Kalina cycle

Last updated

The Kalina cycle, developed by Alexander Kalina, is a thermodynamic process for converting thermal energy into usable mechanical power.

Contents

It uses a solution of 2 fluids with different boiling points for its working fluid. Since the solution boils over a range of temperatures as in distillation, more of the heat can be extracted from the source than with a pure working fluid. The same applies on the exhaust (condensing) end. This provides efficiency comparable to a Combined cycle, with less complexity. [1]

By appropriate choice of the ratio between the components of the solution, the boiling point of the working solution can be adjusted to suit the heat input temperature. Water and ammonia is the most widely used combination, but other combinations are feasible.

Because of this ability to take full advantage of the temperature difference between the particular heat source and sink available, it finds applications in reuse of industrial process heat, geothermal energy, solar energy, and use of waste heat from power plants (Bottoming cycle). Even at lower pressure, a Kalina cycle may have higher efficiency than a comparable Rankine cycle. [2]

Kalina cycle power plants

Recoverable heat from industrial processes.

The Kalina cycle has been thought[ by whom? ] to increase thermal power output efficiencies by up to 50% in suitable installations, and is ideally suited for applications such as steel, coal, oil refineries and cement production plants.

Geothermal

Second generation

A second generation of Kalina cycle systems was developed by Kalina and Kalex LLC. These systems are technically Kalina cycles (in that they utilize multi-component working fluid with variable composition) but they do not use the "Kalina cycle" trademark. [3]

Unlike first generation Kalina cycle systems, which are applicable only for relatively low-temperature heat sources, the second generation of Kalina cycle systems is applicable to both low and relatively high temperature heat sources. [4]

For low temperature heat sources, second generation Kalina cycles are projected to attain thermal efficiencies higher than those possible with first generation cycles. [5]

Licensing

The Kalina cycle trademark and all first generation global patents that are still in force are owned by Wasabi Energy plc. owner of Global Geothermal Ltd., parent company of Recurrent Engineering Inc. [6]

Some of the original Kalina cycle patents have expired and have now entered the public domain. [7] Global Geothermal Ltd. (parent company: Wasabi Energy Ltd.) owns all the worldwide entities licensed to deploy the first generation Kalina Cycle process.[ citation needed ] As a result, GGL controls the Kalina cycle rights and over 200 international patents associated with this technology. The process is currently used via licensing deals with Siemens and Shanghai Shenge New Energy for all their Chinese applications. [8] FLSmidth has the exclusive right in most countries to offer the first generation Kalina cycle technology to the cement and lime industries. [9]

All second generation Kalina cycle patents are currently owned by Kalex LLC, a company founded by Kalina.

Related Research Articles

Ocean Thermal Energy Conversion (OTEC) is a renewable energy technology that harnesses the temperature difference between the warm surface waters of the ocean and the cold depths to produce electricity. It is a unique form of clean energy generation that has the potential to provide a consistent and sustainable source of power. Although it has challenges to overcome, OTEC has the potential to provide a consistent and sustainable source of clean energy, particularly in tropical regions with access to deep ocean water.

<span class="mw-page-title-main">Heat transfer</span> Transport of thermal energy in physical systems

Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.

<span class="mw-page-title-main">Stirling engine</span> Closed-cycle regenerative heat engine

A Stirling engine is a heat engine that is operated by the cyclic compression and expansion of air or other gas between different temperatures, resulting in a net conversion of heat energy to mechanical work.

<span class="mw-page-title-main">Combined cycle power plant</span> Assembly of heat engines that work in tandem from the same source of heat

A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas turbine (CCGT) plant. The same principle is also used for marine propulsion, where it is called a combined gas and steam (COGAS) plant. Combining two or more thermodynamic cycles improves overall efficiency, which reduces fuel costs.

<span class="mw-page-title-main">Rankine cycle</span> Model that is used to predict the performance of steam turbine systems

The Rankine cycle is an idealized thermodynamic cycle describing the process by which certain heat engines, such as steam turbines or reciprocating steam engines, allow mechanical work to be extracted from a fluid as it moves between a heat source and heat sink. The Rankine cycle is named after William John Macquorn Rankine, a Scottish polymath professor at Glasgow University.

<span class="mw-page-title-main">Geothermal heating</span> Use of geothermal energy for heating

Geothermal heating is the direct use of geothermal energy for some heating applications. Humans have taken advantage of geothermal heat this way since the Paleolithic era. Approximately seventy countries made direct use of a total of 270 PJ of geothermal heating in 2004. As of 2007, 28 GW of geothermal heating capacity is installed around the world, satisfying 0.07% of global primary energy consumption. Thermal efficiency is high since no energy conversion is needed, but capacity factors tend to be low since the heat is mostly needed in the winter.

<span class="mw-page-title-main">Supercritical carbon dioxide</span> Carbon dioxide above its critical point

Supercritical carbon dioxide is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure.

A binary cycle is a method for generating electrical power from geothermal resources and employs two separate fluid cycles, hence binary cycle. The primary cycle extracts the geothermal energy from the reservoir, and secondary cycle converts the heat into work to drive the generator and generate electricity.

<span class="mw-page-title-main">Steam-electric power station</span>

The steam-electric power station is a power station in which the electric generator is steam driven. Water is heated, turns into steam and spins a steam turbine which drives an electrical generator. After it passes through the turbine, the steam is condensed in a condenser. The greatest variation in the design of steam-electric power plants is due to the different fuel sources.

Economizers, or economisers (UK), are mechanical devices intended to reduce energy consumption, or to perform useful function such as preheating a fluid. The term economizer is used for other purposes as well. Boiler, power plant, heating, refrigeration, ventilating, and air conditioning (HVAC) uses are discussed in this article. In simple terms, an economizer is a heat exchanger.

<span class="mw-page-title-main">Turboexpander</span>

A turboexpander, also referred to as a turbo-expander or an expansion turbine, is a centrifugal or axial-flow turbine, through which a high-pressure gas is expanded to produce work that is often used to drive a compressor or generator.

<span class="mw-page-title-main">Transcritical cycle</span> Closed thermodynamic cycle involving fluid

A transcritical cycle is a closed thermodynamic cycle where the working fluid goes through both subcritical and supercritical states. In particular, for power cycles the working fluid is kept in the liquid region during the compression phase and in vapour and/or supercritical conditions during the expansion phase. The ultrasupercritical steam Rankine cycle represents a widespread transcritical cycle in the electricity generation field from fossil fuels, where water is used as working fluid. Other typical applications of transcritical cycles to the purpose of power generation are represented by organic Rankine cycles, which are especially suitable to exploit low temperature heat sources, such as geothermal energy, heat recovery applications or waste to energy plants. With respect to subcritical cycles, the transcritical cycle exploits by definition higher pressure ratios, an feature that ultimately yields higher efficiencies for the majority of the working fluids. Considering then also supercritical cycles as a valid alternative to the transcritical ones, the latter cycles are capable of achieving higher specific works due to the limited relative importance of the work of compression work. This evidences the extreme potential of transcritical cycles to the purpose of producing the most power with the least expenditure.

<span class="mw-page-title-main">Geothermal power</span> Power generated by geothermal energy

Geothermal power is electrical power generated from geothermal energy. Technologies in use include dry steam power stations, flash steam power stations and binary cycle power stations. Geothermal electricity generation is currently used in 26 countries, while geothermal heating is in use in 70 countries.

<span class="mw-page-title-main">Organic Rankine cycle</span> Variation on the Rankine thermodynamic cycle

In thermal engineering, the organic Rankine cycle (ORC) is a type of thermodynamic cycle. It is a variation of the Rankine cycle named for its use of an organic, high-molecular-mass fluid whose vaporization temperature is lower than that of water. The fluid allows heat recovery from lower-temperature sources such as biomass combustion, industrial waste heat, geothermal heat, solar ponds etc. The low-temperature heat is converted into useful work, that can itself be converted into electricity.

<span class="mw-page-title-main">Steam</span> Water in the gas phase

Steam is a substance containing water in the gas phase, and sometimes also an aerosol of liquid water droplets, or air. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization. Steam that is saturated or superheated is invisible; however, wet steam, a visible mist or aerosol of water droplets, is often referred to as "steam".

Process heat refers to the application of heat during industrial processes. Some form of process heat is used during the manufacture of many common products, from concrete to glass to steel to paper. Where byproducts or wastes of the overall industrial process are available, those are often used to provide process heat. Examples include black liquor in papermaking or bagasse in sugarcane processing.

<span class="mw-page-title-main">Photovoltaic thermal hybrid solar collector</span>

Photovoltaic thermal collectors, typically abbreviated as PVT collectors and also known as hybrid solar collectors, photovoltaic thermal solar collectors, PV/T collectors or solar cogeneration systems, are power generation technologies that convert solar radiation into usable thermal and electrical energy. PVT collectors combine photovoltaic solar cells, which convert sunlight into electricity, with a solar thermal collector, which transfers the otherwise unused waste heat from the PV module to a heat transfer fluid. By combining electricity and heat generation within the same component, these technologies can reach a higher overall efficiency than solar photovoltaic (PV) or solar thermal (T) alone.

<span class="mw-page-title-main">Hygroscopic cycle</span> Thermodynamic cycle converting thermal energy into mechanical power

The Hygroscopic cycle is a thermodynamic cycle converting thermal energy into mechanical power by the means of a steam turbine. It is similar to the Rankine cycle using water as the motive fluid but with the novelty of introducing salts and their hygroscopic properties for the condensation. The salts are desorbed in the boiler or steam generator, where clean steam is released and superheated in order to be expanded and generate power through the steam turbine. Boiler blowdown with the concentrated hygroscopic compounds is used thermally to pre-heat the steam turbine condensate, and as reflux in the steam-absorber.

In fluid thermodynamics, a heat transfer fluid is a gas or liquid that takes part in heat transfer by serving as an intermediary in cooling on one side of a process, transporting and storing thermal energy, and heating on another side of a process. Heat transfer fluids are used in countless applications and industrial processes requiring heating or cooling, typically in a closed circuit and in continuous cycles. Cooling water, for instance, cools an engine, while heating water in a hydronic heating system heats the radiator in a room.

The Allam Cycle or Allam-Fetvedt Cycle is a process for converting carbonaceous fuels into thermal energy, while capturing the generated carbon dioxide and water. This zero emissions cycle was validated at a 50 MWth natural gas fed test facility in La Porte, Texas in May 2018. This industrial plant is owned and operated by NET Power LLC, a privately held technology licensing company. NET Power is owned by Constellation Energy Corporation, Occidental Petroleum Corporation (Oxy) Low Carbon Ventures, Baker Hughes Company and 8 Rivers Capital, the company holding the patents for the technology. The key inventors behind the process are English engineer Rodney John Allam, American engineer Jeremy Eron Fetvedt, American scientist Dr. Miles R Palmer, and American businessperson and innovator G. William Brown, Jr. The Allam-Fetvedt Cycle was recognized by MIT Technology Review on the 2018 list of 10 Breakthrough Technologies.

References

  1. Overview of the Kalina cycle
  2. "Energy Analysis of Supercritical Water and Ammonia (Kalina) Power Cycle" (PDF). World Sustainability Forum. 2014.
  3. Kalina, Alexander I. (2003). New Binary Geothermal Power System (PDF). International Geothermal Workshop. Sochi, Russia: Geothermal Energy Society.
  4. "Kalina, Alexander I., United States Patent Application 20100101227, April 29, 2010".
  5. Kalina, Alexander I. (2006). "New Thermodynamic Cycles and Power Systems for Geothermal Applications" (PDF). GRC Transactions. 30: 747–750.
  6. "Web Page Under Construction".
  7. "Kalina, Alexander I., United States Patent: 4,548,043 "Method of generating energy", October 22, 1985".
  8. "Wasabi Energy/ Global Geothermal updates on Kalina licenses in Annual Report | ThinkGeoEnergy - Geothermal Energy News". 31 August 2009.
  9. FLSmidth obtains exclusive rights for Kalina Cycle® Waste Heat Recovery technology FLSmidth 20 June 2011. Retrieved 7 December 2022