Dodecane

Last updated
Dodecane
Dodecane-2D-Skeletal.svg
DodecaneFull.png
Dodecane 3D ball.png
Names
Preferred IUPAC name
Dodecane [1]
Identifiers
3D model (JSmol)
1697175
ChEBI
ChEMBL
ChemSpider
DrugBank
ECHA InfoCard 100.003.607 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 203-967-9
201408
KEGG
MeSH n-dodecane
PubChem CID
RTECS number
  • JR2125000
UNII
  • InChI=1S/C12H26/c1-3-5-7-9-11-12-10-8-6-4-2/h3-12H2,1-2H3 Yes check.svgY
    Key: SNRUBQQJIBEYMU-UHFFFAOYSA-N Yes check.svgY
  • CCCCCCCCCCCC
Properties
C12H26
Molar mass 170.340 g·mol−1
AppearanceColorless liquid
Odor Gasoline-like to odorless
Density 0.7495 g mL−1 at 20 °C [2]
Melting point −10.0 to −9.3 °C; 14.1 to 15.2 °F; 263.2 to 263.8 K
Boiling point 214 to 218 °C; 417 to 424 °F; 487 to 491 K
log P 6.821
Vapor pressure 18 Pa (at 25 °C) [3]
1.4 nmol Pa−1 kg−1
1.421
Viscosity 1.34 mPa s
Thermochemistry
376.00 J K−1 mol−1
Std molar
entropy
(S298)
490.66 J K−1 mol−1
−353.5–−350.7 kJ mol−1
−7901.74 kJ mol−1
Hazards
GHS labelling:
GHS-pictogram-silhouette.svg
Danger
H304
P301+P310, P331
NFPA 704 (fire diamond)
1
2
0
Flash point 71 °C (160 °F; 344 K)
205 °C (401 °F; 478 K)
Explosive limits 0.6%
Safety data sheet (SDS) hazard.com
Related compounds
Related alkanes
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Dodecane (also known as dihexyl, bihexyl, adakane 12, or duodecane) is an oily liquid n-alkane hydrocarbon with the chemical formula C12H26 (which has 355 isomers).

Contents

It is used as a solvent, distillation chaser, and scintillator component. It is used as a diluent for tributyl phosphate (TBP) in nuclear reprocessing plants. [4]

Combustion reaction

The combustion reaction of dodecane is as follows:

C12H26(l) + 18.5 O2(g) → 12 CO2(g) + 13 H2O(g)
ΔH° = −7513 kJ

One litre of fuel needs about 15 kg of air to burn (2.6 kg of oxygen), and generates 2.3 kg (or 1.2 m3) of CO2 upon complete combustion.

Jet fuel surrogate

In recent years, n-dodecane has garnered attention as a possible surrogate for kerosene-based fuels such as Jet-A, S-8, and other conventional aviation fuels. It is considered a second-generation fuel surrogate designed to emulate the laminar flame speed, largely supplanting n-decane, primarily due to its higher molecular mass and lower hydrogen-to-carbon ratio which better reflect the n-alkane content of jet fuels.

See also

Related Research Articles

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References

  1. "n-dodecane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 16 September 2004. Identification and Related Records. Retrieved 4 January 2012.
  2. "Dodecane".
  3. "Dodecane".
  4. Rydberg, Jan (2004). Solvent Extraction Principles and Practice. Marcel Dekker. p. 524. ISBN   0-8247-5063-2.