| Thermodynamics |
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An isenthalpic process or isoenthalpic process is a process that proceeds without any change in enthalpy, H; or specific enthalpy, h. [1]
| Thermodynamics |
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An isenthalpic process or isoenthalpic process is a process that proceeds without any change in enthalpy, H; or specific enthalpy, h. [1]
If a steady-state, steady-flow process is analysed using a control volume, everything outside the control volume is considered to be the surroundings. [2] Such a process will be isenthalpic if there is no transfer of heat to or from the surroundings, no work done on or by the surroundings, and no change in the kinetic energy of the fluid. [3] This is a sufficient but not necessary condition for isoenthalpy. The necessary condition for a process to be isoenthalpic is that the sum of each of the terms of the energy balance other than enthalpy (work, heat, changes in kinetic energy, etc.) cancel each other, so that the enthalpy remains unchanged. For a process in which magnetic and electric effects (among others) give negligible contributions, the associated energy balance can be written as
If then it must be that
The throttling process is a good example of an isoenthalpic process in which significant changes in pressure and temperature can occur to the fluid, and yet the net sum the associated terms in the energy balance is null, thus rendering the transformation isoenthalpic. The lifting of a relief (or safety) valve on a pressure vessel is an example of throttling process. The specific enthalpy of the fluid inside the pressure vessel is the same as the specific enthalpy of the fluid as it escapes through the valve. [3] With a knowledge of the specific enthalpy of the fluid and the pressure outside the pressure vessel, it is possible to determine the temperature and speed of the escaping fluid.
In an isenthalpic process:
Isenthalpic processes on an ideal gas follow isotherms, since .
In thermodynamics, an adiabatic process is a type of thermodynamic process that occurs without transferring heat or mass between the thermodynamic system and its environment. Unlike an isothermal process, an adiabatic process transfers energy to the surroundings only as work. As a key concept in thermodynamics, the adiabatic process supports the theory that explains the first law of thermodynamics.
Enthalpy, a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant pressure, which is conveniently provided by the large ambient atmosphere. The pressure–volume term expresses the work required to establish the system's physical dimensions, i.e. to make room for it by displacing its surroundings. The pressure-volume term is very small for solids and liquids at common conditions, and fairly small for gases. Therefore, enthalpy is a stand-in for energy in chemical systems; bond, lattice, solvation and other "energies" in chemistry are actually enthalpy differences. As a state function, enthalpy depends only on the final configuration of internal energy, pressure, and volume, not on the path taken to achieve it.
A calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry.
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics. The requirement of zero interaction can often be relaxed if, for example, the interaction is perfectly elastic or regarded as point-like collisions.
In thermodynamics, the Joule–Thomson effect describes the temperature change of a real gas or liquid when it is forced through a valve or porous plug while keeping it insulated so that no heat is exchanged with the environment. This procedure is called a throttling process or Joule–Thomson process. At room temperature, all gases except hydrogen, helium, and neon cool upon expansion by the Joule–Thomson process when being throttled through an orifice; these three gases experience the same effect but only at lower temperatures. Most liquids such as hydraulic oils will be warmed by the Joule–Thomson throttling process.
The first law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
In thermodynamics, the Gibbs free energy is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions.
The internal energy of a thermodynamic system is the energy contained within it. It is the energy necessary to create or prepare the system in its given internal state. It does not include the kinetic energy of motion of the system as a whole, nor the potential energy of the system as a whole due to external force fields, including the energy of displacement of the surroundings of the system. It keeps account of the gains and losses of energy of the system that are due to changes in its internal state. The internal energy cannot be measured directly. It is measured as a difference from a reference zero defined by a standard state. The difference is determined by thermodynamic processes that carry the system between the reference state and the given state of interest.
In thermodynamics, an isentropic process is an idealized thermodynamic process that is both adiabatic and reversible. The work transfers of the system are frictionless, and there is no net transfer of heat or matter. Such an idealized process is useful in engineering as a model of and basis of comparison for real processes. This is idealized as reversible processes do not occur in reality; thinking of a process as both adiabatic and reversible would show that the initial and final entropies are the same, thus, the reason it is called isentropic. Thermodynamic processes are named based on the effect they would have on the system. Even though in reality it is not necessarily possible to carry out an isentropic process, some may be approximated as such.
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the system stays constant: ΔP = 0. The heat transferred to the system does work, but also changes the internal energy (U) of the system. This article uses the physics sign convention for work, where positive work is work done by the system. Using this convention, by the first law of thermodynamics,
Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics.
In thermodynamics and fluid mechanics, stagnation temperature is the temperature at a stagnation point in a fluid flow. At a stagnation point the speed of the fluid is zero and all of the kinetic energy has been converted to internal energy and is added to the local static enthalpy. In both compressible and incompressible fluid flow, the stagnation temperature is equal to the total temperature at all points on the streamline leading to the stagnation point. See gas dynamics.
Classical thermodynamics considers three main kinds of thermodynamic process: (1) changes in a system, (2) cycles in a system, and (3) flow processes.
A thermodynamic cycle consists of a linked sequence of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat pump. At every point in the cycle, the system is in thermodynamic equilibrium, so the cycle is reversible.
In thermodynamics, work performed by a system is energy transferred by the system to its surroundings, by a mechanism through which the system can spontaneously exert macroscopic forces on its surroundings. In the surroundings, through suitable passive linkages, the work can lift a weight, for example. Energy can also transfer from the surroundings to the system; in a sign convention used in physics, such work has a negative magnitude.
In classical thermodynamics, entropy is a property of a thermodynamic system that expresses the direction or outcome of spontaneous changes in the system. The term was introduced by Rudolf Clausius in the mid-nineteenth century from the Greek word τρoπή (transformation) to explain the relationship of the internal energy that is available or unavailable for transformations in form of heat and work. Entropy predicts that certain processes are irreversible or impossible, despite not violating the conservation of energy. The definition of entropy is central to the establishment of the second law of thermodynamics, which states that the entropy of isolated systems cannot decrease with time, as they always tend to arrive at a state of thermodynamic equilibrium, where the entropy is highest. Entropy is therefore also considered to be a measure of disorder in the system.
Stagnation enthalpy of a fluid at one point is the enthalpy of the fluid at that point at a stagnation point. It represents the enthalpy of a fluid when it is brought to rest from velocity isentropically. When the potential energy of the fluid is negligible, the stagnation enthalpy represents the total energy of a flowing fluid stream per unit mass.
In thermodynamics, heat is energy in transfer to or from a thermodynamic system, by mechanisms other than thermodynamic work or transfer of matter.
The region of space enclosed by open system boundaries is usually called a control volume. It may or may not correspond to physical walls. It is convenient to define the shape of the control volume so that all flow of matter, in or out, occurs perpendicular to its surface. One may consider a process in which the matter flowing into and out of the system is chemically homogeneous. Then the inflowing matter performs work as if it were driving a piston of fluid into the system. Also, the system performs work as if it were driving out a piston of fluid. Through the system walls that do not pass matter, heat and work transfers may be defined, including shaft work.
Conservative temperature is a thermodynamic property of seawater. It is derived from the potential enthalpy and is recommended under the TEOS-10 standard as a replacement for potential temperature as it more accurately represents the heat content in the ocean.
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