A flame (from Latin flamma ) is the visible, gaseous part of a fire. It is caused by a highly exothermic chemical reaction taking place in a thin zone. [1] When flames are hot enough to have ionized gaseous components of sufficient density, they are then considered plasma.[ vague ] [2]
Color and temperature of a flame are dependent on the type of fuel involved in the combustion, as, for example, when a lighter is held to a candle. The applied heat causes the fuel molecules in the candle wax to vaporize (if this process happens in inert atmosphere without oxidizer, it is called pyrolysis). In this state they can then readily react with oxygen in the air, which gives off enough heat in the subsequent exothermic reaction to vaporize yet more fuel, thus sustaining a consistent flame. The high temperature of the flame causes the vaporized fuel molecules to decompose, forming various incomplete combustion products and free radicals, and these products then react with each other and with the oxidizer involved in the reaction of the following flame (fire). One may investigate all the different parts of the flame from a candle with a cold metal spoon: [4] Higher parts are water vapor, the result of combustion; yellow parts in the middle are soot; down just next to the candle wick is unburned wax. Goldsmiths use higher parts of a flame with a metallic blow-pipe for melting gold and silver. Sufficient energy in the flame will excite the electrons in some of the transient reaction intermediates such as the methylidyne radical (CH) and diatomic carbon (C2), which results in the emission of visible light as these substances release their excess energy (see spectrum below for an explanation of which specific radical species produce which specific colors). As the combustion temperature of a flame increases (if the flame contains small particles of unburnt carbon or other material), so does the average energy of the electromagnetic radiation given off by the flame (see Black body).
Other oxidizers besides oxygen can be used to produce a flame. Hydrogen burning in chlorine produces a flame and in the process emits gaseous hydrogen chloride (HCl) as the combustion product. [5] Another of many possible chemical combinations is hydrazine and nitrogen tetroxide which is hypergolic and commonly used in rocket engines. Fluoropolymers can be used to supply fluorine as an oxidizer of metallic fuels, e.g. in the magnesium/teflon/viton composition.
The chemical kinetics occurring in the flame are very complex and typically involve a large number of chemical reactions and intermediate species, most of them radicals. For instance, a well-known chemical kinetics scheme, GRI-Mech, [6] uses 53 species and 325 elementary reactions to describe combustion of biogas.
There are different methods of distributing the required components of combustion to a flame. In a diffusion flame, oxygen and fuel diffuse into each other; the flame occurs where they meet. In a premixed flame, the oxygen and fuel are premixed beforehand, which results in a different type of flame. Candle flames (a diffusion flame) operate through evaporation of the fuel which rises in a laminar flow of hot gas which then mixes with surrounding oxygen and combusts.
Flame color depends on several factors, the most important typically being black-body radiation and spectral band emission, with both spectral line emission and spectral line absorption playing smaller roles. In the most common type of flame, hydrocarbon flames, the most important factor determining color is oxygen supply and the extent of fuel-oxygen pre-mixing, which determines the rate of combustion and thus the temperature and reaction paths, thereby producing different color hues.
In a laboratory under normal gravity conditions and with a closed air inlet, a Bunsen burner burns with yellow flame (also called a safety flame) with a peak temperature of about 2,000 K (3,100 °F). The yellow arises from incandescence of very fine soot particles that are produced in the flame. Also, carbon monoxide is produced, and the flame tends to take oxygen from the surfaces it touches. When the air inlet is opened, less soot and carbon monoxide are produced. When enough air is supplied, no soot or carbon monoxide is produced and the flame becomes blue. (Most of this blue had previously been obscured by the bright yellow emissions.) The spectrum of a premixed (complete combustion) butane flame on the right shows that the blue color arises specifically due to emission of excited molecular radicals in the flame, which emit most of their light well below ≈565 nanometers in the blue and green regions of the visible spectrum.
The colder part of a diffusion (incomplete combustion) flame will be red, transitioning to orange, yellow, and white as the temperature increases as evidenced by changes in the black-body radiation spectrum. For a given flame's region, the closer to white on this scale, the hotter that section of the flame is. The transitions are often apparent in fires, in which the color emitted closest to the fuel is white, with an orange section above it, and reddish flames the highest of all. [7] A blue-colored flame only emerges when the amount of soot decreases and the blue emissions from excited molecular radicals become dominant, though the blue can often be seen near the base of candles where airborne soot is less concentrated. [8]
Specific colors can be imparted to the flame by introduction of excitable species with bright emission spectrum lines. In analytical chemistry, this effect is used in flame tests (or flame emission spectroscopy) to determine presence of some metal ions. In pyrotechnics, the pyrotechnic colorants are used to produce brightly colored fireworks.
When looking at a flame's temperature there are many factors which can change or apply. An important one is that a flame's color does not necessarily determine a temperature comparison because black-body radiation is not the only thing that produces or determines the color seen; therefore it is only an estimation of temperature. Other factors that determine its temperature are:
 | This section possibly contains original research .(December 2019) |
This is a rough guide to flame temperatures for various common substances (in 20 °C (68 °F) air at 1 atm. pressure):
| Material burned | Flame temperature |
|---|---|
| Butane | ~300 °C (~600 °F) (a cool flame in low gravity) [9] |
| Charcoal fire | 750–1,200 °C (1,382–2,192 °F) |
| Methane (natural gas) | 900–1,500 °C (1,652–2,732 °F) |
| Bunsen burner flame | 900–1,600 °C (1,652–2,912 °F) [depending on the air valve, open or close.] |
| Candle flame | ≈1,100 °C (≈2,012 °F) [majority]; hot spots may be 1,300–1,400 °C (2,372–2,552 °F) |
| Propane blowtorch | 1,200–1,700 °C (2,192–3,092 °F) |
| Backdraft flame peak | 1,700–1,950 °C (3,092–3,542 °F) |
| Magnesium | 1,900–2,300 °C (3,452–4,172 °F) |
| Hydrogen torch | Up to ≈2,000 °C (≈3,632 °F) |
| MAPP gas | 2,020 °C (3,668 °F) |
| Acetylene blowlamp/blowtorch | Up to ≈2,300 °C (≈4,172 °F) |
| Oxyacetylene | Up to 3,300 °C (5,972 °F) |
| Material burned | Max. flame temperature (in air, diffusion flame) [7] |
|---|---|
| Animal fat | 800–900 °C (1,472–1,652 °F) |
| Kerosene | 990 °C (1,814 °F) |
| Gasoline | 1,026 °C (1,878.8 °F) |
| Wood | 1,027 °C (1,880.6 °F) |
| Methanol | 1,200 °C (2,192 °F) |
| Charcoal (forced draft) | 1,390 °C (2,534 °F) |
Dicyanoacetylene, a compound of carbon and nitrogen with chemical formula C4N2 burns in oxygen with a bright blue-white flame at a temperature of 5,260 K (4,990 °C; 9,010 °F), and at up to 6,000 K (5,730 °C; 10,340 °F) in ozone. [10] This high flame temperature is partially due to the absence of hydrogen in the fuel (dicyanoacetylene is not a hydrocarbon) thus there is no water among the combustion products.
Cyanogen, with the formula (CN)2, produces the second-hottest-known natural flame with a temperature of over 4,525 °C (8,177 °F) when it burns in oxygen. [11] [12]
At temperatures as low as 120 °C (248 °F), fuel-air mixtures can react chemically and produce very weak flames called cool flames. The phenomenon was discovered by Humphry Davy in 1817. The process depends on a fine balance of temperature and concentration of the reacting mixture, and if conditions are right it can initiate without any external ignition source. Cyclical variations in the balance of chemicals, particularly of intermediate products in the reaction, give oscillations in the flame, with a typical temperature variation of about 100 °C (212 °F), or between "cool" and full ignition. Sometimes the variation can lead to an explosion. [9] [13]
In the year 2000, experiments by NASA confirmed that gravity plays an indirect role in flame formation and composition. [14] The common distribution of a flame under normal gravity conditions depends on convection, as soot tends to rise to the top of a flame (such as in a candle in normal gravity conditions), making it yellow. In microgravity or zero gravity environment, such as in orbit, natural convection no longer occurs and the flame becomes spherical, with a tendency to become bluer and more efficient. There are several possible explanations for this difference, of which the most likely is the hypothesis that the temperature is sufficiently evenly distributed that soot is not formed and complete combustion occurs. [15] Experiments by NASA reveal that diffusion flames in microgravity allow more soot to be completely oxidized after they are produced than do diffusion flames on Earth, because of a series of mechanisms that behave differently in microgravity when compared to normal gravity conditions. [16] These discoveries have potential applications in applied science and private industry, especially concerning fuel efficiency.
Flames do not need to be driven only by chemical energy release. In stars, subsonic burning fronts driven by burning light nuclei (like carbon or helium) to heavy nuclei (up to iron group) propagate as flames. This is important in some models of Type Ia supernovae. In thermonuclear flames, thermal conduction dominates over species diffusion, so the flame speed and thickness is determined by the thermonuclear energy release and thermal conductivity (often in the form of degenerate electrons). [17]
Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combustion does not always result in fire, because a flame is only visible when substances undergoing combustion vaporize, but when it does, a flame is a characteristic indicator of the reaction. While activation energy must be supplied to initiate combustion, the heat from a flame may provide enough energy to make the reaction self-sustaining. The study of combustion is known as combustion science.
Carbon monoxide is a poisonous, flammable gas that is colorless, odorless, tasteless, and slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest carbon oxide. In coordination complexes, the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry.
Fire is the rapid oxidation of a material in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. At a certain point in the combustion reaction, called the ignition point, flames are produced. The flame is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different.
Nitromethane, sometimes shortened to simply "nitro", is an organic compound with the chemical formula CH
3NO
2. It is the simplest organic nitro compound. It is a polar liquid commonly used as a solvent in a variety of industrial applications such as in extractions, as a reaction medium, and as a cleaning solvent. As an intermediate in organic synthesis, it is used widely in the manufacture of pesticides, explosives, fibers, and coatings. Nitromethane is used as a fuel additive in various motorsports and hobbies, e.g. Top Fuel drag racing and miniature internal combustion engines in radio control, control line and free flight model aircraft.
Fuel efficiency is a form of thermal efficiency, meaning the ratio of effort to result of a process that converts chemical potential energy contained in a carrier (fuel) into kinetic energy or work. Overall fuel efficiency may vary per device, which in turn may vary per application, and this spectrum of variance is often illustrated as a continuous energy profile. Non-transportation applications, such as industry, benefit from increased fuel efficiency, especially fossil fuel power plants or industries dealing with combustion, such as ammonia production during the Haber process.
The fire triangle or combustion triangle is a simple model for understanding the necessary ingredients for most fires.
Homogeneous Charge Compression Ignition (HCCI) is a form of internal combustion in which well-mixed fuel and oxidizer are compressed to the point of auto-ignition. As in other forms of combustion, this exothermic reaction produces heat that can be transformed into work in a heat engine.
A pyrotechnic colorant is a chemical compound which causes a flame to burn with a particular color. These are used to create the colors in pyrotechnic compositions like fireworks and colored fires. The color-producing species are usually created from other chemicals during the reaction. Metal salts are commonly used; elemental metals are used rarely.
In atmospheric chemistry, NOx is shorthand for nitric oxide and nitrogen dioxide, the nitrogen oxides that are most relevant for air pollution. These gases contribute to the formation of smog and acid rain, as well as affecting tropospheric ozone.
Colored fire is a common pyrotechnic effect used in stage productions, fireworks and by fire performers the world over. Generally, the color of a flame may be red, orange, blue, yellow, or white, and is dominated by blackbody radiation from soot and steam. When additional chemicals are added to the fuel burning, their atomic emission spectra can affect the frequencies of visible light radiation emitted - in other words, the flame appears in a different color dependent upon the chemical additives. Flame coloring is also a good way to demonstrate how fire changes when subjected to heat and how they also change the matter around them.
In combustion, a diffusion flame is a flame in which the oxidizer and fuel are separated before burning. Contrary to its name, a diffusion flame involves both diffusion and convection processes. The name diffusion flame was first suggested by S.P. Burke and T.E.W. Schumann in 1928, to differentiate from premixed flame where fuel and oxidizer are premixed prior to burning. The diffusion flame is also referred to as nonpremixed flame. The burning rate is however still limited by the rate of diffusion. Diffusion flames tend to burn slower and to produce more soot than premixed flames because there may not be sufficient oxidizer for the reaction to go to completion, although there are some exceptions to the rule. The soot typically produced in a diffusion flame becomes incandescent from the heat of the flame and lends the flame its readily identifiable orange-yellow color. Diffusion flames tend to have a less-localized flame front than premixed flames.
A premixed flame is a flame formed under certain conditions during the combustion of a premixed charge of fuel and oxidiser. Since the fuel and oxidiser—the key chemical reactants of combustion—are available throughout a homogeneous stoichiometric premixed charge, the combustion process once initiated sustains itself by way of its own heat release. The majority of the chemical transformation in such a combustion process occurs primarily in a thin interfacial region which separates the unburned and the burned gases. The premixed flame interface propagates through the mixture until the entire charge is depleted. The propagation speed of a premixed flame is known as the flame speed which depends on the convection-diffusion-reaction balance within the flame, i.e. on its inner chemical structure. The premixed flame is characterised as laminar or turbulent depending on the velocity distribution in the unburned pre-mixture.
A thermal oxidizer is a process unit for air pollution control in many chemical plants that decomposes hazardous gases at a high temperature and releases them into the atmosphere.
Oxy-fuel welding and oxy-fuel cutting are processes that use fuel gases and oxygen to weld or cut metals. French engineers Edmond Fouché and Charles Picard became the first to develop oxygen-acetylene welding in 1903. Pure oxygen, instead of air, is used to increase the flame temperature to allow localized melting of the workpiece material in a room environment. A common propane/air flame burns at about 2,250 K, a propane/oxygen flame burns at about 2,526 K, an oxyhydrogen flame burns at 3,073 K and an acetylene/oxygen flame burns at about 3,773 K.
Silicon monoxide is the chemical compound with the formula SiO where silicon is present in the oxidation state +2. In the vapour phase, it is a diatomic molecule. It has been detected in stellar objects and has been described as the most common oxide of silicon in the universe.
A flame is affected by the fuel introduced and the oxygen available. A flame with a balanced oxygen-fuel ratio is called a neutral flame. The color of a neutral flame is semi-transparent purple or blue. This flame is optimal for many uses because it does not oxidize or deposit soot onto surfaces.
A cool flame or invisible flame is a flame having a typical temperature of about 400 °C (752 °F). It is usually produced in a chemical reaction of a certain fuel-air mixture. In contrast to an ordinary flame, the reaction is not vigorous and releases little heat, light, or carbon dioxide. Cold flames are difficult to observe and are uncommon in everyday life, but they are responsible for engine knock – the undesirable, erratic, and noisy combustion of low-octane fuels in internal combustion engines.
A luminous flame is a burning flame which is brightly visible. Much of its output is in the form of visible light, as well as heat or light in the non-visible wavelengths.
Chemical reaction models transform physical knowledge into a mathematical formulation that can be utilized in computational simulation of practical problems in chemical engineering. Computer simulation provides the flexibility to study chemical processes under a wide range of conditions. Modeling of a chemical reaction involves solving conservation equations describing convection, diffusion, and reaction source for each component species.
In combustion, Burke–Schumann limit, or large Damköhler number limit, is the limit of infinitely fast chemistry, named after S.P. Burke and T.E.W. Schumann, due to their pioneering work on Burke–Schumann flame. One important conclusion of infinitely fast chemistry is the non-co-existence of fuel and oxidizer simultaneously except in a thin reaction sheet. The inner structure of the reaction sheet is described by Liñán's equation.
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