Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science.
Fire is the rapid oxidation of a material in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. At a certain point in the combustion reaction, called the ignition point, flames are produced. The flame is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different.
Smoke is a suspension of airborne particulates and gases emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwanted by-product of fires, but may also be used for pest control (fumigation), communication, defensive and offensive capabilities in the military, cooking, or smoking. It is used in rituals where incense, sage, or resin is burned to produce a smell for spiritual or magical purposes. It can also be a flavoring agent and preservative.
In internal combustion engines, exhaust gas recirculation (EGR) is a nitrogen oxide (NOx) emissions reduction technique used in petrol/gasoline, diesel engines and some hydrogen engines. EGR works by recirculating a portion of an engine's exhaust gas back to the engine cylinders. The exhaust gas displaces atmospheric air and reduces O2 in the combustion chamber. Reducing the amount of oxygen reduces the amount of fuel that can burn in the cylinder thereby reducing peak in-cylinder temperatures. The actual amount of recirculated exhaust gas varies with the engine operating parameters.
A flame is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction made in a thin zone. When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasma.
In spark-ignition internal combustion engines, knocking occurs when combustion of some of the air/fuel mixture in the cylinder does not result from propagation of the flame front ignited by the spark plug, but when one or more pockets of air/fuel mixture explode outside the envelope of the normal combustion front. The fuel–air charge is meant to be ignited by the spark plug only, and at a precise point in the piston's stroke. Knock occurs when the peak of the combustion process no longer occurs at the optimum moment for the four-stroke cycle. The shock wave creates the characteristic metallic "pinging" sound, and cylinder pressure increases dramatically. Effects of engine knocking range from inconsequential to completely destructive.
The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature and formerly also known as kindling point, of a substance is the lowest temperature at which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. This temperature is required to supply the activation energy needed for combustion. The temperature at which a chemical ignites decreases as the pressure is increased.
A flashover is the near-simultaneous ignition of most of the directly exposed combustible material in an enclosed area. When certain organic materials are heated, they undergo thermal decomposition and release flammable gases. Flashover occurs when the majority of the exposed surfaces in a space are heated to their autoignition temperature and emit flammable gases. Flashover normally occurs at 500 °C (932 °F) or 590 °C (1,100 °F) for ordinary combustibles and an incident heat flux at floor level of 20 kilowatts per square metre (2.5 hp/sq ft).
Firefighting is a profession aimed at controlling and extinguishing fire. A person who engages in firefighting is known as a firefighter or fireman. Firefighters typically undergo a high degree of technical training. This involves structural firefighting and wildland firefighting. Specialized training includes aircraft firefighting, shipboard firefighting, aerial firefighting, maritime firefighting, and proximity firefighting.
The fire triangle or combustion triangle is a simple model for understanding the necessary ingredients for most fires.
Fire control is the practice of reducing the heat output of a fire, reducing the area over which the fire exists, or suppressing or extinguishing the fire by depriving it of fuel, oxygen, or heat. Fire prevention and control is the prevention, detection, and extinguishment of fires, including such secondary activities as research into the causes of fire, education of the public about fire hazards, and the maintenance and improvement of fire-fighting equipment.
Firefighting jargon includes a diverse lexicon of both common and idiosyncratic terms. One problem that exists in trying to create a list such as this is that much of the terminology used by a particular department is specifically defined in their particular standing operating procedures, such that two departments may have completely different terms for the same thing. For example, depending on whom one asks, a safety team may be referred to as a standby, a RIT or RIG or RIC, or a FAST. Furthermore, a department may change a definition within its SOP, such that one year it may be RIT, and the next RIG or RIC.
Homogeneous charge compression ignition (HCCI) is a form of internal combustion in which well-mixed fuel and oxidizer are compressed to the point of auto-ignition. As in other forms of combustion, this exothermic reaction produces heat that can be transformed into work in a heat engine.
A flash fire is a sudden, intense fire caused by ignition of a mixture of air and a dispersed flammable substance such as a solid, flammable or combustible liquid, or a flammable gas. It is characterized by high temperature, short duration, and a rapidly moving flame front.
A fire class is a system of categorizing fire with regard to the type of material and fuel for combustion. Class letters are often assigned to the different types of fire, but these differ between territories; there are separate standards for the United States, Europe (DIN EN2 Classification of fires ISO3941 Classification of fires, and Australia. The fire class is used to determine the types of extinguishing agents that can be used for that category.
Spontaneous combustion or spontaneous ignition is a type of combustion which occurs by self-heating, followed by thermal runaway and finally, autoignition. It is distinct from pyrophoricity, in which a compound needs no self-heat to ignite. The correct storage of spontaneously combustible materials is extremely important considering improper storage is the main cause of spontaneous combustion. Materials such as coal, cotton, hay, and oils should be stored at proper temperatures and moisture levels to prevent spontaneous combustion. Allegations of spontaneous human combustion are considered pseudoscience.
A chimney fire is the combustion (burning) of residue deposits referred to as soot or creosote, on the inner surfaces of chimney tiles, flue liners, stove pipes, etc.
A wood-burning stove is a heating or cooking appliance capable of burning wood fuel, often called solid fuel, and wood-derived biomass fuel, such as sawdust bricks. Generally the appliance consists of a solid metal closed firebox, often lined by fire brick, and one or more air controls. The first wood-burning stove was patented in Strasbourg in 1557. This was two centuries before the Industrial Revolution, so iron was still prohibitively expensive. The first wood-burning stoves were high-end consumer items and only gradually became used widely.
The use of a cutting extinguisher is a fire extinguishing technique that combines abrasive waterjet cutting with water spray extinguishing, through a single handpiece or nozzle. The fire-fighter approaches the fire from outside the main fire area, then uses the cutting action to drill a small hole through a door or wall. Switching to a water spray then allows the fire to be fought, as with a conventional fog nozzle.
Oxygen compatibility is the issue of compatibility of materials for service in high concentrations of oxygen. It is a critical issue in space, aircraft, medical, underwater diving and industrial applications. Aspects include effects of increased oxygen concentration on the ignition and burning of materials and components exposed to these concentrations in service.
