Derivation
The internal energy of the photo-Carnot engine is proportional to the volume (unlike the ideal-gas equivalent) as well as the 4th power of the temperature (see Stefan–Boltzmann law) using 
:
The radiation pressure is only proportional to this 4th power of temperature but no other variables, meaning that for this photo-Carnot engine an isotherm is equivalent to an isobar:
Using the first law of thermodynamics (
) we can determine the work done through an adiabatic (
) expansion by using the chain rule (
) and setting it equal to 
Combining these 
gives us 
which we can solve to find 
, or equivalently 
Since the photo-Carnot engine needs a quantum coherence in the gas which is lost during the process, the rebuild of coherency takes more energy than is produced with the machine.
The efficiency of this reversible engine including the coherency must at most be the Carnot efficiency, regardless of the mechanism and so 
Spontaneous emission is the process in which a quantum mechanical system transits from an excited energy state to a lower energy state and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light we see all around us; it is so ubiquitous that there are many names given to what is essentially the same process. If atoms are excited by some means other than heating, the spontaneous emission is called luminescence. For example, fireflies are luminescent. And there are different forms of luminescence depending on how excited atoms are produced. If the excitation is effected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission.
The Stefan–Boltzmann law, also known as Stefan's law, describes the intensity of the thermal radiation emitted by matter in terms of that matter's temperature. It is named for Josef Stefan, who empirically derived the relationship, and Ludwig Boltzmann who derived the law theoretically.
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ε (epsilon), is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor.
The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter. Another statement is: "Not all heat can be converted into work in a cyclic process."
A Fermi gas is an idealized model, an ensemble of many non-interacting fermions. Fermions are particles that obey Fermi–Dirac statistics, like electrons, protons, and neutrons, and, in general, particles with half-integer spin. These statistics determine the energy distribution of fermions in a Fermi gas in thermal equilibrium, and is characterized by their number density, temperature, and the set of available energy states. The model is named after the Italian physicist Enrico Fermi.
In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature T, when there is no net flow of matter or energy between the body and its environment.
In mathematics and classical mechanics, the Poisson bracket is an important binary operation in Hamiltonian mechanics, playing a central role in Hamilton's equations of motion, which govern the time evolution of a Hamiltonian dynamical system. The Poisson bracket also distinguishes a certain class of coordinate transformations, called canonical transformations, which map canonical coordinate systems into canonical coordinate systems. A "canonical coordinate system" consists of canonical position and momentum variables that satisfy canonical Poisson bracket relations. The set of possible canonical transformations is always very rich. For instance, it is often possible to choose the Hamiltonian itself as one of the new canonical momentum coordinates.
In condensed matter physics, Bloch's theorem states that solutions to the Schrödinger equation in a periodic potential can be expressed as plane waves modulated by periodic functions. The theorem is named after the Swiss physicist Felix Bloch, who discovered the theorem in 1929. Mathematically, they are written
The path integral formulation is a description in quantum mechanics that generalizes the stationary action principle of classical mechanics. It replaces the classical notion of a single, unique classical trajectory for a system with a sum, or functional integral, over an infinity of quantum-mechanically possible trajectories to compute a quantum amplitude.
In Hamiltonian mechanics, a canonical transformation is a change of canonical coordinates (q, p) → that preserves the form of Hamilton's equations. This is sometimes known as form invariance. Although Hamilton's equations are preserved, it need not preserve the explicit form of the Hamiltonian itself. Canonical transformations are useful in their own right, and also form the basis for the Hamilton–Jacobi equations and Liouville's theorem.
In quantum mechanics and quantum field theory, the propagator is a function that specifies the probability amplitude for a particle to travel from one place to another in a given period of time, or to travel with a certain energy and momentum. In Feynman diagrams, which serve to calculate the rate of collisions in quantum field theory, virtual particles contribute their propagator to the rate of the scattering event described by the respective diagram. Propagators may also be viewed as the inverse of the wave operator appropriate to the particle, and are, therefore, often called (causal) Green's functions.
In quantum physics, Fermi's golden rule is a formula that describes the transition rate from one energy eigenstate of a quantum system to a group of energy eigenstates in a continuum, as a result of a weak perturbation. This transition rate is effectively independent of time and is proportional to the strength of the coupling between the initial and final states of the system as well as the density of states. It is also applicable when the final state is discrete, i.e. it is not part of a continuum, if there is some decoherence in the process, like relaxation or collision of the atoms, or like noise in the perturbation, in which case the density of states is replaced by the reciprocal of the decoherence bandwidth.
In physics, the Lamb shift, named after Willis Lamb, is an anomalous difference in energy between two electron orbitals in a hydrogen atom. The difference was not predicted by theory and it cannot be derived from the Dirac equation, which predicts identical energies. Hence the Lamb shift is a deviation from theory seen in the differing energies contained by the 2S1/2 and 2P1/2 orbitals of the hydrogen atom.
The classical electron radius is a combination of fundamental physical quantities that define a length scale for problems involving an electron interacting with electromagnetic radiation. It links the classical electrostatic self-interaction energy of a homogeneous charge distribution to the electron's relativistic mass-energy. According to modern understanding, the electron is a point particle with a point charge and no spatial extent. Nevertheless, it is useful to define a length that characterizes electron interactions in atomic-scale problems. The classical electron radius is given as
The Einstein solid is a model of a crystalline solid that contains a large number of independent three-dimensional quantum harmonic oscillators of the same frequency. The independence assumption is relaxed in the Debye model.
In atomic, molecular, and optical physics, the Einstein coefficients are quantities describing the probability of absorption or emission of a photon by an atom or molecule. The Einstein A coefficients are related to the rate of spontaneous emission of light, and the Einstein B coefficients are related to the absorption and stimulated emission of light. Throughout this article, "light" refers to any electromagnetic radiation, not necessarily in the visible spectrum.
The Frank–Tamm formula yields the amount of Cherenkov radiation emitted on a given frequency as a charged particle moves through a medium at superluminal velocity. It is named for Russian physicists Ilya Frank and Igor Tamm who developed the theory of the Cherenkov effect in 1937, for which they were awarded a Nobel Prize in Physics in 1958.
Algorithmic cooling is an algorithmic method for transferring heat from some qubits to others or outside the system and into the environment, which results in a cooling effect. This method uses regular quantum operations on ensembles of qubits, and it can be shown that it can succeed beyond Shannon's bound on data compression. The phenomenon is a result of the connection between thermodynamics and information theory.
Heat transfer physics describes the kinetics of energy storage, transport, and energy transformation by principal energy carriers: phonons, electrons, fluid particles, and photons. Heat is thermal energy stored in temperature-dependent motion of particles including electrons, atomic nuclei, individual atoms, and molecules. Heat is transferred to and from matter by the principal energy carriers. The state of energy stored within matter, or transported by the carriers, is described by a combination of classical and quantum statistical mechanics. The energy is different made (converted) among various carriers. The heat transfer processes are governed by the rates at which various related physical phenomena occur, such as the rate of particle collisions in classical mechanics. These various states and kinetics determine the heat transfer, i.e., the net rate of energy storage or transport. Governing these process from the atomic level to macroscale are the laws of thermodynamics, including conservation of energy.
A quantum heat engine is a device that generates power from the heat flow between hot and cold reservoirs. The operation mechanism of the engine can be described by the laws of quantum mechanics. The first realization of a quantum heat engine was pointed out by Scovil and Schulz-DuBois in 1959, showing the connection of efficiency of the Carnot engine and the 3-level maser. Quantum refrigerators share the structure of quantum heat engines with the purpose of pumping heat from a cold to a hot bath consuming power first suggested by Geusic, Schulz-DuBois, De Grasse and Scovil. When the power is supplied by a laser the process is termed optical pumping or laser cooling, suggested by Wineland and Hänsch. Surprisingly heat engines and refrigerators can operate up to the scale of a single particle thus justifying the need for a quantum theory termed quantum thermodynamics.
