Names | |
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Preferred IUPAC name Tridecane [1] | |
Identifiers | |
3D model (JSmol) | |
1733089 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.010.086 |
EC Number |
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KEGG | |
MeSH | tridecane |
PubChem CID | |
RTECS number |
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UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
C13H28 | |
Molar mass | 184.367 g·mol−1 |
Appearance | Colourless liquid |
Odor | Gasoline-like to odorless |
Density | 0.756 g mL−1 |
Melting point | −6 to −4 °C; 21 to 25 °F; 267 to 269 K |
Boiling point | 232 to 236 °C; 449 to 457 °F; 505 to 509 K |
log P | 7.331 |
Vapor pressure | 0.52 mmHg (at 59.4 °C) |
Henry's law constant (kH) | 4.3 nmol Pa−1 kg−1 |
Refractive index (nD) | 1.425 |
Thermochemistry | |
Heat capacity (C) | 406.89 J K−1 mol−1 |
Std enthalpy of formation (ΔfH⦵298) | −379.3–−376.1 kJ mol−1 |
Std enthalpy of combustion (ΔcH⦵298) | −8.7411–−8.7383 MJ mol−1 |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335 | |
P261, P305+P351+P338 | |
Flash point | 94 °C (201 °F; 367 K) |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 1.161 g kg−1(intravenous, mouse) |
Related compounds | |
Related alkanes | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Tridecane or n-tridecane is an alkane with the chemical formula CH3(CH2)11CH3. Tridecane is a combustible colourless liquid. In industry, they have no specific value aside from being components of various fuels and solvents. In the research laboratory, tridecane is also used as a distillation chaser.
Nymphs of the southern green shield bug produce tridecane as a dispersion/aggregation pheromone, which possibly serves as a defense against predators. [2] It is also the main component of the defensive fluid produced by the stink bug Cosmopepla bimaculata . [3]
In organic chemistry, an alkane, or paraffin, is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula CnH2n+2. The alkanes range in complexity from the simplest case of methane, where n = 1, to arbitrarily large and complex molecules, like pentacontane or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane.
Hexane or n-hexane is an organic compound, a straight-chain alkane with six carbon atoms and the molecular formula C6H14.
Pentatomidae is a family of insects belonging to the order Hemiptera, generally called shield bugs or stink bugs. Pentatomidae is the largest family in the superfamily Pentatomoidea, and contains around 900 genera and over 4700 species. As hemipterans, the pentatomids have piercing sucking mouthparts, and most are phytophagous, including several species which are severe pests on agricultural crops. However, some species, particularly in the subfamily Asopinae, are predatory and may be considered beneficial.
Skatole or 3-methylindole is an organic compound belonging to the indole family. It occurs naturally in the feces of mammals and birds and is the primary contributor to fecal odor. In low concentrations, it has a flowery smell and is found in several flowers and essential oils, including those of orange blossoms, jasmine, and Ziziphus mauritiana. It has also been identified in certain cannabis varieties.
Chemical ecology is a vast and interdisciplinary field utilizing biochemistry, biology, ecology, and organic chemistry for explaining observed interactions of living things and their environment through chemical compounds. Early examples of the field trace back to experiments with the same plant genus in different environments, interaction of plants and butterflies, and the behavioral effect of catnip. Chemical ecologists seek to identify the specific molecules that function as signals mediating community or ecosystem processes and to understand the evolution of these signals. The chemicals behind such roles are typically small, readily-diffusible organic molecules that act over various distances that are dependent on the environment but can also include larger molecules and small peptides.
Pentane is an organic compound with the formula C5H12—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the n-pentane isomer, in which case pentanes refers to a mixture of them; the other two are called isopentane (methylbutane) and neopentane (dimethylpropane). Cyclopentane is not an isomer of pentane because it has only 10 hydrogen atoms where pentane has 12.
Tetradecane is an alkane hydrocarbon with the chemical formula CH3(CH2)12CH3.
Herbivores are dependent on plants for food, and have coevolved mechanisms to obtain this food despite the evolution of a diverse arsenal of plant defenses against herbivory. Herbivore adaptations to plant defense have been likened to "offensive traits" and consist of those traits that allow for increased feeding and use of a host. Plants, on the other hand, protect their resources for use in growth and reproduction, by limiting the ability of herbivores to eat them. Relationships between herbivores and their host plants often results in reciprocal evolutionary change. When a herbivore eats a plant it selects for plants that can mount a defensive response, whether the response is incorporated biochemically or physically, or induced as a counterattack. In cases where this relationship demonstrates "specificity", and "reciprocity", the species are thought to have coevolved. The escape and radiation mechanisms for coevolution, presents the idea that adaptations in herbivores and their host plants, has been the driving force behind speciation. The coevolution that occurs between plants and herbivores that ultimately results in the speciation of both can be further explained by the Red Queen hypothesis. This hypothesis states that competitive success and failure evolve back and forth through organizational learning. The act of an organism facing competition with another organism ultimately leads to an increase in the organism's performance due to selection. This increase in competitive success then forces the competing organism to increase its performance through selection as well, thus creating an "arms race" between the two species. Herbivores evolve due to plant defenses because plants must increase their competitive performance first due to herbivore competitive success.
Raspberry ketone is a naturally occurring phenolic compound that is the primary aroma compound of red raspberries.
The harlequin cabbage bug, also known as calico bug, fire bug or harlequin bug, is a black stinkbug of the family Pentatomidae, brilliantly marked with red, orange, yellow and white markings. It is a major pest of cabbage and related crops in the Brassicaceae, as well as the ornamental flower cleome throughout tropical and North America, especially the warmer parts of the United States. Nymphs are active during the summer and in the tropics the bug can achieve three to six generations a year. In the northern range there is only one generation annually and the insects overwinter as adults in crop residues or field edges. Organic control involves hand-picking the insects off the plants and being especially careful to remove and destroy all the eggs, which are black-and-white striped, laid in clutches of twelve.
Nezara viridula, commonly known as the southern green stink bug (USA), southern green shield bug (UK) or green vegetable bug, is a plant-feeding stink bug. Believed to have originated in Ethiopia, it can now be found across the world. Because of its preference for certain species of legumes, such as beans and soybeans, it is an economically important pest on such crops.
Phlorotannins are a type of tannins found in brown algae such as kelps and rockweeds or sargassacean species, and in a lower amount also in some red algae. Contrary to hydrolysable or condensed tannins, these compounds are oligomers of phloroglucinol (polyphloroglucinols). As they are called tannins, they have the ability to precipitate proteins. It has been noticed that some phlorotannins have the ability to oxidize and form covalent bonds with some proteins. In contrast, under similar experimental conditions three types of terrestrial tannins apparently did not form covalent complexes with proteins.
Formica obscuripes, the western thatching ant, is a species of ant in the family Formicidae. It is native to North America. It produces large mounds covered by small pieces of plant material. The number of adult workers per colony may be as high as 40,000. F. obscuripes feeds upon a number of insect species, consumes nectar from homopterous insects they tend, and occasionally eats plant tissue.
Bisabolenes are a group of closely related natural chemical compounds which are classified as sesquiterpenes. Bisabolenes are produced from farnesyl pyrophosphate (FPP) and are present in the essential oils of bisabol, and of a wide variety of other plants including cubeb, lemon, and oregano. Various derivates also function as pheromones in different insects, such as stink bugs and fruit flies. Bisabolenes are produced by several fungi, though their biological role in that group of organisms remains unclear.
Calliphara nobilis is a species of jewel bug found in Asia. Like all species of jewel bugs, it is phytophagous, feeding on the leaves, fruit and seeds of its host plants. This insect is notable for its multiple defense mechanisms: it is highly mobile and swarms disperse with a loud buzz when disturbed; it is aposematically colored, which serves as a warning to any would-be predators that it is unpalatable; and it possesses a robust chemical defense mechanism: it can secrete an irritating and toxic fluid from a pair of metathoracic scent glands when threatened.
Chemical defense is a strategy employed by many organisms to avoid consumption by producing toxic or repellent metabolites or chemical warnings which incite defensive behavioral changes. The production of defensive chemicals occurs in plants, fungi, and bacteria, as well as invertebrate and vertebrate animals. The class of chemicals produced by organisms that are considered defensive may be considered in a strict sense to only apply to those aiding an organism in escaping herbivory or predation. However, the distinction between types of chemical interaction is subjective and defensive chemicals may also be considered to protect against reduced fitness by pests, parasites, and competitors. Repellent rather than toxic metabolites are allomones, a sub category signaling metabolites known as semiochemicals. Many chemicals used for defensive purposes are secondary metabolites derived from primary metabolites which serve a physiological purpose in the organism. Secondary metabolites produced by plants are consumed and sequestered by a variety of arthropods and, in turn, toxins found in some amphibians, snakes, and even birds can be traced back to arthropod prey. There are a variety of special cases for considering mammalian antipredatory adaptations as chemical defenses as well.
Tessaratomidae is a family of true bugs. It contains about 240 species of large bugs divided into 3 subfamilies and 56 genera.
Cosmopepla lintneriana, the twice-stabbed stink bug, is a species of insect in the family Pentatomidae. Cosmopepla lintneriana was first described in 1798 by Johan Christian Fabricius as Cimex carnifex, and then again in 1865 by Thomas Say as Cosmopepla bimaculata. Cosmopepla lintneriana is hosted by a variety of plants, including milk thistle, echinacea, asparagus, oats, mint and goldenrod, and is widespread throughout North America, from Canada to Mexico. Adult C. lintneriana are black with a red, orange, or yellow band across the pronotum and a short red stripe along the midline, and two red spots at the apex of the scutellum. Nymph coloration ranges from red to white with black markings that change as they grow.
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Hydrocarbonoclastic bacteria are a heterogeneous group of prokaryotes which can degrade and utilize hydrocarbon compounds as source of carbon and energy. Despite being present in most of environments around the world, several of these specialized bacteria live in the sea and have been isolated from polluted seawater.