Thermal radiation

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The peak wavelength and total radiated amount vary with temperature according to Wien's displacement law. Although this shows relatively high temperatures, the same relationships hold true for any temperature down to absolute zero. Wiens law.svg
The peak wavelength and total radiated amount vary with temperature according to Wien's displacement law. Although this shows relatively high temperatures, the same relationships hold true for any temperature down to absolute zero.
Thermal radiation in visible light can be seen on this hot metalwork. Its emission in the infrared is invisible to the human eye. Infrared cameras are capable of capturing this infrared emission (see Thermography). Hot metalwork.jpg
Thermal radiation in visible light can be seen on this hot metalwork. Its emission in the infrared is invisible to the human eye. Infrared cameras are capable of capturing this infrared emission (see Thermography).

Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. All matter with a temperature greater than absolute zero emits thermal radiation. Particle motion results in charge-acceleration or dipole oscillation which produces electromagnetic radiation.

Contents

Infrared radiation emitted by animals (detectable with an infrared camera) and cosmic microwave background radiation are examples of thermal radiation.

If a radiation object meets the physical characteristics of a black body in thermodynamic equilibrium, the radiation is called blackbody radiation. [1] Planck's law describes the spectrum of blackbody radiation, which depends solely on the object's temperature. Wien's displacement law determines the most likely frequency of the emitted radiation, and the Stefan–Boltzmann law gives the radiant intensity. [2]

Thermal radiation is also one of the fundamental mechanisms of heat transfer.

Overview

Thermal radiation is the emission of electromagnetic waves from all matter that has a temperature greater than absolute zero. [3] Thermal radiation reflects the conversion of thermal energy into electromagnetic energy. Thermal energy is the kinetic energy of random movements of atoms and molecules in matter. All matter with a nonzero temperature is composed of particles with kinetic energy. These atoms and molecules are composed of charged particles, i.e., protons and electrons. The kinetic interactions among matter particles result in charge acceleration and dipole oscillation. This results in the electrodynamic generation of coupled electric and magnetic fields, resulting in the emission of photons, radiating energy away from the body. Electromagnetic radiation, including visible light, will propagate indefinitely in vacuum.

The characteristics of thermal radiation depend on various properties of the surface from which it is emanating, including its temperature, its spectral emissivity, as expressed by Kirchhoff's law. [3] The radiation is not monochromatic, i.e., it does not consist of only a single frequency, but comprises a continuous spectrum of photon energies, its characteristic spectrum. If the radiating body and its surface are in thermodynamic equilibrium and the surface has perfect absorptivity at all wavelengths, it is characterized as a black body. A black body is also a perfect emitter. The radiation of such perfect emitters is called black-body radiation. The ratio of any body's emission relative to that of a black body is the body's emissivity, so that a black body has an emissivity of unity (i.e., one).

Spectral response of two paints and a mirrored surface, in the visible and the infrared. From NASA. ThermalPaint.png
Spectral response of two paints and a mirrored surface, in the visible and the infrared. From NASA.

Absorptivity, reflectivity, and emissivity of all bodies are dependent on the wavelength of the radiation. Due to reciprocity, absorptivity and emissivity for any particular wavelength are equal – a good absorber is necessarily a good emitter, and a poor absorber is a poor emitter. The temperature determines the wavelength distribution of the electromagnetic radiation. For example, the white paint in the diagram to the right is highly reflective to visible light (reflectivity about 0.80), and so appears white to the human eye due to reflecting sunlight, which has a peak wavelength of about 0.5 micrometers. However, its emissivity at a temperature of about −5 °C (23 °F), peak wavelength of about 12 micrometers, is 0.95. Thus, to thermal radiation it appears black.

The distribution of power that a black body emits with varying frequency is described by Planck's law. At any given temperature, there is a frequency fmax at which the power emitted is a maximum. Wien's displacement law, and the fact that the frequency is inversely proportional to the wavelength, indicates that the peak frequency fmax is proportional to the absolute temperature T of the black body. The photosphere of the sun, at a temperature of approximately 6000 K, emits radiation principally in the (human-)visible portion of the electromagnetic spectrum. Earth's atmosphere is partly transparent to visible light, and the light reaching the surface is absorbed or reflected. Earth's surface emits the absorbed radiation, approximating the behavior of a black body at 300 K with spectral peak at fmax. At these lower frequencies, the atmosphere is largely opaque and radiation from Earth's surface is absorbed or scattered by the atmosphere. Though about 10% of this radiation escapes into space, most is absorbed and then re-emitted by atmospheric gases. It is this spectral selectivity of the atmosphere that is responsible for the planetary greenhouse effect, contributing to global warming and climate change in general (but also critically contributing to climate stability when the composition and properties of the atmosphere are not changing).

The incandescent light bulb has a spectrum overlapping the black body spectra of the sun and the earth. Some of the photons emitted by a tungsten light bulb filament at 3000 K are in the visible spectrum. Most of the energy is associated with photons of longer wavelengths; these do not help a person see, but still transfer heat to the environment, as can be deduced empirically by observing an incandescent light bulb. Whenever EM radiation is emitted and then absorbed, heat is transferred. This principle is used in microwave ovens, laser cutting, and RF hair removal.

Unlike conductive and convective forms of heat transfer, thermal radiation can be concentrated in a tiny spot by using reflecting mirrors, which concentrating solar power takes advantage of. Instead of mirrors, Fresnel lenses can also be used to concentrate radiant energy. (In principle, any kind of lens can be used, but only the Fresnel lens design is practical for very large lenses.) Either method can be used to quickly vaporize water into steam using sunlight. For example, the sunlight reflected from mirrors heats the PS10 Solar Power Plant, and during the day it can heat water to 285 °C (558 K; 545 °F).

Surface effects

Lighter colors and also whites and metallic substances absorb less of the illuminating light, and as a result heat up less; but otherwise color makes little difference as regards heat transfer between an object at everyday temperatures and its surroundings, since the dominant emitted wavelengths are nowhere near the visible spectrum, but rather in the far infrared. Emissivities at those wavelengths are largely unrelated to visual emissivities (visible colors); in the far infra-red, most objects have high emissivities. Thus, except in sunlight, the color of clothing makes little difference as regards warmth; likewise, paint color of houses makes little difference to warmth except when the painted part is sunlit.

The main exception to this is shiny metal surfaces, which have low emissivities both in the visible wavelengths and in the far infrared. Such surfaces can be used to reduce heat transfer in both directions; an example of this is the multi-layer insulation used to insulate spacecraft.

Low-emissivity windows in houses are a more complicated technology, since they must have low emissivity at thermal wavelengths while remaining transparent to visible light.

Nanostructures with spectrally selective thermal emittance properties offer numerous technological applications for energy generation and efficiency, [4] e.g., for cooling photovoltaic cells and buildings. These applications require high emittance in the frequency range corresponding to the atmospheric transparency window in 8 to 13 micron wavelength range. A selective emitter radiating strongly in this range is thus exposed to the clear sky, enabling the use of the outer space as a very low temperature heat sink. [5]

Personalized cooling technology is another example of an application where optical spectral selectivity can be beneficial. Conventional personal cooling is typically achieved through heat conduction and convection. However, the human body is a very efficient emitter of infrared radiation, which provides an additional cooling mechanism. Most conventional fabrics are opaque to infrared radiation and block thermal emission from the body to the environment. Fabrics for personalized cooling applications have been proposed that enable infrared transmission to directly pass through clothing, while being opaque at visible wavelengths, allowing the wearer to remain cooler.

Properties

There are 4 main properties that characterize thermal radiation (in the limit of the far field):

As for photon statistics thermal light obeys Super-Poissonian statistics.

Near-field and far-field

The general properties of thermal radiation as described by the Planck's law apply if the linear dimension of all parts considered, as well as radii of curvature of all surfaces are large compared with the wavelength of the ray considered' (typically from 8-25 micrometres for the emitter at 300 K). Indeed, thermal radiation as discussed above takes only radiating waves (far-field, or electromagnetic radiation) into account. A more sophisticated framework involving electromagnetic theory must be used for smaller distances from the thermal source or surface (near-field thermal radiation). For example, although far-field thermal radiation at distances from surfaces of more than one wavelength is generally not coherent to any extent, near-field thermal radiation (i.e., radiation at distances of a fraction of various radiation wavelengths) may exhibit a degree of both temporal and spatial coherence. [6]

Planck's law of thermal radiation has been challenged in recent decades by predictions and successful demonstrations of the radiative heat transfer between objects separated by nanoscale gaps that deviate significantly from the law predictions. This deviation is especially strong (up to several orders in magnitude) when the emitter and absorber support surface polariton modes that can couple through the gap separating cold and hot objects. However, to take advantage of the surface-polariton-mediated near-field radiative heat transfer, the two objects need to be separated by ultra-narrow gaps on the order of microns or even nanometers. This limitation significantly complicates practical device designs.

Another way to modify the object thermal emission spectrum is by reducing the dimensionality of the emitter itself. [4] This approach builds upon the concept of confining electrons in quantum wells, wires and dots, and tailors thermal emission by engineering confined photon states in two- and three-dimensional potential traps, including wells, wires, and dots. Such spatial confinement concentrates photon states and enhances thermal emission at select frequencies. [7] To achieve the required level of photon confinement, the dimensions of the radiating objects should be on the order of or below the thermal wavelength predicted by Planck's law. Most importantly, the emission spectrum of thermal wells, wires and dots deviates from Planck's law predictions not only in the near field, but also in the far field, which significantly expands the range of their applications.

Subjective color to the eye of a black body thermal radiator

°C (°F)Subjective color [8]
480 °C (896 °F)faint red glow
580 °C (1,076 °F)dark red
730 °C (1,350 °F)bright red, slightly orange
930 °C (1,710 °F)bright orange
1,100 °C (2,010 °F)pale yellowish orange
1,300 °C (2,370 °F)yellowish white
> 1,400 °C (2,550 °F)white (yellowish if seen from a distance through atmosphere)

Selected radiant heat fluxes

The time to a damage from exposure to radiative heat is a function of the rate of delivery of the heat. Radiative heat flux and effects: [9] (1 W/cm2 = 10 kW/m2)

kW/m2Effect
170Maximum flux measured in a post-flashover compartment
80Thermal Protective Performance test for personal protective equipment
52 Fiberboard ignites at 5 seconds
29 Wood ignites, given time
20Typical beginning of flashover at floor level of a residential room
16 Human skin: sudden pain and second-degree burn blisters after 5 seconds
12.5 Wood produces ignitable volatiles by pyrolysis
10.4Human skin: Pain after 3 seconds, second-degree burn blisters after 9 seconds
6.4Human skin: second-degree burn blisters after 18 seconds
4.5Human skin: second-degree burn blisters after 30 seconds
2.5Human skin: burns after prolonged exposure, radiant flux exposure typically encountered during firefighting
1.4 Sunlight, sunburns potentially within 30 minutes. Sunburn is NOT a thermal burn. It is caused by cellular damage due to ultraviolet radiation.

Interchange of energy

Radiant heat panel for testing precisely quantified energy exposures at National Research Council, near Ottawa, Ontario, Canada Radiant heat panel nrc ottawa.jpg
Radiant heat panel for testing precisely quantified energy exposures at National Research Council, near Ottawa, Ontario, Canada

Thermal radiation is one of the three principal mechanisms of heat transfer. It entails the emission of a spectrum of electromagnetic radiation due to an object's temperature. Other mechanisms are convection and conduction.

Radiation heat transfer is characteristically different from the other two in that it does not require a medium and, in fact it reaches maximum efficiency in a vacuum. Electromagnetic radiation has some proper characteristics depending on the frequency and wavelengths of the radiation. The phenomenon of radiation is not yet fully understood. Two theories have been used to explain radiation; however neither of them is perfectly satisfactory.

First, the earlier theory which originated from the concept of a hypothetical medium referred as ether. Ether supposedly fills all evacuated or non-evacuated spaces. The transmission of light or of radiant heat are allowed by the propagation of electromagnetic waves in the ether. [10] Electromagnetic waves have similar characteristics to television and radio broadcasting waves they only differ in wavelength. [11] All electromagnetic waves travel at the same speed; therefore, shorter wavelengths are associated with high frequencies. Since every body or fluid is submerged in the ether, due to the vibration of the molecules, any body or fluid can potentially initiate an electromagnetic wave. All bodies generate and receive electromagnetic waves at the expense of its stored energy [11]

The second theory of radiation is best known as the quantum theory and was first offered by Max Planck in 1900. [10] According to this theory, energy emitted by a radiator is not continuous but is in the form of quanta. Planck claimed that quantities had different sizes and frequencies of vibration similarly to the wave theory. [12] The energy E is found by the expression E = hν, where h is the Planck's constant and ν is the frequency. Higher frequencies are originated by high temperatures and create an increase of energy in the quantum. While the propagation of electromagnetic waves of all wavelengths is often referred as "radiation," thermal radiation is often constrained to the visible and infrared regions. For engineering purposes, it may be stated that thermal radiation is a form of electromagnetic radiation which varies on the nature of a surface and its temperature. [10] Radiation waves may travel in unusual patterns compared to conduction heat flow. Radiation allows waves to travel from a heated body through a cold nonabsorbing or partially absorbing medium and reach a warmer body again. [10] This is the case of the radiation waves that travel from the sun to the earth.

The interplay of energy exchange by thermal radiation is characterized by the following equation:

Here, represents the spectral absorption component, spectral reflection component and the spectral transmission component. These elements are a function of the wavelength () of the electromagnetic radiation. The spectral absorption is equal to the emissivity ; this relation is known as Kirchhoff's law of thermal radiation. An object is called a black body if, for all frequencies, the following formula applies:

Reflectivity deviates from the other properties in that it is bidirectional in nature. In other words, this property depends on the direction of the incident of radiation as well as the direction of the reflection. Therefore, the reflected rays of a radiation spectrum incident on a real surface in a specified direction forms an irregular shape that is not easily predictable. In practice, surfaces are assumed to reflect in a perfectly specular or diffuse manner. In a specular reflection, the angles of reflection and incidence are equal. In diffuse reflection, radiation is reflected equally in all directions. Reflection from smooth and polished surfaces can be assumed to be specular reflection, whereas reflection from rough surfaces approximates diffuse reflection. [13] In radiation analysis a surface is defined as smooth if the height of the surface roughness is much smaller relative to the wavelength of the incident radiation.

In a practical situation and room-temperature setting, humans lose considerable energy due to thermal radiation in infra-red in addition to that lost by conduction to air (aided by concurrent convection, or other air movement like drafts). The heat energy lost is partially regained by absorbing heat radiation from walls or other surroundings. (Heat gained by conduction would occur for air temperature higher than body temperature.) Otherwise, body temperature is maintained from generated heat through internal metabolism. Human skin has an emissivity of very close to 1.0. [14] Using the formulas below shows a human, having roughly 2 square meter in surface area, and a temperature of about 307  K, continuously radiates approximately 1000 watts. If people are indoors, surrounded by surfaces at 296 K, they receive back about 900 watts from the wall, ceiling, and other surroundings, so the net loss is only about 100 watts. These heat transfer estimates are highly dependent on extrinsic variables, such as wearing clothes, i.e. decreasing total thermal circuit conductivity, therefore reducing total output heat flux. Only truly gray systems (relative equivalent emissivity/absorptivity and no directional transmissivity dependence in all control volume bodies considered) can achieve reasonable steady-state heat flux estimates through the Stefan-Boltzmann law. Encountering this "ideally calculable" situation is almost impossible (although common engineering procedures surrender the dependency of these unknown variables and "assume" this to be the case). Optimistically, these "gray" approximations will get close to real solutions, as most divergence from Stefan-Boltzmann solutions is very small (especially in most STP lab controlled environments).

Spectral response of two paints and a mirrored surface, in the visible and the infrared. From NASA. ThermalPaint.png
Spectral response of two paints and a mirrored surface, in the visible and the infrared. From NASA.

If objects appear white (reflective in the visual spectrum), they are not necessarily equally reflective (and thus non-emissive) in the thermal infrared – see the diagram at the left. Most household radiators are painted white, which is sensible given that they are not hot enough to radiate any significant amount of heat, and are not designed as thermal radiators at all – instead, they are actually convectors, and painting them matt black would make little difference to their efficacy. Acrylic and urethane based white paints have 93% blackbody radiation efficiency at room temperature [15] (meaning the term "black body" does not always correspond to the visually perceived color of an object). These materials that do not follow the "black color = high emissivity/absorptivity" caveat will most likely have functional spectral emissivity/absorptivity dependence.

Calculation of radiative heat transfer between groups of object, including a 'cavity' or 'surroundings' requires solution of a set of simultaneous equations using the radiosity method. In these calculations, the geometrical configuration of the problem is distilled to a set of numbers called view factors, which give the proportion of radiation leaving any given surface that hits another specific surface. These calculations are important in the fields of solar thermal energy, boiler and furnace design and raytraced computer graphics.

Human-Infrared.jpg
Human-Visible.jpg
A comparison of a thermal image (top) and an ordinary photograph (bottom). The plastic bag is mostly transparent to long-wavelength infrared, but the man's glasses are opaque.

A selective surface can be used when energy is being extracted from the sun. Selective surfaces can also be used on solar collectors. We can find out how much help a selective surface coating is by looking at the equilibrium temperature of a plate that is being heated through solar radiation. If the plate is receiving a solar irradiation of 1350 W/m2 (minimum is 1325 W/m2 on 4 July and maximum is 1418 W/m2 on 3 January) from the sun the temperature of the plate where the radiation leaving is equal to the radiation being received by the plate is 393 K (248 °F). If the plate has a selective surface with an emissivity of 0.9 and a cut off wavelength of 2.0 μm, the equilibrium temperature is approximately 1250 K (1790 °F). The calculations were made neglecting convective heat transfer and neglecting the solar irradiation absorbed in the clouds/atmosphere for simplicity, the theory is still the same for an actual problem.

To reduce the heat transfer from a surface, such as a glass window, a clear reflective film with a low emissivity coating can be placed on the interior of the surface. "Low-emittance (low-E) coatings are microscopically thin, virtually invisible, metal or metallic oxide layers deposited on a window or skylight glazing surface primarily to reduce the U-factor by suppressing radiative heat flow". [16] By adding this coating we are limiting the amount of radiation that leaves the window thus increasing the amount of heat that is retained inside the window.

Since any electromagnetic radiation, including thermal radiation, conveys momentum as well as energy, thermal radiation also induces very small forces on the radiating or absorbing objects. Normally these forces are negligible, but they must be taken into account when considering spacecraft navigation. The Pioneer anomaly, where the motion of the craft slightly deviated from that expected from gravity alone, was eventually tracked down to asymmetric thermal radiation from the spacecraft. Similarly, the orbits of asteroids are perturbed since the asteroid absorbs solar radiation on the side facing the sun, but then re-emits the energy at a different angle as the rotation of the asteroid carries the warm surface out of the sun's view (the YORP effect).

Radiative power

Power emitted by a black body plotted against the temperature according to the Stefan-Boltzmann law. Emissive Power.svg
Power emitted by a black body plotted against the temperature according to the Stefan–Boltzmann law.

Thermal radiation power of a black body per unit area of radiating surface per unit of solid angle and per unit frequency is given by Planck's law as:

or instead of per unit frequency, per unit wavelength as

This formula mathematically follows from calculation of spectral distribution of energy in quantized electromagnetic field which is in complete thermal equilibrium with the radiating object. Plancks law shows that radiative energy increases with temperature, and explains why the peak of an emission spectrum shifts to shorter wavelengths at higher temperatures. It can also be found that energy emitted at shorter wavelengths increases more rapidly with temperature relative to longer wavelengths. [17] The equation is derived as an infinite sum over all possible frequencies in a semi-sphere region. The energy, , of each photon is multiplied by the number of states available at that frequency, and the probability that each of those states will be occupied.

Integrating the above equation over the power output given by the Stefan–Boltzmann law is obtained, as:

where the constant of proportionality is the Stefan–Boltzmann constant and is the radiating surface area.

The wavelength , for which the emission intensity is highest, is given by Wien's displacement law as:

For surfaces which are not black bodies, one has to consider the (generally frequency dependent) emissivity factor . This factor has to be multiplied with the radiation spectrum formula before integration. If it is taken as a constant, the resulting formula for the power output can be written in a way that contains as a factor:

This type of theoretical model, with frequency-independent emissivity lower than that of a perfect black body, is often known as a grey body. For frequency-dependent emissivity, the solution for the integrated power depends on the functional form of the dependence, though in general there is no simple expression for it. Practically speaking, if the emissivity of the body is roughly constant around the peak emission wavelength, the gray body model tends to work fairly well since the weight of the curve around the peak emission tends to dominate the integral.

Constants

Definitions of constants used in the above equations:

Planck's constant 6.626 069 3(11)×10−34 J·s = 4.135 667 43(35)×10−15 eV·s
Wien's displacement constant 2.897 768 5(51)×10−3 m·K
Boltzmann constant 1.380 650 5(24)×10−23 J·K−1 = 8.617 343 (15)×10−5 eV·K−1
Stefan–Boltzmann constant 5.670 373 (21)×10−8 W·m−2·K−4
Speed of light 299 792 458 m·s−1

Variables

Definitions of variables, with example values:

Absolute temperature For units used above, must be in kelvins (e.g. average surface temperature on Earth = 288 K)
Surface area Acuboid = 2ab + 2bc + 2ac;
Acylinder = 2π·r(h + r);
Asphere = 4π·r2

Radiative heat transfer

The net radiative heat transfer from one surface to another is the radiation leaving the first surface for the other minus that arriving from the second surface.

where is surface area, is energy flux (the rate of emission per unit surface area) and is the view factor from surface 1 to surface 2. Applying both the reciprocity rule for view factors, , and the Stefan–Boltzmann law, , yields:

where is the Stefan–Boltzmann constant and is temperature. [18] A negative value for indicates that net radiation heat transfer is from surface 2 to surface 1.

where and are the emissivities of the surfaces. [18]

Formulas for radiative heat transfer can be derived for more particular or more elaborate physical arrangements, such as between parallel plates, concentric spheres and the internal surfaces of a cylinder. [18]

See also

Related Research Articles

Electromagnetic radiation Form of energy emitted and absorbed by particles which are charged which shows wave-like behavior as it travels through space

In physics, electromagnetic radiation refers to the waves of the electromagnetic field, propagating through space, carrying electromagnetic radiant energy. It includes radio waves, microwaves, infrared, (visible) light, ultraviolet, X-rays, and gamma rays. All of these waves form part of the electromagnetic spectrum.

Infrared Form of electromagnetic radiation

Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from the nominal red edge of the visible spectrum around 700 nanometers, to 1 millimeter (300 GHz). Black-body radiation from objects near room temperature is almost all at infrared wavelengths. As a form of electromagnetic radiation, IR propagates energy and momentum, with properties corresponding to both those of a wave and of a particle, the photon.

Radiation Waves or particles propagating through space or through a medium, carrying energy

In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or through a material medium. This includes:

Wiens displacement law

Wien's displacement law states that the black-body radiation curve for different temperatures will peak at different wavelengths that are inversely proportional to the temperature. The shift of that peak is a direct consequence of the Planck radiation law, which describes the spectral brightness of black-body radiation as a function of wavelength at any given temperature. However, it had been discovered by Wilhelm Wien several years before Max Planck developed that more general equation, and describes the entire shift of the spectrum of black-body radiation toward shorter wavelengths as temperature increases.

Black body idealized physical body that absorbs all incident electromagnetic radiation

A black body or blackbody is an idealized physical body that absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence. The name "black body" is given because it absorbs all colors of light. A black body also emits black-body radiation. In contrast, a white body is one with a "rough surface that reflects all incident rays completely and uniformly in all directions."

Brightness temperature or radiance temperature is the temperature at which a black body in thermal equilibrium with its surroundings would have to be in order to duplicate the observed intensity of a grey body object at a frequency . This concept is used in radio astronomy, planetary science and materials science.

Stefan–Boltzmann law Physical law on the emissive power of black body

The Stefan–Boltzmann law describes the power radiated from a black body in terms of its temperature. Specifically, the Stefan–Boltzmann law states that the total energy radiated per unit surface area of a black body across all wavelengths per unit time is directly proportional to the fourth power of the black body's thermodynamic temperature T:

Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature T, when there is no net flow of matter or energy between the body and its environment.

Ultraviolet catastrophe Classical physics prediction that black body radiation grows unbounded with frequency

The ultraviolet catastrophe, also called the Rayleigh–Jeans catastrophe, was the prediction of late 19th century/early 20th century classical physics that an ideal black body at thermal equilibrium will emit radiation in all frequency ranges, emitting more energy as the frequency increases. By calculating the total amount of radiated energy, it can be shown that a black body is likely to release an arbitrarily high amount of energy. This would cause all matter to instantaneously radiate all of its energy until it is near absolute zero – indicating that a new model for the behaviour of black bodies was needed.

Thermography Imaging in mid- to long-wavelength infrared to reveal temperature

Infrared thermography (IRT), thermal video and thermal imaging, is a process where a thermal camera captures and creates an image of an object by using infrared radiation emitted from the object in a process, which are examples of infrared imaging science. Thermographic cameras usually detect radiation in the long-infrared range of the electromagnetic spectrum and produce images of that radiation, called thermograms. Since infrared radiation is emitted by all objects with a temperature above absolute zero according to the black body radiation law, thermography makes it possible to see one's environment with or without visible illumination. The amount of radiation emitted by an object increases with temperature; therefore, thermography allows one to see variations in temperature. When viewed through a thermal imaging camera, warm objects stand out well against cooler backgrounds; humans and other warm-blooded animals become easily visible against the environment, day or night. As a result, thermography is particularly useful to the military and other users of surveillance cameras.

Kirchhoffs law of thermal radiation Law of wavelength-specific emission and absorption

In heat transfer, Kirchhoff's law of thermal radiation refers to wavelength-specific radiative emission and absorption by a material body in thermodynamic equilibrium, including radiative exchange equilibrium.

Black-body radiation Thermal electromagnetic radiation

Black-body radiation is the thermal electromagnetic radiation within or surrounding a body in thermodynamic equilibrium with its environment, emitted by a black body. It has a specific spectrum of wavelengths, inversely related to intensity that depend only on the body's temperature, which is assumed for the sake of calculations and theory to be uniform and constant.

Emissivity

The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that may include both visible radiation (light) and infrared radiation, which is not visible to human eyes. The thermal radiation from very hot objects is easily visible to the eye. Quantitatively, emissivity is the ratio of the thermal radiation from a surface to the radiation from an ideal black surface at the same temperature as given by the Stefan–Boltzmann law. The ratio varies from 0 to 1. The surface of a perfect black body emits thermal radiation at the rate of approximately 448 watts per square metre at room temperature ; all real objects have emissivities less than 1.0, and emit radiation at correspondingly lower rates.

Wien approximation Physical law

Wien's approximation is a law of physics used to describe the spectrum of thermal radiation. This law was first derived by Wilhelm Wien in 1896. The equation does accurately describe the short wavelength spectrum of thermal emission from objects, but it fails to accurately fit the experimental data for long wavelengths emission.

In radiometry, radiosity is the radiant flux leaving a surface per unit area, and spectral radiosity is the radiosity of a surface per unit frequency or wavelength, depending on whether the spectrum is taken as a function of frequency or of wavelength. The SI unit of radiosity is the watt per square metre, while that of spectral radiosity in frequency is the watt per square metre per hertz (W·m−2·Hz−1) and that of spectral radiosity in wavelength is the watt per square metre per metre (W·m−3)—commonly the watt per square metre per nanometre. The CGS unit erg per square centimeter per second is often used in astronomy. Radiosity is often called intensity in branches of physics other than radiometry, but in radiometry this usage leads to confusion with radiant intensity.

Planck constant Physical constant in quantum mechanics

The Planck constant, or Planck's constant, is a fundamental physical constant denoted , and is of fundamental importance in quantum mechanics. A photon's energy is equal to its frequency multiplied by the Planck constant. Due to mass–energy equivalence, the Planck constant also relates mass to frequency.

The surface of the Sun radiates light and heat at approximately 5,500 °C. The Earth is much cooler and so radiates heat back away from itself at much longer wavelengths, mostly in the infrared range. The idealized greenhouse model is based on the fact that certain gases in the Earth's atmosphere, including carbon dioxide and water vapour, are transparent to the high-frequency, high-energy solar radiation, but are much more opaque to the lower frequency infrared radiation leaving the surface of the earth. Thus heat is easily let in, but is partially trapped by these gases as it tries to leave. Rather than get hotter and hotter, Kirchhoff's law of thermal radiation says that the gases of the atmosphere also have to re-emit the infrared energy that they absorb, and they do so, also at long infrared wavelengths, both upwards into space as well as downwards back towards the Earth's surface. In the long-term, thermal equilibrium is reached when all the heat energy arriving on the planet is leaving again at the same rate. In this idealized model, the greenhouse gases cause the surface of the planet to be warmer than it would be without them, in order for the required amount of heat energy finally to be radiated out into space from the top of the atmosphere.

Non-ionizing radiation Any type of electromagnetic radiation that does not carry enough energy per quantum to ionize atoms or molecules

Non-ionizingradiation refers to any type of electromagnetic radiation that does not carry enough energy per quantum to ionize atoms or molecules—that is, to completely remove an electron from an atom or molecule. Instead of producing charged ions when passing through matter, non-ionizing electromagnetic radiation has sufficient energy only for excitation. Non-ionizing radiation can cause some health problems, especially sunburn, melanoma, and non-melanoma skin cancers, but is generally not a significant health risk. In contrast, ionizing radiation has a higher frequency and shorter wavelength than non-ionizing radiation, and can be a serious health hazard: exposure to it can cause burns, radiation sickness, many kinds of cancer, and genetic damage. Using ionizing radiation requires elaborate radiological protection measures, which in general are not required with non-ionizing radiation.

The “radiation effect” results from radiation heat exchange between human bodies and surrounding surfaces, such as walls and ceilings. It may lead to phenomena such as houses feeling cooler in the winter and warmer in the summer at the same temperature. For example, in a room in which air temperature is maintained at 22° Celsius at all times, but in which the inner surfaces of the house is estimated to be an average temperature of 10° Celsius in the winter or 25° Celsius in the summer, heat transfer from the surfaces to the individual will occur, resulting in a difference in the perceived temperature.

Satellite surface salinity refers to measurements of surface salinity made by remote sensing satellites. The radiative properties of the ocean surface are exploited in order to estimate the salinity of the water's surface layer.

References

  1. K. Huang, Statistical Mechanics (2003), p.278
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Further reading

Thermal Infrared Remote Sensing: