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"An Inquiry Concerning the Source of the Heat Which Is Excited by Friction" is a scientific paper by Benjamin Thompson, Count Rumford, which was published in the Philosophical Transactions of the Royal Society in 1798. [1] The paper provided a substantial challenge to established theories of heat, and began the 19th century revolution in thermodynamics.
Rumford was an opponent of the caloric theory of heat which held that heat is a fluid that could be neither created nor destroyed. He had further developed the view that all gases and liquids are absolute non-conductors of heat. His views were out of step with the accepted science of the time and the latter theory had particularly been attacked by John Dalton [2] and John Leslie. [3]
Rumford was heavily influenced by the argument from design [4] and it is likely that he wished to grant water a privileged and providential status in the regulation of human life. [5]
Though Rumford was to come to associate heat with motion, there is no evidence that he was committed to the kinetic theory or the principle of vis viva .
In his 1798 paper, Rumford acknowledged that he had predecessors in the notion that heat was a form of motion. [6] [a] Those predecessors included Francis Bacon, [7] [b] Robert Boyle, [8] [c] Robert Hooke, [9] [d] John Locke, [10] [e] and Henry Cavendish. [11] [f]
Rumford had observed the frictional heat generated by boring out cannon barrels at the arsenal in Munich. At that time, cannons were cast at the foundry with an extra section of metal forward of what would become the muzzle, and this section was removed and discarded later in the manufacturing process. [12] [g] Rumford took an unfinished cannon and modified this section to allow it to be enclosed by a watertight box while a blunted boring tool was used on it. He showed that water in this box could be boiled within roughly two and a half hours, and that the supply of frictional heat was seemingly inexhaustible. Rumford confirmed that no physical change had taken place in the material of the cannon by comparing the specific heats of the material machined away and that remaining were the same.
Rumford also argued that the seemingly indefinite generation of heat was incompatible with the caloric theory. He contended that the only thing communicated to the barrel was motion.
Rumford made no attempt to further quantify the heat generated or to measure the mechanical equivalent of heat.
Most established scientists, such as William Henry, [13] as well as Thomas Thomson, believed that there was enough uncertainty in the caloric theory to allow its adaptation to account for the new results. It had certainly proved robust and adaptable up to that time. Furthermore, Thomson, [14] Jöns Jakob Berzelius, and Antoine César Becquerel observed that electricity could be indefinitely generated by friction. No educated scientist of the time was willing to hold that electricity was not a fluid.
Ultimately, Rumford's claim of the "inexhaustible" supply of heat was a reckless extrapolation from the study. Charles Haldat made some penetrating criticisms of the reproducibility of Rumford's results [15] and it is possible to see the whole experiment as somewhat tendentious. [16]
However, the experiment inspired the work of James Prescott Joule in the 1840s. Joule's more exact measurements were pivotal in establishing the kinetic theory at the expense of caloric.
Physics is a branch of science whose primary objects of study are matter and energy. Discoveries of physics find applications throughout the natural sciences and in technology. Historically, physics emerged from the scientific revolution of the 17th century, grew rapidly in the 19th century, then was transformed by a series of discoveries in the 20th century. Physics today may be divided loosely into classical physics and modern physics.
Thermodynamics deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics plays a role in a wide variety of topics in science and engineering.
William Thomson, 1st Baron Kelvin was a British mathematician, mathematical physicist and engineer. Born in Belfast, he was the professor of Natural Philosophy at the University of Glasgow for 53 years, where he undertook significant research and mathematical analysis of electricity, was instrumental in the formulation of the first and second laws of thermodynamics, and contributed significantly to unifying physics, which was then in its infancy of development as an emerging academic discipline. He received the Royal Society's Copley Medal in 1883 and served as its president from 1890 to 1895. In 1892, he became the first scientist to be elevated to the House of Lords.
A timeline of events in the history of thermodynamics.
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James Prescott Joule was an English physicist, mathematician and brewer, born in Salford, Lancashire. Joule studied the nature of heat, and discovered its relationship to mechanical work. This led to the law of conservation of energy, which in turn led to the development of the first law of thermodynamics. The SI derived unit of energy, the joule, is named after him.
The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. The law distinguishes two principal forms of energy transfer, heat and thermodynamic work, that modify a thermodynamic system containing a constant amount of matter. The law also defines the internal energy of a system, an extensive property for taking account of the balance of heat and work in the system. Energy cannot be created or destroyed, but it can be transformed from one form to another. In an isolated system the sum of all forms of energy is constant.
Colonel Sir Benjamin Thompson, Count Rumford, FRS, was an American-born British military officer, scientist, inventor and nobleman. Born in Woburn, Massachusetts, he supported the Loyalist cause during the American War of Independence, commanding the King's American Dragoons during the conflict. After the war ended in 1783, Thompson moved to London, where he was recognised for his administrative talents and received a knighthood from George III in 1784.
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Experimental physics is the category of disciplines and sub-disciplines in the field of physics that are concerned with the observation of physical phenomena and experiments. Methods vary from discipline to discipline, from simple experiments and observations, such as Galileo's experiments, to more complicated ones, such as the Large Hadron Collider.
Vis viva is a historical term used to describe a quantity similar to kinetic energy in an early formulation of the principle of conservation of energy.
In the history of science, the mechanical equivalent of heat states that motion and heat are mutually interchangeable and that in every case, a given amount of work would generate the same amount of heat, provided the work done is totally converted to heat energy. The mechanical equivalent of heat was a concept that had an important part in the development and acceptance of the conservation of energy and the establishment of the science of thermodynamics in the 19th century. Its independent and simultaneous discovery by James Prescott Joule and by Julius Robert von Mayer led to a priority dispute.
The history of thermodynamics is a fundamental strand in the history of physics, the history of chemistry, and the history of science in general. Due to the relevance of thermodynamics in much of science and technology, its history is finely woven with the developments of classical mechanics, quantum mechanics, magnetism, and chemical kinetics, to more distant applied fields such as meteorology, information theory, and biology (physiology), and to technological developments such as the steam engine, internal combustion engine, cryogenics and electricity generation. The development of thermodynamics both drove and was driven by atomic theory. It also, albeit in a subtle manner, motivated new directions in probability and statistics; see, for example, the timeline of thermodynamics.
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, or cause changes in electromagnetic, or gravitational variables. Also, the surroundings can perform thermodynamic work on a thermodynamic system, which is measured by an opposite sign convention.
In the history of physics, the history of energy examines the gradual development of energy as a central scientific concept. Classical mechanics was initially understood through the study of motion and force by thinkers like Galileo Galilei and Isaac Newton, the importance of the concept of energy was made clear in the 19th century with the principles of thermodynamics, particularly the conservation of energy which established that energy cannot be created or destroyed, only transformed. In the 20th century Albert Einstein's mass–energy equivalence expanded this understanding by linking mass and energy, and quantum mechanics introduced quantized energy levels. Today, energy is recognized as a fundamental conserved quantity across all domains of physics, underlying both classical and quantum phenomena.
Reflections on the Motive Power of Fire and on Machines Fitted to Develop that Power is a scientific treatise written by the French military engineer Sadi Carnot. Published in 1824 in French as Réflexions sur la puissance motrice du feu et sur les machines propres à développer cette puissance, the short book sought to advance a rational theory of heat engines. At the time, heat engines had acquired great technological and economic importance, but very little was understood about them from the point of view of physics.
In thermodynamics, heat is energy in transfer between a thermodynamic system and its surroundings by modes other than thermodynamic work and transfer of matter. Such modes are microscopic, mainly thermal conduction, radiation, and friction, as distinct from the macroscopic modes, thermodynamic work and transfer of matter. For a closed system, the heat involved in a process is the difference in internal energy between the final and initial states of a system, and subtracting the work done in the process. For a closed system, this is the formulation of the first law of thermodynamics.
