ is the work extracted from the engine. (It is negative since work is done by the engine.)
$Q_{h}=T_{h}\Delta S_{h}$ is the heat energy taken from the high temperature system. (It is negative since heat is extracted from the source, hence $(-Q_{h})$ is positive.)
$Q_{c}=T_{c}\Delta S_{c}$ is the heat energy delivered to the cold temperature system. (It is positive since heat is added to the sink.)

In other words, a heat engine absorbs heat energy from the high temperature heat source, converting part of it to useful work and delivering the rest to the cold temperature heat sink.

In general, the efficiency of a given heat transfer process (whether it be a refrigerator, a heat pump or an engine) is defined informally by the ratio of "what is taken out" to "what is put in".

In the case of an engine, one desires to extract work and puts in a heat transfer.

$\eta ={\frac {-W}{-Q_{h}}}={\frac {-Q_{h}-Q_{c}}{-Q_{h}}}=1-{\frac {Q_{c}}{-Q_{h}}}$ The theoretical maximum efficiency of any heat engine depends only on the temperatures it operates between. This efficiency is usually derived using an ideal imaginary heat engine such as the Carnot heat engine, although other engines using different cycles can also attain maximum efficiency. Mathematically, this is because in reversible processes, the change in entropy of the cold reservoir is the negative of that of the hot reservoir (i.e., $\Delta S_{c}=-\Delta S_{h}$ ), keeping the overall change of entropy zero. Thus:

$\eta _{\text{max}}=1-{\frac {T_{c}\Delta S_{c}}{-T_{h}\Delta S_{h}}}=1-{\frac {T_{c}}{T_{h}}}$ where $T_{h}$ is the absolute temperature of the hot source and $T_{c}$ that of the cold sink, usually measured in kelvins. Note that $dS_{c}$ is positive while $dS_{h}$ is negative; in any reversible work-extracting process, entropy is overall not increased, but rather is moved from a hot (high-entropy) system to a cold (low-entropy one), decreasing the entropy of the heat source and increasing that of the heat sink.

The reasoning behind this being the maximal efficiency goes as follows. It is first assumed that if a more efficient heat engine than a Carnot engine is possible, then it could be driven in reverse as a heat pump. Mathematical analysis can be used to show that this assumed combination would result in a net decrease in entropy. Since, by the second law of thermodynamics, this is statistically improbable to the point of exclusion, the Carnot efficiency is a theoretical upper bound on the reliable efficiency of any thermodynamic cycle.

Empirically, no heat engine has ever been shown to run at a greater efficiency than a Carnot cycle heat engine.

Figure 2 and Figure 3 show variations on Carnot cycle efficiency. Figure 2 indicates how efficiency changes with an increase in the heat addition temperature for a constant compressor inlet temperature. Figure 3 indicates how the efficiency changes with an increase in the heat rejection temperature for a constant turbine inlet temperature.

### Endo-reversible heat-engines

By its nature, any maximally efficient Carnot cycle must operate at an infinitesimal temperature gradient; this is because any transfer of heat between two bodies of differing temperatures is irreversible, therefore the Carnot efficiency expression applies only to the infinitesimal limit. The major problem is that the objective of most heat-engines is to output power, and infinitesimal power is seldom desired.

A different measure of ideal heat-engine efficiency is given by considerations of endoreversible thermodynamics, where the system is broken into reversible subsystems, but with non reversible interactions between them. A classical example is the Curzon-Ahlborn engine,  very similar to a Carnot engine, but where the thermal reservoirs at temperature $T_{h}$ and $T_{c}$ are allowed to be different from the temperatures of the substance going through the reversible Carnot cycle: $T'_{h}$ and $T'_{c}$ . The heat transfers between the reservoirs and the substance are considered as conductive (and irreversible) in the form $dQ_{h,c}/dt=\alpha (T_{h,c}-T'_{h,c})$ . In this case, a tradeof has to be made between power output and efficiency. If the engine is operated very slowly, the heat flux is low, $T\approx T'$ and the classical Carnot result is found

$\eta =1-{\frac {T_{c}}{T_{h}}}$ ,

but at the price of a vanishing power output. If instead one choses to operate the engine at its maximum output power, the efficiency becomes

$\eta =1-{\sqrt {\frac {T_{c}}{T_{h}}}}$ (Note: Units K or °R)

This model does a better job of predicting how well real-world heat-engines can do (Callen 1985, see also endoreversible thermodynamics):

Efficiencies of power stations 
Power station$T_{c}$ (°C)$T_{h}$ (°C)$\eta$ (Carnot)$\eta$ (Endoreversible)$\eta$ (Observed)
West Thurrock (UK) coal-fired power station 255650.640.400.36
CANDU (Canada) nuclear power station 253000.480.280.30
Larderello (Italy) geothermal power station 802500.330.1780.16

As shown, the Curzon-Ahlborn efficiency much more closely models that observed.

## History

Heat engines have been known since antiquity but were only made into useful devices at the time of the industrial revolution in the 18th century. They continue to be developed today.

## Enhancements

Engineers have studied the various heat-engine cycles to improve the amount of usable work they could extract from a given power source. The Carnot cycle limit cannot be reached with any gas-based cycle, but engineers have found at least two ways to bypass that limit and one way to get better efficiency without bending any rules:

1. Increase the temperature difference in the heat engine. The simplest way to do this is to increase the hot side temperature, which is the approach used in modern combined-cycle gas turbines. Unfortunately, physical limits (such as the melting point of the materials used to build the engine) and environmental concerns regarding NOx production restrict the maximum temperature on workable heat-engines. Modern gas turbines run at temperatures as high as possible within the range of temperatures necessary to maintain acceptable NOx output [ citation needed ]. Another way of increasing efficiency is to lower the output temperature. One new method of doing so is to use mixed chemical working fluids, then exploit the changing behavior of the mixtures. One of the most famous is the so-called Kalina cycle, which uses a 70/30 mix of ammonia and water as its working fluid. This mixture allows the cycle to generate useful power at considerably lower temperatures than most other processes.
2. Exploit the physical properties of the working fluid. The most common such exploitation is the use of water above the critical point, or supercritical steam. The behavior of fluids above their critical point changes radically, and with materials such as water and carbon dioxide it is possible to exploit those changes in behavior to extract greater thermodynamic efficiency from the heat engine, even if it is using a fairly conventional Brayton or Rankine cycle. A newer and very promising material for such applications is CO2. SO2 and xenon have also been considered for such applications, although SO2 is toxic.
3. Exploit the chemical properties of the working fluid. A fairly new and novel exploit is to use exotic working fluids with advantageous chemical properties. One such is nitrogen dioxide (NO2), a toxic component of smog, which has a natural dimer as di-nitrogen tetraoxide (N2O4). At low temperature, the N2O4 is compressed and then heated. The increasing temperature causes each N2O4 to break apart into two NO2 molecules. This lowers the molecular weight of the working fluid, which drastically increases the efficiency of the cycle. Once the NO2 has expanded through the turbine, it is cooled by the heat sink, which makes it recombine into N2O4. This is then fed back by the compressor for another cycle. Such species as aluminium bromide (Al2Br6), NOCl, and Ga2I6 have all been investigated for such uses. To date, their drawbacks have not warranted their use, despite the efficiency gains that can be realized. 

## Heat engine processes

CycleCompression, 1→2Heat addition, 2→3Expansion, 3→4Heat rejection, 4→1Notes
Power cycles normally with external combustion - or heat pump cycles:
Carnot isentropicisothermalisentropicisothermal Carnot heat engine
Ericsson isothermalisobaricisothermalisobaricThe second Ericsson cycle from 1853
and volume
Stirling isothermalisochoricisothermalisochoric Stirling engine
Manson isothermalisochoricisothermalisochoric then adiabatic Manson engine, Manson-Guise Engine
Power cycles normally with internal combustion:
Brayton adiabaticisobaricadiabaticisobaric Jet engine. The external combustion version of this cycle is known as first Ericsson cycle from 1833.
Lenoir isochoricadiabaticisobaric Pulse jets. Note, 1→2 accomplishes both the heat rejection and the compression.
Otto isentropicisochoricisentropicisochoric Gasoline / petrol engines

Each process is one of the following:

• isothermal (at constant temperature, maintained with heat added or removed from a heat source or sink)
• isobaric (at constant pressure)
• isometric/isochoric (at constant volume), also referred to as iso-volumetric
• isentropic (reversible adiabatic process, no heat is added or removed during isentropic process)

## Related Research Articles A Carnot heat engine is a theoretical engine that operates on the Carnot cycle. The basic model for this engine was developed by Nicolas Léonard Sadi Carnot in 1824. The Carnot engine model was graphically expanded by Benoît Paul Émile Clapeyron in 1834 and mathematically explored by Rudolf Clausius in 1857, work that led to the fundamental thermodynamic concept of entropy. Entropy is a scientific concept, as well as a measurable physical property that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication. Sous-lieutenantNicolas Léonard Sadi Carnot was a French mechanical engineer in the French Army, military scientist and physicist, and often described as the "father of thermodynamics." Like Copernicus, he published only one book, the Reflections on the Motive Power of Fire, in which he expressed, at the age of 27 years, the first successful theory of the maximum efficiency of heat engines. In this work, he laid the foundations of an entirely new discipline: thermodynamics. Carnot's work attracted little attention during his lifetime, but it was later used by Rudolf Clausius and Lord Kelvin to formalize the second law of thermodynamics and define the concept of entropy. His father used the suffix Sadi to name him because of his intense interest in the character of Saadi Shirazi, a well-known Iranian poet. Based on purely technical concerns, such as improving the performance of the steam engine, Sadi Carnot's intellect laid the groundwork for modern science technological designs, such as the automobile or jet engine. The thermodynamic free energy is a concept useful in the thermodynamics of chemical or thermal processes in engineering and science. The change in the free energy is the maximum amount of work that a thermodynamic system can perform in a process at constant temperature, and its sign indicates whether a process is thermodynamically favorable or forbidden. Since free energy usually contains potential energy, it is not absolute but depends on the choice of a zero point. Therefore, only relative free energy values, or changes in free energy, are physically meaningful. The second law of thermodynamics establishes the concept of entropy as a physical property of a thermodynamic system. Entropy predicts the direction of spontaneous processes, and determines whether they are irreversible or impossible, despite obeying the requirement of conservation of energy, which is established in the first law of thermodynamics. The second law may be formulated by the observation that the entropy of isolated systems left to spontaneous evolution cannot decrease, as they always arrive at a state of thermodynamic equilibrium, where the entropy is highest. If all processes in the system are reversible, the entropy is constant. An increase in entropy accounts for the irreversibility of natural processes, often referred to in the concept of the arrow of time. An Otto cycle is an idealized thermodynamic cycle that describes the functioning of a typical spark ignition piston engine. It is the thermodynamic cycle most commonly found in automobile engines. Carnot's theorem, developed in 1824 by Nicolas Léonard Sadi Carnot, also called Carnot's rule, is a principle that specifies limits on the maximum efficiency any heat engine can obtain. The efficiency of a Carnot engine depends solely on the temperatures of the hot and cold reservoirs. In thermodynamics, an isothermal process is a type of thermodynamic process in which the temperature of the system remains constant: ΔT = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and the change in the system will occur slowly enough to allow the system to continue to adjust to the temperature of the reservoir through heat exchange. In contrast, an adiabatic process is where a system exchanges no heat with its surroundings (Q = 0). A thermodynamic system is a body of matter and/or radiation, confined in space by walls, with defined permeabilities, which separate it from its surroundings. The surroundings may include other thermodynamic systems, or physical systems that are not thermodynamic systems. A wall of a thermodynamic system may be purely notional, when it is described as being 'permeable' to all matter, all radiation, and all forces. A thermodynamic system can be fully described by a definite set of thermodynamic state variables, which always covers both intensive and extensive properties. The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University. A thermodynamic cycle consists of a linked sequence of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat pump. At every point in the cycle, the system is in thermodynamic equilibrium, so the cycle is reversible. In thermodynamics, the thermal efficiency is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, a steam turbine or a steam engine, a boiler, furnace, or a refrigerator for example. For a heat engine, thermal efficiency is the fraction of the energy added by heat that is converted to net work output. In the case of a refrigeration or heat pump cycle, thermal efficiency is the ratio of net heat output for heating, or removal for cooling, to energy input. The Clausius theorem (1855) states that for a thermodynamic system exchanging heat with external reservoirs and undergoing a thermodynamic cycle,

The concept of entropy developed in response to the observation that a certain amount of functional energy released from combustion reactions is always lost to dissipation or friction and is thus not transformed into useful work. Early heat-powered engines such as Thomas Savery's (1698), the Newcomen engine (1712) and the Cugnot steam tricycle (1769) were inefficient, converting less than two percent of the input energy into useful work output; a great deal of useful energy was dissipated or lost. Over the next two centuries, physicists investigated this puzzle of lost energy; the result was the concept of entropy.

In classical thermodynamics, entropy is a property of a thermodynamic system that expresses the direction or outcome of spontaneous changes in the system. The term was introduced by Rudolf Clausius in the mid-nineteenth century from the Greek word τρoπή (transformation) to explain the relationship of the internal energy that is available or unavailable for transformations in form of heat and work. Entropy predicts that certain processes are irreversible or impossible, despite not violating the conservation of energy. The definition of entropy is central to the establishment of the second law of thermodynamics, which states that the entropy of isolated systems cannot decrease with time, as they always tend to arrive at a state of thermodynamic equilibrium, where the entropy is highest. Entropy is therefore also considered to be a measure of disorder in the system. The Carnot cycle is a theoretical ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. It provides an upper limit on the efficiency that any classical thermodynamic engine can achieve during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference by the application of work to the system. It is not an actual thermodynamic cycle but is a theoretical construct. Thermodynamic heat pump cycles or refrigeration cycles are the conceptual and mathematical models for heat pump, air conditioning and refrigeration systems. A heat pump is a mechanical system that allows for the transmission of heat from one location at a lower temperature to another location at a higher temperature. Thus a heat pump may be thought of as a "heater" if the objective is to warm the heat sink, or a "refrigerator" or “cooler” if the objective is to cool the heat source. In either case, the operating principles are close. Heat is moved from a cold place to a warm place. In thermodynamics, heat is energy in transfer to or from a thermodynamic system, by mechanisms other than thermodynamic work or transfer of matter. The various mechanisms of energy transfer that define heat are stated in the next section of this article. Temperature is a physical quantity that expresses hot and cold. It is the manifestation of thermal energy, present in all matter, which is the source of the occurrence of heat, a flow of energy, when a body is in contact with another that is colder or hotter. Endoreversible thermodynamics is a subset of irreversible thermodynamics aimed at making more realistic assumptions about heat transfer than are typically made in reversible thermodynamics. It gives an upper bound on the energy that can be derived from a real process that is lower than that predicted by Carnot for a Carnot cycle, and accommodates the exergy destruction occurring as heat is transferred irreversibly.

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