Biogasoline

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Biogasoline is a type of gasoline produced from biomass such as algae. Like traditionally produced gasoline, it is made up of hydrocarbons with 6 (hexane) to 12 (dodecane) carbon atoms per molecule and can be used in internal combustion engines. However, unlike traditional gasoline/petroleum based fuels, which are mainly composed from oil, biogasolines are made from plants such as beets and sugarcane or cellulosic biomass- substances normally referred to as plant waste. [1]

Contents

Biofuels most often apply to the product of compounded biomass substance called feedstocks. Biomass is abstract in nature and used to produce gasoline that generates net 0 carbon emissions through a process called gasification. There are multi-various methods through which this fuel can be produced; however, determining the optimal gasification route through which to apply a particular feedstock or biomass relies on experimentation and trial and error. [2]

Biogasoline chemically differs from common biofuels, such as biobutanol and bioethanol, as these substances are alcohols, however, is chemically similar to biodiesel substances, which are additionally made from carbons.

Biodiesel

Biodiesel in liquid state Biodiesel.JPG
Biodiesel in liquid state

There are two main types of biofuels produced: Ethanol and Biodiesel.

Biodiesel is a liquid fuel composed of vegetable oils and or animals fats. To create the gasoline itself, these subsequent liquids are combined with alcohol. Biodiesel is used to fuel compression ignition engines, otherwise known as diesel engines. The most common product of biodiesel is B20, a 20:80 blend: 20% biodiesel to 80% petroleum diesel. However, biodiesel is flexible in nature and can combine with petroleum diesel at varying levels. As of 2021, Biodiesel serves as the second largest asset of biofuel consumption and production-ranging 23% overall. [3]

Ethanol

Absolute ethanol Sample of Absolute Ethanol.jpg
Absolute ethanol

Ethanol fuel is assembled from numerous plants and their respective biomasses and is mainly used as a mix-in alcohol. When these substances are combined, the pressure at which a fuel will combust, otherwise known as octane, increases. [4] Ethanol works to combat the byproducts produced by many modern day vehicles-such as carbon monoxide, nitrogen oxides and volatile organic compounds. [5] Majority of Ethanol gasolines are E10 or E15, however some vehicles allow for differing configurations of ethanol. [6] [7]

Due to its composition and versatility, ethanol accounted for approximately 83% of biofuel consumption and production rates in the U.S. in 2021.

Structure and properties

Biodiesel Structure

Ethanol's chemical composition Ethanol .png
Ethanol's chemical composition

Similar to other gasoline structures, biodiesel is built from a foundation of hydrocarbons. BG100, or 100% biogasoline, is formulated so that it can immediately be used as a drop-in substitute for petroleum-derived gasoline in any conventional gasoline engine, unlike ethanol. Additionally, biogasoline's chemical similarities allow it to be fully miscible with regular gasoline and can be distributed in the same fueling infrastructure as its properties match traditional gasoline from petroleum. [8] Biodiesel works within today's engines, car systems, and corresponding products and requires a small percentage of octane booster to match gasoline.

Ethanol Structure

In order to produce Ethanol, it is likely to engage in a process of fermentation. Most forms of ethanol found within the United States are corn starch or plant starch and sugars, which then need to be metabolized by microorganisms in order to produce ethanol. [9] These microorganisms include varying bacteria and yeast. Ethanol fuel (E85) requires specialized fuel systems and has lower combustion energy and corresponding fuel economy. [10]

Comparison of biogasoline to other common fuels

Fuel [11] Energy Density
MJ/L
Air-fuel
ratio
Specific Energy
MJ/kg
Heat of Vaporization
MJ/kg
RON MON
Gasoline 34.614.646.90.3691–9981–89
Butanol fuel 29.211.236.60.439678
Ethanol fuel 24.09.030.00.92129102
Methanol fuel 19.76.515.61.2136104

Production

Biogasoline Production

Biogasoline Production Process BiogasolineProduction.png
Biogasoline Production Process

In late March, 2010, the world’s first biogasoline demonstration plant was started in Madison, WI by Virent Energy Systems, Inc. [12] In 2001, Virent discovered and developed a technique called Aqueous Phase Reforming (APR). APR includes processes such as reforming to generate hydrogen, dehydrogenation of alcohols/hydrogenation of carbonyls, deoxygenation reactions, hydrogenolysis and cyclization. [13]

The input for APR is a carbohydrate solution created from plant material, and the product is a mixture of chemicals and oxygenated hydrocarbons. From there, the materials go through further conventional chemical processing to yield the final result: a mixture of non-oxygenated hydrocarbons. These hydrocarbons are the exact hydrocarbons found in petroleum fuels, which is why today’s cars do not need to be altered to run on biogasoline. The only difference is in origin.

Biodiesel Production

Diesel fuel is made up of linear hydrocarbons. These are long straight carbon atom chains which differ from the shorter, branched hydrocarbons that make up common gasoline.

In a 2014 experiment, held at the University of California, Davis, researchers used a feedstock of levulinic acid to create biogasoline. [14] Levulinic acid is derived from cellulose material, such as corn stalks, straw or other plant waste and does not have to be fermented. The fuel-making process is reportedly inexpensive and offers yields of over 60 percent. [15]

Research

Research is conducted in both academic and private sectors.

Academic

Virginia Polytechnic Institute and State University has been researching the production of stable biogasoline in current oil refineries. Their focus surrounded bio-oil’s shelf-life. The use of catalysts was applied in order to remove impurities from the processed plant sugars. The researchers extended the time from three months to over a year. [16]

Iowa State University researchers use a type of fermentation in their practices. First, they form a gaseous mixture and then pyrolyze it. The result of the pyrolysis is bio-oil, of which the sugar-rich portion is fermented and distilled to create water and ethanol, while the high-acetate portion is separated into biogasoline, water, and biomass. [17]

Princeton University researchers within José Avalos's lab presented new glowing biofuel in January 2022. This process presents a powerful and efficient tool in yeast strain separation; instead of fermentation and curation of a few cultures over a 24 to 48 hour time period, thousands of yeast stains are being produced each minute. [18]

Private

Virent Energy Systems, Inc., in conjunction with Marathon Petroleum, has developed a technique to turn plant sugars from wheat straw, corn stalks, and sugarcane pulp into biogasoline. The sugars are converted into hydrocarbons similar to those in regular gasoline by the use of catalysts. [19]

History of Biofuels

Consumption and Production of biofuels has played an essential role in the gasoline economy since the beginning of the 1980's. [20] Most recently, companies and organizations, such as the federal Renewable Fuel Standard (RFS) Program and California's Low Carbon Fuel Storage have set initiatives to promote the use of biofuels and reduce fossil fuel-based gasoline. [21] Moreover, in 2016, the Oregon Legislature enacted the Clean Fuels Program (CPF)-managed by the Department of Environmental Quality Commission-and Washington, their own program in January, 2023. [22] Other locations known to have created their own clean fuel program include California and British Columbia. [23]

Economic viability and future

One of the major problems facing the economic viability of biogasoline is the high up-front cost. [24] Another, tax relief: The government is providing tax relief for ethanol fuels but has yet to offer tax relief for biogasoline. [25] If biogasoline became a serious alternative, a large percentage of existing arable land would be converted to grow crops solely for biogasoline. This could decrease the amount of land used to farm food for human consumption and may decrease overall feedstock. [25]

While there may be problems facing the economic viability of biogasoline, the partnership between Royal Dutch Shell and Virent Energy Systems, Inc., a bioscience firm based in Madison, WI, to further research biogasoline is an encouraging sign for biogasoline’s future. [26] Companies are developing new approaches: taking triglyceride inputs and, through deoxygenation process and reforming (cracking, isomerizing, aromatizing, and producing cyclic molecules), producing biogasoline. This biogasoline is intended to match the chemical, kinetic, and combustion characteristics of its petroleum counterpart, but with much higher octane levels. Others are pursuing similar approaches based on hydrotreating or using woody biomass and enzymatic processes. [26]

Moreover, nations are enacting policies that increase the use of biogasoline. This helps restrain the use of fossil fuels and create more energy independence. [26] Current efforts by this partnership are focused on improving the technology and making it available for large-scale production. [26]

See also

Related Research Articles

<span class="mw-page-title-main">Biofuel</span> Type of biological fuel produced from biomass from which energy is derived

Biofuel is a fuel that is produced over a short period from biomass, rather than by the very slow natural processes involved in the formation of fossil fuels, such as oil. Biofuel can be produced from plants or agricultural, domestic, or industrial biowaste. Biofuels are mostly used for transportation but can also be used for heating and electricity. Biofuels are regarded as a renewable energy source. However, the use of biofuel has been controversial because of the several disadvantages associated with the use of it. These include for example : the "food vs fuel" debate, biofuel production methods being sustainable or not, leading to deforestation and loss of biodiversity or not.

<span class="mw-page-title-main">Biodiesel</span> Fuel made from vegetable oils or animal fats

Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made from fats.

<span class="mw-page-title-main">Ethanol fuel</span> Type of biofuel

Ethanol fuel is fuel containing ethyl alcohol, the same type of alcohol as found in alcoholic beverages. It is most often used as a motor fuel, mainly as a biofuel additive for gasoline.

Cellulosic ethanol is ethanol produced from cellulose rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a biofuel. The carbon dioxide that plants absorb as they grow offsets some of the carbon dioxide emitted when ethanol made from them is burned, so cellulosic ethanol fuel has the potential to have a lower carbon footprint than fossil fuels.

<span class="mw-page-title-main">Biorefinery</span> Refinery that converts biomass to energy and other beneficial byproducts

A biorefinery is a refinery that converts biomass to energy and other beneficial byproducts. The International Energy Agency Bioenergy Task 42 defined biorefining as "the sustainable processing of biomass into a spectrum of bio-based products and bioenergy ". As refineries, biorefineries can provide multiple chemicals by fractioning an initial raw material (biomass) into multiple intermediates that can be further converted into value-added products. Each refining phase is also referred to as a "cascading phase". The use of biomass as feedstock can provide a benefit by reducing the impacts on the environment, as lower pollutants emissions and reduction in the emissions of hazard products. In addition, biorefineries are intended to achieve the following goals:

  1. Supply the current fuels and chemical building blocks
  2. Supply new building blocks for the production of novel materials with disruptive characteristics
  3. Creation of new jobs, including rural areas
  4. Valorization of waste
  5. Achieve the ultimate goal of reducing GHG emissions
<span class="mw-page-title-main">Bioenergy</span> Energy made from recently-living organisms

Bioenergy is energy made or generated from biomass, which consists of recently living organisms, mainly plants. Types of biomass commonly used for bioenergy include wood, food crops such as corn, energy crops and waste from forests, yards, or farms. The IPCC defines bioenergy as a renewable form of energy. Bioenergy can either mitigate or increase greenhouse gas emissions. There is also agreement that local environmental impacts can be problematic.

<span class="mw-page-title-main">Synthetic fuel</span> Fuel from carbon monoxide and hydrogen

Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas.

<span class="mw-page-title-main">Biomass to liquid</span>

Biomass to liquid is a multi-step process of producing synthetic hydrocarbon fuels made from biomass via a thermochemical route.

<span class="mw-page-title-main">Alcohol fuel</span>

Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols are of interest as fuels because they can be synthesized chemically or biologically, and they have characteristics which allow them to be used in internal combustion engines. The general chemical formula for alcohol fuel is CnH2n+1OH.

The United States produces mainly biodiesel and ethanol fuel, which uses corn as the main feedstock. The US is the world's largest producer of ethanol, having produced nearly 16 billion gallons in 2017 alone. The United States, together with Brazil accounted for 85 percent of all ethanol production, with total world production of 27.05 billion gallons. Biodiesel is commercially available in most oilseed-producing states. As of 2005, it was somewhat more expensive than fossil diesel, though it is still commonly produced in relatively small quantities.

<span class="mw-page-title-main">Butanol fuel</span> Fuel for internal combustion engines

Butanol may be used as a fuel in an internal combustion engine. It is more similar to gasoline than it is to ethanol. A C4-hydrocarbon, butanol is a drop-in fuel and thus works in vehicles designed for use with gasoline without modification. Both n-butanol and isobutanol have been studied as possible fuels. Both can be produced from biomass (as "biobutanol" ) as well as from fossil fuels (as "petrobutanol"). The chemical properties depend on the isomer (n-butanol or isobutanol), not on the production method.

Renewable Fuels are fuels produced from renewable resources. Examples include: biofuels, Hydrogen fuel, and fully synthetic fuel produced from ambient carbon dioxide and water. This is in contrast to non-renewable fuels such as natural gas, LPG (propane), petroleum and other fossil fuels and nuclear energy. Renewable fuels can include fuels that are synthesized from renewable energy sources, such as wind and solar. Renewable fuels have gained in popularity due to their sustainability, low contributions to the carbon cycle, and in some cases lower amounts of greenhouse gases. The geo-political ramifications of these fuels are also of interest, particularly to industrialized economies which desire independence from Middle Eastern oil.

Biofuel is fuel that is produced from organic matter (biomass), including plant materials and animal waste. It is considered a renewable source of energy that can assist in reducing carbon emissions. The two main types of biofuel currently being produced in Australia are biodiesel and bioethanol, used as replacements for diesel and petrol (gasoline) respectively. As of 2017 Australia is a relatively small producer of biofuels, accounting for 0.2% of world bioethanol production and 0.1% of world biodiesel production.

On April 25, 2006, Executive Order S-06-06, the Bioenergy Action Plan was issued by the then governor of California, Arnold Schwarzenegger, outlining a set of target goals which would establish the increasing use and production of biofuels and biopower for both electricity generation and substitution of natural gas and petroleum within the state of California. The plan asked multiple state agencies to work towards the advancement of biomass programs in California. The order would also help provide statewide environmental protection, mitigation and economic advancement. The plan was passed on July 7, 2006, with progress reports issued in 2007 and 2009.

Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel.

China has set the goal of attaining one percent of its renewable energy generation through bioenergy in 2020.

<span class="mw-page-title-main">Algae fuel</span> Use of algae as a source of energy-rich oils

Algae fuel, algal biofuel, or algal oil is an alternative to liquid fossil fuels that uses algae as its source of energy-rich oils. Also, algae fuels are an alternative to commonly known biofuel sources, such as corn and sugarcane. When made from seaweed (macroalgae) it can be known as seaweed fuel or seaweed oil.

<span class="mw-page-title-main">Biofuels by region</span> Use of biofuel as energy source across the world

The use of biofuels varies by region. The world leaders in biofuel development and use are Brazil, United States, France, Sweden and Germany.

United States policy in regard to biofuels, such as ethanol fuel and biodiesel, began in the early 1990s as the government began looking more intensely at biofuels as a way to reduce dependence on foreign oil and increase the nation's overall sustainability. Since then, biofuel policies have been refined, focused on getting the most efficient fuels commercially available, creating fuels that can compete with petroleum-based fuels, and ensuring that the agricultural industry can support and sustain the use of biofuels.

References

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