Energy density

Last updated
Energy density
SI unit J/m 3
Other units
J/L, W⋅h/L
In SI base units m−1⋅kg⋅s−2
Derivations from
other quantities
U = E/V
Dimension

In physics, energy density is the quotient between the amount of energy stored in a given system or contained in a given region of space and the volume of the system or region considered. Often only the useful or extractable energy is measured. It is sometimes confused with stored energy per unit mass, which is called specific energy or gravimetric energy density.

Contents

There are different types of energy stored, corresponding to a particular type of reaction. In order of the typical magnitude of the energy stored, examples of reactions are: nuclear, chemical (including electrochemical), electrical, pressure, material deformation or in electromagnetic fields. Nuclear reactions take place in stars and nuclear power plants, both of which derive energy from the binding energy of nuclei. Chemical reactions are used by organisms to derive energy from food and by automobiles from the combustion of gasoline. Liquid hydrocarbons (fuels such as gasoline, diesel and kerosene) are today the densest way known to economically store and transport chemical energy at a large scale (1 kg of diesel fuel burns with the oxygen contained in ≈ 15 kg of air). Burning local biomass fuels supplies household energy needs (cooking fires, oil lamps, etc.) worldwide. Electrochemical reactions are used by devices such as laptop computers and mobile phones to release energy from batteries.

Energy per unit volume has the same physical units as pressure, and in many situations is synonymous. For example, the energy density of a magnetic field may be expressed as and behaves like a physical pressure. The energy required to compress a gas to a certain volume may be determined by multiplying the difference between the gas pressure and the external pressure by the change in volume. A pressure gradient describes the potential to perform work on the surroundings by converting internal energy to work until equilibrium is reached.

In cosmological and other contexts in general relativity, the energy densities considered relate to the elements of the stress–energy tensor and therefore do include the rest mass energy as well as energy densities associated with pressure.

Chemical energy

When discussing the chemical energy contained, there are different types which can be quantified depending on the intended purpose. One is the theoretical total amount of thermodynamic work that can be derived from a system, at a given temperature and pressure imposed by the surroundings, called exergy. Another is the theoretical amount of electrical energy that can be derived from reactants that are at room temperature and atmospheric pressure. This is given by the change in standard Gibbs free energy. But as a source of heat or for use in a heat engine, the relevant quantity is the change in standard enthalpy or the heat of combustion.

There are two kinds of heat of combustion:

A convenient table of HHV and LHV of some fuels can be found in the references. [1]

In energy storage and fuels

Selected energy densities plot Energy density.svg
Selected energy densities plot

For energy storage, the energy density relates the stored energy to the volume of the storage equipment, e.g. the fuel tank. The higher the energy density of the fuel, the more energy may be stored or transported for the same amount of volume. The energy of a fuel per unit mass is called its specific energy.

The adjacent figure shows the gravimetric and volumetric energy density of some fuels and storage technologies (modified from the Gasoline article). Some values may not be precise because of isomers or other irregularities. The heating values of the fuel describe their specific energies more comprehensively.

The density values for chemical fuels do not include the weight of the oxygen required for combustion. The atomic weights of carbon and oxygen are similar, while hydrogen is much lighter. Figures are presented in this way for those fuels where in practice air would only be drawn in locally to the burner. This explains the apparently lower energy density of materials that contain their own oxidizer (such as gunpowder and TNT), where the mass of the oxidizer in effect adds weight, and absorbs some of the energy of combustion to dissociate and liberate oxygen to continue the reaction. This also explains some apparent anomalies, such as the energy density of a sandwich appearing to be higher than that of a stick of dynamite.

Given the high energy density of gasoline, the exploration of alternative media to store the energy of powering a car, such as hydrogen or battery, is strongly limited by the energy density of the alternative medium. The same mass of lithium-ion storage, for example, would result in a car with only 2% the range of its gasoline counterpart. If sacrificing the range is undesirable, much more storage volume is necessary. Alternative options are discussed for energy storage to increase energy density and decrease charging time, such as supercapacitors. [9] [10] [11] [12]

No single energy storage method boasts the best in specific power, specific energy, and energy density. Peukert's law describes how the amount of useful energy that can be obtained (for a lead-acid cell) depends on how quickly it is pulled out.

Efficiency

In general an engine will generate less kinetic energy due to inefficiencies and thermodynamic considerations—hence the specific fuel consumption of an engine will always be greater than its rate of production of the kinetic energy of motion.

Energy density differs from energy conversion efficiency (net output per input) or embodied energy (the energy output costs to provide, as harvesting, refining, distributing, and dealing with pollution all use energy). Large scale, intensive energy use impacts and is impacted by climate, waste storage, and environmental consequences.

Nuclear energy

The greatest energy source by far is matter itself, according to the mass–energy equivalence. This energy is described by E = mc2, where c is the speed of light. In terms of density, m = ρV, where ρ is the volumetric mass density, V is the volume occupied by the mass. This energy can be released by the processes of nuclear fission (~ 0.1%), nuclear fusion (~ 1%), or the annihilation of some or all of the matter in the volume V by matter–antimatter collisions (100%).[ citation needed ]

The most effective ways of accessing this energy, aside from antimatter, are fusion and fission. Fusion is the process by which the sun produces energy which will be available for billions of years (in the form of sunlight and heat). However as of 2024, sustained fusion power production continues to be elusive. Power from fission in nuclear power plants (using uranium and thorium) will be available for at least many decades or even centuries because of the plentiful supply of the elements on earth, [13] though the full potential of this source can only be realized through breeder reactors, which are, apart from the BN-600 reactor, not yet used commercially. [14]

Fission reactors

Nuclear fuels typically have volumetric energy densities at least tens of thousands of times higher than chemical fuels. A 1 inch tall uranium fuel pellet is equivalent to about 1 ton of coal, 120 gallons of crude oil, or 17,000 cubic feet of natural gas. [15] In light-water reactors, 1 kg of natural uranium – following a corresponding enrichment and used for power generation– is equivalent to the energy content of nearly 10,000 kg of mineral oil or 14,000 kg of coal. [16] Comparatively, coal, gas, and petroleum are the current primary energy sources in the U.S. [17] but have a much lower energy density.

The density of thermal energy contained in the core of a light-water reactor (pressurized water reactor (PWR) or boiling water reactor (BWR)) of typically 1 GW (1000 MW electrical corresponding to ≈ 3000 MW thermal) is in the range of 10 to 100 MW of thermal energy per cubic meter of cooling water depending on the location considered in the system (the core itself (≈ 30 m3), the reactor pressure vessel (≈ 50 m3), or the whole primary circuit (≈ 300 m3)). This represents a considerable density of energy that requires a continuous water flow at high velocity at all times in order to remove heat from the core, even after an emergency shutdown of the reactor.

The incapacity to cool the cores of three BWRs at Fukushima after the 2011 tsunami and the resulting loss of external electrical power and cold source caused the meltdown of the three cores in only a few hours, even though the three reactors were correctly shut down just after the Tōhoku earthquake. This extremely high power density distinguishes nuclear power plants (NPP's) from any thermal power plants (burning coal, fuel or gas) or any chemical plants and explains the large redundancy required to permanently control the neutron reactivity and to remove the residual heat from the core of NPP's.

Antimatter–matter annihilation

Because antimatter–matter interactions result in complete conversion of the rest mass to radiant energy, the energy density of this reaction depends on the density of the matter and antimatter used. A neutron star would approximate the most dense system capable of matter-antimatter annihilation. A black hole, although denser than a neutron star, does not have an equivalent anti-particle form, but would offer the same 100% conversion rate of mass to energy in the form of Hawking radiation. Even in the case of relatively small black holes (smaller than astronomical objects) the power output would be tremendous.

Electric and magnetic fields

Electric and magnetic fields can store energy and its density relates to the strength of the fields within a given volume. This (volumetric) energy density is given by

where E is the electric field, B is the magnetic field, and ε and µ are the permittivity and permeability of the surroundings respectively. The SI unit is the joule per cubic metre.

In ideal (linear and nondispersive) substances, the energy density is

where D is the electric displacement field and H is the magnetizing field. In the case of absence of magnetic fields, by exploiting Fröhlich's relationships it is also possible to extend these equations to anisotropic and nonlinear dielectrics, as well as to calculate the correlated Helmholtz free energy and entropy densities. [18]

In the context of magnetohydrodynamics, the physics of conductive fluids, the magnetic energy density behaves like an additional pressure that adds to the gas pressure of a plasma.

Pulsed sources

When a pulsed laser impacts a surface, the radiant exposure, i.e. the energy deposited per unit of surface, may also be called energy density or fluence. [19]

Table of material energy densities

The following unit conversions may be helpful when considering the data in the tables: 3.6  MJ = 1  kW⋅h ≈ 1.34  hp⋅h. Since 1 J = 10−6 MJ and 1 m3 = 103 L, divide joule/m 3 by 109 to get MJ/L = GJ/m3. Divide MJ/L by 3.6 to get kW⋅h/L.

Chemical reactions (oxidation)

Unless otherwise stated, the values in the following table are lower heating values for perfect combustion, not counting oxidizer mass or volume. When used to produce electricity in a fuel cell or to do work, it is the Gibbs free energy of reaction (ΔG) that sets the theoretical upper limit. If the produced H2O is vapor, this is generally greater than the lower heat of combustion, whereas if the produced H
2
O
is liquid, it is generally less than the higher heat of combustion. But in the most relevant case of hydrogen, ΔG is 113 MJ/kg if water vapor is produced, and 118 MJ/kg if liquid water is produced, both being less than the lower heat of combustion (120 MJ/kg). [20]

Electrochemical reactions (batteries)

Common battery formats

Nuclear reactions

In material deformation

The mechanical energy storage capacity, or resilience, of a Hookean material when it is deformed to the point of failure can be computed by calculating tensile strength times the maximum elongation dividing by two. The maximum elongation of a Hookean material can be computed by dividing stiffness of that material by its ultimate tensile strength. The following table lists these values computed using the Young's modulus as measure of stiffness:

Other release mechanisms

See also

Footnotes

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Further reading

Related Research Articles

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A fossil fuel power station is a thermal power station which burns a fossil fuel, such as coal, oil, or natural gas, to produce electricity. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating gas engine. All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat.

<span class="mw-page-title-main">Methanol economy</span> Economic theory

The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.

<span class="mw-page-title-main">Nuclear fuel</span> Material fuelling nuclear reactors

Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other nuclear devices to generate energy.

<span class="mw-page-title-main">Sodium-cooled fast reactor</span> Type of nuclear reactor cooled by molten sodium

A sodium-cooled fast reactor is a fast neutron reactor cooled by liquid sodium.

Hydrogen gas is produced by several industrial methods. Nearly all of the world's current supply of hydrogen is created from fossil fuels. Most hydrogen is gray hydrogen made through steam methane reforming. In this process, hydrogen is produced from a chemical reaction between steam and methane, the main component of natural gas. Producing one tonne of hydrogen through this process emits 6.6–9.3 tonnes of carbon dioxide. When carbon capture and storage is used to remove a large fraction of these emissions, the product is known as blue hydrogen.

<span class="mw-page-title-main">Alternative fuel vehicle</span> Vehicle not powered by petrol or diesel

An alternative fuel vehicle is a motor vehicle that runs on alternative fuel rather than traditional petroleum fuels. The term also refers to any technology powering an engine that does not solely involve petroleum. Because of a combination of factors, such as environmental and health concerns including climate change and air pollution, high oil-prices and the potential for peak oil, development of cleaner alternative fuels and advanced power systems for vehicles has become a high priority for many governments and vehicle manufacturers around the world.

The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few.

<span class="mw-page-title-main">Fuel</span> Material used to create heat and energy

A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy.

A liquid nitrogen engine is powered by liquid nitrogen, which is stored in a tank. Traditional nitrogen engine designs work by heating the liquid nitrogen in a heat exchanger, extracting heat from the ambient air and using the resulting pressurized gas to operate a piston or rotary motor. Vehicles propelled by liquid nitrogen have been demonstrated, but are not used commercially. One such vehicle, Liquid Air, was demonstrated in 1902.

<span class="mw-page-title-main">Corium (nuclear reactor)</span> Material in core during nuclear meltdown

Corium, also called fuel-containing material (FCM) or lava-like fuel-containing material (LFCM), is a material that is created in a nuclear reactor core during a nuclear meltdown accident. Resembling lava in consistency, it consists of a mixture of nuclear fuel, fission products, control rods, structural materials from the affected parts of the reactor, products of their chemical reaction with air, water, steam, and in the event that the reactor vessel is breached, molten concrete from the floor of the reactor room.

<span class="mw-page-title-main">Supercapacitor</span> High-capacity electrochemical capacitor

A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than solid-state capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and rechargeable batteries. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much faster than batteries, and tolerates many more charge and discharge cycles than rechargeable batteries.