Nine-volt battery

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Vintage PP3-size 9-volt batteries Vintage 9 Volt Transistor Radio Batteries, Made In Japan, USA, Great Britain, Taiwan And Hong Kong (34634957785).jpg
Vintage PP3-size 9-volt batteries
Size comparison of batteries: D, C, AA, AAA, AAAA, 9-volt (PP3) 6 most common battery types-1.jpg
Size comparison of batteries: D, C, AA, AAA, AAAA, 9-volt (PP3)

The nine-volt battery, or 9-volt battery, is an electric battery that supplies a nominal voltage of 9 volts. Actual voltage measures 7.2 to 9.6 volts, depending on battery chemistry. Batteries of various sizes and capacities are manufactured; a very common size is known as PP3, introduced for early transistor radios. The PP3 has a rectangular prism shape with rounded edges and two polarized snap connectors on the top. This type is commonly used for many applications including household uses such as smoke and gas detectors, clocks, and toys. [1]

Contents

The nine-volt PP3-size battery is commonly available in primary zinc–carbon and alkaline chemistry, in primary lithium iron disulfide and lithium manganese dioxide (sometimes designated CRV9 [2] ), and in rechargeable form in nickel–cadmium (Ni–Cd), nickel–metal hydride (Ni–MH) and lithium-ion. Mercury batteries of this format, once common, have been banned in many countries due to their toxicity. [3] Designations for this format include NEDA 1604 and IEC 6F22 (for zinc-carbon) or MN1604 6LR61 (for alkaline). The size, regardless of chemistry, is commonly designated PP3—a designation originally reserved solely for carbon-zinc, or in some countries, E or E-block. [4] A range of PP batteries was produced in the past, with voltages of 4.5, 6, and 9 volts and different capacities; the larger 9-volt PP6, PP7, and PP9 are still available. A few other 9-volt battery sizes are available: A10 and A29. [2]

Most PP3-size alkaline batteries are constructed of six individual cylindrical 1.5 V LR61 cells enclosed in a wrapper. [5] These cells are slightly smaller than LR8D425 AAAA cells and can be used in their place for some devices, even though they are 3.5 mm shorter. Carbon-zinc types are made with six flat cells in a stack, enclosed in a moisture-resistant wrapper to prevent drying. Primary lithium types are made with three cells in series. [6]

9-volt batteries accounted for 4% of alkaline primary battery sales in the United States in 2007, and 2% of primary battery sales and 2% of secondary (rechargeable) battery sales in Switzerland in 2008. [7] [8]

History

PP (power pack) battery family from left to right: PP1, PP3, PP4, PP6, PP7, PP8, PP9, PP10, PP11 PP series batteries.JPG
PP (power pack) battery family from left to right: PP1, PP3, PP4, PP6, PP7, PP8, PP9, PP10, PP11

Historically, the now-popular PP3 battery size was a member of the power pack (PP) battery family that was originally manufactured by Ever Ready in the United Kingdom and Eveready in the United States. The company says that it introduced the PP3 battery in 1956. [9] In the 1940s, 1950s, and 1960s, they were commonly marketed as transistor radio batteries, or TR for short (meant to emulate the function of the old B battery). The PP3 battery was added as an ANSI standard in 1959, currently known as ANSI-1604A. [10]

Power pack (PP) battery family
NameVoltage Capacity DepthWidthHeight
PP16 volt4 Ah55.6 mm65.1 mm55.6 mm
PP39 volt0.5 Ah17.5 mm26.5 mm48.5 mm
PP49 volt0.9 AhDia. 25.8 mm, length: 49.8 mm; 41.5 mm ex. contacts
PP69 volt1 Ah34.1 mm35.7 mm69.9 mm
PP79 volt2.5 Ah46 mm46 mm63 mm
PP86 volt15 Ah55 mm61 mm200 mm
PP99 volt5 Ah51.5 mm65 mm80 mm
PP109 volt15 Ah66 mm65 mm267 mm
PP114.5 volt × 25 Ah51.5 mm65 mm91 mm

The PP11 consists of two isolated 4.5-volt batteries with four terminals.

Only the PP3, PP6, PP7 and PP9 sizes are still manufactured, with the PP3 being extremely common. Modern batteries have higher capacities and lower internal resistances than early versions.[ citation needed ]

Before the mid-1950s, in the days of vacuum tube (valve) radios used batteries designed specifically for vacuum tubes, there was a nine-volt grid bias battery or (US) "C" battery, which had taps for various voltages from 1.5 to 9 volts.

Early transistorized radios and other equipment needed a suitable voltage miniature battery. Early transistor radios required a 22+12-volt battery. Although the transistors would theoretically operate from lower voltages, the point-contact transistors used in 1954 had to be operated very close to the collector-base junction voltage (VCBO) limit in order to get the required frequency response. However, a suitable miniature battery was already marketed for (vacuum tube) hearing aids.[ citation needed ]

The PP3 (physically identical to 6LR61 and 1604A) appeared when portable transistor radios became common, and was referred to as a transistor battery or transistor-radio battery. [11] [12]

PP3 connectors

Nine-volt battery snap 9 volt Battery Snap.jpg
Nine-volt battery snap

The PP3 battery has both terminals in a snap connector on one end. The smaller circular (male) terminal is positive, and the larger hexagonal or octagonal (female) terminal is the negative contact. The connectors on the battery are the same as on the load device; the smaller one connects to the larger one. [5] The same snap-style connector is used on other battery types in the PP series. Battery polarization is normally obvious, since mechanical connection is usually only possible in one configuration.

A problem with this type of connector is that two loose batteries with terminals exposed can touch and short circuit, discharging them, and generating heat and possibly a fire. [1] Keeping nine-volt batteries in their packaging until use helps to avoid accidental discharge. [13]

Technical specifications

9V innards 3 different cells.jpg
Three different kinds of 9-volt primary battery internals: rectangular cell zinc-carbon (6F22), rectangular cell alkaline (6LP3146), and cylindrical cell alkaline (6LR61)
9V-NiMH-opened-battery.jpg
Rechargeable (NiMH) 9-volt battery internals (stacked, 6HF~8/~22/~17) [lower-alpha 1]

Very often, a "9-volt" battery refers to the transistor radio size called PP3 or IEC 6F22 or NEDA 1604, although there are less common nine-volt batteries of different sizes.[ citation needed ]

Batteries of all types are manufactured in consumer and industrial grades. Costlier industrial-grade batteries may use chemistries that provide higher power-to-size ratio, have lower self-discharge and hence longer life when not in use, more resistance to leakage and, for example, ability to handle the high temperature and humidity associated with medical autoclave sterilization. [14]

Type [lower-alpha 2] IEC
name [lower-alpha 3] [15]
ANSI/NEDA
name [16]
Typical capacity
(mAh)
Typical capacity (Wh)Nominal
voltages
Primary
(disposable)
Alkaline, six-cylinder6LR611604A5504.959
Alkaline, six-stack6LP3146 [17] 1604A5504.959
Zinc–carbon 6F221604D4003.69
Lithium (varies)1604LC [lower-alpha 4] 120010.89
Rechargeable Ni–Cd 6KR61116041200.864, 1.0087.2, 8.4
Ni–MH 6HR617.2H5175–3001.26-2.16, 1.47-2.52, 1.68-2.88,7.2, 8.4, 9.6
Lithium polymer (varies)5203.8487.4
Lithium-ion (varies)6204.5887.4
Lithium iron phosphate 200–3201.92-3.0729.6

Testing and charging

Battery chargers are devices that charge batteries, some of which may also be able to charge nine-volt batteries. Whether a charger can charge the battery depends largely on the dimensions of the battery and internal chemistry (I.E., disposable batteries cannot be charged).

Testing a nine-volt battery can be done using a multi-meter by probing the voltage across the two terminals. The voltage measured by the multi-meter can then be used to roughly assess the charge of the battery.

If the positive and negative terminals of the battery are close enough, licking a nine-volt battery can be a quick test to check if a battery has any charge left. A tingling sensation can be felt across the tongue depending on the voltage of the battery; The higher the current flowing through the tongue the more intense the tingling sensation. Although largely safe, some people may find the tingling sensation unpleasant. [18]

Lithium

Lithium 9-volt batteries are disposable high-energy-density batteries. In the PP3 size they are typically rated at 0.8–1.2 Ah (e.g. >1.2 Ah @ 900 ohms to 5.4 V @ 23 °C for one type), [19] about twice the capacity of alkaline batteries. Some manufacturers claim the energy density can be five times that of alkaline. [19] Common applications for lithium nine-volt batteries are smoke and carbon monoxide detectors. [6]

See also

Notes

  1. Presumed cell size
  2. Some types are not found in a battery nomenclature, hence N/A.
  3. The granularity of IEC nomenclature means that each cell may have more than one match. This is partially due to the chemistry types being open to interpretation (especially for lithium cells) and partially due to the possibility of different geometric constructions (e.g. stacked versus cylinder). For example, the NiMH code listed in the table (6HR61) assumes a cylindrical geometry and would not apply to the pictured NiMH cell.
  4. There is a similar issue in "lithium" being vague here. The example gives LC, the three-volt Li–MnO2 system. Alternatively six 1.6-volt Li–FeS2 cells may be used, giving 1604LF (or 6FR61 in IEC).

Related Research Articles

<span class="mw-page-title-main">Volt</span> SI derived unit of voltage

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<span class="mw-page-title-main">Nickel–metal hydride battery</span> Type of rechargeable battery

A nickel–metal hydride battery is a type of rechargeable battery. The chemical reaction at the positive electrode is similar to that of the nickel–cadmium cell (NiCd), with both using nickel oxide hydroxide (NiOOH). However, the negative electrodes use a hydrogen-absorbing alloy instead of cadmium. NiMH batteries can have two to three times the capacity of NiCd batteries of the same size, with significantly higher energy density, although only about half that of lithium-ion batteries.

<span class="mw-page-title-main">Nickel–cadmium battery</span> Type of rechargeable battery

The nickel–cadmium battery is a type of rechargeable battery using nickel oxide hydroxide and metallic cadmium as electrodes. The abbreviation Ni–Cd is derived from the chemical symbols of nickel (Ni) and cadmium (Cd): the abbreviation NiCad is a registered trademark of SAFT Corporation, although this brand name is commonly used to describe all Ni–Cd batteries.

<span class="mw-page-title-main">Rechargeable battery</span> Type of electrical battery

A rechargeable battery, storage battery, or secondary cell, is a type of electrical battery which can be charged, discharged into a load, and recharged many times, as opposed to a disposable or primary battery, which is supplied fully charged and discarded after use. It is composed of one or more electrochemical cells. The term "accumulator" is used as it accumulates and stores energy through a reversible electrochemical reaction. Rechargeable batteries are produced in many different shapes and sizes, ranging from button cells to megawatt systems connected to stabilize an electrical distribution network. Several different combinations of electrode materials and electrolytes are used, including lead–acid, zinc–air, nickel–cadmium (NiCd), nickel–metal hydride (NiMH), lithium-ion (Li-ion), lithium iron phosphate (LiFePO4), and lithium-ion polymer.

<span class="mw-page-title-main">Alkaline battery</span> Type of electrical cell

An alkaline battery is a type of primary battery where the electrolyte has a pH value above 7. Typically these batteries derive energy from the reaction between zinc metal and manganese dioxide.

<span class="mw-page-title-main">AAA battery</span> Standard size of dry cell battery

The AAA battery is a standard size of dry cell battery. One or more AAA batteries are commonly used in low-drain portable electronic devices. A zinc–carbon battery in this size is designated by IEC as R03, by ANSI C18.1 as 24, by old JIS standard as UM-4, and by other manufacturer and national standard designations that vary depending on the cell chemistry. The size was first introduced by The American Ever Ready Company in 1911. In China, they are called #7 batteries, the name originating from the Burgess Battery Company designating his AAA batteries "Number 7".

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The AA battery is a standard size single cell cylindrical dry battery. The IEC 60086 system calls the size R6, and ANSI C18 calls it 15. It is named UM-3 by JIS of Japan. Historically, it is known as D14, U12 – later U7, or HP7 in official documentation in the United Kingdom, or a pen cell.

<span class="mw-page-title-main">D battery</span> Standard battery size

A D battery is a standardized size of a dry cell. A D cell is cylindrical with an electrical contact at each end; the positive end has a nub or bump. D cells are typically used in high current drain applications, such as in large flashlights, radio receivers, and transmitters, and other devices that require an extended running time. A D cell may be either rechargeable or non-rechargeable. Its terminal voltage and capacity depend upon its cell chemistry.

<span class="mw-page-title-main">C battery</span> Standard size of dry cell battery

The C battery is a standard size of dry cell battery typically used in medium-drain applications such as toys, flashlights, and musical instruments.

<span class="mw-page-title-main">Zinc–carbon battery</span> Type of dry cell battery

A zinc–carbon battery (or carbon zinc battery in U.S. English) is a dry cell primary battery that provides direct electric current from the electrochemical reaction between zinc (Zn) and manganese dioxide (MnO2) in the presence of an ammonium chloride (NH4Cl) electrolyte. It produces a voltage of about 1.5 volts between the zinc anode, which is typically constructed as a cylindrical container for the battery cell, and a carbon rod surrounded by a compound with a higher Standard electrode potential (positive polarity), known as the cathode, that collects the current from the manganese dioxide electrode. The name "zinc-carbon" is slightly misleading as it implies that carbon is acting as the oxidizing agent rather than the manganese dioxide.

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A rechargeable alkaline battery, also known as alkaline rechargeable or rechargeable alkaline manganese (RAM), is a type of alkaline battery that is capable of recharging for repeated use. The formats include AAA, AA, C, D, and snap-on 9-volt batteries. Rechargeable alkaline batteries are manufactured fully charged and have the ability to hold their charge for years, longer than nickel-cadmium and nickel-metal hydride batteries, which self-discharge. Rechargeable alkaline batteries can have a high recharging efficiency and have less environmental impact than disposable cells.

<span class="mw-page-title-main">Button cell</span> Small battery

A button cell, watch battery, or coin battery is a small battery made of a single electrochemical cell and shaped as a squat cylinder typically 5 to 25 mm in diameter and 1 to 6 mm high – resembling a button. Stainless steel usually forms the bottom body and positive terminal of the cell; insulated from it, the metallic top cap forms the negative terminal.

<span class="mw-page-title-main">CR-V3 battery</span>

A CR-V3 battery is a type of disposable high-capacity 3-volt battery used in various electronic appliances, including some digital cameras. It has the shape and size of two side-by-side AA batteries. This allows CR-V3 batteries to function in many devices originally designed for only AA batteries. An RCR-V3 battery is a rechargeable 3.7 V lithium-ion battery.

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<span class="mw-page-title-main">Electric battery</span> Power source with electrochemical cells

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<span class="mw-page-title-main">Nickel oxyhydroxide battery</span>

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Standard battery nomenclature describes portable dry cell batteries that have physical dimensions and electrical characteristics interchangeable between manufacturers. The long history of disposable dry cells means that many manufacturer-specific and national standards were used to designate sizes, long before international standards were reached. Technical standards for battery sizes and types are set by standards organizations such as International Electrotechnical Commission (IEC) and American National Standards Institute (ANSI). Popular sizes are still referred to by old standard or manufacturer designations, and some non-systematic designations have been included in current international standards due to wide use.

References

  1. 1 2 "9-Volt Battery Safety". National Fire Protection Association. 2016. Archived (PDF) from the original on 2016-07-27. Retrieved 2022-05-01.
  2. 1 2 "Non-Rechargeable Batteries (filtered for 9V)". CPC Farnell. Retrieved 2022-04-22. 9-volt batteries supplied by a typical distributor: PP3 (or CRV9), PP6, PP7, and PP9 are the PP sizes; A10 and A29 the only other 9v types.
  3. Hunter, Rod; Muylle, Koen J., eds. (1999). European Community Deskbook. An ELI deskbook - ELR - The Environmental Law Reporter. Environmental Law Institute. p. 75. ISBN   0-911937-82-X.
  4. "AP300 NiMH 9 Volt 300mAh". AccuPower. Archived from the original on 2018-02-06. Retrieved 6 February 2018.
  5. 1 2 IEC 60086-2-2011 §7.6.1.12
  6. 1 2 Lee, Arthur (2002-06-28). "Preliminary Test Results on Lithium Batteries Used in Residential Smoke Alarms" (PDF). CPSC.gov. U.S. Consumer Product Safety Commission. Archived from the original (PDF) on 2017-02-23. Retrieved 2022-07-24.
  7. "Life Cycle Impacts of Alkaline Batteries with a Focus on End-of-Life" (PDF). EPBAEurope.net. EPBA-EU. Archived from the original (PDF) on 2016-03-03.
  8. "INOBAT 2008 Statistics" (PDF). INOBAT.ch. Archived from the original (PDF) on 2012-03-25.
  9. "Battery History". Energizer. Retrieved 2018-02-16.
  10. "Product Datasheet: Energizer 522" (PDF). Energizer. 2019-10-25. Retrieved 2022-03-26.
  11. "Transistor Battery 9 Volts 1604-1". RadioMuseum.org. Retrieved 2023-03-03.
  12. "Transistor Radio Battery 9V 6F22". RadioMuseum.org. Retrieved 2023-03-03.
  13. "9 Volt Batteries a Fire Hazard". Division of Fire Safety – NH Department of Safety. 2017-01-29. Archived from the original on 2017-01-29.
  14. Adams, Louis (November 2015). "Powering Tomorrow's Medicine: Critical Decisions for Batteries in Medical Applications". Medical Design Briefs.
  15. IEC 60086-2011 pt2-§7.6.1.12
  16. ANSI C18.1M Part 1 and C18.3M Part 1
  17. "MN1604" (PDF). Bethel, Connecticut: Procter & Gamble. Archived from the original (PDF) on 2018-05-27. Retrieved 2022-02-12.
  18. Hymel, Shawn (2014-02-04). "The Science of Licking a 9V Battery". SparkFun.com. SparkFun Electronics . Retrieved 2024-01-25.
  19. 1 2 "Farnell: Datasheet for Ultralife U9VL-J-P 9V lithium manganese dioxide PP3-size battery" (PDF). Farnell.com.