Rechargeable alkaline battery

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Rechargeable alkaline battery
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Rechargeable Alkaline AA battery
Self-discharge rate<1%/month at 20 °C [1] [2]
Cycle durability25 cycles (deep), 500+ shallow [3] [2]
Nominal cell voltage1.5 V

A rechargeable alkaline battery, also known as alkaline rechargeable or rechargeable alkaline manganese (RAM), is a type of alkaline battery that is capable of recharging for repeated use. The formats include AAA, AA, C, D, and snap-on 9-volt batteries. Rechargeable alkaline batteries are manufactured fully charged and have the ability to hold their charge for years, longer than nickel-cadmium and nickel-metal hydride batteries, which self-discharge. [4] Rechargeable alkaline batteries can have a high recharging efficiency and have less environmental impact than disposable cells.

Contents

History

The first generation rechargeable alkaline batteries were introduced by Union Carbide and Mallory in the early 1970s. [3] [5] Several patents were introduced after Union Carbide's product discontinuation and eventually, in 1986, Battery Technologies Inc of Canada was founded to commercially develop a 2nd generation product based on those patents, under the trademark "RAM". Their first product to be licensed out and sold commercially was to Rayovac under the trademark "Renewal". [6] The next year, "Pure Energy" batteries were released by Pure Energy. After the Renewals were reformulated to be mercury-free in 1995, subsequent licensed RAM alkalines were mercury-free and included ALCAVA, AccuCell, Grandcell and EnviroCell. [3] Subsequent patent and advancements in technology have been introduced.

Construction of rechargeable cells

Rechargeable alkaline cells are constructed very similarly to disposable alkaline cells. A cathode paste is pressed into a steel can that forms the positive terminal of the battery. The negative electrode consists of zinc powder suspended in a gel, with a steel nail contact that runs to the base of the cell to form the negative terminal. Features of the rechargeable alkaline that differ from a disposable alkaline cell include:

The cells are manufactured in the charged state, ready to use.

Charge behavior

Although these batteries can be used in any device that supports a standard size (AA, AAA, C, D, etc.), they are formulated to last longest in periodical use items. This type of battery is better suited for use in low-drain devices such as remote controls or for devices that are used periodically such as flashlights, television remote control handsets, portable radios, etc. If they are discharged by less than 25%, they can be recharged for hundreds of cycles to about 1.42 V. If they are discharged by less than 50%, they can be almost fully recharged for a few dozen cycles, to about 1.32 V. After a deep discharge, they can be brought to their original high-capacity charge only after a few charge-discharge cycles.

Recharging of disposable alkalines

Manufacturers do not support recharging of disposable alkaline batteries, and warn that it may be dangerous. [7] Despite this advice, alkaline batteries have been recharged, and chargers have been available. [8] [9] The capacity of a recharged alkaline battery declines with number of recharges, until it becomes unusable after typically about ten cycles. Low-ripple direct current is not suitable for charging disposable alkaline batteries; more suitable is a current pulsed at a rate of 40 to 200 pulses per second, with an 80% duty cycle. Pulsed charging appears to reduce the risk of electrolyte—usually potassium hydroxide (KOH)—leakage. The charging current must be low to prevent rapid production of gases that can rupture the cell. Cells that have leaked electrolyte are unsafe and unsuitable for reuse. Fully discharged cells recharge less successfully than only partly depleted cells, particularly if they have been stored in a discharged state—battery charger manufacturers do not claim to recharge dead cells. [9]

Attempting to recharge a discharged alkaline battery can cause the production of gas within the sealed canister; pressure generated by rapid accumulation of gas can open the pressure-relief seal and cause leakage of electrolyte. Potassium hydroxide in the electrolyte is corrosive and may cause injury and damage, particularly corroding the battery contacts[ citation needed ] in the equipment.

As an alkaline battery is discharged, chemicals inside the battery react to create an electric current. As the chemicals are used up and the products of the reaction accumulate, eventually the battery is no longer able to deliver adequate current, and the battery is depleted. By driving a current through the battery in the reverse direction, the equilibrium can be shifted back towards the original reactants. Different batteries rely on different chemical reactions. Some reactions are readily reversible, some are not. The reactions used in most alkaline batteries fall into the latter category. In particular, the metallic zinc generated by driving a reverse current through the cell will generally not return to its original location in the cell, and may form crystals that damage the separator layer between battery anode and electrolyte.[ citation needed ]

Comparison to other rechargeable batteries

The rechargeable alkaline battery was, at one time, cheaper than other rechargeable types. [4] Cells can be manufactured in the fully charged state and retain capacity well. Their capacity is about 2/3 that of primary cells. They are of dry-cell construction, completely sealed and not requiring maintenance. Cells have a limited cycle life, which is affected by deep discharge; the first cycle gives the greatest capacity, and if deeply discharged a cell may provide only 20 cycles. The available energy on each cycle decreases. Like primary alkaline cells, they have a relatively high internal resistance, making them unsuitable for high discharge current (for example, discharging their full capacity in one hour).

Unlike rechargeable alkaline batteries, NiMH batteries can endure anywhere from a few hundred to a thousand (or more) deep discharge cycles, resulting in a long useful life; their limitation is now more usually by age rather than cycles. [10] Capacity of NiMH batteries is close to that of alkaline batteries. [10] Unlike all alkaline batteries (rechargeable or otherwise), internal resistance is low. This makes them well suited for high current capacity applications. [10] Self-discharge rates are comparable, at least up to six months. [10]

Rechargeable alkaline batteries produce a voltage of about 1.5V, compared with NiCd and NiMH batteries which produce about 1.2V. For some applications, this can make a significant difference. In cases where resistance is not strongly dependent on voltage or current, since power varies as the square of voltage, rechargeable alkaline batteries provide about 50% more power. For example, incandescent lamps are much brighter when powered by rechargeable alkaline than by NiCd or NiMH batteries.

Environmental notes

Rechargeable alkaline batteries are developed from primary alkaline batteries, designed to resist leakage that a recharge could cause, so they can be safely recharged many times.

According to the websites of EnviroCell, [11] PureEnergy and old Rayovac packaging, these manufacturers' rechargeable alkaline batteries have no mercury or cadmium.

See also

Related Research Articles

<span class="mw-page-title-main">Nickel–metal hydride battery</span> Type of rechargeable battery

A nickel metal hydride battery is a type of rechargeable battery. The chemical reaction at the positive electrode is similar to that of the nickel–cadmium cell (NiCd), with both using nickel oxide hydroxide (NiOOH). However, the negative electrodes use a hydrogen-absorbing alloy instead of cadmium. NiMH batteries can have two to three times the capacity of NiCd batteries of the same size, with significantly higher energy density, although much less than lithium-ion batteries.

<span class="mw-page-title-main">Nickel–cadmium battery</span> Type of rechargeable battery

The nickel-cadmium battery is a type of rechargeable battery using nickel oxide hydroxide and metallic cadmium as electrodes. The abbreviation Ni-Cd is derived from the chemical symbols of nickel (Ni) and cadmium (Cd): the abbreviation NiCad is a registered trademark of SAFT Corporation, although this brand name is commonly used to describe all Ni-Cd batteries.

<span class="mw-page-title-main">Lithium-ion battery</span> Rechargeable battery type

A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. The negative electrode of a conventional lithium-ion cell is typically graphite, a form of carbon. This negative electrode is sometimes called the anode as it acts as an anode during discharge. The positive electrode is typically a metal oxide; the positive electrode is sometimes called the cathode as it acts as a cathode during discharge. Positive and negative electrodes remain positive and negative in normal use whether charging or discharging and are therefore clearer terms to use than anode and cathode which are reversed during charging.

<span class="mw-page-title-main">Rechargeable battery</span> Type of electrical battery

A rechargeable battery, storage battery, or secondary cell, is a type of electrical battery which can be charged, discharged into a load, and recharged many times, as opposed to a disposable or primary battery, which is supplied fully charged and discarded after use. It is composed of one or more electrochemical cells. The term "accumulator" is used as it accumulates and stores energy through a reversible electrochemical reaction. Rechargeable batteries are produced in many different shapes and sizes, ranging from button cells to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of electrode materials and electrolytes are used, including lead–acid, zinc–air, nickel–cadmium (NiCd), nickel–metal hydride (NiMH), lithium-ion (Li-ion), lithium iron phosphate (LiFePO4), and lithium-ion polymer.

<span class="mw-page-title-main">Alkaline battery</span> Type of battery

An alkaline battery is a type of primary battery where the electrolyte has a pH value above 7. Typically these batteries derive energy from the reaction between zinc metal and manganese dioxide, nickel and cadmium, or nickel and hydrogen.

A primary battery or primary cell is a battery that is designed to be used once and discarded, and not recharged with electricity and reused like a secondary cell. In general, the electrochemical reaction occurring in the cell is not reversible, rendering the cell unrechargeable. As a primary cell is used, chemical reactions in the battery use up the chemicals that generate the power; when they are gone, the battery stops producing electricity. In contrast, in a secondary cell, the reaction can be reversed by running a current into the cell with a battery charger to recharge it, regenerating the chemical reactants. Primary cells are made in a range of standard sizes to power small household appliances such as flashlights and portable radios.

<span class="mw-page-title-main">Dry cell</span> Electric battery type

A dry cell is a type of electric battery, commonly used for portable electrical devices. Unlike wet cell batteries, which have a liquid electrolyte, dry cells use an electrolyte in the form of a paste, and are thus less susceptible to leakage.

<span class="mw-page-title-main">AA battery</span> Standardized type of battery

The AA battery is a standard size single cell cylindrical dry battery. The IEC 60086 system calls the size R6, and ANSI C18 calls it 15. It is named UM-3 by JIS of Japan. Historically, it is known as D14, U12 – later U7, or HP7 in official documentation in the United Kingdom, or a pen cell.

<span class="mw-page-title-main">Zinc–air battery</span> High-electrical energy density storage device

Zinc–air batteries (non-rechargeable), and zinc–air fuel cells are metal–air batteries powered by oxidizing zinc with oxygen from the air. These batteries have high energy densities and are relatively inexpensive to produce. Sizes range from very small button cells for hearing aids, larger batteries used in film cameras that previously used mercury batteries, to very large batteries used for electric vehicle propulsion and grid-scale energy storage.

<span class="mw-page-title-main">Zinc–carbon battery</span> Type of dry cell battery

A zinc–carbon battery (or carbon zinc battery in U.S. English) is a dry cell primary battery that provides direct electric current from the electrochemical reaction between zinc (Zn) and manganese dioxide (MnO2) in the presence of an ammonium chloride (NH4Cl) electrolyte. It produces a voltage of about 1.5 volts between the zinc anode, which is typically constructed as a cylindrical container for the battery cell, and a carbon rod surrounded by a compound with a higher Standard electrode potential (positive polarity), known as the cathode, that collects the current from the manganese dioxide electrode. The name "zinc-carbon" is slightly misleading as it implies that carbon is acting as the oxidizing agent rather than the manganese dioxide.

<span class="mw-page-title-main">Nine-volt battery</span> Form of small battery

The nine-volt battery, or 9-volt battery, is an electric battery that supplies a nominal voltage of 9 volts. Actual voltage measures 7.2 to 9.6 volts, depending on battery chemistry. Batteries of various sizes and capacities are manufactured; a very common size is known as PP3, introduced for early transistor radios. The PP3 has a rectangular prism shape with rounded edges and two polarized snap connectors on the top. This type is commonly used for many applications including household uses such as smoke and gas detectors, clocks, and toys.

<span class="mw-page-title-main">Mercury battery</span>

A mercury battery is a non-rechargeable electrochemical battery, a primary cell. Mercury batteries use a reaction between mercuric oxide and zinc electrodes in an alkaline electrolyte. The voltage during discharge remains practically constant at 1.35 volts, and the capacity is much greater than that of a similarly sized zinc-carbon battery. Mercury batteries were used in the shape of button cells for watches, hearing aids, cameras and calculators, and in larger forms for other applications.

<span class="mw-page-title-main">Nickel–zinc battery</span> Type of rechargeable battery

A nickel–zinc battery, abbreviated NiZn, is a type of rechargeable battery similar to NiCd batteries, but with a higher voltage of 1.6 V.

<span class="mw-page-title-main">Button cell</span> Small battery

A button cell, watch battery, or coin battery is a small single-cell battery shaped as a squat cylinder typically 5 to 25 mm in diameter and 1 to 6 mm high — resembling a button. Stainless steel usually forms the bottom body and positive terminal of the cell; insulated from it, the metallic top cap forms the negative terminal.

Aluminium–air batteries produce electricity from the reaction of oxygen in the air with aluminium. They have one of the highest energy densities of all batteries, but they are not widely used because of problems with high anode cost and byproduct removal when using traditional electrolytes. This has restricted their use to mainly military applications. However, an electric vehicle with aluminium batteries has the potential for up to eight times the range of a lithium-ion battery with a significantly lower total weight.

<span class="mw-page-title-main">History of the battery</span> History of electricity source

Batteries provided the primary source of electricity before the development of electric generators and electrical grids around the end of the 19th century. Successive improvements in battery technology facilitated major electrical advances, from early scientific studies to the rise of telegraphs and telephones, eventually leading to portable computers, mobile phones, electric cars, and many other electrical devices.

<span class="mw-page-title-main">Nickel–hydrogen battery</span>

A nickel–hydrogen battery (NiH2 or Ni–H2) is a rechargeable electrochemical power source based on nickel and hydrogen. It differs from a nickel–metal hydride (NiMH) battery by the use of hydrogen in gaseous form, stored in a pressurized cell at up to 1200 psi (82.7 bar) pressure. The nickel–hydrogen battery was patented on February 25, 1971 by Alexandr Ilich Kloss and Boris Ioselevich Tsenter in the United States.

<span class="mw-page-title-main">Electric battery</span> Power source with electrochemical cells

A battery is a source of electric power consisting of one or more electrochemical cells with external connections for powering electrical devices. When a battery is supplying power, its positive terminal is the cathode and its negative terminal is the anode. The terminal marked negative is the source of electrons that will flow through an external electric circuit to the positive terminal. When a battery is connected to an external electric load, a redox reaction converts high-energy reactants to lower-energy products, and the free-energy difference is delivered to the external circuit as electrical energy. Historically the term "battery" specifically referred to a device composed of multiple cells; however, the usage has evolved to include devices composed of a single cell.

<span class="mw-page-title-main">Nickel oxyhydroxide battery</span>

Nickel oxyhydroxide battery is a type of primary cell. It is not rechargeable and must be disposed after a single use. NiOx batteries can be used in high-drain applications such as digital cameras.

The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.

References

  1. "Rechargeable Batteries — compared and explained in detail" . Retrieved 2016-02-28.
  2. 1 2 "Data Sheet of Pure Energy XL Rechargeable Alkaline Cells, AAA" (PDF). Retrieved 2016-03-01. (AA cell)
  3. 1 2 3 Daniel-Ivad, J.; Kordesch, K. (3 April 2002). "Rechargeable Alkaline Manganese Technology: Past-Present-Future" (PDF). Electrochemical Society . Retrieved 28 August 2020.
  4. 1 2 3 David Linden, Thomas Reddy (ed.), "Handbook of Batteries Third Edition", McGraw Hill, 2002 ISBN   0-07-135978-8 chapter 36 Rechargeable zinc/alkaline/manganese dioxide batteries
  5. C. R. Lewart (Autumn–Winter 1975). "Supercharger" (PDF). World Radio History / Electronics Hobbyist: 46. Retrieved 28 August 2020.
  6. "Reusable Alkaline Battery From Rayovac (2007)" (PDF). Archived from the original (PDF) on August 31, 2017. Retrieved May 11, 2022.
  7. Duracell disposable alkaline cells are marked "Do not charge ... Battery may explode or leak."
  8. "Battery Wizard". Gizoo. Archived from the original on April 29, 2014. Retrieved May 11, 2022.
  9. 1 2 It was tested by discharging batteries until completely dead, and recharging them successfully, to a lower capacity than the original capacity, a few times. Other chargers warn that they "will revive partially discharged batteries", but "will not restore completely dead" ones.
  10. 1 2 3 4 "Nickel Metal Hydride" (PDF). Energizer Battery Manufacturing Inc.
  11. "Envirocell Alkaline Rechargeable Batteries". Envirocell. Archived from the original on February 25, 2010. Retrieved May 11, 2022.