A cathode is the electrode from which a conventional current leaves a polarized electrical device such as a lead-acid battery. This definition can be recalled by using the mnemonic CCD for Cathode Current Departs. A conventional current describes the direction in which positive charges move. Electrons have a negative electrical charge, so the movement of electrons is opposite to that of the conventional current flow. Consequently, the mnemonic cathode current departs also means that electrons flow into the device's cathode from the external circuit. For example, the end of a household battery marked with a + (plus) is the cathode.
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an electronically conducting phase between electrodes separated by an ionically conducting and electronically insulating electrolyte.
An electrochemical cell is a device that generates electrical energy from chemical reactions. Electrical energy can also be applied to these cells to cause chemical reactions to occur. Electrochemical cells that generate an electric current are called voltaic or galvanic cells and those that generate chemical reactions, via electrolysis for example, are called electrolytic cells.
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell. The voltage that is needed for electrolysis to occur is called the decomposition potential. The word "lysis" means to separate or break, so in terms, electrolysis would mean "breakdown via electricity."
A galvanic cell or voltaic cell, named after the scientists Luigi Galvani and Alessandro Volta, respectively, is an electrochemical cell in which an electric current is generated from spontaneous oxidation–reduction reactions. An example of a galvanic cell consists of two different metals, each immersed in separate beakers containing their respective metal ions in solution that are connected by a salt bridge or separated by a porous membrane.
In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound. The IUPAC "Gold Book" defines it as; "the value of the standard emf of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".
High-temperature electrolysis is a technology for producing hydrogen from water at high temperatures or other products, such as iron or carbon nanomaterials, as higher energy lowers needed electricity to split molecules and opens up new, potentially better electrolytes like molten salts or hydroxides. Unlike electrolysis at room temperature, HTE operates at elevated temperature ranges depending on the thermal capacity of the material. Because of the detrimental effects of burning fossil fuels on humans and the environment, HTE has become a necessary alternative and efficient method by which hydrogen can be prepared on a large scale and used as fuel. The vision of HTE is to move towards decarbonization in all economic sectors. The material requirements for this process are: the heat source, the electrodes, the electrolyte, the electrolyzer membrane, and the source of electricity.
An atomic battery, nuclear battery, radioisotope battery or radioisotope generator uses energy from the decay of a radioactive isotope to generate electricity. Like a nuclear reactor, it generates electricity from nuclear energy, but it differs by not using a chain reaction. Although commonly called batteries, atomic batteries are technically not electrochemical and cannot be charged or recharged. Although they are very costly, they have extremely long lives and high energy density, so they are typically used as power sources for equipment that must operate unattended for long periods, such as spacecraft, pacemakers, underwater systems, and automated scientific stations in remote parts of the world.
Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen:
A dye-sensitized solar cell is a low-cost solar cell belonging to the group of thin film solar cells. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, a photoelectrochemical system. The modern version of a dye solar cell, also known as the Grätzel cell, was originally co-invented in 1988 by Brian O'Regan and Michael Grätzel at UC Berkeley and this work was later developed by the aforementioned scientists at the École Polytechnique Fédérale de Lausanne (EPFL) until the publication of the first high efficiency DSSC in 1991. Michael Grätzel has been awarded the 2010 Millennium Technology Prize for this invention.
The photovoltaic effect is the generation of voltage and electric current in a material upon exposure to light. It is a physical phenomenon.
Thermophotovoltaic (TPV) energy conversion is a direct conversion process from heat to electricity via photons. A basic thermophotovoltaic system consists of a hot object emitting thermal radiation and a photovoltaic cell similar to a solar cell but tuned to the spectrum being emitted from the hot object.
In electrochemistry, overpotential is the potential difference (voltage) between a half-reaction's thermodynamically determined reduction potential and the potential at which the redox event is experimentally observed. The term is directly related to a cell's voltage efficiency. In an electrolytic cell the existence of overpotential implies that the cell requires more energy than thermodynamically expected to drive a reaction. In a galvanic cell the existence of overpotential means less energy is recovered than thermodynamics predicts. In each case the extra/missing energy is lost as heat. The quantity of overpotential is specific to each cell design and varies across cells and operational conditions, even for the same reaction. Overpotential is experimentally determined by measuring the potential at which a given current density is achieved.
An alkali-metal thermal-to-electric converter is a thermally regenerative electrochemical device for the direct conversion of heat to electrical energy. It is characterized by high potential efficiencies and no moving parts except for the working fluid, which make it a candidate for space power applications.
In battery technology, a concentration cell is a limited form of a galvanic cell that has two equivalent half-cells of the same composition differing only in concentrations. One can calculate the potential developed by such a cell using the Nernst equation. A concentration cell produces a small voltage as it attempts to reach chemical equilibrium, which occurs when the concentration of reactant in both half-cells are equal. Because an order of magnitude concentration difference produces less than 60 millivolts at room temperature, concentration cells are not typically used for energy storage.
A thermoelectric generator (TEG), also called a Seebeck generator, is a solid state device that converts heat directly into electrical energy through a phenomenon called the Seebeck effect. Thermoelectric generators function like heat engines, but are less bulky and have no moving parts. However, TEGs are typically more expensive and less efficient. When the same principle is used in reverse to create a heat gradient from an electric current, it is called a thermoelectric cooler.
Thermophotonics is a concept for generating usable power from heat which shares some features of thermophotovoltaic (TPV) power generation. Thermophotonics was first publicly proposed by solar photovoltaic researcher Martin Green in 2000. However, no TPX device is known to have been demonstrated to date, apparently because of the stringent requirement on the emitter efficiency.
The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few.
A Johnson thermoelectric energy converter or JTEC is a type of solid-state heat engine that uses the electrochemical oxidation and reduction of hydrogen in a two-cell, thermal cycle that approximates the Ericsson cycle. It is under investigation as a viable alternative to conventional thermoelectric conversion. Lonnie Johnson invented it and claims the converter exhibits an energy conversion efficiency of as much as 60%, however, this claim is at a theoretical level based on comparison with a Carnot cycle and assumes a temperature gradient of 600 °C. It was originally proposed for funding to the Office of Naval Research but was refused. Johnson obtained later funding by framing the engine as a hydrogen fuel cell. Johnson had been collaborating with PARC on development of the engine.
A thermoelectric battery stores energy when charged by converting heat into chemical energy and produces electricity when discharged. Such systems potentially offer an alternative means of disposing of waste heat from plants that burn fossil fuels and/or nuclear energy.
