A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations.
The Occupational Safety and Health Administration (OSHA) of the United States Department of Labor defines a liquid as flammable if it has a flash point at or below 93 °C/199.4 °F. [1] Prior to bringing regulations in line with the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS) in 2012, OSHA considered flammable liquids to be those with a flash point below 37.8 °C/100 °F. Those with flash points above 37.8 °C/100 °F and below 93.3 °C/200 °F were classified as combustible liquids. [2] [3] Studies show that the actual measure of a liquid's flammability, its flash point, is dependent on the local air pressure, meaning that at higher altitudes where the air pressure is lower, the flash point is also lower. [4]
Both OSHA and GHS further divide flammable liquids into 4 categories:
These categorizations are dependent upon a set altitude and atmospheric pressure, as both boiling point and flash point change with changes in pressure. [4]
Both GHS and OSHA require the labeling of flammable liquids, on containers and safety data sheets, as follows: [3] [5]
Category I | Category II | Category III | Category IV | |
---|---|---|---|---|
Symbol | Flame | Flame | Flame | none |
Signal Word | Danger | Danger | Warning | Warning |
Hazard Statement | Extremely flammable liquid and vapour | Highly flammable liquid and vapor | Flammable liquid and vapour | Combustible liquid |
An oil refinery or petroleum refinery is an industrial process plant where petroleum is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day.
The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture".
A safety data sheet (SDS), material safety data sheet (MSDS), or product safety data sheet (PSDS) is a document that lists information relating to occupational safety and health for the use of various substances and products. SDSs are a widely used system for cataloguing information on chemicals, chemical compounds, and chemical mixtures. SDS information may include instructions for the safe use and potential hazards associated with a particular material or product, along with spill-handling procedures. The older MSDS formats could vary from source to source within a country depending on national requirements; however, the newer SDS format is internationally standardized.
A boiling liquid expanding vapor explosion is an explosion caused by the rupture of a vessel containing a pressurized liquid that has reached a temperature above its boiling point. Because the boiling point of a liquid rises with pressure, the contents of the pressurized vessel can remain a liquid as long as the vessel is intact. If the vessel's integrity is compromised, the loss of pressure drops the boiling point, which can cause the liquid to convert to a gas expanding rapidly. If the gas is combustible, as in the case with hydrocarbons and alcohols, further damage can be caused by the ensuing fire.
"NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the U.S.-based National Fire Protection Association. First "tentatively adopted as a guide" in 1960, and revised several times since then, it defines the "Safety Square" or "Fire Diamond" which is used to quickly and easily identify the risks posed by hazardous materials. This helps determine what, if any, special equipment should be used, procedures followed, or precautions taken during the initial stages of an emergency response. It is an internationally accepted safety standard, and is crucial while transporting chemicals.
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials. An example for dangerous goods is hazardous waste which is waste that has substantial or potential threats to public health or the environment.
Chloroprene is the common name for 2-chlorobuta-1,3-diene (IUPAC name) with the chemical formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber.
In electrical and safety engineering, hazardous locations are places where fire or explosion hazards may exist. Sources of such hazards include gases, vapors, dust, fibers, and flyings, which are combustible or flammable. Electrical equipment installed in such locations can provide an ignition source, due to electrical arcing, or high temperatures. Standards and regulations exist to identify such locations, classify the hazards, and design equipment for safe use in such locations.
Mixtures of dispersed combustible materials and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation.
The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms, and harmonized safety data sheets which provide users of dangerous goods with a host of information. The system acts as a complement to the UN Numbered system of regulated hazardous material transport. Implementation is managed through the UN Secretariat. Although adoption has taken time, as of 2017, the system has been enacted to significant extents in most major countries of the world. This includes the European Union, which has implemented the United Nations' GHS into EU law as the CLP Regulation, and United States Occupational Safety and Health Administration standards.
The Hazardous Materials Identification System (HMIS) is a numerical hazard rating that incorporates the use of labels with color developed by the American Coatings Association as a compliance aid for the OSHA Hazard Communication (HazCom) Standard.
A fire class is a system of categorizing fire with regard to the type of material and fuel for combustion. Class letters are often assigned to the different types of fire, but these differ between territories; there are separate standards for the United States, Europe, and Australia. The fire class is used to determine the types of extinguishing agents that can be used for that category.
Xylidine can refer to any of the six isomers of xylene amine, or any mixture of them.
A combustible material is a material that can burn in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.
A flammable liquid is a liquid with flash point of not more than 60.5 °C (141 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging.
Isoprenol, also known as 3-methylbut-3-en-1-ol, is a hemiterpene alcohol. It is produced industrially as an intermediate to 3-methylbut-2-en-1-ol (prenol): global production in 2001 can be estimated as 6–13 thousand tons.
The Hazard Communication Standard (HCS) requires employers to disclose toxic and hazardous substances in workplaces. This is related to the Worker Protection Standard.
Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.
Chemical storage is the storage of controlled substances or hazardous materials in chemical stores, chemical storage cabinets, or similar devices.
Pipe marking is the used to identify the contents, properties and flow direction of fluids in piping. Marking assists personnel to identify the correct pipes for operational, maintenance or emergency response purposes. Pipes are marked by labels, typically color coded, to identify the use, contents and flow direction.
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